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By G. G. Barbante

An understanding of the thermodynamics of smelting copper anode slimes is a prerequisite for improvements to the process. During slimes smelting, a silver-copper selenide matte is formed and subsequently oxidised to silver metal. As part of a series of investigations, molten silver selenide matte was oxidised at 1 100 degrees C with pure oxygen. The chemical potential diagram for the system was developed and used for qualitative prediction of the results of the experiments. A simple, computational thermodynamic model of converting is presented, the adjustable parameters of which were determined by matching the model with the experimental results. The practical usefulness of the model was demonstrated by predicting the effect on silver recovery of smelting temperature and of using either oxygen or air as the smelting gas

Jun 21, 1905

By L. T. Isaacs, W. H. Traves

A numerical model for analysing the drainage of fill in mine stopes has been described. The model can be used to analyse the process of fill drainage in existing and proposed mine stopes. The validity and potential value of the model have been established by experience with a simpler, 2-dimensional numerical model and by testing the new model against the earlier model. The new model is more useful than the 2-dimensional model because it allows for heterogeneity of fill material within the stope - a factor that has been demonstrated to affect drainage characteristics significantly. The 3-dimensional model is also capable of predicting pore pressures and drainage rates at specific locations in the stope without the need to resort to 2-dimensional generalisations. Such information, integrated with relevant field data as they become available, will provide valuable mine planning information for the scheduling of filling operations and design of fill mixes

May 1, 1991

By S. Kelebek

DETA exhibits a highly selective depressant action on pyrrhotite without adversely affecting the collectorless flotability of pentlandite and chalcopyrite in nickel-copper ores of the Sudbury region. A simplified Eh-pH diagram has been constructed to illustrate the extended stability of elemental sulphur and to explain the collectorless flotation of pentlandite and chalcopyrite. Cu and Ni ions, which are known to exist on the surface of pyrrhotite, promote the flotation of this mineral whether a collector is present or not. Thermodynamic calculations indicate that the action of DETA involves the sequestration of Cu and Ni ions from surfaces under a wide range of redox conditions; analysis of flotation test filtrate indicates as much as a 20-fold increase in the concentration of Ni and Cu ions. It appears that DETA may enhance the self-hydrophobicity of chalcopyrite and pentlandite by exposing more of the sulphur-rich surface sites for bubble contact in flotation. There are various possible explanations for its depression of pyrrhotite

Jun 18, 1905

By C. McCall, J. T. Knight, J. R. Ridley

Gold mineralisation in the gabbro sills is mainly stratabound to quartz- and Fe-rich, granophyric-textured units and is sited in undeformed, brittle quartz vein sets, which form pipe-like orebodies. Hydrothermal wallrock alteration consists of hornblende-plagioclase-calcite-quartz with minor biotite, garnet and chlorite and with arsenopyrite and pyrrhotite as the dominant sulphides. Geothermobarometric data suggest that gold was deposited at around 520 degrees C at 2.8-3.8 bar. Mineralisation is thought to have occurred during amphibolite-facies metamorphism. Fluid inclusion and isotope data indicate that gold mineralisation was the result of deposition from a low-salinity H2O-CO2-CH4 fluid of either metamorphic or magmatic origin. Although the Three Mile Hill deposit differs from others in the area in its wallrock-alteration assemblages, peak-metamorphic timing of gold deposition and distinct geochemical associations it forms a brittle stratabound ore body which suggests structural and gold-depositional mechanisms in common with those of the other gabbro-hosted gold deposits

Jun 18, 1905

By R. Ciccu, P. P. Manca, A. Bortolussi, G. Massacci

Tool performance and the unit cost of cutting depend on a number of operational variables (peripheral velocity, pull-back force, water injection rate, angles of the sections of wire outside the rock) as well as on the geometric features of the cut itself (area and shape). Cutting rate and wire productivity are also influenced by the type and number of diamond beads per unit length of wire and by the characteristics of the rock (granite or marble). A computer program aimed at handling a problem of this complexity has been developed and tested with the use of available field and laboratory data and has been found acceptably reliable. Discrepancies between current industrial data and some of the results suggest future lines of research, while the simulation should also be extended to include different types of rock and tool and a variety of bench face geometries

Aug 1, 1994

By A. Dean, J. Roberts, I. Stone, J. R. Merefield

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 11 refs. No completely reliable method for characterising and quantifying airborne dust risk exists. A new monitoring technology has been developed whereby dust collected from four-way directional and high volume samplers is analysed for mineral content and particle size for integrated dust mapping. A dust database was set up for the area surrounding the Ffos Las open cast coal site in South Wales. It included XRD directional traces from 17 gauges over 20 months, XRD traces from window ledges in the nearby communities, the major soil types in the area, dust data from haulage roads and public roads and reference-type mineral samples. The database can be accessed relationally to compare and analyse the data using mineral, direction, time, weather and geographical relationships. The data has been used to assess areas of low, intermediate and high levels of risk from dust fall-out

Apr 1, 1995

By F. C. Gennari, D. M. Pasquevich

With the gradual exhaustion of natural rutile, there has been extensive research into its synthesising from lower-grade titanium minerals. The removal of Fe from pseudobrookite (Fe2TiO5) by chlorination was studied, using both isothermal and non-isothermal thermogravimetric measurements. Correlation of the results obtained from element distribution maps, scanning electron microscopy, energy-dispersive X-ray analysis and phases detected by X-ray diffraction in the chlorinated samples showed clearly two associated processes. First, the pseudobrookite particles reacted with chlorine and iron was removed selectively as FeCl3(g), leaving a solid residue rich in the TiO2 phases anatile and rutile, separated from an inner layer of unreacted pseudobrookite by a distinct interphase boundary. Second, chlorine allowed TiCl4(g) to form in the reaction bed, where it removed iron from the Fe2O3 crystals as FeCl3(g) and substituted Ti through a pseudomorphic reaction

Jun 21, 1905

By N. B. J. Kieser

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. Platinum-group minerals (PGM) in the enriched zone at Dust Mountain occur in two separate parageneses, the first representing primary magmatic PGM and the second primary magmatic PGM that have been reduced to alloys during serpentinisation. Minerals in the first group were unaffected by hydrothermal alteration on account of their textural setting or stable chemical composition. Despite substantial alteration of the serpentinised assemblage, most evidence points to the dominant role of primary magmatic processes in determining PGM occurrence. Several base metals have nevertheless been introduced hydrothermally. With respect to surficial dispersion the single most important paragenetic factor was the reduction of sulphides to alloys, rendering them more susceptible to mechanical erosion and less so to chemical leaching. The different textural setting of Pd-group and Ir-group phases results in different dispersion characteristics, with major implications for stream sediment sampling

Apr 1, 1994

During a programme to determine the suitability of the UK site for deep disposal of radioactive wastes, geostatistical methods were used to characterise rock heterogeneity on the basis of seismic and wireline acoustic-impedance data. The data were analysed to yield semi-variogram models that quantified the three-dimensional spatial heterogeneity of acoustic impedance. These models were reconciled with geological interpretations of the area and used to generate simulations of acoustic impedance, with wireline acoustic impedance as conditioning data. The three-dimensional simulated images were compared with actual seismic acoustic impedance. The variography confirmed a vertical zoning effect in the Borrowdale Volcanics, showing that it is caused by preferential clusters of high acoustic impedance values corresponding to regions of relatively low porosity. The method provided realistic three-dimensional models from sparse, one-dimensional wireline data

Jun 19, 1905

By R. A. Lord, H. M. Prichard

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The complex exemplifies a class of olivine-rich, platiniferous ophiolite complexes generated by unusually high degrees of hydrous melting above a subduction zone. Crystallisation of abundant olivine from unusually picritic magmas produced an exceptionally thick sequence of crustal dunite cumulates. Significant (1-4 ppm) concentrations of Pt+Pd occur where sulphide-bearing dunites are spatially associated with podiform chromite concentrations. In the area north of the Balta Sound, the chromitites appear to lie in distinct stratigraphic zones. A detailed programme of lithogeochemical and soil-rock interface geochemical exploration led to the intersection by diamond drilling of three stratiform horizons of sulphide-bearing dunites and associated precious-metal mineralisation. Patterns of cryptic geochemical layering, at scales from 200 m to less than 1 cm, suggests open-system fractionation

Jun 19, 1905

By S Durucan, A Korre

The application of simple methods of statistical analysis, coupled with geostatistical analysis and geographic information systems, can only summarise and give an outline of the spatial distribution of the parameters measured. Spatial analysis of the components or factors calculated, through principal component analysis or factor analysis, allows assessment of the geographical distribution of the dominant processes contributing to soil composition and/or contamination. Neither of these tools, however, distinguishes between the different sources of pollution. The application of canonical correlation to the data, driven by expert appraisal of the potential pollution sources, allows their quantitative and spatial assessment while GIS provides the environment in which to organise and present the results. The methodology is illustrated by its application to soil-contamination data from the Lavrio area in Greece, where silver-bearing orebodies have been mined for more than 25 centuries

Jun 21, 1905

By R. G. Kidel, S. C. Doming

The project has shown that it is feasible for a junior company to reopen a narrow vein-style gold mine and successfully take it into production. An intimate understanding of the mineralisation and a flexible approach to mining are crucial, as are stringent cost control and efforts to keep overheads low. The project has confirmed the geological complexity of the Main Lodes, which consist of highly sheared quartz-sulphide infill in strongly sericitised granodiorite. The existence of discrete high-grade zones within the Hangingwall Lodes has also been confirmed. Broad low-grade zones continue to be recognised and require the local application of bulk longhole mining methods. The initial mine plan called for predominantly longhole stoping, but adverse ground conditions have meant that a switch to air-leg mining has produced higher run-of-mine grades. The excess capacity at the processing plant can best be used by batch processing, with its reduced maintenance requirements

Jun 21, 1905

By M. J. Scoble, L. M. Daneshmend, C. Hendricks

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. An attempt is made to relate emerging technologies to education and training requirements by examining the nature of the Canadian mining industry's human resources. Particular attention is given to the trends evident in mine automation and their likely impact on instructional needs. The characteristics of "computer-aided instruction" systems are reviewed and related to the implementation and support of mine-wide monitoring and communication networks, which are seen as fundamental to the eventual automation of underground hardrock mines

Apr 1, 1994

By P. Grainger, P. G. Kalaugher

Paper presented at conference and first published in preprint volume of: Risk assessment in the extractive industries, held in University of Exeter, 23-24 March 1994. London: IMM, 1994. Large, unpredicted ground movements resulting from open cast or underground mining present risks to the safety and economy of extractive industries. As large, sudden failures are usually preceded by small displacements at a much slower rate, the detection and monitoring of these minor changes to the ground surface provides a means of assessing the risks. It is recommended that a visual approach is often preferable to surveying or fixed instrumental measurements. An optical system has been devised, incorporating a 35 mm camera, which allows an immediate comparison on site between a colour transparency taken on a previous inspection and the scene it represents. The observer fuses the transparency stereoscopically with the directly viewed scene. The impression is close to that of normal vision except that differences in detail which have occurred since the transparency was taken are immediately obvious, enabling a qualitative assessment of changes to be made on site. If repeat photography is required it can be taken with exactly the same alignment and coverage. The two images are then available for office analysis using simple micro-photogrammetry

Apr 1, 1996

By G. E. Christidis, P. W. Scott

The deposits were formed from low-temperature alteration of pyroclastic rocks. Properties investigated include their cation exchange capacity, swelling capacity, pH, rheological properties, the green and dry compressive strengths, shatter index, wet tensile strength, compactability and permeability. It was found that deposits with abundant opal-CT have poor physical properties. The rheological and swelling properties were found to be influenced by the bentonite grade (smectite content) and the degree of disaggregation of the smectite quasi-crystals. The only deposits of high grade which had good foundry properties were those with no opal-CT. Hydrothermal alteration was detrimental to the physical and chemical properties of bentonites in that it decreased the smectite content and the pH and changed the smectite layer charge and the lattice dimensions

Jun 18, 1905

By J. D. Appleton, J. Ridgway, K. B. Greally

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The results suggest that meaningful geochemical maps can be produced from very low-density surveys, and that existing data sets could perhaps be incorporated into such a map series with the use of a system such as Uniras software. There are still many problems to be resolved, however, including the compatibility of data derived from different analytical methods, and the precise methods to be employed will necessarily require international agreement. Sampling densities should be chosen on the basis of the scale of the geochemical and geological features to be distinguished and will vary from region to region. Reanalysis of selected samples from archives to increase the range of elements determined or to unify analytical methods is only likely to be effective if the original survey was at quite a low density

Jul 1, 1991

By P. P. Jenkins, T. G. Ball

Paper presented at the Drillex '90 conference held in London, 5 April 1990. Two drilling techniques are employed - guided longhole drilling and reverse circulation coring - for underground longhole exploration of the coal reserves and the fault structures that affect them. These are complementary to, or replacements for, surface boreholes, underground development drivages and seismic techniques. The developments of the drilling techniques and some case histories are presented in detail.

Jan 1, 1991

By O. R. Eckstrand, M. Asif, P. L. Schwann, A. J. Naldrett, R. J. F. Scoates

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. PGE-bearing sulphide mineralisation is contained in the lower 600 m of the Upper Central Layered Zone of the intrusion. There are four regimes with distinctive crystallisation characteristics. PGE content is low, both in bulk rock and in terms of metal in 100% sulphides, in the sulphide-rich cumulates but increases sharply in the sulphide-poor cumulates at the base of regime 1. Increases in regime 2 have no such clear relationship with incoming cumulus sulphides. PGE contents are low throughout regime 3, but regime 4 has sulphides with high PGE content, decreasing rapidly upwards, at the base of many of its cyclic units. The observations are interpreted as indicating that sulphide saturation occurred in the middle of a cyclic unit in regime 1, after which fractional segregation of sulphide caused a systematic decrease in PGE content. The resulting contrast between 40 000 ppb PGE in sulphides below the mineralised zone and less than 1 000 ppb above is of practical importance in exploration for such zones. In regime 2 the magma chamber was open to fresh influxes and PGE content was not so sensitive to sulphide saturation. In many regime 4 units influxes of new magma caused immediate sulphide saturation and PGE depletion, so that PGE-rich cumulates do not underlie PGE-bearing sulphide zones. Theoretical analysis indicates that regime 1-type behaviour is likely to characterise intrusions below the level at which plagioclase has entered as a cumulus phase and regime 4-type behaviour above

Apr 1, 1994

By S. A. Sayed, M. N. M. Ahmed, M. A. Doheim

The performance of a 12.7 cm hydrocyclone was investigated by considering the effect of design variables (diameters of the vortex finder and apex) and operating variables (pressure drop and solids content of the feed) at a medium feed solids concentration of mixed minerals. Cut-size was found to be the most important parameter in hydrocyclone design and operation. The effect of feed pressure in reducing hydrocyclone cut-size is less pronounced at medium feed solids concentration with a mixed mineral feed. The choice of vortex finder diameter and apex diameter becomes more sensitive at medium feed solids concentrations. The effect of feed solids concentration in increasing the cut-size becomes less marked at higher concentrations. Predictions of an empirical model were found to be in good agreement with experimental data. Comparison of results obtained from the model with those predicted by theoretically derived models showed the latter to be more promising, with the turbulent two-phase model giving closer agreement with the experimental data

Apr 1, 1995

By S. Kelebek, J. A. Finch, Zhenghe Xu, S. R. (Ram) Rao

To improve SO2 emission compliance, pyrrhotite from Sudbury copper-nickel ores is being depressed with DETA. To understand the mechanism of depression, the role of complexing in controlling metal-ion activation of pyrrhotite was investigated. DETA was found to remove Cu and Ni ions but leave hydrophilic ferric species on the pyrrhotite surface. The metal:DETA ratio appeared to be 1:2. Cu was more readily removed than Ni, but the combination of DETA with sulphur dioxide was equally effective for both metal ions. Certain combinations of DETA, Ni ions, xanthate and dithionite (S2O4) or dithionate (S2O6), as representative derivatives of SO2 in water, produced hydrophilic precipitates. These may enhance pyrrhotite depression

Jun 19, 1905