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By MAX VOS

Lithium is the lightest and electrochemically most reactive of all metals. Renewed interest in lithium coincides with research in lithium batteries and power generation by atomic fusion. Ontario lithium resources are contained in spodumene pegmatites that can form where medium- to high-grade metamorphic volcanic-sedimentary formations are intruded by pegmatite and porphyritic granitic rocks. Spodumene pegmatites occur in at least twelve locales throughout northern Ontario, all of which are in the Superior Province of the Precambrian Shield. Tantalum, cesium, rubidium, beryllium, niobium and tin also were noted with lithium in spodumene pegmatites. Considerable potential remains for discovery of additional lithium and rare-element pegmatites in northern Ontario.

Jan 1, 1984

This paper states how alloy and welding advances have made possible the rapid development of the use of aluminum in the construction of equipment for earth moving and off -highway rock hauling. The main details are given regarding the construction and field testing carried out on an aluminum prototype body. The test results of strain gauge readings are analysed, and a description is given of how these have been applied in subsequent designs. The increase in the number of aluminum units put into the various types of service in Canada, as well as the problems encountered, is described, and the experience gained from five years of field service is discussed in some detail. An assessment is also made of the durability of the e units. The economics of using aluminum, together with the current development position, are reviewed, and predictions are made for considerable future increases in the use of aluminum units in open-pit and off-highway operations.

Jan 1, 1964

By M. Tanaka, H. Narita, K. Morisaku

"The selective separation of palladium (Pd), platinum (Pt), and rhodium (Rh) from a hydrochloric acid solution by solvent extraction was investigated using amide-type extractants, i.e., N,N,N’,N’-tetra-n-octyl-thiodiglycolamide (TDGA) and N-n-hexyl-bis(N-methyl-N-n-octyl-ethylamide) amine (BisAA). The separation experiments employed two separation schemes: (1) extraction of Pd with TDGA and that of Rh and Pt with BisAA; and (2) extraction of Rh, Pd, and Pt with BisAA. Separation scheme 1 achieved the highly selective separation of each metal. For separation scheme 2, Rh can be recovered prior to Pd and Pt, despite having a lower selectivity for Pd/Pt than separation scheme 1. INTRODUCTIONThe recent increase in the use of platinum group metals (PGMs) in industry (especially auto catalysts containing palladium (Pd), platinum (Pt), and rhodium (Rh)) has lead to their increasing waste; therefore, improvements in the recovery techniques for PGM have received significant attention. In metal refineries, PGMs are mainly separated and purified by solvent extraction (Cox, 2004). The extraction process used in INCO’s Acton precious metal refinery is one of the most famous commercial processes and is utilized worldwide. In this process, silver is first removed as a residue (AgCl), and then gold, Pd and Pt are extracted from hydrochloric acid (HCl) solutions using dibutylcarbitol (DBC), dialkylsulfide (DAS), and tri-n-butylphosphate (TBP), respectively. Finally, Rh remains in the raffinate (Barns & Edwards, 1982).The development of a successful solvent extraction process depends on the choice of the appropriate extractants. We have studied the extraction of PGM using N,N-disubstituted amide compounds (Narita, Tanaka, Morisaku, & Abe, 2004; Narita, Tanaka, Morisaku, & Tamura, 2006; Narita, Tanaka, & Morisaku, 2008a, 2008b). They are relatively stable against acids, and their metal extractability can be improved by changing the side chain length and/or introducing additional donor atoms like sulfur and nitrogen. We have recently found that thiodiglycolamide and an amide-containing tertiary amine have good extractabilities for Pd and Rh, respectively."

Jan 1, 2012

By H. Clare Horwood

"In the Red Lake area in northwestern Ontario the relationships between general structures and structures containing ore deposits are among the most unusual and most interesting of any in the Precambrian Shield. The more important orebodies, which are in the central-eastern part of the area, occur in a variety of rocks on the northeastern, eastern, or southeastern sides of a series of granite stocks. Other deposits in the western part of the camp also are structurally associated with granite masses .The relationships were determined in the course of general and detailed geological mapping by detailed analyses of the fracture patterns in the rocks adjacent to the orebodies. In every case it was found that the structures containing the ore were produced by compressive stresses from the direction of intrusion of the granite masses( 2).The Red Lake area lies in the Patricia part of the district of Kenora and is accessible by boat from Hudson or by airplane from Kenora, Sioux Lookout, or Winnipeg. A road from Vermilion lake, on highway No. 17, was opened in August, 1947.The first discoveries of mineralization in the area that proved to be of economic importance were made in 1925 by Lorne Howey and George McNeely for Haileybury interests and by Ray Howey and W. F. Morgan for Mcintyre-Porcupine Mines, Limited. Both prospecting ventures were organized because of information presented by Bruce(l) in his map and report for the Ontario Department of Mines. The discoveries, which were both along the same structure, a quartz porphyry dyke, later developed into the Howey and Hasaga gold mines. Other discoveries were made at intervals as a result of prospecting and development work on ground staked for its location."

Jan 1, 1954

By Victor F. Hollister

Although none of the deposits discovered to date are of commercial interest, significant Frasch or sedimentary sulphur deposits occur in Nova Scotia in Upper Mississippian Windsor Group evaporites. The evaporite sequence contains anyhdrite and is overlain by impervious shales. It also is •mderlain by locally petrolijerous formations that are potential hydrocarbon sources for reaction with anhydrite to produce sulphur. As well, stratigraphic and structural traps are known to exist in the Mississippian beds. Thus, all requisites for sedimentary sulphur genesis are present. Available hydrocarbon sources are numerous but small; resultant sulphur deposits therefore are probably also small. Evidence suggests, however, that sulphur deposition is not yet complete.

Jan 1, 1984

By A. E. Cameron

The theory of atomic distribution of the stranger atoms in the space lattice of the solvent metal has been well developed by Rosenhain. It has long been known that the addition of one metal to another to form a solid solution increases the strength and hardness of the solvent metal. This increase is practically proportional to the amount of added substance up to the limit of solid solubility. To account for this increase in hardness and strength, Rosenhain assumes that the stranger atoms occupy positions on the solvent metal space lattice. Atomic attractions about the stranger atoms will not be the same as in the case of the pure metal, and there will thus be a disturbance of the orderly arrangement of the atoms on the space lattice, or a distortion of the lattice. Such a disturbance would interfere with the ease of slip along the planes and would thus tend to promote strength and hardness. Rosenhain notes that not only may there be a local disturbance of the lattice about the stranger atom but there may well be also a measurable change in the dimensions of the lattice as a whole. The relative amounts of local and general distortion of the lattice will depend upon the nature of the lattice itself. As Rosenhain says, "If the lattice is comparatively soft and flexible the distortion is likely to be largely local. In a stiff lattice, however, local distortion will be resisted and there will be a correspondingly increased general distortion."

Jan 1, 1927

By S. Shairp

At the Hudbay zinc pressure leach plant, filtration and washing of the second stage leach slurry takes place on a vacuum belt filter prior to disposal to tailings. Due to periods of poor filterability, laboratory studies were undertaken to investigate the effect of temperature of the filter feed slurry, and to compare filterability to the resulting cake particle size distribution.

Jan 1, 2014

By M. Clotilde Apua, A. F. Mulaba-Bafubiandi

"The efficiency of hydrochloric acid (HCl) leaching of gold from low grade gold-bearing material has been investigated in the presence of sodium hypochlorite (NaOCl) to produce in situ chlorine gas which is an oxidizing agent able to oxidize gold metal to its soluble forms. The effect of concentrations of HCl, NaOCl, and mixtures of HCl + NaOCl was sought. Iron and potassium present in the feed were leached and consumed all the HCl. Gold found as inclusion in pyrite was not exposed to the lixiviant. Therefore, leaching of gold from low grade gold-bearing material in aqueous chlorine solution is not an effective process for now.INTRODUCTIONHydrometallurgy of gold is commonly based on cyanide leaching solution. Due to the environmental concerns related to cyanidation and mercury processes, and inefficiency of cyanide gold leaching to dissolve refractory ores, sustainable alternative lixiviant systems, capable of generating gold (I) and gold (III) complexes must be studied. Amongst non-cyanide gold lixiviants there is the chloride/chlorine system (Hilson and Monhemius, 2006; Senanayake, 2004; Pilsniak and Trochimczuck, 2007; Wang et al., 2007; Reeves et al., 1999; Khodadad et al., 2008).In practice, the most oxidizing agents utilized for the leaching of gold as chloride, are chlorine (Cl2) or hypochlorite (HOCl) which are either generated in situ by suitable reaction or added in solution (Adamson, 1972). The dissolution of gold concentrate using hydrochloric acid, sodium chloride and sodium hypochlorite (Cl-/HOCl system) were studied (Puvada and Murthy, 2006). The effect of NaOCl and NaCl concentrations were also investigated. The leaching was performed under the following conditions; time: 4h, solid–liquid ratio = 1:4, at room temperature. It was found that the increase of the NaOCl concentration from 25 to 75 g/L did not have any meaningful effect on the recovery of gold which was about 30% (experimental conditions; S/L ratio = 1:4, NaCl concentration: 25 g/L, HCl concentration: 0.35 M). It was also found that from 25 g/L to 200 g/L NaCl, the recovery of gold rose from 30% to 40% (experimental conditions; S/L ratio: 1:4, NaOCl concentration: 25 g/L, HCl concentration: 0.35 M)."

Jan 1, 2012

By Bradley Stoughton

The magnetic oxide of iron, F eO4 , contains a theoretically larger amount of iron ( 72.4 per cent.) than any other commercial ore. It is probable that it has originated in many cases by the prolonged exposure of the hydrated oxide, ZF e20 a + 3H20 to heat and pressure which converts it first into hematite, F e20 3, and then into magnetite. It would thus appear as if nature had already done part of the work of removing all the oxygen and that magnetite should be relatively easy to reduce. That it is, in fact, less reducible than either limonite or hematite, is due chiefly to its dense and compact physical structure, which makes it less pervious to the furnace gases, and also to its characteristic action in resisting crushing to a uniform size, with consequent irregularity in reducing conditions within the furnace. The net result is that the magnetic oxide requires more fuel and more time for its reduction in the blast-furnace than any other iron ore of similar iron content and physical condition. There is another very important reason why the smelting of magnetite is more costly than that of hematite, and its treatment viewed with a great deal of adverse prejudice by blast furnace operators, namely, that magnetite decreases the proportion of heat developed by the fuel in the stack of the furnace, and increases the already excessive heat requirements of the heart.

Jan 1, 1924

By J. Keith Haddock

"Introduction The Boundary Dam Mine is located 5 km south of the City of Estevan, Saskatchewan and is operated by Manitoba and Saskatchewan Coal Company Ltd., one of the Luscar companies. The entire production of 1.7 million tonnes per year is delivered to the Boundary Dam Generating Station of Saskatchewan Power Corporation. Geology There are basically two seams mined on the property, the main Estevan seam ranging in thickness from 3.0 m to 4.5 m with partings and the upper Roche Percee seam (roughly 15 m to 23 m above the Estevan) which ranges from 0.6 m to 2.0 m in thickness. Most of the reserves are concentrated in the Estevan seam, the Roche Percee only being mined whenever its thickness makes it economic to recover. The coal measures belong to the Ravenscrag Formation of Tertiary (Paleocene) Age. This formation is widespread in North Dakota and Montana and contains the lignite fields of North Dakota and subbituminous coals of Montana. The formation is gently tilted to the southeast at Boundary (0.5 degrees) and consists of weak sandstones, siltstones and silty mudstones. Reserves and Coal Quality The present minesite encompasses a coal reserve of approximately 50 million tonnes calculated to a maximum stripping depth of 37 metres or 20:1 mining ratio. The reserves form only a part of the total reserves in the Estevan area which are owned by the Saskatchewan Power Corporation. The coal being mined is classed as Lignite ""A"" and has the following specifications:"

Jan 1, 1985

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By W. H. Patterson

The history and experience of early companies in the Islands is illustrated by the typical transactions of Trans-Western from 1959 to date. Trans-Western had entered into farmout agreements with companies strong enough to carry out at least the required minimum exploratory work and then such development as might be warranted. The farmee companies were required to make deposits to guarantee work performance during the first period of validity, i.e. the first 3 years of the 12-year life of the permits, and at the rate of 5 cents per acre. At that time, a good deal of geology was available, as a result of extensive exploration that had been carried on by the Geological Survey of Canada and other geological enterprises, with field parties travelling over and camping on all of those Islands. Trans-Western's farmees then selected, from Trans-Western's priority on 13.5 million acres, what they believed were the lands most prospective of producing large oil and gas discoveries, and, having the right to trim off acreage which they considered less prospective, thereby reducing the acreage of Trans-Western and its farmees to in excess of 5.5 million acres. The farmees then commenced a 3-year program carrying out geological exploration to the required minimum of 5 cents per acre, and with some permanent and many mobile camps.

Jan 1, 1969

By J. H. Starkey

Large differences between macro and micro grindability relationships have been discovered for mill design measurements using the patented SAGDesign(TM) test. Crushing, Rod and Ball Mill Wi tests, and breakage parameter measurements have previously been used to design SAG mills but have not revealed the true magnitude of these differences. A SAGDesign(TM) test measures the SAG/Bond Wi Ratio (defined below) for every sample tested and gives a good design result because the F80 of the SAG stage test feed is 19 mm and because the test includes a Bond Ball Mill Work Index on SAG ground ore. Good flotation operation demands properly sized grinding mills and steady feed to the flotation circuit.

Jan 1, 2009

By R. A. Hemstock

AREAS in which the surface de-posits consist of organic material -known in some parts of Canada as muskeg and in Europe, more generally, as peat lands -have long been some of the least rewarding of lands of the north temperature zone. Even in such countries as Great Britain, Holland, and Denmark where a good deal of incentive exists to develop all available land, the use of peat land has been negligible except as a source of fuel. Only recently have efforts shown promise in re-claiming these lands for farming or for forestry. Russia has large areas of peat and use is made of it for power generation. The Russian people have also ?developed a variety of machines for handling peat, which would indicate that they are well ahead of the Wes tern World in their technical and physical ability to solve some of the problems. Certainly in Canada, where there are over 500,000 square miles of muskeg, the economic aspects of this problem are important. This is especially true in considering the shifting emphasis to northern development. Not only is muskeg in possession of great stretches of terrain, thereby rendering it useless for agricultural purposes, but it is apparently moving into forested areas and reducing their productivity. In addition, it lies as a great barrier to movement in the search for and development of such natural resources as petroleum, natural gas and minerals generally. This situation has long been recognized in Canada but only recently have organized efforts been made to study the problems and search out ways of overcoming them.

Jan 1, 1958

By John L. Rich

A New Field for the Mining Industry A new field for the mining industry is in prospect. This is the recovery of the petroleum which has been left in the ground in the older oil fields whose yield has declined until they are no longer profitable to operate in the ordinary way. The fact that an oil field has reached the economic limit for operation by pumping does not necessarily 'mean that the oil has ? been exhausted. In many such cases not over one-fifth, or even one-tenth, of the total oil content of the field may have been taken out when this stage has been reached. This means that there exists a large reserve of oil which can be recovered by whatever process best takes advantage of the natural conditions under which the oil occurs. Mine drainage is one of the processes by which this oil may be recovered. Its relative importance will depend partly on the ingenuity and wide-awakeness of mining engineers, and on mining capital. The opportunity is undoubtedly at hand. In order that we may be in a position to judge the possible advantages of mining methods for the recovery of this oil, I have reviewed, on the following pages, the methods now in use, and have discussed the physical conditions of the reservoir rocks in which the oil is found, and the suitability of the various recovery processes, in use or proposed, in the light of these reservoir conditions.

Jan 1, 1927

By Ramin ArameshAsl

Urumieh-Dokhtar is the well-known vast metallogenic belt extended from NW to SE of Iran and basically is referenced in copper mineralization studies in Iran. Hashtjin 1:100000 sheet (NW Iran) is located on this belt and rock units are consisted of Oligocene intrusive, volcanic rocks and Eocene Sedimentary rocks. Concerning the significance of identifying the alterations and faults zones in copper exploration, the aim of this study is identifying the copper mineralization by multi-spectral analysis of ASTER (Advanced Space borne, Thermal Emission and Reflection Radiometer) satellite images in the limitation SD-SWIR (Spectral Domain of Short Wave Infrared). Several analytical methods are implemented in this study such as SAM (Spectral Angle Mapper), MF (Matched Filtering) and PCA (Principal Components Analysis). These methods have been utilized for recognizing the Argillic, Propylitic and Sericitic alteration zones and all of them are relying on the remote sensing methods as well as geological studies of new targets for copper mineralization identification in the area.

Aug 1, 2013

By C. R. Hocott

"IntroductionRESEARCH in petroleum production consists primarily in investigations related to the drilling for and recovery of oil. As an organized activity of individual oil companies, production research is now 30 to 35 years old, and the petroleum industry may point with justifiable pride to the achievements of this third of a •century. Emphasis on research has grown through the years until at the present time many of the larger companies operating in the United States •have well-organized production research staffs.In addition to the efforts of the oil companies, significant research and development in petroleum production technology have been performed by oilfield service companies and others. Valuable contributions have been made through fundamental research carried on by the U. S. Bureau of Mines and by various colleges and universities, both in their own programmes and in programmes sponsored by industry, such as those of the American Petroleum Institute. However, the total effort of these groups is small when compared to the sum of the effort devoted to research by the individual .oil companies. In contrast to some industries which conduct the major portion of their research through co-operative, sponsored research at universities or research institutions, research by the petroleum industry is done predominantly by individual company research staffs. These industrial research groups have usually been organized in such a way as to provide liaison and co-ordination with operating technical staffs. In this way, the research groups are kept aware of the major problems confronting the operating departments and, correspondingly, the operating technical people •are able to keep informed on research activity and progress. This type of close contact generally results in prompt testing of research developments in actual operations."

Jan 1, 1953

By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By H. Stutchbury

Alberta is labouring, and has laboured, under serious difficulties in the marketing of ?her coals, due to a number of conditions which now obtain, but all of which appear capable of solution, and their elimination would insure a very largely increased market for the vast coal resources of that province. It is perhaps necessary to again mention the fact that 15 per cent of the world's coal resources are to be found in Alberta; 21 per cent of that of North America; 72 per cent of that of the British Empire, and 87 per cent of that of all Canada. While we talk largely of the great wealth of Canada, the immensity of her vast natural resources, it is axiomatic that the mere presence of any natural product in a country does not in itself constitute wealth for that country, unless these raw materials can find a market, either in their raw state, or by the process of manufacture. There are many factors, however, which enter into the marketing of any commodity. The chief of these, in my opinion, is price competition. High costs of production materially reduce the radius in which any product can be marketed, and this applies particularly to coal. Mining costs in the province of Alberta are necessarily high at the present time, due in a large measure to the ease with which the 'gopher hole' mine can be opened with small capital.

Jan 1, 1925