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By J. Lapointe, S. Leger, D. Proulx

"Une méthode non-électrolytique est utilisée pour plaquer au cuivre la fibre d'amiante chrysotite. En variant les paramètres de placage du bain, on détermine les conditions optimales du taux de deposition du cuivre . Une analyse par diffraction aux rayons-X permet une comp araison relative des résultats de placage et de précipitation d'oxyde cuivreux dans Ie bain. Le traitement de placage a pour but d'assurer une adhésion suffisante de la fibre dans une matrice métallique Iors de la fabrication éventuelle de materiaux composites.IntroductionCette communication se veut un compte-rendu de nos travaux sur Ie placage au cuivre de la fibre d'amiante chrysotile, en vue de I'incorporer éventuellernent dans une matrice métallique. La fibre d'amiante est constituée de fib rilles élementaires d'un diamètre d'environ 0.02 um qui ont une résistance en tension de I'ordre de celie de la fibre de verre ou de carbone(1). Pour être efficace, la fibre de renf'ort d'un matériau composite doit d'une part, avo ir des propriétés mécaniques intrinsèques élevées, et d'autre part, adhérer solidement â la matrice pour que Ie transfert de charge s'effectue sans qu'il y ait décohésion entre les composantes du matériau.La fibre d'amiante étant naturellement soyeuse, il faut la traiter superficiellement pour que l'adhésion avec la matrice soit suffisante. Ainsi, on recouvre la fibre de phénol-formaldéhyde(2) ou de silane(3) lorsqu'elle est employée avec une matrice polymere. Dans Ie cas d'une matrice métallique, ces dépôts organiques ne peuvent resister aux températures de mise en oeuvre, d'où l'intérêt de plaquer les fibres par un dépôt métallique.Dans cette étude, nous rapportons les résultats relatifs à la methode utilisée pour plaquer au cuivre la fibre d'amiante chrysotile. Une analyse par diffraction aux rayons-X permet de comparer les différentes conditions de placage non-électrolytique."

Jan 1, 1985

By Amyn S. Dahya, David J. King

"The object of the paper is to discuss the developments in Carbon-In-Pulp (C.I.P.) technology for gold recovery. The CIP process is comprised of four major operations:(a) adsorption of precious metals onto activated carbon;(b) elution (stripping) of precious metals from the loaded carbon;(c) electrowinning of the precious metals from the concentrated eluate;(d) regeneration of the eluted carbon before recycle to the adsorption process.A detailed review of the technological developments in each of the above operations is presented together with a brief theoretical background of the underlying processes. The advantages and disadvantages of the CIP process are discussed in comparison with conventional zinc precipitation. IntroductionThe carbon-in-pulp (CIP) process involves the use of activated carbon for treatment of pulps containing dissolved precious metals, and provide s an alternative to the conventional gold recover y processes using filtration or counter-current decantation in conjunction with the Merrill-Crowe zinc precipitation process. The commercial application o f the CIP process in gold processing technology is a fairly recent development and it is of growing importance around the world.The fact that activated carbon ha s the property of adsorbing precious metals from solution was first published in 1847. In the following years , a great deal of work was carried out to develop an over-all recover y process using carbon, but all attempts were uneconomical because the loaded carbon had to be smelted to recover the gold.It was not until 1950 that Zadra, at the United States Bureau of Mines Research Centre in Reno, Nevada, developed a technique for stripping the loaded carbon using sodium sulphite-sodium hydroxide mixtures and then recovering the gold from the stripping solution by electrolysis. However, this process was not effective for stripping silver and further testwork was carried out on alternative stripping techniques. In 1952, Zadra published a paper describing the use of a hot sodium hydroxide- sodium cyanide stripping technique, which was effective in stripping both gold and silver. This paper included a description and flowsheet for the CIP process which is essentially the same as we know it today. This technique was used in the first major CIP plant, constructed and commissioned in 1973 by Hornestake Gold Mining Company. Since then there have been numerous CIP plants built in the U.S A., South Africa and Australia."

Jan 1, 1983

By A. G. Pronk, D. M. Burton

"A regional till sampling program in the Upsalquitch Forks-Tetagouche Lakes area, centred some 70km west of the city of Bathurst, has proven an effective method for gold exploration in the heavily glaciated interior of northern New Brunswick. Prospecting activities within this area over the past three years, have led to the discovery of several gold occurences associated with quartz-carbonate alteration in a variety of intrusive rock types emplaced along major fault zonesQuaternary mapping shows that the glacial history is complex. However, the displacement of material is uniform in distance and direction, and the till is generally thin (0.5 m to 2.0 m) and locally derived, making the interpretation of till geochemical patterns relatively simple for the explorationist. Previous studies have shown the the fin e-grained gold is best detected in the -250 mesh (-0.063 mm) till fraction (clay plus silt) and that the C-horizon is the preferred medium for analyses.Samples were collected on a 2 km grid and analyzed f or Cu, Pb, Zn, Au, Ag, As, Sb, Mn, Fe, Ni, Co, and Cd. Results indicate that concentrations of 10 to 20 ppb Au can effectively delineate areas of anomalous gold in bedrock associated with fault structures, and that a good potential for discoveries exists to the west of the known occurrences, where up to 678 ppb A u has been detected in tills. IntroductionThis paper reports on the result s of surficial geological investigations conducted over the past two field seasons in north-central New Brunswick. The stud y area is located in the Upsalquitch Forks-Tetagouche Lakes map area s (N.T.S. 21 0 19 and 21 0 (10) 70 km west of the city of Bathurst (Fig. I). The area is situated on the margin of the New Brunswick Highlands and has a maximum elevation of 640 m (for a detailed description of the physiography, see Rampton et al. 1984).Historically, exploration in northern New Brunswick has concentrated on base metals within the Cambro-Ordovician Tetagouche Group, resulting in the discovery of man y significant massive sulphide deposits (Brunswick No.6 and No. 12, Heath Steele, Caribou, Armstrong Brook, Orvan Brook, McMaster, Murray Brook, and Restigouche). Auriferous base metal occurrences along the Rocky Brook-Millstream Fault have also been previously investigated."

Jan 1, 1988

By J. M. Whatley

"IntroductionFEW COUNTRIES equal Canada in the diversity of its mineral output, the range of size of its mine operations, and the extremes of climatic and topographic conditions under which its mining is carried out. Camps large and small are scattered over thousands of miles, some served by excellent communication lines, many in remote regions of the north. Common to most of the deposits is that they are worked by underground methods, and rely on adequate hoisting installations for the success of their operations.Hoisting in some form •pre-dates all other mechanical operations in mines and the hoist remains one of the most important pieces of equipment at the average mine. It provides the single line of communication along which must pass the men and materials to mine the rock, and in turn carry the ore to a place for refinement.Development of Mine Hoists in CanadaCanadian designed hoists were first built and •placed in operation about the year 1880 and have since developed in pace with the rapid growth of the Canadian mining industry. Early machines were all of the steam or compressed-air driven types, of light construction and driven by two duplex slide-valve open-frame type engines. As their application and size increased, designs became more rugged and more efficient."

Jan 1, 1955

By F. P. Agterberg

"IntroductionTHE KNOWLEDGE about the mineral resources in a region ranges from relatively precise ore-reserve estimates for known deposits to probabilistic estimates concerning the speculative resources which may be discovered in future at greater depths and in the less-explored parts of the region. Previously developed probabilistic methods for regional resource evaluation (1) are based on the following two assumptions.(1) The probability that a specific block of rock, or part of a region close to the topographic surface, contains undiscovered deposits can be estimate d by weighting selected geological, geophysical or geochemical parameters for that block. The weights are computed by considering similar environments which are known to contain deposits.(2) Some of the characteristics of the undiscovered deposits, such as ore tonnages and average grades of metals contained in the ore, can be evaluated by considering probability distributions f or known deposit data. These methods were initially applied to Precambrian deposits in the Abitibi Volcanic Belt of the Canadian Shield (1).Since 1972, statistical methods for quantitative resource evaluation have been applied to the occurrences of the mainly Paleozoic base metal deposits in t he Canadian Appalachian Region. The objectives of this project (Project Appalachia) have been discussed by Leech (2) in a paper that introduces 8 papers with results of the exploratory data analysis. Project Appalachia represents an effort to develop and apply methods of combining information and concepts from regional geology, metallogeny and geomathematics for computer- aided regional mineral resource evaluation."

Jan 1, 1977

By J. A. Chamberlain

DURING a recent trip across Canada and parts of the northern United States, the. writer examined some forty mine models. Construction -details and the uses to which the models were being put were outlined in a report to Eldorado Mining and Refining, Limited, and a specific model was proposed on the basis of the Company's particular needs at their Beaverlodge operation. It was felt, however, that portions of the report would be of some value to anyone contemplating building a mine model. For this reason, a synopsis of some of the more important aspects of the problem is presented here, together with a suggested model type that appears to have wide application. Thanks are due not only to Eldorado for permission to publish the following material, but also to the many mine personnel across Canada who allowed the writer to examine their models and gave freely of their time in discussion.

Jan 1, 1958

By J. W. Meier, J. O. Edwards, R. C. Bell

"IntroductionTHE DIE CASTING industry .as we know it today is the direct result of the invention and development of die casting machines during the nineteenth century and of reliable alloys in the twentieth. The early machines were designed to cast low melting point metals such as lead .and tin, and their alloys.It was inevitable that, as these die castings were put into service, the demand should arise for stronger materials. Zinc alloys, often containing lead, tin, copper, and aluminum as major constituents, were relatively easy to cast and stronger than the lead and tin alloys. However, it became apparent after a number of years that these zinc alloys tended to become brittle, distort, and corrode, particularly if kept in warm, humid atmospheres. Thus, considerable quantities of zinc-base .alloys were in use before the trouble was realized and effective measures could .be taken to determine the cause of the instability.The deleterious effect of certain metallic impurities on the properties of zinc •die casting .alloys has now been known for about thirty years. Brauer .and Peirce, and, later, other research workers of the New Jersey Zinc Company such as Anderson and Werley, discovered the pronouned effect of lead, cadmium, and tin on the stability of zinc-alloys."

Jan 1, 1952

By Paul Girard

"The copper property of Madeleine Mines Ltd. is in Lapotardiere and Boisbuisson townships, Gaspe North. The initial find was made in 1964, and subsequently a copper deposit of 5.3 million tons of ore was outlined. The property lies in Ordovician sedimentary and volcanic rocks near the major granite intrusive of the McGerrigle Range. The host-rock is a 300-foot-thick metamorphosed silty shale unit, close to the contact of the intrusive. The structure itself coµsists of a southerly-dipping monocline or the south limb of an anticline, on which a large dragfold has been imposed.Chalcopyrite, bornite and chalcocite are the principal sulphides present in the ore. Of particular interest is the zoning arrangement of these sulphides. The orebody is chimney-like in shape and appears to be a fracture-filling deposit that is genetically related to the granite intrusive and is confined within a highly fractured zone of very brittle rock. The deposit presents features uncommon to any of the other known copper deposits in the Gaspe Peninsula."

Jan 1, 1969

By G. R. Tostengard

"The paper identifies functional areas which frequently can yield significant productivity improvement. Emphasis is placed on the repair and maintenance, material supply and training functions. Successful approaches are discussed in some detail, and typical results which have been achieved are reviewed.IntroductionA challenge which at all times confronts the manager o f any mineral operation is the potential to improve his operation no matter how effective it might be a t the present time. The challenge has been present through my entire lifetime and I suspect a good many years prior to that and, I expect, will continue many year s and decades in the future. The competitive and economic situation in which we in the minerals industry find ourselves today makes the challenge eve n more important during the 1980s. In many cases it’s a question of survival, not simply pr of it improvement.There are, of course, many avenues to improving profitability; technological changes, new equipment and facilities, improved products, improved mine plans, etc. All of these are important and must be addressed by each manager. This paper focusses on just one avenue to improvement and that is ""improved management"", not so much of management at the boardroom level but of improved management o f the facilities and workforce as the y currently exist. Management implies control. There are three areas where control is often found lacking:1, Repair and maintenance of equipment and facilities;2. Material supply including procurement, inventory control and warehousing; and3. Training.These three areas are all complex and difficult to manage and they are all but ignored in the formal education which our industry's manager s normally receive. They are areas which can be improved with relatively small investments and therefore, they represent especially attractive improvement targets during the 80s when, for most of us, investment dollars are very difficult to come by."

Jan 1, 1983

By J. Ouellet

The design of hydrostatic liner for a deep potash mine shaft in Saskatchewan poses tremendous technological challenges. Technology has evolved to a point where one could consider a new innovative approach to hydrostatic liner design. But there is still a place for conventional technologies such as cast iron tubbings. As will be discussed in this paper, improvement to manufacturing process, installation procedures and even new materials can bring this technology to an excellent level of performance. With the spur of new projects in the potash industry of Saskatchewan, the authors worked in various shaft liner designs from the conceptual stage through to the construction phase. They were either directly leading the design work on some of these projects or acting as an external reviewer on others. Most of these shaft liner designs involved cast iron tubbing technology and ground freezing. The major challenge in sinking potash shafts in Saskatchewan is to go through a water-bearing ground formation under high pressure, known as the Blairmore or Manville fm. The only proven stabilizing technology for these formations is ground freezing. For a potash shaft, dry shaft conditions are highly desired, so a fully waterproof hydrostatic liner is required. All the existing potash mine shafts in Saskatchewan, except for two with composite steelconcrete lining, used the cast iron tubbing technology. Two new shaft tubbing liners have been constructed recently, one in the Athabasca Basin and one for a potash mine in Saskatchewan. When the authors began working on these new projects, what became quickly evident is that the technological knowhow for designing and constructing tubbing liners was no longer available within Canada and that the past construction methods used to sink tubbing lined shafts was obsolete. The tubbing liner for the shafts sunk in the sixties were designed either by German or British companies. In both of these countries only few tubbing lined shafts were sunk in last 40 years and the technology used in the sixties was not improved. There are only few countries where tubbing is routinely produced and installed: China, Russia, Ukraine and Poland. Out of these countries Poland is the one where this technology is the most advanced. The authors, working in close collaboration with engineers from Poland, attempted to rebuild this knowledge for the mining industry in Canada. This process involved thorough analysis of old technical reports, literature review and study of current polish design and construction practices as well as site visits of existing shafts. Through actual construction experience, some lessons were learned as well as ideas for improvements. In this paper, the authors will present a succinct review of design and procurement process. But, the practical aspects of the construction and installation methodology will be treated with more emphasis, more specifically the practice leading to good liner performance. Some of the poorly understood technical aspects of tubbing installation will be discussed more thoroughly and some currently accepted myths dispelled.

Aug 1, 2013

By Ian R. Muirhead

Over the past year or so, a number of mining companies have been meeting to examine the role of research in surface mining and, in particular, how to establish a collaborative research effort for the surface mining industry. A review has been completed which has identified the topics that are of interest to the surface mining companies for undertaking collaborative research. This has identified key subject areas such as Operations & Equipment; Maintenance; Environment & Reclamation; and Stability. Specific research projects for the initial research effort have been selected which include Wireless Data Communications, Analysis and Management; Application of GPS in Mining; and Tires for Heavy Haulers. In addition, attention has also been focussed on finding a suitable low cost, but effective, organization to coordinate and manage the collaborative research. The recently formed CONRAD Organization (Canadian Oilsands Network for Research and Development) appears to be a suitable candidate and discussions are ongoing with that group. This paper provides a summary of the review of surface mining research needs and of the status of the establishment of a collaborative research body for surface mining.

Jan 1, 1996

By M. E. Grimes

"The future of the uranium industry in Canada during the next twenty years will be very dependent on political and social issues on a world scale. Technology, as such, will tend to be of lesser importance. Nonetheless, some technical changes can be anticipated.This paper deals with milling of uranium ore, leaving further processing and nuclear power production to specialists in these fields. An attempt has been made to look at uranium production technology in Canada in relation to that in other countries, and to draw interference regarding future changes that seem probable in the Canadian context. In particular, recent advances in mill equipment are considered.The chemistry of uranium and its relatively low concentration in most ores has been responsible for a completely hydrometallurgical approach to mill processing, and this should continue. In spite of little commercial success to date, pre-concentration of lower grade ores will be researched further in order that these ores can compete with higher grade deposits in Canada.The discovery of the relatively high-grade ores of the Athabasksa region will undoubtedly influence choice of mill processes and equipment. The potential effect on innovations is discussed"

Jan 1, 1986

By F. K. McKean

Introduction The present paper may be considered as a sequel to a paper, A Process for Cleaning Molybdenite .Concentrate, which was presented by the author at the annual meeting of the Institute last year. In that paper, a description was given of the laboratory work leading up to the adoption of a new process for treating complex molybdenite ores of the Molybdenite Corporation of Canada. A bare outline of mill performance with the new flow-sheet was included. With this writing, the purpose is to describe the highly interesting work of translating laboratory experience into mill practice, to show what changes were required in design to put the scheme on an operational basis, and to point out the gratifying improvements in mill products which resulted from the new procedure. The process has been placed in operation at the La Corne mine of the Molybdenite Corporation of Canada. This mine was operated during the war by Wartime Metals Corporation, and, earlier, by the Molybdenite Reduction Company, which installed a small plant. The property is situated on the highway from Amos to Val d'Or, Quebec. The claims held by the Company are at the boundary between La Corne and Vassan townships.

Jan 1, 1947

By Cheryl Devine, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg

The microbial-mediated recovery of valuable metals locked in mining wastes presents an economical alternative to conventional hydrometallurgical processes. The present study investigated the bioleaching response of a low-grade nickeliferous pyrrhotite tailings (0.6 wt% Ni) and an upgraded pyrrhotite tailings (1 wt% Ni) produced by Vale Base Metals in the Sudbury Basin of Ontario, with the ultimate aim of maximizing Ni recovery. The initial part of the study focused on the bacterial adaptive evolution protocol, by repeatedly sub-culturing an indigenous culture from an acid mine drainage site on 2% (w/v) pyrrhotite tailings. The results showed that the extent of Ni dissolution is positively correlated with microbial activity. Microbial profiling revealed A. ferroxidans to be the dominant member of the microbial consortium. The enriched culture was used for optimizing the growth medium by varying the concentration of essential growth nutrients. Finally, an aerated biotic and abiotic leach of a 10% (w/v) upgraded pyrrhotite tailings with and without pH control, showed a higher recovery of Ni in the pH controlled experiments. These results demonstrate that a high concentration of the oxidant Fe3+ in solution promotes the dissolution of Ni. Furthermore, the sulphide conversion into So was found to be higher in the pH controlled experiments (32%), relative to the experiment without pH control (10%).

Jan 1, 2015

By P. O. Sandvik, George Erdosh

"AbstractThe Cargill phosphate deposit, located 32 kilometers southwest of Kapuskasing, Ontario, was discovered by the Resource Development Group of International Minerals & Chemical Corporation in 1975 and has been evaluated through an extensive program of 190 drill holes, numerous chemical analyses, metallurgical tests, and engineering and economic studies.The Cargill alkalic complex, comprising principally car-bonatite and pyroxenite-amphibolite rocks, was intruded in to the rift system of the Kapuskasing High during late Precambrian time about 1,800 million year s ago, near the intersection of northeast- and northwest- trending faults. The Cargill complex is one of at least ten known alkalic complexes in or close to the Kapuskasing magnetic-gravity-high system and is expressed by an elongated, northeast- oriented, three-part magnetic anomaly 7.2 kilometers long by 2.8 kilometers wide . Weathering and leaching under assumed temperate to cool, moist climatic conditions , and controlled by faulting, shearing and/or initial petrographic variations within the carbonatite , developed a small, locally confined karst system in the car bonatite rocks and resulted in a thick enriched leached carbonatite zone, capped by troughs and sinks, filled with a residuum of apatite, goethite, clay and other minerals stable in the near -surface, oxidizing environment. Overburden is 5 to 165 meters thick."

Jan 1, 1977

By S. Dessureault, M. Yildirim

More mining companies are now investing in IT, including updating one of the traditional IT process control tools used in the mining industry: real time in-pit truck allocation control and monitoring systems, or fleet management systems (FMS). These systems have been used to maximize the overall mine production by improving equipment utilization and reducing production costs. Most modern operations monitor the in-pit operations using GPS and wireless communications to produce data. Improvements in bandwidth, sensors, and computing power are causing modern systems to become more complex and generate more data. However, human analysis by simple regression or table generation in spreadsheets of the data is becoming impossible. Data mining solves this data management problem. Data mining finds patterns and relationships in very large data sets. This paper describes the application of modern data mining techniques on truck dispatching systems in a real open pit hard-rock copper mine. The analyses conducted included determining how the trucks performed under particular conditions and allocation systems. The long-term benefits of this work are to identify strengths and improvement opportunities in truck assignment systems and establish the skill sets and IT infrastructure needed in undertaking more complex datadriven technology such as a truck dispatcher trainer.

Jan 1, 2007

By E. V. Konopleva, H. J. McQueen

"The isothermal bainite transformation kinetics of low- and medium-carbon alloy steels after hot deformation and the rmocycling treatment (TC) has been studied by the magneto - metric method. Deformation was produced by rolling at 800°C-1000°C. TC included three cycles of rapid (30°C/s) electro-heating up to 900°C-1000°C followed by quenching.Hot deformation retards bainite transformation in the lower part of bainite range (<400°C) and accelerates it in the upper part (>400°C). The effect is greater for higher strain and lower deformation temperature. Deformation also diminishes the overall bainite fraction below 400°C and increases the completeness of reaction above 400°C.Thermocycling provides more uniform ultrafine austenite grains with average size of 3 µm -4 µm compared to 12 µm -14 µm after conventional heating. The transformation rate after TC was almost the same as after conventional heating in low-carbon steel but was faster in medium-carbon with no change in the completeness of reaction. The degree of acceleration increased with rise of transformation temperature.There are a number of factors which are responsible for a change in bainite transformation kinetics in austenite deformed at high temperatures or subjected to TC. One of the most important factors is the refinement of structure, another one is structural and chemical inhomogenity of austenite due to deformation or to rapid heating. To estimate the contribution of these factors, ?-transformation was studied after different austenitizing conditions (low-temperature heating at 850°C- 950°C; high-temperature heating at 1100°C; step treatment – austenitizing at 1100°C, then cooling to 950°C-850°C). The results obtained make it possible to conclude that the structural and chemical inhomogeneity of austenite activate the bainite reaction while the grain refinement retards it. Intensity of the effect produced by each factor depends strongly on the steel composition."

Jan 1, 1997

"The Val d&apos;Or Division now comprises the Lucien C. Beliveau Mine and Concentrator (formerly the Pascalis, described below) and the Chimo Mine. Cambior acquired an initial 50% interest in the Chimo Mine in May 1989 and the remaining 50% in April 1990. Cambior&apos;s share of 1989 production was 2121 ounces; the company expects to net 23 750 ounces from Chimo in 1990. Pascalis MineUPDATERenamed the Lucien C. Beliveau Mine at its official inauguration in September 1989, the mine is exceeding forecasts, producing over 11 500 ounces of gold in the first half of 1990. Cambior expects 1990 production to total 34 000 ounces.IntroductionThe Pascalis Mine is located 16 miles east o f Val d&apos;Or, Quebec, and is accessible by a three mile gravel road off highway 117 (Fig. I).The property is wholly owned by Cambior.The Pascalis gold deposit consists o f a sub-vertical diorite dyke 1000 ft long by 30 ft wide containing quartz and tourmaline veins with inclusions of pyrite and native gold . Three vein systems ca n be seen in the deposit , the most important being tensile veins oriented at a right angle to the direction of the dyke and inclined at 40 degrees. These overlapping veins vary in thickness from 4 in. to 40 in. and occur at intervals of six to ten ft. The deposit is, therefore, very difficult to evaluate; a complete evaluation would require drifts over the whole width of the dyke combined with relatively short drill holes (Fig . 2)."

Jan 1, 1990

By Magdy Ibrahim

This paper presents experimental design and development of a low-cost remote sensing hardware designed to support automated site data acquisition for near real-time progress reporting of construction operations. The developed hardware utilizes open source microcontroller equipped with multiple sensors that include 3D accelerometer, GPS, Data logger and Bluetooth. The use of open source microcontroller makes the developed design cost effective; freeing it from the need for costly license fees. Its platform configuration is flexible; enabling the addition of temperature, weight and other sensors, Wi-Fi and Xbee capabilities to suit individual field applications. Pilot tests have been carried out in laboratory and outdoor environments. The results prove effectiveness and robustness of the developed configuration. The paper provides description of the individual components used in the development of this prototype hardware. It also describes the technical characteristics, capabilities and limitations of the developed hardware. The findings of comparison with alternative technologies used for outdoor tracking of construction operations are presented. The comparison is carried out with respect to range, cost and suitability for outdoor environment. The developed hardware is expected to support a wide range of applications including tracking of earthmoving operations, highway construction and onsite resources. As well, it is expected to enhance safety on construction jobsites.

Aug 1, 2013

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Dialkyl dithiophosphinates are a unique class of collectors used in the flotation processing of Cu- Au, complex polymetallic, and precious metal ores. They are known to exhibit higher selectivity and flotation rates for Cu sulfides, galena, and precious metal values in the presence of other gangue sulfides, than the traditionally used collectors such as dialkyl dithiophosphates and xanthates. They also have an attractive HSE profile. Historically, for most reagents used in flotation, practical methods of chemical usage have preceded detailed scientific understanding of how they work; this applies also to dithiophosphinates. Recently, however, the research community has shown significant interest in this chemistry, and numerous studies have been conducted to understand the fundamentals of interactions of dithiophosphinates with several base metal sulfides and precious metals. A critical overview of fundamental studies, laboratory ore flotation, and plant practice of dithiophosphinates is given in this paper. The findings from these studies are rationalized by drawing on concepts and insights from coordination chemistry. A comparison between the interactions of dithiophosphinates and dithiophosphate analogues with various minerals and metals is also made throughout. We believe that such a critical analysis/overview will be invaluable in identifying gaps in knowledge regarding this important set of compounds, which in turn may provide a basis for the design of studies that can advance understanding of their flotation performance. INTRODUCTIONDialkyl dithiophosphinates are an important member of the class of thiophosphorus compounds that are widely used in flotation beneficiation of base metal sulfide and precious metals ores. Ore flotation studies and plant practice experience have demonstrated their unique properties compared to the traditionally used sulfide collectors such as dialkyl dithiophosphates (their closest analogues) and xanthates. The predominant dialkyl dithiophosphinate used in the industry today is sodium diisobutyl dithiophosphinate (a.k.a. DIBDTPi; AEROPHINE® 3418A1 introduced by American Cyanamid in the late 1970s; Figure 1). The widest application of AEROPHINE 3418A is found in complex polymetallic ores of Cu-Pb-Zn-Ag, Pb-Zn-Ag, and Cu-Zn where it has demonstrated improved recoveries (and flotation rates) of sulfide minerals of Cu, Pb and Ag and selectivity against sphalerite, iron sulfides, and penalty elements (Mingione, 1991). More recently, it has also been used as a collector in the processing of Cu, Cu-Ni, and Ni ores (Guitard et al., 2015) and Cu-Au ores (Dunne, 2005). In general, it is considered to possess the collecting power of xanthates together with the selectivity (against pyrite) of dithiophosphates (Hope et al., 2003a, 2003b), while requiring lower dosages than those reagents (Guitard et al., 2015). AEROPHINE® 3418A has also found an important place in several targeted formulations to improve flotation performance. Other benefits of this reagent include higher flotation rates, having a better HSE (health, safety and environmental) profile2 compared to xanthate, and exhibiting resistance to hydrolysis and oxidation (Guitard et al., 2015). Compared to diisobutyl dithiophosphate (DIBDTP), which is known to contribute significantly to frothing (often leading to over-frothing), AEROPHINE® 3418A is observed to be froth neutral (i.e. it does not alter the existing froth characteristics). As is the case for other flotation reagents, the design and application of AEROPHINE® 3418A has preceded understanding of its behavior at a fundamental level. Recently, there have been numerous fundamental and application studies designed to develop a better understanding of its interaction with sulfide minerals and precious metals. This should help in optimizing its application in flotation and provide a basis to better rationalize its unique selectivity and activity characteristics. Past studies on the interacti"

Jan 1, 2016