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By Richard S. McCaffery, Joseph F. Oesterele

This investigation was undertaken to determine the quality of different iron blast-furnace slags as desulfurizing agents, and the possibility of using, in the blast furnace, materials of higher sulfur content than is now common. The solution of the problem would render possible the use of higher sulfur iron ores for pig iron and cokes containing more sulfur than now employed, and the economic manufacture of irons and steels of lower sulfur content. It is generally assumed that the sulfur that reaches the lower part of the iron blast furnace is removed from the pig iron by combining with lime to form calcium sulfide. Most of the sulfur introduced with the charge is in combination with iron or manganese or, perhaps in the coke, as a carbon compound.1 The iron and manganese sulfides are more soluble in the iron than is calcium sulfide, and as the latter is generally said to to be more soluble in the slag than the iron and manganese sulfides, this greater solubility of calcium sulfide in the slag tends to free the metal from sulfur. This greater solubility of the calcium sulfide is used not only to reduce the sulfur contents of the pig iron in the blast furnace, but by this means also low-sulfur steels are produced in the open-hearth and electric furnaces. The reaction2 FeS + CaO + CO = Fe + CaS + CO2 requires a high temperature and strongly reducing conditions in the presence of lime. The constitution of blast-furnace slags, first studied scientifically by Vogt13 indicated certain ranges of composition of the slag in which a

Jan 1, 1923

By John P. Cosgro

The increasing use of internal furnace-boilers for power-plants at mines (doubtless due to the facility with which they may be installed by reason of their portability; the fact that they require no masonry setting, cast-iron fronts, buck-stays, etc., and practically no foundation; and the successful maintenance of their claim to equal and even superior economy, as compared with boilers of other types1) warrants this description of a method of remedying an injury which may occur, to such a furnace, even though it satisfies the requirements of the formula adopted by the U. S. Board of Supervising Inspectors of Steam Vessels.2 I refer to the sagging and deformation which may result from overloading the boilers for a considerable period—say, several days. This is sometimes unavoidable under the exacting conditions of continuous day-and-night service, and (in spite of all rules and precautions) the occasional careless or unskillful work of attendants. Such a trouble is by no means unknown on shipboard, where this type of boiler is so largely employed.

Jan 1, 1906

By J. F. Wolff, Anson A. Betts

The following correspondence relating to a paper bearing the above title, presented by J. F. Wolff, at the New York meeting in February, 1917, and published in the Transactions, Volume LVI, page 142, has passed between the author of the paper, and Mr. Anson G. Betts, and is interesting, although it was received much too late for incorporation in its proper place in Volume LVI. Anson G. Betts, Asheville, N. C.—1. I should like to ask Mr. Wolff if he finds from analysis of the iron formation and of the iron ore, and from the relative amounts of each in each unit area of the formation, unleached and after leaching, that the iron remains entirely insoluble and the total quantity still remains present; or whether he finds that some of the iron is removed, or possibly even added by deposition from the water passing through the formation. 2. The water that passed into the iron formation had to go somewhere; was it absorbed by underlying formations through hydration, or, after passing through the ore formation, did it come to the surface in springs at a lower elevation, or how did it escape from the ground? 3. I should like to ask Mr. Wolff whether he finds that the iron formation in the sedimentary series does not come next to the quartzites and generally between the quartzites and slates. J. I?. Wolff, Duluth, Minn.—1. In common with others, you appear to have some hesitancy in accepting the fact of the removal, by solution, of the enormous quantity of silica which has been leached out of portions of the Biwabik iron formation, thus forming orebodies of merchantable iron ore. I believe that even Dr. Waldemar Lindgren once hesitated to accept this fact. However, the evidence is so simple and absolutely conclusive that the fact is established beyond all question. At the contact of orebodies with their rock walls, the bands of iron ore in the orebody can be seen in contact with the corresponding bands of original iron oxide in the rock wall, and the chert layers in the rock wall can be seen to give place to fine granular material (fine silica and iron oxide) and pore space. This is especially noticeable where slumping at the rock walls has not been so great as to displace the layers in the orebody from their contact with their corresponding layers in the rock wall. Although complete analyses of the entire original rocks in the iron series have not been made in any place, to my knowledge, from the best data at hand as to the average analysis of the Biwabik series and the

Jan 1, 1920

By A. A. Collins

When we speak of high copper on a lead blast furnace we think in terms of 4 to 5 pct, or. any lead charge carrying over 1 pct. Any copper on charge will produce its corresponding troubles such as lead well, extra slag losses, drossing problems, and the working up of the dross. This is indeed a very interesting subject and one that used to give the old-time lead metallurgists such as Eiler, Hahn and lles many worries, not so much in the actual operation of the hlast furnace but in the working up of the copper. When the American nletallurgists commenced with the American rectangular-shaped lead blast furnace in the 1870's and got away from the reverberatories such as were in use in Germany and other parts of the world, they went to greater tonnages, as 80 to 100 tons per day in comparison to the 20 to 30 tons per day in the other processes. With the greater tonnages along with insuficient settling capacity, the silver losses in some cases were increased. Hence the lead-fall was low, for there were no leady concentrates in those days to assist the metallurgist to gain lead or an absorber for the precious metals; and in some cases copper sulphides were added intentionally to the charge to produce a copper matte to lessen the silver losses through the dump slag. The operators in those days thought that where some copper was always present in the lead ores the copper should not enter into the reduced lead and alloy with it. This, by the way, is just the reverse of our present-day practice, when we try to put all of the copper into the blast furnace lead and to remove the same through the drossing kettles. Therefore the furnace was operated to produce a certain amount of matte or artificial sulphides, since, due to the great affinity of copper for sulphur, any copper present would enter the matte almost completely. Thus, the lead bullion produced was practically free from copper. The products of the furnace were metallic lead or lead bullion, containing 05 to 95 pct of the lead and about 96 pct of the silver which were in the ore—a lead-copper-iron matte which contained nearly all the copper in the ore and the slag, the waste product. In the United States, up through the year 1092, we find the small furnace 100 X 32 1/2 in. with 12 tuyeres, some 6 on each side, plagued with a small amount of poorly roasted sulphides— either from heap or hand roasters that produced matte. This matte was roasted and if poor in copper was returned for the ore smelting. Otherwise it was smelted either alone or with additions of rich slags or argentiferous copper ores, the products being lead and a highly cupriferous matte, the latter being subsequently worked up for its copper. The lead metallurgists kept trying and improving on furnace and roasting equipment designs until we find blalvin W. Iles constructing at the old Globe Plant at Denver what came to be the modern furnace. That is, in 1900 he built a furnace of 42 in. width by 140 in. at the tuyeres with a 10 in. bosh and a 16-ft ore column. This type has been more or less standard to the present time, though modified in width and length to meet the demand for large tonnages and improvements in structural details. In 1905 at Cananea, Mexico, Dwight and Lloyd developed the present down-draft sinter machine that has meant so much in producing a well-processed material for the lead blast furnace. In 1912 Guy C. Riddell came forth with double roasting at the East Helena Plant of the American Smelting and Refining Co., which removed the "zinc mush plague." Incidentally, with the introduction of double roasting, which most lead plants were forced into after 1924, when lead flotation came into its own, less matte or no matte was produced. When this stage arrived, the copper was forced into the dross and the casting of lead at the blast furnace lead-wells was stopped. In plants with a fair copper carry 1 pct or better on the blast furnace charge, the lead wells became inoperative once the production of matte stopped. The copper drosses clogged the lead wells and even with bombing, either water or dynamite, the operators could not keep them open. Thus, the lead wells were abandoned in some plants, such as at the El Paso and Chihuahua smelters of the American Smelting and Refinillg Co., and all lead taken out through the first settlers. The elimination of sulphur, espccially sulphide sulphur, from the blast furnace charge and the nonproductiori of matte resulted in a great saving of tinie, energy and equipment in the recirculation of the copper, With the copper content in the dross and dross-fall ranging in quantities from a few percent up to 60 pct, such as at El Paso, a drossing problem was created. As the old-time operators hated dross and buried the same in the shipping bullion, the modern metallurgists from 1925 on decided that with increasing dross-falls they would have to adopt the lead refiner's ideas of drossing kettles with subsequent treatment of the lead with a sulphur addition to have the shipping lead of 0.01

Jan 1, 1950

By R. A. Vandermeer, C. J. McHargue

The (001) fiber-texture component, found in aluminum rods extruded at subzero temperatures, consists of particles of various sizes having extremely irregular shapes dispersed in a nonuniform way throughout a matrix of the (111) orientation. Apparently the (001) texture component is not a result of recrystallization but rather is due to the presence of reimanents of the original grains which fragmented from the main body of material as it reoriented towards the (111) orientation during the extrusion process. Both X-ray line-broadening measurements and electron-microscopic observatwns indicate that, after extrusion, regions having (001) orientations are in a state of relatively less strain and distortion than (111) regions, suggesting that the former have undergone less plastic deformation. A (001) fiber-texture component is also found after complete recrystallization of extruded specimens. Approximately one third of the recrys-stallized volume has this orientation. The (001) fragments, formed during the extrusion process, act as nuclei for recrystallization; i.e., the pain boundaries separating these fragments from the matrix are capable of migrating during annealing. Electron-transmission microscopic observations and X-ray line-broadening measurements indicate that (001) regions recover at a much more rapid rate than (111) regions at annealing temperatures up to 187°C. DURING the extrusion of a rod or the drawing of a wire the individual grains comprising the piece tend to reorient towards a preferred orientation (texture) which is of the fiber type where a particular crys-tallographic direction, (uvw), in each crystallite tends to be aligned parallel to the longitudinal axis

Jan 1, 1964

By Saburo Shigeno, Kunzo Amano

As shafts and tunnels move deeper levels in underground mining, development planning becomes more complex. The most serious problem is the aggravation of environmental conditions due to the imposition of higher-than-natural temperatures upon exposed strata. Since such a problem is a potential hazard to health, safety, and production, the authors have developed a system of computer-derived ambient-air temperature data for every major point of an underground mine under a given set of conditions. This system is comprised of two subsystems: 1) Ventilation network analysis, 2) Estimation of air - current temperature. The former is based on the Hiramatsu-Oka method, an improvement of the Scott-Hinsley method. The Hiramatsu-Oka method allows fast convergence and consideration of various fan characteristics. The latter subsystem considers heat radiation from strata, and the humidity. In several tests conducted at Besshi and Sazare Mines of Japan, the computer-derived data correlated with actual conditions.

Jan 1, 1969

By F. Lawson, N. A. Sareyed-Dim

A rotating disk of iron precipitant in a high temperature batch reactor has been used to study the kinetics of precipitation of nickel from low concentration aqueous solutions. Under inert atmosphere conditions, for temperatures up to 150°C, the rate of nickel deposition at pH25°C of 5 to 6 is controlled both by the rate at which nickel ions reach the surface and the rate of chemical reaction at the surface. However, the presence of oxygen in the atmosphere above the reacting system increases the nickel deposition rate dramatically. It is suggested that under the experimental conditions used, hydrogen atoms are adsorbed on both the iron and nickel, thus reducing the number of sites available for the cementation reaction. Oxygen acts as a depolarizer for hydrogen.

Jan 1, 1977

By FREDERICK C. BROWN

THE practice of fine-grinding is now being so successfully - carried on in some fields, notably in West Australia, and its advisability has been so frequently pointed out' that the matter in this paper is not put forward as being new ; its chief object being to call attention to the importance of fine-grinding in the treatment of comparatively low-grade ores. I have been engaged during the last five years in the cyanide-treatment of ores in the Ohinemuri district (North Island), New Zealand, and I consider that, in the near future, extremely fine-grinding (almost sliming) will become a very important feature of the milling-methods in this field, since it seems absolutely necessary to reduce the most of ores to a very fine state of division if a high extraction is to be obtained; and, in most cases, the extra percentage of saving will leave a good margin above the increased cost of treatment due both to the fine-grinding and to the interest on the capital spent for the grinding-machinery. The average ore of the Ohinemuri field is composed of a quartz-gangue with some calcite, carrying the gold-value in the form of an alloy of gold and silver in about equal proportions, and the silver-value in the form of mixed sulphides of silver, usually associated with a considerable amount of iron pyrites. In the upper levels, the ores are decomposed and carry large quantities of black manganese oxide and some iron oxide, but, as. depth is reached, the decomposed ore gives place to sulphides and, in some mines, rhodonite, manganese silicate, is present in fairly large quantities. The average value of the

Jan 1, 1906

By S. F. Ramseyer, E. A. Steigerwald

INFILTRATED structures represent composite materials which are capable of combining high-temperature strength with adequate low-temperature toughness and thermal shock resistance. Although copper- and silver-infiltrated tungsten structures are actually being used in rocket nozzle hardware, adequate understanding of the fracture mechanics of these composite systems is not available. Specifically the relative importance of the strength, ductility, and modulus of the infiltrant in determining composite properties is not known to the extent that optimum composites can be selected. The major portion of experimental effort in the area of composite strength has been devoted to fiber-reinforced systems1 or to systems where a discontinuous phase is imbedded in a relatively ductile matrix.2'3 In the case of high-temperature systems, which are composed of a relatively brittle matrix, such as tungsten or an oxide, a continuous phase exists for the propagation of a crack. The method by which the presence of a conjugate ductile continuous phase influences the gross properties of the composite represents an area which requires further investigation. This technical note presents results which evaluate the effect of infiltrant strength on the strength of the tungsten-base composite. A tungsten matrix and copper-base infiltrant were selected for the initial studies because of the ease of fabrication. Tungsten structures with nominally 20 and 30 pct porosity were evaluated. The porosity was controlled by varying the initial powder size and a ratio of open-to-total porosity greater than 95 pct was obtained by selective sintering cycles. The processing sequence involved hydrostatic pressing followed by a 72-hr presinter in hydrogen at 2000° F and a final sinter at 4000°F for 4 hr in vacuum. The 20 pct porous structure was obtained

Jan 1, 1965

Papers published by the Institute are issued in a variety of forms MINING TECHNOLOGY, issued every other month, contains the TECHNICAL PUBLICATIONS on Metal Mining, Minerals Beneficiation (milling and concentration), Industrial Minerals (nonmetallic) and Mining Geology, Mining Administration, and Geophysics papers relating to Metal Mining (A, B, H, I, K, L ) METALS TECHNOLOGY, issued eight times a year, contains the TECHNICAL PUBLICATIONS of the Iron and Steel Division and the Institute of Metals Division, and once or twice during the year those on Non-ferrous Metallurgy (reduction and refining of nonferrous metals) (C, E, and D ) PETROLEUM TECHNOLOGY, issued every other month, contains the TECHNICAL PUBLICATIONS of the Petroleum Division, together with Geophysics papers relating to -the finding of Petroleum (G, L ) COAL TECHNOLOGY, issued four times a year, contains the TECHNICAL PUBLICATIONS of the Coal Division (F ) MINERAL INDUSTRY EDUCATION DIVISION papers appear in a TECHNOLOGY according to classification of subject matter DISCUSSIONS appear in the respective TECHNOLOGY as available MINING AND METALLURGY is the monthly magazine, which contains papers of general interest and news of the membership

Jan 1, 1952

By C. H. Mathewson

UNFORTUNATE evasions of metals specifications recently brought to public attention through news items and editorials have caused executives of at least two great corporations to set up defensive procedures and to re¬affirm the patriotic purpose and conscientious effort of their plants in this battle of production. Whatever the exact conditions affecting these cases, in which the public interest has been safe-guarded by vigorous action, my reaction to such offenses in general is a feeling that they arise from the pressure and limitations that afflict our overextended war effort and that inevitably there will be more of them, doubtless more and more expertly conceived and less and less subject to detection as simple faked, or substituted analyses or tests. To the ladies, who doubtless are already beginning to ac¬quire a sense of painful resignation to a dry technical talk, may I say that the cookbook is full of specifications which customarily are varied within rather wide limits but it is generally recognized that the proof of the pudding is in the eating without regard to its exact composition or some scientific evaluation of its texture.

Jan 1, 1943

This story of the salting of a supposed diamond mine is a part of our Western history and deserves to be recorded in this book. It was more than a local affair, because it was concerned with persons in London and New York, as well as San Francisco. Part of the story has been told by Asbury Harpending in a little book published 12 years ago. Harpending (who died at New York in 1923) was in London in March, 1872, when he received a cable dispatch from William C. Ralston, the president of the Bank of California, stating that "a vast diamond field" had been discovered "in a remote section of the United States". Before starting for San Francisco, Harpending had an interview with Baron Rothschild, who showed a lively interest in the story, which was as follows: two weather-beaten prospectors went to the Bank of California and deposited some uncut diamonds and rubies for safe keeping; these precious stones were estimated to be worth $125,000. The men said that they had found the gems in "a desert portion of the West". They departed quietly, but the story was told in business circles; whereupon George D. Roberts, a mining engineer of wide experience and an associate of Ralston, sought an interview with the prospectors. One of them proved to be a man that had been in the employ of Roberts. Both prospectors, named Slack and Arnold, appeared "coy and cautious"; they were "simpleminded fellows", and were "afraid to trust anyone with the momentous secret ". They refused to divulge the place of discovery and declined "to part with their rights", but later "they became more amenable to reason" and expressed willingness to sell a half interest to

Jan 1, 1932

By H. A. Dierks

PENNSYLVANIA's anthracite region lies in the heart of the richest and most densely populated area of the U. S. Nearly 70 million people live within a radius of 500 miles, in which 130,000 manufacturing plants employ more than 8 million workers. The region comprises some 3000 sq miles and contains 484 sq miles of coal measures, which folding and erosion have divided into four separate and distinct fields, known as the Northern, Eastern Middle, Western Middle, and Southern. One million people live in the anthracite region proper, and their prosperity depends to a great extent on the anthracite industry, which produces more than $200 million in new wealth for the U. S. each year. Nearly 80 pct of the tonnage shipped out of the region is handled by nine railroads, which depend on this traffic for a large part of their revenue. It follows that the economic health and the very existence 0: this industry is of real concern not only to the region itself but also to the state of Pennsylvania and the country as a whole. Anthracite mining is one of the oldest mineral industries in America. About 1760 burning rock or stone coal was discovered on the hillsides of northeastern Pennsylvania. Within a few years a systematic search for coal bed outcrops was under way, and hand mining was begun. At first production was very limited, since anthracite was difficult to burn and was not readily accepted as a fuel. Pennsylvania anthracite is one of the densest and hardest of all coals, and its content of volatile matter is low. Consequently it does not ignite easily and it burns without smoke. About 1808 Judge Fell of Wilkes-Barre burned anthracite in an open grate fireplace and demonstrated proper handling of an anthracite fire. From

Jan 1, 1958

By W. Francis

Before attempting to describe the application of recently acquired knowledge to the classification of coal it will be as well to consider the objects at which a scientific classification should aim. Here one can not do better than to follow the example of Clarence Seyler,l by quoting from Huxley's "Classification of Animals:" "By the classification of any series of objects is meant the actual or ideal arrangement together of those which are like and the separation of those which are unlike, the purpose of the arrangement being to facilitate the operation of the mind in clearly conceiving and retaining in the memory the characters of the object in question. Thus there are as many classifications of any series of natural or other bodies as they have properties or relations to one another or to other things. But the statement of the characters of the class ... is something more than an arbitrary definition ... it expresses firstly, a generalization based on and constantly verified by very with experience; and, secondly, a belief arising out of that generalization—in other worda. the definition of the class is a statement of a law of correlation or coexistence . . . from which the most important conclusions are deducible." In that same sense writes John Stuart Mill, in the chapter on classification in his "Logic:" "The ends of scientific classification are best answered when the objects are formed into groups concerning which a greater number of general propositions can be made, and these properties more important, than could be made respectiug any other groups into which the same things could be distributed. The properties, therefore, according to which objects arc classified should, if possible, be those which are causes of many other properties, or, at any rate, which are sure marks of them." Now in the case of coal, the properties which have been used from time to time for classification purposes are the ultimate analysis, volatile matter, caking power, calorific power, burning properties, etc. Seyler has shown that there is a general law of correlation or coexistence between the ultimate composition and the other properties. The ultimate composition, therefore, of the natural series of bodies known as coal is the

Jan 1, 1930

By G. Sachs, A. W. Dana, C. C. Chow

A great number of the investigations on the plastic flow of metals have been concerned with the establishment of a "universal" stress-strain relation. In such a relation some stress function when plotted against a strain function should yield identical curves for the various stress states. In the first investigation of this type, Ludwik and Scheu1 plotted the maximum shearing stress as a function of the maximum principal strain. Later Ros and Eichinger2 introduced two universal stress-strain relations, the one relating the maximum shearing stress to the maximum shearing strain, and the other relating a stress invariant, suggested by von Mises and Haigh, to the corresponding strain invariant. (In more recent investigations the stress and strain invariants are frequently supplemented with some factor to render their meaning more lucid.) A further suggestion which has not attracted appreciable attention is that by Baranski³ who used stress and strain deviators. The most common means of experimentation to determine the relation between stress and strain consists in subjecting thin walled tubes to combined internal pressure and axial tension.4a,4b,4c This method allows the study of plastic flow under stresses which are variable in two directions. However, the plastic flow which can be obtained in this manner is comparatively small, being limited by either tension failure or instability. For copper,'. only the relation between maximum shearing stress and maximum shearing strain yielded good agreement. On the other hand, tests on a stee14b and on an aluminum alloy4c. resulted in systematic deviations if any of the discussed universal stress-strain relations were used. It would seem, therefore, that the agreement mentioned above for copper is only incidental and explained by its high rate of strain hardening compared to that of other metals. Much larger strains than experienced in the tube tests can be obtained by subjecting a thin membrane of a ductile metal, which is restrained at its periphery, to a uniform hydraulic pressure. The thin sheet forms a deep bulge before it fails. The stresses and strains in such a bulge increase with increasing distance from the edge of the clamping "die," the maximum stresses and strains occurring at the pole (crown) of the bulge. While the stress and strain states are determined by the contour of the bulge, the absolute magnitude of the stresses and strains depends upon the hydraulic pressure. The bulge contour is in turn correlated with the geometry of the die opening. The deformation and fracture characteristics of circular bulges, that is, bulges formed with circular clamping dies, have been the subject of numerous experimental and analytical investi-gations.5,6,7 It has been shown that plastically deformed circular bulges develop large and comparatively uniform strains before failure by instability"6b,6c,6d and closely assume a spherical shape.6d Also the distribution of strains across the contour of the bulge is dependent on the metal being investigated and is correlated with, but cannot be predicted from, the metal's stress-strain characteristics. On the other hand, oblong or elliptical bulges, that is, bulges formed with elliptical clamping dies, are not as susceptible to analytical analysis and have not been investigated to the extent that circular bulges have. The few available data6c,7c indicate that stress states are obtained at the poles of the bulges, varying between plane strain and balanced biaxial tension, depending upon the geometry of the die opening. In this paper, the strain state and curvatures exhibited by three bulge shapes, a circular and two elliptical bulges, Fig 1, are analyzed experimentally using methods described in previous publications.6a,6c An attempt is made to derive the stress-strain relations for these bulges, which represent strain states in which the ratio of the two positive principal strains varied between 1.0 and 0.35. In addition, tension tests yielded data for a value of —0.5 for this strain ratio. Such an analysis should indicate the applicability of the various laws correlating stress with strain to the stress and strain states occurring in bulged shapes. Definitions and Nomenclature The definitions of the major stress and strain quantities used in this paper are as follows: s1, s2, s3 = principal normal stresses Sl > s2 > S3 t = shear stress e = conventional (unit) strain e = In (1 + e) El, E2, E3 = principal natural strains 7 = shear strain The maximum shear stress: , _ S1 — S3 lmax = 2 Frequently, the flow stress, s1 — s3 = 2lmax rather than the maximum shear stress is used.

Jan 1, 1950

By R. I. Jaffee, F. C. Holden, H. R. Ogden

Alpha solutes increase the strengths of Ti-Mn alloys through solid-solution strengthening. The substitutional a addition, aluminum, decreases, and the interstitial solutes, carbon and nitrogen, increase the rate of nucleation and growth of a from ß. The best combinations of properties of a-ß alloys are obtained when there is a sufficient quantity of a phase in the structure to dissolve the a solutes. OF the many different titanium-base alloy systems, the predominant alloy type is the a-ß alloy. The properties of the a-ß alloys are dependent on solid-solution strengthening and heat-treatment effects involving the a-ß ratio and transformation reactions. Another variable which influences the mechanical properties of a-ß alloys is the a-stabilizer content of the alloy. An a solute may be present as an intentional addition, such as aluminum, or as an impurity element, such as carbon, oxygen, or nitrogen. It is known that these a stabilizers, when added to titanium, form single-phase alloys which are not heat treatable but which obtain their strength from solid-solution strengthening. Thus, it would be expected that a additions to a-ß alloys would increase the strength of the alloys by solid-solution strengthening of the a phase. In addition, they would affect the transformation kinetics of the ß-to-a reactions and other processes based on the instability of the ß phase. The effects of heat treatment and structure on the mechanical properties of Ti-Mn alloys have been shown in a previous paper.6 This system offers a good base to demonstrate the effects of typical a solutes on the properties of a-ß alloys. The three a solutes described in this work are aluminum, representative of a substitutional a solute, nitrogen, representative of an interstitial a solute, and carbon, representative of an interstitial compound-forming element. The effects of heat treatment and microstructure on the properties of a alloys containing these three elements are described in concurrent publications. Some of these data are used for base-line points in several of the curves used for illustration herein. Experimental Procedures Iodide titanium was used as the base for all of the alloys studied in this work. The alloys were prepared as ½ lb ingots by double arc melting in an argon atmosphere. The ingots were forged to ¾ in. rounds, vacuum annealed for 6 hr at 900°C at a pressure of 10 ' to 10-5 mm of Hg to remove hydrogen, and hot swaged to 1/4 in. diam rod. After me- chanical descaling, test specimens were prepared for heat treatment. The alloys used in this study together with the fabrication temperatures are given in Table I. Heat treatments were done in argon. For the most part, the specimens were sealed in Vyeor capsules under a partial pressure of argon. Quenching was accomplished by breaking the capsule under water. Other cooling methods used included oil quench, argon cool (simulated air cool in an argon atmosphere), and furnace cool. The times for the various heat-treating temperatures are given in Table 11. The tests performed on the alloys consisted of tensile tests on ? in. diam specimens, hardness tests, and microimpact tests. Specimen sizes have been adequately described in a previous publication.' The micrographs presented in this paper were taken from specimens cut from the shoulders of broken tensile specimens. Final polishing was done with Linde B on a slow-speed wheel, and the specimens were etched with a 1½ HF — 3½ HNO, solution. Ti-N-Mn Alloys The transformation diagram and microstructures of the Ti-0.1 pct N-Mn alloys used in this investigation are given in Fig. 1. The effect of small nitrogen additions on the binary Ti-Mn diagram is to raise the ß-transus temperature with little effect on the a solubility of manganese. Also, as has been noted previously,' high manganese-content alloys containing nitrogen, when quenched from temperatures high in the ß field, contain a subgrain boundary phase which appears to be nitrogen-rich a. Marten-site is formed when alloys containing less than about

Jan 1, 1956

By R. S. McClellan

DURING the last year or so, with higher prices for gold and silver, many old properties in the West have come back to life. Almost every profitable producer in the old days has been considered, and the reasons for its shut-down investigated. If it seems likely that modern ore-finding, mining, and metallurgical methods, and S35 gold can again put the property on a profitable basis, someone can usually be found to back the venture. Methods of rejuvenation vary with the property, of course, but the following outline of what has been done with one group of mines in Idaho is fairly typical and may be suggestive to others. The Golden Chariot gold-silver properties, near Silver City, consist of seven old mines, working a vein system striking north and south, which had a productive length of some 3500 ft. The vein is a quartz-filled fissure with granite walls. Gold occurs in native, and with silver in the form of electrum which is the natural alloy of the two metals. Silver also occurs in a variety of sulfides. From 1064 to 1876, these old properties were worked intensively to an average depth of about 700 ft., through seven shafts which range in

Jan 1, 1934

By O. W. Ellis

IN VIEW of the extensive use of the brasses and bronzes in engineering practice it is indeed surprising that so little scientific work has been done on the oxides in these alloys. Recognition of the ill effects of these compounds is universally accorded, both in foundry procedure and in such specifications as cover the melting of these useful mixtures. In the latter, limits, for example, are placed on the proportions of scrap metal in the charge, and clauses governing the use of fluxes are included, the addition of fluxes to the charge being made with the object of avoiding oxidation during the process of melting and of subducing and separating non-metallic matter from the melt.1 In the manufacture of brass it occasionally, though rarely, occurs that the virgin metals, copper and zinc, alone are used. In the event of virgin metals being employed, that of the higher melting point is always melted first. If it is melted under suitable conditions, little or no oxidation will occur. Whether oxidation has occurred or not, however, can best be determined by microscopic examination of a sample taken from the melt.

Jan 1, 1930

By Alexander Anderson

In many oil fields a great variation in the production of adjoining wells has long been observed, and a certain proportion of dry holes, situated between prolific producers, has been regarded as normal without thorough investigation as to cause. Similarly, an occasional prolific producer has been found in a part of a field where all other holes have proven disappointing. Adjoining wells which showed an unreasonable difference in production have been surveyed, and the bottom of the poorest producer has been found to have lost sufficient vertical depth, through its drift, to diminish seriously its penetration in the oil zone. Again, the bottom of the good producer has been found to he more favorably situated by its migration up structure. Surveying of wells in California fields has shown many instances where the dry hole has drifted far off the structure to such a degree that no amount of deepening could ever convert it into an oil well. In other cases, edge wells have been found to drift into the field. At this time, in California, the surveying of oil wells is beginning to he accepted as a routine part of operating procedure. Some operators are surveying all of their new wells and, in some of the recently discovered fields, this practice is providing invaluable assistance in methodical development. The information that has been obtained from the surveying of many wells has convinced most operators that it pays to give careful attention to the drilling of wells. Chews are now usually cautioned to avoid reckless competition with each other. Whereas, formerly, certain companies demanded a large footage from their drillers, they now issue orders that a very moderate speed in drilling shall he maintained and that every care be taken to avoid practices likely to cause excessive deviation of the hole frorn vertical. As a result of these new instructions to drilling crews, a distinct decline in the average drift of the wells drilled by these operators has taken place and fewer dry holes are being drilled from good locations. To the petroleum engineer and the geologist, oil-well surveys provide the necessary data required for the construction of the correct cross-

Jan 1, 1929

BRADEN, the most southerly of the three big Porphyries in Chile and the first to start production (in 1910), is a remarkable mine. It would be interesting to know just how much it has contributed, and will contribute, to the earnings of the Kennecott Copper Corporation, which acquired 95 per cent of Braden stock in 1915 by an exchange of shares and which subsequently obtained the remainder. Because of this complete ownership no separate annual report is published (as is the case with Anaconda's South American subsidiaries, Chile and Andes). Income, taxes, operating costs, earnings, and other financial data, including the balance sheet, are consolidated with corresponding items applying to Kennecott's manifold operations in the United States and other foreign countries. If Braden were in the United States it would be possible to arrive at a pretty accurate estimate of revenue realized each year from the sale of copper simply by applying the average published market price to the production as reported by the company. However, because of the restrictions on sales imposed by the Chilean Government and the almost fantastic regulation of exchange rates in the past, no estimate of the sort would be reliable. This point is illustrated by the following comparison made by Charles R. Cox, president, in Kennecott's report for 1955: In each year, 1954 and 1955, Braden supplied about 30 per cent of Kennecott's total copper deliveries; but Braden's operations contributed 16.7 per cent of consolidated net income in 1955 against only 6.2 per cent in 1954. More will be said later about exchange rates, taxes, and restrictions, and the recent improvement in the situation. Of course another element of

Jan 1, 1957