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By G. Gagnon

"HistoryMining of the Schefferville iron deposits began in 1954 on completion of the 357 mile railway linking the mines and the St-Lawrence river port of Sept-Iles. Apart from crushing, no treatment of these ores was required before smelting. In the late 1950's, testwork began at schefferville to develop a process for upgrading the extensive lower grade deposits containing 51% iron with 15% silica (natural analysis). Engineering for a six million ton per year beneficiation plant using cationic silica flotation and the A-C grate kiln Began in 1970 and the first pellets were produced in mid-1973.Production requirements and operating difficulties have restricted capacity to approximately 85% of design but on going improvements are being made continuously to attain design capacity.GeologyThe sedimentary ore bodies of the labrador trough occur in a belt 5 to 10 miles wide and 60 miles long and contain 51 individual deposits varying in size from 1 and 60 million tons. The ores are classified into three main color groups."

Jan 1, 1981

By H. J. Oterdoom

SMS Siemag (SMS) has always been the front runner in safety aspects of electric smelter plants for the ferro-alloy and non-ferrous industry. The awareness for safety increased significantly over the past decades and SMS contributed with its design features greatly to a safer design and operation. Today, safety aspects are not only part of the smelter design but also of the overall plant layout. Explosions in electric smelters are rare, but have a huge impact on peoples’ lives, on equipment and on production. For this reason, SMS wanted to have a better overview of explosions within the smelting industry in order to see if useful statistics could be extracted. Generally, there is a lack of statistics regarding explosions in the electric smelting industry, and not enough information is collected or published. A significant portion of the explosions seems to be water related. Many companies, both operating and engineering, are trying to handle the risks of water, and apply methods to detect water leakages. Installing such a system is a management decision and management has then to make sure the system is properly implemented. The disadvantages and limitations of these systems should be carefully considered and communicated to operators and authorities.

Jan 1, 2014

By N. Kolev, M. Poibrenski, I. Nishkov

"The following paper examines the flotation of copper porphyry ores in Assarel concentrator with focus on the reasons for low molybdenum recovery in the final copper concentrate. The copper-porphyry ore of the Assarel deposit is characterized by its variable mineral composition and high clay content, which influence the process efficiency of their concentration. Particle size distribution, chemical and mineralogical analyses have been made on various flotation products showing the distribution of the main elements of interest - copper and molybdenum. It was found that molybdenum is not concentrated into the final copper concentrate as usual in the flotation of copper-molybdenum ores but into the tailings of the copper selective flotation (cleaner tailings). An attempt to explain these results has been made with proposals to improve molybdenum flotation. Low floatability of molybdenite is caused by the ultrafine clay minerals content in both the run-of-mine ore and copper flotation streams. In order to achieve selectivity of copper minerals against pyrite a significant amount of lime is used in the plant leading to higher pH conditions, which could be another possible explanation for the molybdenite depression. The results obtained after the laboratory experiments, showed that it is possible to restore molybdenite floatability using traditional reagents such as diesel, kerosene, etc., and introducing a new polymeric reagent as froth modifier.INTRODUCTIONOne of the main technical difficulties in the area of copper-molybdenum flotation is the selective recovery of both metals, especially the fine (<40 micron) mineral particles. The problem is even more serious when Cu-Mo ore treated contains a lot of natural fine particles, predominantly clays, micas and other gangue minerals. Peng and Zhao (2011) conclude that the mineral processing industry is well aware of the difficulty in treating ores in the presence of clay minerals. Tremolada et al (2010) found that clay minerals have been named as the main problem in ore beneficiation processes due to their small size, which cause a higher viscosity in grinding. In flotation, these clay minerals have natural hydrophobicity or float by entrainment.The impact of clay mineralogy on flotation performance has been reviewed in the literature and the various deleterious roles of clay minerals have been investigated (Bulatovic, Wyslouzil & Kant 1999; Jorjani et al, 2011; Farrokhpay, Bradshaw & Dunn, 2013). It is widely accepted that the actual flotation recovery problem appears to be caused by the properties of these fine particles: small mass (and/or momentum) – high interfacial free energy (Rubio et al., 2007; Farrokhpay, 2011). In most cases, the loss in recovery is found to be insignificant, but the detrimental effect on the concentrate grade is found to be more prominent. The main reasons for the flotation inefficiency are the low probability of bubble-particle collision and adhesion, formation of dense froths and as a result - low process kinetics. A great deal of fine valuable minerals is discarded as slime in flotation due to lack of effective recovery methods."

Jan 1, 2016

By G. Molloy

The purpose of this paper is to demonstrate the value of applying continuous improvement, in particular 5S and standard work, in an underground environment. 5S and standard work are two aspects of Lean manufacturing that have been applied in many industries. At Vale Canada Limited, the focus is to first stabilize the process, commonly through the use of 5S, standard work and other continuous improvement techniques. In parallel with building an engaged workforce, these approaches aim to incrementally stabilize and improve a process. 5S is an employee-driven, systematic methodology to reduce waste in all its forms through attaining, maintaining, and improving workplace organization. Identified as a foundational part of any improvement process, 5S aims to remove wastes that impact on the overall efficiency of the area. Standard work is used to formulate a common approach to how tasks are carried out to ensure consistency. Standardization involves identifying, establishing, and following the best method. The aim is to eliminate the variation that can occur when there is not a pre-defined established standard. Demonstrating the value of 5S and standard work in an underground environment will be achieved by first understanding the overall concept of Operational Excellence and continuous improvement as practiced within our operations. The paper will then cover a real application of 5S and standard work within the underground environment at Thompson, Manitoba.

Aug 1, 2013

By A. Tohn, K. Adham, R. Lu, D. Lemieux

"To remove sulphur, carbon and arsenic from the gold concentrates of Dundee Sustainable Technologies (DST), Hatch has designed a demonstration plant roaster using the fluid bed technology. The fluid bed was selected for its ability to maintain stable temperatures and uniform reaction conditions. Data points from a small pilot plant (operated by DST) were used for setting the parameters of the demo plant roaster.The DST demonstration plant is being built to further prove their patented gold extraction process at an industrial scale. Their gold extraction process is based on halogenation at atmospheric pressure and relatively low temperatures. Before the halogen leaching, most of the sulphur, carbon and arsenic should be roasted out of the feed concentrate.The Hatch fluid bed roaster design includes a moist feed introduction system, simple bed cooling for temperature control, and cyclone fines recirculation. The demonstration plant roaster is planned for construction in 2014, and the performance results will be presented in a future paper."

Jan 1, 2014

By W. L. Strand, D. N. Madge

"Experimental and pilot operations in bituminous sand processing require due care and attention in the design and analysis of measurement programs. This paper deals with a case study in experimental design and data analysis for a series of experimental campaigns that have been conducted over the past five years by Kilborn Western Inc., acting on behalf of Bitmin Resources. Beginning with the design of the experiment and following into the use of linear and nonlinear regression models, the phenomenology of bitumen extraction is illustrated. The final testing program tested 13 oil sand types as well as a wide range of process variables for all the unit operations of the complete process.The program was successful in developing process fundamentals and scale-up criteria. Several phenomenological models were proposed and tested. Their range of applicability was explored. This paper illustrates the range of applicability of these models and discusses the development of alternative models.IntroductionOver the past five years Kilborn has conducted a series of bench scale and pilot scale experiments designed to explore the phenomenolgy of a new concept in medium temperature processing of bituminous ores. These experiments at feed rates ranging from .1 to 24 t/h were conducted on water wet sands from the .Athabasca region near Fort McMurray. They were based on experimental designs chosen to provide a systematic means of identifying the response surfaces of the process over a range of conceptual designs. The following diagram shows the experimental arrangement:"

Jan 1, 1998

By Franco Oboni

Numerous voices are raising around the world to show how misleading and fuzzy commonly used risk assessments methods are. These criticisms come at a time when public trust in ?proponents of new projects?, operators, private or governmental, seems to have hit a low and the legal system ?targets? public officers. It is common that technical experts and the public strongly disagree in their analysis of risks. Risk definition requires the evaluation of probability and consequences and those words are oftentimes enough to stir great worry to the public. Thus it is nowadays commonly understood that ?reality? is not scientific, but resides in public opinion, hence urging technical people to communicate better, more transparently. Blatant failures on both counts have lead to the emergence of ?new myths? used to justify complacency using ?complexity? and other buzz words as an alibi. This paper (together with its companion presented elsewhere) explores how poor ?common practices? in Risk Assessment contribute to biasing project team, design teams opinions, skew decision-making process and finally misrepresent reality to the public resulting precisely in the raise of public distrust, legal implication witnessed around the world. The discussion first reviews the pitfalls of common approaches (FMEA, Probability Impact Graphs) pinpointing them as possible causes of future legal liabilities. An alarming disconnect also comes from various codes, ISO 31000 itself has this flaw, invoking the term ?acceptable?/?tolerable? without defining it or giving any guidance for its determination. Wide-spectrum public consultation could be developed to define a ?modern? social acceptability criteria helping all the stakeholders making/understanding decisions. Another alarming disconnect comes from the poor definition of consequences of mishaps and their societal ripple effects. This aspect is indeed mostly ignored in codes, leaving ample room to biases and censoring applied to potential losses. In our society no one seems to have anymore the possibility of hiding behind a shroud of ?carefully maintained? misrepresentation. It is time to act and ?write the book? for proper risk assessments avoiding misrepresentations.

May 1, 2013

By W. J. Kuit

"Complex facilities which provide for the collection, management and treatment of effluents emanating from the Sullivan mine and concentrator tailings were made operational in October, 1979. Key features of the system are the use of upgraded tailings ponds for the storage of up to 800 million litres of metals-contaminated effluents, a treatment plant employing lime in a high density sludge process and a sludge-impoundment facility designed for maximum long-term environmental safety. The completed works are cap1ble of satisfying a difficult range of operating requirements imposed by highly variable weather conditions, drainage flows and soluble metals loadi11gs. Final capital expenditures for the project will approach $10 million and annual operating costs are estimated at $0.8 million.This paper discusses the Kimberley effluents treatment project and the major considerations in its development. The treatment process, major plant equipment and initial operating experience are also described."

Jan 1, 1980

By A. J. Sinclair

"Abstract-Geology contributes essential information toward obtaining high-quality resource/reserve estimates. In this context, geology can be considered under the following overlapping topics: regional geology, detailed (deposit) geology, mineralogy, ore deposit models and continuity, with geological mapping being fundamental to all. Each of these topics is considered here in terms of potential contributions to "improved" mineral inventory estimation. Some of the principal conclusions are:1. Regional geological relations must be consistent with deposit geology. It is common that important geological relations are more clearly evident in various regional locales than in highly altered and/or highly deformed mineralized areas containing mineral deposit.2. Detailed geology provides information for a geometric model of a deposit, a model that serves as a basis for mine planning. It is important to distinguish fact from interpretation in such models. Substantial effort is required to characterize the geometric margins of a deposit and the relation of these margins to the simplistic geometric form that normally emerges as an interpretation.3. Mineralogical studies relate to many aspects of deposit evaluation including abundance of ore and deleterious minerals, spatial distribution of ore and deleterious minerals, grain size characteristics of important minerals, mill design, etc.4. Ore deposit models contribute substantially to confidence in developing a three-dimensional geometric model of a deposit for mine planning. Specifically, they are a basis on which to develop rules for interpolation and extrapolation of ore, and they contribute to recognition of domains, each with its own characteristic continuity and margin character.5. Continuity is dependent on mineralization style and may be controlled structurally and/or chemically. It is important to distinguish geological continuity and value continuity. A wide range of classical geological methods are useful in examining geological continuity; value continuity is best viewed as a statistical characteristic that is quantified by any of several measures of autocorrelation."

Jan 1, 1998

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By J. R. Johanson, A. W. Jenike

"A solid flows out of a bin provided that the outlet is sufficiently large so that stable obstructions to flow do not develop. The geometry and surface finish of a bin and the construction of the feeder determine the type of flow pattern which then develops within the bin. The pattern, in turn, affects the uniformity and consistency of the stream, segregation, caking, degradation, live capacity and the action of level measuring devices.In most bins now in operation, material flows toward the feeder through a channel which forms within the stationary solid. This is referred to as funnel flow. If the hopper of the bin is sufficiently steep and smooth and the feeder capable of drawing material across the whole area of the outlet, all the solid flows whenever the feeder is in operation; this is referred to as mass flow. Mass-flow bins are usually far superior to funnel-flow bins; their initial cost is also usually higher.The paper describes the design criteria used in deter-mining the minimum bin outlet needed for flow and the bin geometry needed for mass flow."

Jan 1, 1970

By D. E. M. Plaumann, B. S. Fee, R. D. Hansen, R. R. Klimpel

"This paper briefly summaries the status of a recent program aimed at identifying new chemistry for use as sulfide mineral frothers and collectors. The background motivation and planning behind this work is given along with the general families of chemical structures synthesied and studied in detail followed by typical flotation application results in various laboratory and plant scale tests. Flotation testing to date has been very encouraging with often improved recoveries of certain minerals and improved pyrite selectivity being observed over commercially available reagents. In addition, in some cases, the dosage and lime requirements of these new collectors are significantly less than that associated with standard sulfide mineral collectors. INTRODUCTIONFroth flotation is one of the most widely used and economic means of concentrating metal sulfide ores. There are numerous reference books that have been published on the chemical aspects of flotation [e.g., ref. 1-7] which are based on studying the influence on selected minerals of chemical structures that have been used commercially for many years. In fact, almost 98% of the volume of flotation collector and frother reagents used at the industrial level today were known and manufactured in some form 25 years ago [8]. There are many reasons for this lack of significant new flotation reagent development [9] including the general utility and relative cheapness of existing collectors such as xanthates and existing frothers such as the alcohols and glycol ethers. Another reason is the inherent complexity of the flotation process itself coupled with highly variable and difficult to standardize feed materials. This environment makes reliable reagent comparisons difficult and seriously limits the use of theoretically based chemical structure studies to predict new or optimal reagents. In addition, the higher cost of specialty flotation reagents demands that their performance attributes be significantly greater than that achieved with existing all-purpose commercial reagents - something often difficult to prove in practice."

Jan 1, 1988

By R. Bridge

Mining companies are progressively finding themselves having to develop operations for more complex, deeper ore bodies, which require the use of more complicated mining and mineral processing methods. This coupled with the generally increasing trend of higher capital and operational costs have led to a need in the industry for improving ore body knowledge, mining and mineral processing. Geometallurgy is a relatively new concept that can link the three aspects, and when used effectively it is a method that can produce the necessary information for designing and building operations for reliable and optimum performance. Geometallurgy not only involves the integration of geological, mining, and metallurgical fields, but it can also be expanded to include environmental and economic information to produce a block model that can be used to obtain the best outcome in terms of plant response and plant sustainability. The geometallurgical program should not end once the block model has been populated. A detailed geometallurgical approach should be applied to all stages of the operation encompassing sample selection, through to equipment sizing and production forecasting. It can also become a useful optimisation tool thereby allowing the operation to be proactive rather than reactive against changes in the ore characteristics. With the development of metallurgical performance predictors it is possible to quantify how the ore will behave in the process plant in terms of throughput, recoveries, reagent consumption, etc. Therefore, in terms of responsible mining and sustainable resource development, a geometallurgical approach to operations is the logical step for plant development. In this paper we describe the state of the technology with respect to the application of geometallurgical modeling and its utilisation in the fields of design, forecasting and optimisation of mining operations.

Aug 1, 2013

By F. Cheuk, E. Krause, V. G. Papangelakis, G. A. Moldoveanu, S. Abendschein

Systematic studies have been conducted at the University of Toronto in order to evaluate lanthanide extraction from clay minerals from different geographical regions. It was found that rare earth elements (REE) are easily recovered into an aqueous solution via an ion exchange mechanism by leaching with electrolyte solutions containing monovalent cations under ambient conditions. In this study we assessed extraction levels of individual REEs as a function of initial clay composition and leaching conditions. It was found that, in spite of variations in clay origin, all clays consistently reached peak REE extraction levels with fast kinetics. However, terminal extractions were clay-specific. The feasibility of using seawater as a leaching solution and potential synergies with ammonium sulphate as a lixiviant was also investigated. Seawater was found to be inferior to using ammonium sulphate, and provided no observable synergy in leaching performance when used together. The aqueous phase trapped in leached clays was shown to contain significant amounts of REE, as demonstrated in clay washing tests. Techniques to improve the REE concentration in leachate through process variations were investigated. However, it was found that most techniques capable of increasing REE concentrations in the resultant leachate also resulted in reduced REE extraction.

Jan 1, 2014

By I. Mc Dougall, H. Joubert, G. de Villiers

The use of sidewall copper cooling systems to prolong furnace campaign life is becoming an accepted technology solution in the base metals industry. Tenova Pyromet has designed and installed a number of sidewall copper cooling systems in base metals furnaces, including the platinum industry. Apart from increasing the furnace campaign life through the formation of a stable freeze lining, a well-designed copper cooling system enables the plant operator to focus more on optimizing the process to achieve throughput and recovery targets, and to accommodate more varied and available concentrate feed blends. The paper discusses the design of sidewall copper cooling systems for copper smelting and converting furnaces to achieve the above objectives. More specifically, the design of copper cooling systems for top submerged lance furnaces are discussed. An overall increase in furnace heat losses has been raised as a concern for intensively cooled sidewalls. The paper explores the overall heat loss expectations for copper cooled furnaces versus traditional refractory lined furnaces. In addition, the potential use of alternative cooling media is discussed. INTRODUCTION Base metal smelting and converting furnace technologies have been evolving continuously over the past century to satisfy the need for higher throughput, improved efficiency, and longer campaign life. To accommodate these demands, in particular higher smelting intensity and throughput, furnace bath containment systems had to improve. The use of pure refractory lining systems has slowly made room for the use of more intensively cooled lining systems (Joubert, Nikolic, Bakker & Mc Dougall, 2016). These cooling systems evolved from external shell cooling, such as shower or film cooling, to copper plate coolers extending into the furnace refractory lining, and high intensity stave or panel coolers (Verscheure, Kyllo, Filzwieser, Blanpain & Wollants, 2006). Consequently, an increasing number of base metal smelting and converting furnaces are equipped with copper cooling systems, including flash furnaces (Bryk, Ryselin, Honkasalo, & Malmstrom, 1958; Yasuda, Motomura & Kawasaki, 2014; Marx, Shapiro & Henning, 2010), top submerged lance primary smelting and fuming furnaces (Bhappu, Larson & Tunis, 1994; Kim, Lee & Lee, 2000; MacRae & Steinborn, 2018), top submerged lance converting furnaces (Viviers & Hines, 2005; Nikolic, Hogg & Voigt, 2018), primary platinum smelting electric furnaces (Nelson, Stober, Ndlovu, De Villiers & Wanblad, 2005; Jones, 2005; Hundermark, De Villiers & Ndlovu, 2006; Mc Dougall, 2013), and electric slag cleaning furnaces (Joubert, Nourse, Masters & Hundermark, 2005).

Jan 1, 2019

By George A. Guess

The making of contracts for the purchase of ores is a business which the metallurgist usually understands better than the miner. Companies in the custom ore business often employ an ore buyer who is aware of the class of ore which the smelter needs, and is thoroughly conversant with the business. The miner on the other hand makes ore contracts but seldom, and it is often only after a settlement has been made that he realizes the meaning of the terms of the contract under which he has sold his ores. He has expectations usually greatly in excess of the amount &apos;net proceeds&apos; shown at the bottom of the settlement sheet. Seldom does the occasional shipper really know his contract. A somewhat similar parallel is to be found in insurance policies. We all have insurance policies; we never know the conditions contained in them until after the fire. The clauses in the policy are for the protection of the Insurance Company. An Insurance Company has no friends.

Jan 1, 1926

By B. Adams, T. Angelov, G. Sasov, D. Steinhilber, A. L. Tsekov, S. Neufeind

A complementary ion exchange/solvent extraction process for the recovery of copper from low- grade ores is described. It has successfully been implemented on a full-scale plant level at the Buchim Copper Mine in Macedonia, yielding a maximum copper cathode production of 2400 tons per year. Compared with conventional SX/EW operations, this technology makes the exploitation of low-grade copper ores economically attractive, due to reduced operational and capital expenditures. Furthermore, the additional Lewatit® ion-exchange installations diminish the volumes of harmful organic substances in the following SX step and minimise the risks associated with the handling and usage of these chemicals, such as environmental pollution or fires. Finally, the significantly diminished quantities of liquids for the SX operation have a tremendous effect on the footprint of the plant (ca. 50% less) thereby leading to a reduction of capital expenditures. This paper reviews the main stages of the combined IX/SX process, the applications for metal recovery and introduces projects where the process is applied. Key findings of the process are also presented. A comprehensive technical comparison between processes has been carried out. This paper also evaluates the advantages of using combined IX/SX technology as a purification and separation step in copper production process, with the aim of further increasing the overall copper recovery and to ensure that a suitable copper concentration in the advanced electrolyte is achieved. The implementation of a Ion Exchange (IX) process in the classic Solvent Extraction-Electrowinning process(SX/EW) is found to be beneficial for processing of pregnant leach solutions both from spent and new copper heaps and dumps, acid mine drainage and other industrial streams without any preconditioning as well as in terms of achieving improved recoveries and copper cathode quality. INTRODUCTION The concentration and separation of copper from primary leachates is one of the key operations in the hydrometallurgical processing of oxide ores (Langner, 2011). Conventionally, this basic operation is conducted by submitting the pregnant leach solution (PLS), with a 1–5 g/L Cu content, from the initial sulfuric acid leach to a solvent-extraction (SX) process in which copper reports to the organic phase. After phase separation, the metal is stripped from the extractant/diluent mixture employing sulfuric acid to furnish a concentrated metal solution, usually containing 40–50 g Cu/L. The final products of the overall process are copper cathodes, which are obtained from a terminal electrowinning step.

Jan 1, 2019

By Gerardo Fuentes

Arsenic extraction from Chilean copper concentrates up to nearly 99% was achieved, using hydrothermal reactions. Arsenic appears in nature in more than 200 mineral species, being arsenopyrite (FeAsS), enargite (Cu3AsS4), and tennantite (Cu12As4S13) the most common species. In addition, arsenic is present in a large amount of copper concentrates, produced in northern Chile. Medical statistics show that in northern Chile, the amount of cancer to the lung, skin and bladder are the highest in the country. The latter situation, demonstrates the importance of studying metallurgical processes that do not generate atmospheric pollution. The hydrometallurgical processes such as hydrothermal treatment in autoclave reactors, do not produce gaseous emissions. On the other hand, the arsenic remains in solution from where it can be transformed in scorodite by widely known methods. Previous works about hydrothermal treatment of enargite have shown the feasibility of transforming the enargite of the copper concentrates into chalcocite or mineral species of the chalcocite family such as djurleite, digenite and for this reason enrich the concentrate in copper and pass the arsenic to solution. For this research, two Chilean copper concentrates were used, concentrate 1 with 5.5% arsenic and concentrate 3 with 1.8% arsenic. These concentrates were subjected to a complete chemical and mineralogical characterization. Later these concentrates were carry out to batch tests of hydrothermal treatment. Also, these concentrates were subjected to grinding to have different particle sizes. For the hydrothermal tests, a liter capacity Autoclave Engineer reactor was used. Characteristic of this reactor was the maximum temperature 350°C, 5000 PSI pressure, and 900 rpm agitation speed. Kinetic tests were carried out with the two concentrates maintaining the same solid: liquid relationship, the same agitation velocity and the variables studied were treatment temperature, time of reaction, concentration of copper in the solution and grain size of the concentrates. The conclusions of the study indicated arsenic extraction of the order of 93.98% from the concentrate 1 and arsenic extraction of the order of 98.74% from concentrate 3. After the hydrothermal treatment, the solids and solutions were characterized chemically, by electron microscopy and X ray diffraction. Also the solids were characterized by grainsize through a particle size analyzer (MICROTRAC). Results of batch treatment shows that arsenic can be release almost completely from real copper concentrates using this hydrothermal process and the next stage will be a scale up process in order obtain results for pilot plant design. INTRODUCTION Arsenic is an impurity that appears associated with copper minerals forming enargite, tennantite, tetrahedrite, and that due to the pyrometallurgical treatment either in conversion or roasting furnaces, it goes into the atmosphere together with the sulfur dioxide. A great quantity of literature can be found to eliminate arsenic or try to separate arsenic from copper. The methods used are mainly leaching processes with or without pressure (Padilla, Jerez & Ruiz, 2015) with different reagents like chloride media (Herreros, Fuentes, Quiroz & Viñals, 2003) or chloride media with sulphuric acid (Riveros & Dutrizac, 2008) or sodium hypochlorite (Mihajlovic, Strbac, Zivkovic, Kovacevic & Stehernik, 2007). It is known too that Chile is the first copper producer in the world and a great quantity of its minerals are in the north of the country, in Antofagasta.

Jan 1, 2019

By Jiahao Xu, Namsoo P. Kim, Guikuan Yue

Iron (ferrous ions and ferric ions) plays an important role in the heap leaching of copper sulfide minerals and copper electrowinning. In our previous study, a novel oxidation-reduction potential (ORP) equation only based on the variables of temperature and nominal ferric/ferrous ratio was developed to predict the redox potential of the quaternary H2SO4-Fe2(SO4)3-FeSO4-H2O system, and its applicability was also extended to more complex acidic iron sulfate solutions, especially those generated during the acidic leaching and bioleaching of Printed Circuit Boards (PCBs) to recover copper. In this work, the broader range of applicability of this equation to other complicated acidic iron solutions containing copper ions has been extended and determined. Specifically, synthetic iron-containing solutions with copper ions according to the conditions of industrial electrolyte during copper electrowinning and heap leaching have been used to measure the ORP and test the developed equation. It seems that this equation can still be employed to predict the redox potential of the Fe3+/Fe2+ couple for the simulated solutions under conditions related to copper electrowinning and pregnant leaching solution generated during heap leaching over a wide range of solution concentration, nominal Fe3+/Fe2+ ratio and temperature. It has shown that the prediction and measurement of redox potential is highly useful to estimate and understand the iron chemistry of industrial leaching and electrowinning processes. INTRODUCTION It is well-known that iron (ferric or ferrous) ions are widely involved in the hydrometallurgical production of non-ferrous metals such as Cu, Au and Zn, mainly in the form of acidic iron sulfate solutions. As far as Cu is concerned, in a typical leaching-solvent extraction-electrowinning process, ferric ion plays a central role in the heap leaching process and is reduced to ferrous ions in the pregnant leaching solution. Ferric ion is the most important surrogate oxidant and the dissolved ferric/ferrous couple plays an important catalytic role in accelerating the leaching rate with oxygen as an oxidant (Peters et al., 1986; Schlesinger, King, Sole, & Davenport, 2011). In addition, during the traditional electro-winning process, oxygen is evolved at the anode, and copper is reduced at the cathode. A common idea is that iron in the electrolyte in copper electrowinning cell (with total iron of 1–4.4 g/L) plays an important role in reducing the current efficiency. According to the published results (Winand et al., 1975; Dew et al., 1985; Moats et al., 2009; Khouraibchia et al., 2010), thecurrent efficiency decreases linearly with increasing ferric ion concentration and the energy consumption increase was mainly caused by the decrease in current efficiency.

Jan 1, 2019

By C. T. Wiliams, John B. Bush, John Lamb

"THE TOWN OF HEDLEY is in the valley of the Similkameen River, about 200 miles east of Vancouver and 25 miles north of the International Boundary between British Columbia and the State of Washington. The main ore deposits are located on Nickel Plate Mountain, northeast of the town.The outcrop of the Nickel Plate system of orebodies is at an elevation of 5,900 feet. It was discovered in 1898 by prospectors and sold in the following year to the Marcus Daly interests of Butte, Montana. Production commenced in 1904 under the name of Daly Reduction Company. In 1909 control passed into the hands of the Hedley Gold Mining Company. Operation of the mine continued until 1930, when exhaustion of known ore reserves forced it to close. Upon the recommendation of Paul Billingsley (3) the mine was optioned by the 1. W. Mercer Exploration Company in 1932. Production began once more in 1934 under the name of Kelowna Exploration Company Limited, and was practically continuous until August 1955, when the mine was again shut down. The name of the latter company was changed in 1951 to Kelowna Mines Hedley Limited.The Mascot Fraction, a small wedge-shaped claim lying astride the Nickel Plate orebodies, was mined by Hedley Mascot Gold Mines Limited between 1935 and 1949. The geological setting and structural control of ore are essentially the same as in the adjoining Nickel Plate Mine.Total production from all operations on Nickel Plate Mountain to the end of 1954 was approximately 3,800,000 tons of gold ore, with a gross value in excess of $48,000,000.General GeologyNickel Plate Mountain occupies the gentle westerly dipping limb of an asymmetrical anticline, the axis of which trends northeasterly. The rocks are composed of a thick pile of Triassic limestone, limy argillite, and quartzite, -resting on a flattish floor of granodiorite near the base of the mountain. Associated with these sediments is a host of porphyritic sills and dykes of gabbro-diorite composition. In the mine area east-west brown soda-rhyolite dykes and north-south black andesite dykes crosscut all the other formations and the ore, probably following steep later fractures."

Jan 1, 1949