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By C. McLachlan, J. R. Donald

"Positioned at the forefront of the seafloor minerals industry, DeepGreen Resources is on track to becoming a leading producer of base and strategic metals obtained from vast high-grade seafloor polymetallic nodule deposits. DeepGreen believes the seafloor minerals industry is an opportunity for developing a more environmentally and societally attractive way to produce cleaner base and strategic metals. Polymetallic nodules contain nickel, manganese, copper, cobalt and other base and strategic metals. Polymetallic nodules represent an exceptional multi-metal-bearing resource, and no current metallurgical operation or flowsheet exists that can recover the primary metallic values while managing the distinct mineralogy. DeepGreen Resources is developing a new process to maximize the business outcomes consistent with the highest environmental standards, including targeting a near zero waste facility. The present paper discusses the history, context and driving forces of polymetallic nodule project development. An overview of DeepGreen?s Nauru Ocean Resources Inc. (NORI) project is presented along with a literature review of polymetallic nodule processing and the on-shore project development scope and plan at DeepGreen Resources is outlined.INTRODUCTION AND CONTEXT Polymetallic Nodules in the Clarion-Clipperton Zone Containing nickel, cobalt, copper and manganese, polymetallic nodules occur in most oceans of the world. The nodules lie on the seafloor sediment. The largest deposit in terms of nodule abundance and metal concentration occurs in the Clarion-Clipperton Zone (CCZ) on vast abyssal plains at a depth of 4,000 to 6,000 metres. The CCZ is located almost entirely in international waters as presented in Figure 1. It has been estimated that the CCZ contains (International Seabed Authority, 2010): •,>21 billion tonnes of nodules; •,>270 million tonnes of nickel; •,>6 billion tonnes of manganese; •,>234 million tonnes of copper; •,>46 million tonnes of cobalt. There are several active hypotheses for the mechanism of formation of the nodules including precipitation, hydrothermal decomposition of basaltic debris, and involvement of microorganisms. Nodules require a nucleus to start forming, which could be a piece of pumice, a shark tooth, old nodule piece, basalt debris or even microfossils like radiolaria and foraminifera. Nodules form concentrically with layers of iron and manganese hydroxides around a core. Although composed mainly of Mn, Fe, silicates and hydroxides, it is the significant content of Ni, Cu, Co, Zn and Rare Earth Elements (REE) that is generating the economic interest in harvesting these deposits. Nodules vary in size from micro-nodules to about 20 cm, the common size being two to eight centimeters. A typical polymetallic nodule and polished cross-section is presented in Figure 2."

Jan 1, 2017

By Jie Deng, Wenliang Xiong, Binyan Chen

"With falling rare earth metal prices, low cost beneficiation of rare earth minerals is essential. The “Flotation-Agglomeration-Magnetic” (FAM) separation process is a newly developed technology by IMUMR to economically recover rare earth elements from different types of deposits. The theory of FAM process is to selectively agglomerate rare earth particles and separate from gangue minerals by bubble flotation process. The flotation product is further upgraded by magnetic separation. The FAM process has been successfully applied in industrial production on the Dalucao rare earth ore, Sichuan, China. The average REO grade of rare earth concentrate is 65% in the latest 12 month production run, with an average recovery of 55%.INTRODUCTIONRare earth elements (REEs) include fifteen lanthanide elements coupled with two chemically similar elements (yttrium and scandium). These elements are split into two sub-groups, La to Sm are classified as light rare earth elements (LREEs) and the remaining elements including yttrium are heavy rare earth elements (HREEs) (Kumari & Panda, 2015). The demand of rare earth elements surged in recent years due to their increasing usage in diverse industrial aspects including high strength magnets, phosphors, clean energy, polishing compounds and catalysts (Goley &Scott, 2014).More than 250 REE-bearing minerals have been discovered, but many minerals are with very low concentrations of REEs, varying from 10-300 ppm (Adam &Ping, 2013). The most common rare earth minerals mined are bastnaesite, monazite, xenotime and ion-adoption REE (Chelgani & Rudolph, 2015; Kanazawa & Kamitani, 2006). Before the 1960s, most rare earth resources were extracted from monazite in the beach placer, with the exploiting of Mountain Pass in the United States and Bayan Obo mine in China, bastnaesite became the chief mineral source of rare earth resources (Klinger, 2015). These minerals are commonly separated with gangue minerals by froth flotation, gravity concentration, magnetic separation, or any combination thereof based on their specific physical characteristics (Zhou & Wang, 2014; Adam & Richard, 2014; Yang & Satur, 2015; Xia & Brian, 2015a,b)."

Jan 1, 2016

By S. Beskri, N. Geoffroy

When metallurgical plants are designed, a lot of consideration is almost always given to material selection and possible damage mechanisms. Materials engineers are generally involved and will strive to select optimal alloys or refractories for the design conditions. Once in operation however, things often change. Equipment is overstressed to increase production, corrosive leaks are not always promptly addressed, proper welding procedures are disregarded, etc. This paper describes various cases from the mining and metals industry where serious mishaps, associated consequences, and costs could have been avoided if simple and proactive steps had been taken. It also presents a strategy, based on safety reviews, to help predict and prevent damage to critical pieces of equipment.

Jan 1, 2015

By F. Habashi

"While bioleaching of pyrite concentrates has been successfully used in industry to liberate gold from the sulphide matrix for subsequent cyanidation, the same technology cannot be recommended for leaching chalcopyrite concentrates for copper recovery. It will be shown to be uneconomical and cannot compete with pressure leaching technology. Data on the pilot plants that were constructed for this purpose and were shut down will be given.INTRODUCTIONBacterial leaching has been successfully applied for heap leaching of low-grade copper ores (Habashi, 1978, 1999). One of the major operations is that at Bingham in Utah (Figure 1). The leach solution collected at the bottom of the heap is extracted by organic solvents and the strip solution is electrolyzed to get high purity copper. The process was extended to treat auriferous pyrite concentrates to liberate gold and render it amenable to cyanidation by a process known as BIOX (Marsden & House, 2006; Lunt & Briggs, 2005).BIOX plants currently or recently in operation are the following:??Ashanti Goldfields Company, Ghana. Designed with an initial capacity of treating 720 tonnes of concentrate per day, the Sansu plant has since been expanded and currently has four modules processing 960 tonnes per day in all. It is by far the largest biooxidation plant in the world. The capital cost of the plant totalled US $25 million (1994 terms) and the operating cost is currently US $17/tonne milled.??Fairview, South Africa. The plant at the Fairview mine in Barberton, which was the initial pilot plant, has been fully operational since 1986. It was originally designed to treat 10 tonnes/day of concentrate but with the success of the project this has been increased to 55 tonnes per day. With the purchase of Fairview by Avgold’s Eastern Transvaal Consolidated, Avgold concluded a licensing agreement with Gold Fields, formerly known as Gencor, entitling it to use the BIOX technology to treat itsconcentrate.??Saõ Bento, Brazil. A BIOX plant was recently in operation in Brazil at the Saõ Bento Mine where a pressure oxidation circuit is used to treat the refractory flotation concentrate. This plant has confirmed the viability of combining bio-oxidation with pressure oxidation as a cost-effective method ofincreasing capacity at an existing oxidation plant.??Wiluna, Australia. The plant at Wiluna Gold Mine, Western Australia, was commissioned in 1993. Although originally designed to treat 115 tonnes per day of concentrate this has subsequently been increased to 158.??Other plants at Tamboraque in Peru, Harbour Lights and at Youanami in Australia have been commissioned recently."

Jan 1, 2012

By Kati Tschöpe

Cathode wear has become an increasing challenge in the aluminum industry due to the use of more graphitized materials. Today, there exist no standard laboratory methods for measuring cathode wear where different commercial materials can be ranked. The typical average wear rate in an electrolysis cell is quite small. The aim of this work was to design a test method where the wear could be accelerated compared to industrial cells. It was focused on polarized tests where the cathode is exposed to electrolyte, which gives higher aluminium carbide solubility. The cathode materials were characterized by microscopy and image analysis.

Jan 1, 2011

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

By L. E. Young

"The Red Dog deposit of the western Brooks Range, Alaska was discovered in the 1970s. Two mineralized areas are present, the Main and Hilltop deposits. With indicated and inferred reserves of 77 million tonnes of 17.1% zinc, 5.0% lead and 82 g/ tonne silver, the Main deposit of Red Dog represents one of the world's largest zinc-lead deposit s. Since serious evaluation by Cominco commenced in 1980, a better understanding of deposit geology has been gained through 10 715m of diamond drilling and concurrent geologic, geophysical and geotechnical studies. The Red Dog deposit is of Mississippian to Pennsylvanian or Early Permian age, and straddles a redox transition in fine-grained and chemical sediments of the Red Dog structural sequence.The Main deposit has been modified by regional Mesozoic thrust faulting and isoclinal folding, resulting in complex interrelationships between silica rock, sulphide rock and barite. Multiple lines of evidence suggest the Main deposit contains both a syngenetic stratiform and a replacement component. Ore fluids were probably derived by regional lateral movement of brines through a coarse clastic footwall aquifer, then upwards along block faults to the site of the Red Dog deposit.Historical PerspectiveThe region in the vicinity of the Red Dog deposit (Fig. 1) was first prospected by J. W. Kelley in the late 1880s (Orth, 1967). The first coordinated inland exploration was conducted by the U.S. Geological Survey in 1910-1911 and 1923-1926 (Smith, 1913; Smith and Mertie, 1930). The earliest reports of zinc-lead mineralization in the region include reference to samples collected at unknown locales by Eskimo prospectors (Anderson, 1944). In 1955 stratiform pyrite was discovered 19 km west of Red Dog by I.L. Tailleur of the U.S. Geological Survey (Tailleur, 1970). The first reported visit to what is known as Red Dog was by I.L. Tailleur in 1968, who was field checking a colour anomaly noted by B. Baker, a local bush pilot (Tailleur, 1970; Moore et al., 1986) ."

Jan 1, 1989

By K. Enns, J. J. Byerley

"While thiocyanate (SCN-) is used in a number of industrial processes (production of polyacrylonitrile filaments, synthesis of agricultural chemicals and certain metallurgical solvent extraction and flotation circuits) it is recognized more as an undesirable by-product associated with ' the metallurgical industry. Thiocyanate is present at low concentrations in some waste streams from the iron and steel industry. Of particular significance is the formation of thiocyanate during cyanidation of gold and silver ores, concentrates, tailing s and residues. The thiocyanate levels present in the resulting effluents may range from a few mg/I to several thousand mg/I.At present, thiocyanate does not appear to be as hazardous in the environment as cyanide (CN-) at the same concentration although its interaction with other species and resulting decomposition of products may be unacceptable. Of course the presence of thiocyanate in the leaching circuit and ultimately in the effluent streams may add considerably to the oxidative requirments of any non-selective treatment process for cyanidation wastes.With respect to the thiocyanate as it relates to the cyanidation process, two aspects are evident. Thiocyanate forms and persists in the cyanidation circuit resulting in a ""fouling"" condition with subsequent loss of leaching activity. In order to reduce or control this problem, it is common practice for some mills to discharge daily as much as 20% of the barren leach liquor. Besides contributing to fouling of the leach liquor the formation of thiocyanate represents an irreversible loss of reagent cyanide. It is noteworthy that in some present or proposed mill practice reagent cyanide loss through thiocyanate formation may reach 50%(1). The purpose of this paper is to discus s the application of controlled electrooxidation of thiocyanate with the view of suggesting a process for regenerating cyanide from waste thiocyanate(2). The paper describes the important theoretical aspects and presents experimental data obtained for thiocyanate electrooxidation using both small and large scale electrochemical reactors. Some economic conclusions are presented."

Jan 1, 1984

By J. M. Skeaff

"The main solution, ore and residue pulp streams in the Rio Algom Quirke I uranium mill at Elliot Lake have been sampled and analyzed for radium-226. Analysis of the ore and leached residues indicates that Ra-226 dissolves and precipitates within the first pachuca tank. A maximum of approximately 0.2% of the Ra-226 in the ore remains in solution during leaching.IntroductionConcern over the acid drainage and radionuclide dissolution problems associated with uranium tailings disposal sites in Canada has prompted investigation into methods for improving current uranium processing practice.Present commercial practice usually involves leaching of the uranium ore with sulphuric acid, ion-exchange separation of the uranyl sulphate complex from the leach liquor and"" precipitation of the uranium as yellowcake. Daughter products of U-238, such as Th-230, Pb-21O and Ra-226 remain with the tailings and undergo long-term dissolution.Table I summarizes the probable behaviour of the radionuclides during milling. The concern here is with Ra-226, because it will deposit in the bones if ingested and is ""thus considered a serious health hazard(1), Similarly, Po-218 and Bi-214, which are daughter products of Rn-222, can be retained in the lungs and are considered to be the principal sources of radiation dosage(2) arising from the inhalation of Rn-222. Previous investigations(3-9l indicate or imply that Ra-226 undergoes redistribution during milling. However, detailed published information on the behaviour of Ra-226 in the uranium milling process appears to be lacking. A knowledge of the behaviour of Ra-226 in uranium mills, particularly during leaching, could lead to improved methods for its control.This paper reports the occurrence of Ra-226 in the Rio Algom mill. The main objectives of the study were to determine (1) the distribution of Ra-226 within the solids, (2) at what point, and how rapidly, redistribution occurs and (3) whether there are high concentrations of Ra-226 in solution."

Jan 1, 1981

By P. W. Percival, J. J. Janssens

"Whitehorse Copper is a 2600-ton-per-day underground copper mine located within the city limits of Whitehorse, Yukon . In early 1978, due to increasingly difficult ground conditions. it was decided to investigate the conversion from longhole open stoping to vertical crater retreat mining. On-site crater testing by C-I-L demonstrated the feasibility of V.C.R. mining at Whitehorse Copper.After some investigation. a down-the-hole drilling rig was chosen and drilling began in November /978. Blasting began in June /979. and to September 1980 approximately one million tons of ore had been blasted. In-field changes to both drilling and blasting techniques have been implemented. Some of these changes were dictated by problems encountered; others were made to improve efficiencies.To date. V.C.R. mining has proven successful from a drilling and blasting aspect.IntroductionWhitehorse Copper Mines Ltd ., a division of Hudson Bay Mining and Smelting Co., Limited , is a 2600-Lp.d. underground copper mine. The plant site is located I mile west of the Alaska Highway, and approximately 7 miles south of Whitehorse city center. Production is from the Little Chief orebody, and total output is from vertical crater retreat stopes.The Little Chief and Middle Chief orebodies at Whitehorse Copper had original reserves in excess of 6 million tons, most of which graded 2.00/0 copper or higher . The orebodies are typical skarn deposits that have developed along the contact between an intrusive diorite and a limestone-quartzite flank pendant. The limestone has been metasomatized to form a calcium-magnesium skarn which, along the limestone / quartzite contact, has locally further developed into a mineralized magnetite-serpentine skarn. The principal copper minerals are bornite and chalcopyrite, with minor chalcocite and valleriite. Skarn gangue minerals are serpentine, diopside, garnet, epidote, calcite and wollastonite. Appreciable values in gold with some silver are present and recovered as well."

Jan 1, 1981

By Ludwig Strah

"The paper outlines the history of rubber mill liners beginning with the awarding of the first North American patent rights in 1923. It includes the early-day applications and installations of the 1920s and 1930s through to their present-day application. Over-all rubber mill liner design is discussed in relation to present day installations employing rubber mill liners in various grinding applications. A brief overview is given of a manufacturer's procedures to produce rubber mill liners.IntroductionIn early 1910, it became apparent that the productive life of the silver mines in Cobalt, Ontario, could be substantially prolonged by mining lower-grade ores.The mining of lower-grade ores required the establishment of treatment facilities which initially employed jaw crushers, stamp mills, jigs and concentrating tables. The recovery of silver in other than a coarse metallic form required the additional step which was introduced at that time: the cyanidation of silver concentrates from the tables. The resultant requirement for increased and improved recovery led to the introduction of grinding mills, i.e. tube mills.Shortly after the introduction of the tube mills to the Nipissing Mine's mill in 1914, the idea of using rubber as a mill liner material was spawned. However, no action was taken due to the advent of World War I. It is interesting to note that the idea of rubber mill liners emanated from having used pieces of solid rubber tire as an emergency repair on a set of liners when a liner had broken and no immediately available spare was on site.The credit for this ingenuity and subsequent application for a patent on rubber mill liners falls to James John Denny, the mill superintendent, and Rolla Barnum Watson, the general manager of Coniagas Mines Limited. The patent application was formally made on December 3, 1921. The U.S. Patent Office issued Patent No. 1,470,597 on October 16, 1923."

Jan 1, 1982

By Simon Houlding

"Part 1 (CIM Bulletin, August 1991) of this article identified the limitations of the traditional modelling methods and demonstrated the approximations and errors introduced by their application to complex mining situations. The objective of Part 2 is to describe the evolution of new, proven technology which eliminates these deficiencies and provides precise and practical alternatives. These promote the use of realistic geological and mining shapes and eliminate altogether the rectangular approximations of traditional methods. Limitations of the Traditional MethodsThe limitations of the traditional modelling method s (viz. simple block modelling, gridded modelling and their more recent variations) were discussed in detail in Part I . These methods are all based on the use of rectangular discretization to represent the boundaries and volumes of ore deposits and mining excavations. As a result they are unsuited to the representation of nonrectangular geological complexities such as folding, faulting and irregular surfaces . They are equally unsuited to the representation of realistic excavation limits, particularly in the case of underground mining.Recently these methods, with limited variations in technique, have been applied to increasingly more complex geological and mining situations. The resulting potentials for error and conflict within the modelling pro cess were demon strated in Part I . The effects can be summarized as follows:• volume and boundary approximations introduced by therepresentation of irregular three-dimensional boundaries andvolumes by rectangular modelling elements ; • geostatistical errors and conflicts caused by neglect of the relationships between grade estimates and the geometric/ spatial aspects of irregular volumes and associated observations (samples), including an inability to produce precise estimates with meaningful confidence limits;• a compounding of these effects by using rectangular element sizes other than the geostatistical optimum, and by using differentelement sizes within a model; and• general inefficiencies introduced throughout the modelling pro cess by the requirement to represent geology, grade distribution and excavation limits with a singular modelling method and model."

Jan 1, 1991

By P. E. Weidmark

"PART I - Published PapersBallivy, G., and Dupuis, M., ""Laboratory testing for the design of grouted rock anchors""; Proc 6th Pan Am Conf Soil Mech Found Eng; Lima; 1:277-291; 1979.Ballivy, G., Ladanyi, B., and Gill, D., ""The effects of moisture content on the strength of fissured rocks""; Proc 1// 1ntnl Congr 1.A.E.G.; Madrid; //:2:7-16; 1978.Baumgartner, P., and Stimpson, B., ""Development of a tiltable base friction frame for kinematic studies of caving at various depths""; Int J Rock Mech Min Sci Geomech Abstr; 16:4:265-267; 1979.Bawden, W.F., and Roegiers, J.-c., ""Discussion and interpretation of the mathematics governing radial flow in a single horizontal rock fracture""; ISBN 07727-7002-6; Dept Civil Engng publication 79-11; Univ Toronto: 134p;1979.Chatterji, P.K., Smith, L.B., and Insley, A.E., ""Construction of Saline Creek Tunnel in Athabasca oil sand""; Can Geotech J; 16:1:90-107: 1979.Coates, D.F., and Gyenge, M., ""A case history of pit slope design""; Proc 4th ISRM Congr; Montreux, Switzerland; Sept 1979; 1:Theme IV:591-596; 1979.Crawford, A.M., and Curran, J.H., ""A dynamic direct shear machine for determining the time-dependent behaviour of rock joints"": Dept Civil Engng publication 79-08; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A displacement discontinuity approach to modelling the creep behavior of rock and its discontinuities""; Dept Civil Engng publication 79-09; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A higher-order displacement discontinuity element""; Dept Civil Engng publication 79-10; Univ Toronto; 1979.Cruden, D.M., ""A computer-based system for rock mass description""; Proc 1// Intnl Congr I.A.E.G.; Madrid; //:2:155-159; 1978.Cruikshank, D.J., and Curran, J.H., ""A.B.LE. approach to modelling of fluid flow in fractured rock masses""; Proc 7th Cdn Congr Appl Mech; May 1979; Sherbrooke, Que; 887-888; 1979."

Jan 1, 1980

By Erwin L. Zodrow

"For 25 chemical elements in electrostatically precipitated fly ash (Lingan coal-fired power station), concentration changes are studied as a function of increasing proportions of fines (ash particle diameter less than 45 micrometres). Elements that are involved when concentrations increase as the proportions of fines increase are likely to escape into the atmosphere. These are Th, U, As, S, P, Sb, Na, Ag, Zn, Pb, Ni, Ba, Sc, AI, Mo (and Bi, Ge, Ga, F and Li), i.e., more or less highly volatilized elements. Of the less volatilized metals such as Fe, Ca, Cu, Ti, K, Co, Mn (and lanthanides), certain portions presumably also escape as stack emissions. Diadochy and spinel formation in bottom slag is presented as an emission-reducing agent for certain metals.IntroductionThe Lingan coal-fired power generation plant, owned and operated by the Nova Scotia Power Corporation, produces annually about 140,000 metric tons of ash (the residual mineral content after burning coal). The tonnage is based on a 15 per cent average ash content of Cape Breton coal.For purposes of this report, samples of the hard, fused slag (bottom slag) that is accumulated at bottoms of boilers, and electrostatically precipitated fly ash (ep ash), were collected and investigated. Bottom slag is a minor component of the produced ashes.The ashes were surveyed and the presence of over 75 major, minor and trace elements is reported. From this survey, 25 elements were selected to establish elemental enrichment/depletion trends when the proportions of the less than 45 micrometre <45µm) fractions in ep ashes increase. The results are significant in that, taking the case of elemental enrichment, the elements involved are likely to escape into the atmosphere, i.e, highly volatilized elements. Depletion trends for elements are presumably associated with less volatilized elements during coal-firing. Quantification of the emission of atmospheric pollutants is not considered part of this work. ""Igneous"" minerals generated during coal combustion include spinels (found mainly in the bottom slag), quartz, glass and mullite."

Jan 1, 1982

By H. M. Giegerich

"INTRODUCTIONThe Red Dog Project in Alaska is being developed by Cominco Alaska, a subsidiary of Corninco Ltd. of Canada, and the Nana Regional Corporation, one of the 12 native corporations created by the Alaska Native Claims Settlement Act of1971.The State of Alaska is also a very key part of the project through its financing of the transportation system for Red Dog. Red Dog will be the third, and largest, of Cominco&apos;s Arctic mining developments in the past thirteen years, after the Black Angel Mine in Greenland, which started up in 1973, and the Polaris Mine in the Canadian Arctic, which began production six years ago in 1982.Red Dog is one of the world&apos;s great mineral deposits, with a unique combination of large size, high-grade, and a waste-to- ore ratio less than I: I, which will make it the world&apos;s largest, and one of the lowest cost zinc producers, when at full production. The present mineral reserve is estimated to be 85 million tons , at a grade of 17.1010 zinc, 5% lead, and 2.4 ounces per ton of silver. Based on the current production forecast, this will give a mine life of almost 50 years, and the deposit is still open in two directions, although the structure is becoming thinner at depth. As well, there is a satellite zone about one mile south of the main deposit which could contain up to another 8 million tons of mineral at Red Dog grades or better. This is not presently included in the reserve due to potential processing difficulties.In relation to other zinc deposits, Red Dog is the second largest ever discovered, smaller than the original Broken Hill deposit in Australia, but larger than Cominco&apos;s own Sullivan Mine in British Columbia, which is number three. It is quite possible that, when the area is adequately explored, Red Dog will be number one."

Jan 1, 1989

By Wei Zhang, Jinhong Zhang

"The adsorption of ethyl xanthate on copper sulfides, i.e., chalcopyrite, chalcocite and bornite, has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). AFM images show that xanthate, such as potassium ethyl xanthate (KEX), adsorbs strongly on chalcocite and bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is totally different from the one obtained with chalcopyrite/xanthate system, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The findings obtained from the present AFM study suggest that an AFM image analysis is a powerful tool for the study of the collector’s adsorption on mineral surface and as well the development of novel collector for copper sulfide flotation.INTRODUCTIONIn mining industry, copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite, are usually separated selectively from non-valuable gangue by froth flotation, which treats the highest throughput and produces the maximum economic outcome of any surface chemistry process. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineralbubble attachment and thus a high flotation recovery.The adsorption of collector on mineral surface, therefore, is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2016

By J. F. Perreault, J. Paraszczak

"The profitability of an underground mine depends to a great extent on the production cost.Random equipment failures and their consequences have significant influence on the total operating cost of a mining system. Having this in mind, a reliability study has been initiated for loadhaul- dump machines in an underground mine. The main purpose of this study is to identify the critical machine subsystems, determine their failure pattern and help work out an effective maintenance strategy. In the first part of this study, the failure data of diesel powered LHDs, gathered during an I8-month period have been analyzed. For the purpose of the analysis, the machines have been treated as systems comprising seven subsystems connected in series. The most critical subsystems, i.e. electrical and hydraulic, were further investigated, and analyzed by graphical and analytical methods. Different failure distribution models were applied and discussed. Basic Defmitions and ConceptsIn order to avoid confusion, several terms used in this paper are defined below, as compiled by O&apos;Connor (1991). The acronymsBS and MIL-STD stand respectively for: British Standard and US Military Standard.Failure: the termination of the ability of an item to perform a required function (after BS 4778).Time Between Failures (TBF): the length of time between two consecutive failures.Observed Mean Time Between Failures (MTBF): For a stated period in the life of an item, the mean value of the length of time between consecutive failures computed as a ratio of the cumulative observed time to the number of failures under stated conditions (after BS 4778).Maintenance, Corrective: The actions performed, as a result of failure, to restore an item to a specified condition (after MIL-STD-721 B).Maintenance, Preventive: The actions performed in attempt to retain an item in a specified condition by providing systematic inspection, detection and prevention of incipient failure (after MIL-STD-721B)."

Jan 1, 1994

By Wayne D. Goodfellow, William M. Luff, Steven J. Juras

Brunswick No. 12 is a vent-proximal massive sulfide deposit that formed above a feeder pipe with associated hydrothermal alteration. Because of the replacement of bedded sulfides deposited above the hydrothermal vent, individual sulfide lenses show the following vertical and lateral zoning outward from the vent complex: massive pyrite-pyrrhotite-ehalcopyrite core interlayered pyrite-sphalerite-galena (pb-Zn ore zone) - bedded pyrite. The feeder zone which underlies the Cu-rich core consists of an anastomosing network of pyrite-pyrrhotite-chalcopyritequartz veins with variable and generally minor contents of ferroan carbonate, Fe-rich chlorite, sphalerite, galena and arsenopyrite. Hydrothermal alteration of felsic igneous rocks hosting and adjacent to the feeder pipe is represented by an inner zone (zone I) characterized by sulfide stringers, Fe-rich chlorite, muscovite, quartz, and ferroan carbonate that formed at the expense of feldspars and what was probably glass; outer zones (II and III) are represented by Mg-rich chlorite and muscovite formation, and the albitization and silicification of K-feldspar. Accompanying these alteration trends is a marked decrease of Na + Ca, and an increase in Fe + Mg + C03 in zone I, and increases in Mg + Na in the outer zones. The classic zoning of metals within the sulfide lenses, the formation of a feeder pipe below the vent-proximal sulfide core, and the hydrothermal alteration of felsic volcanic rocks cut by the feeder pipe all support a vent-proximal origin for the Brunswick No. 12 deposit. Furthermore, restriction of sulfide stringer mineralization to the footwall sequence, the folding of the stringer zone by an F, fold, and the difficulty of long distance mass transfer of metals from the sulfides into the host rocks all argue against a tectonic origin for the stringer zone. All of the evidence indicates that the feeder pipe formed during the ore forming hydrothermal event, but has been distorted and in some areas detached from the overlying massive sulfides during subsequent deformation.

Jan 1, 1992

By Roy EI. Durr, Glen R. Davidge

"This paper presents the results of structural analyses and full-scale destructive tests conducted on liner plate culverts. The purpose of this work was to establish a design method and evaluate the suitability of using these structures in potential roof-fall areas for a rehabilitation application in lower stress and relaxed mining environments. Field evaluation of the design is currently in progress.Theoretical ultimate resistance functions were established for two different culvert shapes and were found to be representative of their experimental behaviour. The ultimate resistance function was used to determine their plastic behaviour to a rapidly increasing deflection condition, to determine the energy absorption capacity of these structures, and to predict their response to impact loading.IntroductionThe Kidd Creek mine of Falconbridge Limited is located justnorth of Timmins, Ontario. The area under rehabilitation for which this program was developed is the 2600 level of the No. I mine. The problem of effectively securing selected drifts at the 2600 level in NO.1 mine, for access to a high-grade ore block, is key to the economics of the operation. Diamond drill test holes had indicated a loosened rock mass above the 2600 level of about 7.5 m thick in response to the extensive mining operation below this level. This level forms the arbitrary boundary between the No. I and No. 2 mines, and has extensive volumes of cemented rock fill below it and largely untouched ore above it to the 2000 level in the North orebody. The walls at that level were showing relaxed ground conditions typical of de-stress: sub-horizontal joints opening up, and peeling.Due to the ground conditions, the consequent safety risks, the high grade of the ore, the potential production delays, and the likelihood of several phases of rehabilitation, regularly used drift rehabilitation employing rock bolts, cable bolting, or shotcrete was not practical. Two options were deemed possible alternatives to suit these conditions, steel sets with blocking and lagging, and liner plate culverts with backfill. Culverts were chosen."

Jan 1, 1995