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By Mahmood Alemrajabi, Ake Rasmuson, Kerstin Forsberg, Kivanc Korkmaz

"In the present study, the recovery of rare earth elements (REE) in the nitrophosphate process of fertilizer production is investigated. The apatite has been recovered from iron ore tailings by flotation. After digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REEs are recovered by precipitation. Optimum conditions in these steps have been determined in a previous study. The precipitate mainly consists of CaHPO4.2H2O and REE phosphates.In the present study, selective dissolution and re-precipitation have been studied in order to obtain a precipitate that is more concentrated in REEs. The precipitate was selectively dissolved in nitric and phosphoric acid at different acidities (pH 6 to 0) with the liquid /solid ratio of 100 mL/g. It is shown that most of the CaHPO4.2H2O and other calcium containing compounds will be dissolved at pH 2 while the REE phosphates are not dissolved above a pH of approximately 2. Thus, by partial dissolution of the REE precipitate at pH 2.5 most of the solid calcium phosphates will be dissolved and the remaining solid phase, which is more concentrated in REEs, can be filtered off as a fairly concentrated REE solid mass and the liquor can be recycled back to recover more P nutrients. Alternatively, the REE enriched precipitate was dissolved completely in nitric acid and re-precipitated again by addition of ammonium hydroxide to pH 1.2. A chemical equilibrium software, MEDUSA (Puigdomenech, 2013) has been used to evaluate the experimental results and to estimate the optimum conditions for selectively dissolving the precipitate."

Jan 1, 2016

By S. Castro

Molybdenite flotation is strongly depressed at pH higher than 9.5 in the flotation of Cu-Mo ores in sea water. Chemically sea water contains mainly Na+ and Cl- ions, but also some secondary ions, such as SO42-, Mg2+; Ca2+, HCO3-; etc., which are not necessarily indifferent for the flotation of molybdenite. The natural floatability of molybdenite in sea water and in NaCl solutions containing different secondary ions is investigated by micro-flotation tests. The tests indicate that the floatability of molybdenite in alkaline media in 0.6 M NaCl solutions is not affected by the presence of anions, such as, SO42- and HCO3-, at concentrations similar to those occurring in sea water. However, a strong depression of molybdenite at pH ranging from 9.5-10.0, is produced by the alkaline earth metal cations (Ca2+ and Mg2+ ions), dissolved in distilled water or in 0.6M NaCl solutions. It was found that effect of Mg2+ions is significantly stronger than Ca2+ ions. Effect of both ions is attributed to hydrolysis and adsorption of MOH+ hydroxy-complexes. This is followed by subsequent precipitation of hydrophilic colloidal hydroxides at the molybdenite/solution interface, and in bulk solution.

Sep 1, 2012

By Kan Song, Lin Liu, Hengzhi Fu, Jun Zhang, Haijun Su, Xiaojiao Jia

"Al2O3/YAG/ZrO2 eutectic in situ composite has been regarded as new generation of high temperature structural material due to its excellent performance even close to its melting point. The directionally solidified Al2O3/YAG/ZrO2 eutectic ceramics are prepared by recently developed Laser Floating Zone Melting (LFZM) apparatus in which a splitter mirror is used to obtain two beams with the same quality from one CO2 laser. With the two laser beams irradiate the sample from opposite directions, the sample is zone melted. The apparatus configuration and the solidification processing are described in detail. The solid/liquid interface morphology is studied and the mechanism of microstructure formation especially the characteristic of eutectic cellular is discussed. It is shown that YAG and ZrO2 phases play a leading role during the ternary eutectic growth. Meanwhile, the relationship between the solidification microstructure and the processing parameters are investigated.IntroductionAl2O3/YAG/ZrO2 ternary eutectic in situ composite, due to its excellent high temperature mechanical properties, is now considered to be a promising candidate material as a replacement of nickel based super alloy for new generation aero space engine turbine blade [1]. They exhibit flexural strength of 360-500 MPa from room temperature to 2073K in air atmosphere [2]. The compression creep strength at 1873K is 433MPa with the strain rate of 104/s [3]. However, because of the high melting point and complex physical properties, there remain still many difficulties for its application. One of the bottlenecks is the poor understanding of the relationship between microstructure and solidification conditions."

Jan 1, 2012

Study on a Novel Polymer/Bentonite Compound Adsorbent for Removal of Cu(II) from Aqueous Solution

Sep 13, 2010

By Luiz Filipe Cardoso de Oliveira, Alex Milton Albergaria Campos, Paulo Santos Assis

Em usinas siderúrgicas integradas a coque, o carvão mineral tem papel fundamental principalmente na produção de coque metalúrgico, que será utilizado nos altos-fornos para produção do ferro-gusa. O coque é produzido a partir de misturas, de carvões minerais com diferentes propriedades, formuladas para atender os requisitos operacionais do processo de coqueificação e a garantir a qualidade do ferro-gusa que será produzido nos altos-fornos. Além disso, está mistura deve ter o menor custo possível uma vez que a maior parte do carvão metalúrgico utilizado no Brasil é importado, representando assim uma grande parcela do custo do aço. O grande desafio do setor é obter misturas de carvões que atendam a coqueria e produzam coque com alta qualidade e baixo custo. Para tanto, é necessário uma otimização de vários processos, desde a compra e transporte do carvão até sua estocagem, formação das misturas e abastecimento da coqueria. Com isto, este trabalho vem com o objetivo de sugerir uma otimização e planejamento da mistura de carvão para a coqueria com a utilização de rejeitos plásticos de menor valor agregado na mistura que possibilitem a produção de coque com menor custo e com a qualidade exigida no processo de fabricação de aço.

Oct 1, 2019

By R. G. Hall

WHEN we want to interpret some problem which faces us at the present, if that problem be a social or political movement, we turn to the pages of history for 'information. If the problem be one of science or of industry we turn to the library of the subject and endeavor to translate the present from the experience of the past. I wonder if you would bear with me for a few minutes as I look back to the time when I was going through mining school and looking forward with hope, it is true and with confidence also, but still with some trepidation and an occasional qualm, to the month of June when the class of 1897 would be hunting jobs. Those were the years 1893 to 1897. Those years saw the Treasury of the United States so empty of gold that the President had to appeal to financiers to accept the country's promises to pay in return for $100,000,000 in gold. And the invectives that were hurled at both their heads for such a betrayal of the people sound strangely similar to those you read today being daily written and screamed at another President for taking us into the League of Nations or for not issuing bonds in huge amounts for unemployment relief, or for not adopting somebody else's particular specific for the relief of hard times.

Jan 1, 1931

By R. R. Sayars

"Carbon monoxide is a gas slightly lighter than air, with which it diffuses readily to make a homogeneous mixture. It will burn and has a wide explosive range, that is, an explosion is possible when the air contains from 15 to 73 per cent of the gas3. This explosive range is about the same as that for hydrogen and over nine times As Tide as that for marsh gas (methane). Like air, it has neither color nor taste and has no odor in concentrations usually encountered, therefore it cannot be detected by the ordinary senses with which men are endowed. It is produced by burning carbon containing fuels, no coal, wood, gasoline, etc., whenever not enough air or oxygen is supplied to burn and oxidize the fuel completely.The human race has probably been exposed to this gas since men first began using fires in confined or sheltered places. The poisoning as usually encountered is an acute condition resulting from breathing atmospheres con¬taining this gas. A number of eases described in the ancient literature Indicate that carbon monoxide was a frequent cause of death by accident, suicide and is a means of punishment or torture. A quotation by Lewin from Aristotle who lived in 384-322 B.C., states that ""animals collapse from harmful odors as men gets a severe headache and often dies through charcoal vapors"". The Roman knew that smoke was poisonous, and used the greenest most smoke-producing wood to put persons to death. The occurrence of carbon monoxide increased in frequency through the years until at the present time it is found in the home as well as in many industries. The following table gives the approximate percentage of carbon monoxide found in gases from various sources of poisoning.4"

Apr 1, 1924

By J. L. Huiatt

The U.S. Bureau of Mines and Great Salt Lake Minerals and Chemical Corp. developed a froth flotation process for concentrating potassium salts from Great Salt Lake solar evaporites containing about 5 percent K. The crude evaporites, which were predominately halite (NaCl) with smaller amounts of kainite (KCl.MgSO4.2.7H20) and schoenite (K2SO4MgSO4.6H20), were conditioned in a saturated brine solution, thus converting nonfloatable kainite to the floatable mineral schoenite. Schoenite was then selectively floated with a medium-molecular weight fatty acid. Continuous small-scale pilot plant testing indicated that 80 percent of the potassium could be recovered from the crude evaporites in flotation concentrates assaying about 11 percent K.

Jan 1, 1975

By Mark S. Sanders

Based on laboratory tests and preliminary field tests of off-the-shelf steel toed rubber boots, a molded sole design was developed to provide increased traction over conventional calendared sole miners' boots. The pattern provided sharp edges perpendicular to both lateral and fore-aft slip vectors. The sole was designed to reduce mud caking. An instep lace-up capability was added to better secure the foot inside the boot. A five month field evaluation compared the prototype boots to the boots the participants usually wear. Although objective slip and fall data showed no significant advantage for the prototype, subjective evaluations made by the participants indicated increased traction for the prototype boots. Approximately 75 percent preferred the prototype to their own boot. Approximately one-third used the lace-up capability. It was concluded that molded soles provide better traction than calendared soles for the underground mining environment.

Jan 1, 1982

By P. H. Tolcher

Canada, as the Free World's largest mine producer of zinc and the third largest mine producer of lead, has a vital interest in the future growth in demand for these metals. This paper traces the development of lead and zinc consumption in the last two decades, both on a total-Free-World basis and by major market areas. How Canada, as a major mine producer, has shared in this growth is also indicated. In addition, future consumption for both metals in the current decade of the 1970's is fore-cast. The demand these projections will make on Free World mines, particularly on Canadian mines, is examined. Some of the opportunities and challenges the Canadian mining industry will likely face during this period are also dealt with.

Jan 1, 1971

By Cleciano Berlando Miranda de Oliveira

A Engenharia de manutenção em equipamentos siderúrgicos da CSN vem desenvolvendo habilidade e aplicando com ótimos resultados os recursos computacionais avançados com modelagem 3D e simulação numérica através de métodos de elementos finitos. Estes recursos estão se tornado um diferencial na dinâmica dos trabalhos de manutenção com foco em análises de falhas crônicas e respostas rápidas para a solução dos problemas. Caracterizando e estratificando as falhas é possível desenvolver melhorias e defendê-las com maior assertividade e credibilidade. O recurso computacional já está no mercado há tempos e a CSN está na vanguarda na formação de sua equipe própria com um nível avançado e grande potencial para otimização de resultados da engenharia de manutenção de equipamentos (GEM) da CSN-UPV. A missão principal é agregar valor aos ativos, com agilidade e confiabilidade na caracterização de oportunidades de melhorias dos projetos ou restabelecimento funcional. Trilhando um caminho contínuo no que tange a qualidade e assertividade nas soluções de problemas de equipamentos mecânicos, serão apresentados alguns casos de sucesso que estão em desenvolvimento e um projeto de melhoria nos rolos de entrada de um laminador de encruamento, localizado na saída da linha de recozimento contínuo para chapas número um (LRCC#1). Estes rolos apresentavam fraturas com frequências mensais gerando paradas de mais de 8 horas e, após os estudos e implantação do projeto em 2012, não houve mais registros de paradas por falhas nos rolos. O projeto foi padronizado e multiplicado para os demais rolos da LRCC#1 e outras linhas com projetos semelhantes.

Aug 17, 2017

By M. Rudolph, A. D. Renno, H. Wu

In this study, synthetic pure cassiterite and cassiterite doped with Fe were successfully produced by sintering. Their crystal structure and chemical compositions are characterised by optical microscopy, X-ray powder diffraction (XRD) as well as scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) based chemical composition analysis. The electrostatic behaviour of synthetic and natural cassiterite was studied by electrophoretic measurements. Their floatability was studied by microflotation with two types of anionic collectors. Results show that the cassiterite floatability with these collectors behaves differently and lead to two opposite results: Natural cassiterite (enriched with Fe) > undoped pure SnO2 by using sulfosuccinamate (Aerosol® 22) Undoped pure SnO2 > Fe3+ doped > natural cassiterite (enriched with Fe) by using styrene phosphonic acid (SPA). Keywords: Synthetic cassiterite, lattice impurities, flotation, zeta potential, Aerosol® 22, styrene phosphonic acid

Jan 1, 2020

By Manqiu Xu, Andrew Lee, Frederick D. Ford, Cara Wercholaz

"Platinum-group minerals (PGM) typically occur in such low concentrations that quantitative mineralogical evaluation is difficult or impossible. The FEI MLA system used by Vale Base Metals Technology Development has been successfully employed to produce large PGM data sets that are statistically robust. The MLA Sparse Phase Liberation mapping routine produces false colored images that accurately document mineral textures, including intergrowths between various platinum group minerals and between PGMs and other tellurides and sulfides. MLA PGM search results can be used in conjunction with mineral chemistry to calculate platinumgroup element distribution to minerals and the MLA PGM images can be used to produce model grade-recovery curves.INTRODUCTIONThe platinum-group minerals (PGM) found in Sudbury area deposits have been extensively catalogued and reviewed by many authors including, but not limited to: Farrow and Lightfoot (2002), Cabri and Laflamme (1984; 1976) and Cabri (1981). The PGM list currently used has 12 minerals summarized in Table 1. As noted by Farrow and Lightfoot (2002), platinum-group minerals in Sudbury are dominated by tellurides, bismuth-tellurides and arsenides, with an absence of platinum-group element (PGE) sulphides or ferro-platinum alloys such as tetraferroplatinum - PtFe."

Jan 1, 2011

By Masaki Kitazume, Yoshiaki Kikuchi

"Abstract Pile foundation is one of fundamental techniques to improve the bearing capacity and settlement characteristics of superstructures. Wide varieties of piles having various shape, size and material were developed and have been applied to a lot of construction projects throughout the world. The deep mixing method, an in-situ admixture stabilization method, was developed in 1970s in Japan and the European countries, and has been frequently applied to many construction projects for various improvement purposes such as increasing bearing capacity and horizontal resistance, reducing ground settlement, preventing liquefaction and so on. The design methods, execution procedure and quality control and assurance (QC/QA) of the method are standardized or specified in many countries. These standards, specification and/or technical manual have been a remarkable contribution to spread the techniques throughout the world. The QC/QA is one of the major concerns for clients and engineers who have poor or no experience of the technologies. In order to assure the high quality of deep mixing work in the global market, it is necessary to establish the concept of QC/QA and correlate the output of different procedures. Upon the request by the organizing committee of the DFI-EFFC International Conference on Piling & Deep Foundations, the authors conducted survey of the specifications and standards on the piling and deep mixing technologies in Asian countries. In this manuscript, the results of survey are briefly introduced by comparing these specifications and standards.IntroductionThe pile foundation is one of fundamental techniques to improve the bearing capacity and settlement characteristics of superstructures. Wide varieties of piles having various shape, size and material were developed and have been applied to a lot of construction projects throughout the world. The design method, execution procedure and quality control and assurance of pile foundations are standardized in many countries based on the accumulate research results, laboratory and field experiences. In Japan, steel pipe piles are mainly constructed by hammer driven in port construction. On the other hand, precast pre-stressed concrete piles or cast-in-place piles are mainly used in on land construction. When precast pre-stressed concrete piles are constructed, piles are usually set by inner excavation method because of preventing noise and vibration problems. More than 50 years ago, noise and vibration problems had not been serious problem in Japan, but around 50 years ago, they became serious and now less noise and vibration construction methods are used for pile construction on land in Japan. In Asian countries, though piles used for construction have a lot of variety, precast pre-stressed piles are commonly used. In this report, execution controls of construction methods of steel pipe piles and precast concrete piles are mainly considered."

Jan 1, 2014

By A. S. Usrnani

Due to both turbulence and the highly variable geometry of castings, a realistic numerical simulation of the metal flow is prohibitvely expensive with current technology. However, when the chief purpose is to achieve realistic thermal fields a precise How simulation is not necessarily required. In this paper we assume a laminar flow regime and obtain the flow field by solving the incompressible Navier-Stokes Equations using a velocity-pressure segregated semi-implicit finite element method. The free metal surface is predicted by advecting a pseudo-concentration function via the computed How field. This involves an explicit finite element solution of a pure advection equation. The thermal field is calculated by solving the convective-diffusive energy equation by an explicit finite element method using the computed flow field and the location of the free surface. All the advection terms are discretized using a Taylor-Galerkin method. The interface between the metal and mould is modelled using special interface elements. The model is demonstrated by solving practical example problems. The results show that a sharp thermal front is maintained during the course of filling without excessive diffusion. The heat diffusion in the mould can be controlled by varying the metal mould heat transfer coefficient.

Jan 1, 1994

By R. Gilman Brown

INTRODUCTION. MINES are interesting by reason of what they have done for man, or of what has been done for them by nature. Not all are interesting on both scores. Many profitable mines are commonplace to the geologist; and many presenting unique geological conditions have been sad failures commercially. The Standard group at Bodie has produced in 25 years, $14,500,000, paying $5,000,000 in dividends.' On the other hand, this output has been mined (almost wholly above the 1,000-ft. level) from a system of more than 100 veins, ranging in thickness-from 0.5 in. of "specimen rock" to 30 ft. of clay and quartz; distributed through a zone about 2,000" ft. in width, and representing from three to five distinct periods of formation. This group, therefore, by reason of its industrial record as well as its geological features, may fairly be regarded as doubly interesting. The Bodie district occupies an island of recent (Tertiary) hornblende-andesite, surrounded by a complex of igneous rocks and breccias. It lies at the summit of the eastern foot-hills of the Sierra Nevada mountains, and within the Great Basin, a few miles from its western edge, marked here by Mono lake on the line of the Great Fault. The average elevation of the outcroppings of the veins may be taken at about 5,700 ft. The andesite projects from south to north in a great tongue, 12,000 ft. long and 5,000 ft. wide, reaching an extreme height at the northern end of perhaps 1,000 ft. above the adjoining small canyons. These separate it from the main mass of the foot-hill

Jul 1, 1907

By D. C. Fleck

The Bureau of Mines, in a cooperative research program with four lead companies, has investigated ferric chloride leaching of galena to prepare lead chloride for molten-salt electrowinning to produce lead metal. The hydrometallurgical-electrolytic process is an alternative to the sintering-smelting-refining process currently used to produce lead metal and avoids the environmental problems associated with a conventional smelter. During investigations on the electrowinning aspects of the work, it was noted that certain cations, moisture, and sulfate in the electrolyte affect lead metal purity, cell voltage, current efficiency, and viscosity of the electrolyte. Results of bench-scale tests are re-ported on the effects of CaCI2, CuCI2, FeCI2, MgCI2, NaCI, ZnCI2, PbS04, and moisture on electrolysis. As impurities increased in the electrolyte, current efficiency decreased. CaCI2, CuCI2, and FeC12 decreased current efficiency by 12 to 47 pct. ZnCl2 gave a small voltage increase, while CaCI2 addition equivalent to 4.9 pct Ca caused a 50-pet increase in voltage. The lead metal was contaminated in direct proportion to the CuCI2 buildup in the electrolyte, Anode corrosion was observed with MgCI2 and MgC12?6H20. Viscosity increased appreciably with the buildup of NaCI, CaCI2, and sulfate. Electrolyte foaming occurred with ZnC12, MgC12?6H20, MgC12, FeC12?2H20, and FeCI2. Moisture inhibited the coalescence of the lead metal.

Jan 1, 1983

By M A. Gontalves, A F. D C Varajpo, S A. Stachissini

Clays from the Santa Elena Peninsula, south-east of the Ecuador coast, were investigated with a view to identifying their main mineralogical, physical, chemical and textural characteristics as well as their potential for industrial use as adsorbents. Identified as calcic bentonites, two representative samples from the Tosagua Formation (Oligocene to Lower Miocene) were selected for acid activation trials. The selection criterion was based on the greatest amount of clay fraction (<2 ¦m fraction) associated with the greatest content of montmorillonite. For the activation treatments, HCl and H2SO4 solutions of 4, 6 and 8 N were used in a stirred glass reaction vessel with the clay sample under reflux during four hours at temperatures of 70¦C for HCl and 85¦C for H2SO4. Mineralogical analysis by X-ray diffraction (XRD), chemical analysis by X-ray fluorescence (XRF), differential and gravimetric thermal analysis and measures of density, surface area and porosity indicated the changes occurred in the crystal structure of the montmorillonite. The acid treated clays were utilised in trials of purification and decolourisation of soybean vegetable oil in a ratio of 2:100 (clay/oil) at 90¦C for 30 min, under constant stirring. After centrifugation of the suspension, the wavelength of the bleached oil was measured by UV-visible spectrophotometer and the bleaching capacity of the clays was determined. The best bleaching capacity of the samples was obtained with 6 N H2SO4 acid-activated clays. The bleaching capacity was compared to Tonsil, a commercial acid-activated clay and similar results between them evidenced the potential industrial application of the Ecuadorian clays to bleaching of vegetable oil.

Jan 1, 2008

Comparison of Industrial Cyanide Destruction Processes

Sep 13, 2010

By D. van der Westhuizen, H. Krieg, M. Kruger

In the field of Fischer-Tropsch synthesis catalysts, cobalt, platinum, and aluminium are the primary metal constituents of the conventionally used cobalt catalyst. While platinum recovery remains a focal point in this field, a recent endeavour by a South African company emerged, which aimed to recover cobalt and aluminium from spent Fischer-Tropsch synthesis catalysts for potential use in the agricultural sector. This study aimed to optimally separate cobalt and aluminium from spent Fischer-Tropsch synthesis catalyst for this purpose. It further leverages the OLI database to predict metal speciation during solvent extraction to aid with experimental planning. Shake-out tests were conducted to determine optimal separation. conditions, which were validated using three distinct methods: (i) evaluating the experimental error, (ii) comparing results with similar research, and (iii) validating results against the OLI database. The investigation revealed the pivotal role of the aqueous pH yielding effective separation at pH 3.13 ([H2SO4] = 2.5 × 10−4 M) when using 20 vol.% CYANEX 272 and 50 mol.% pre-neutralisation. Effective cobalt scrubbing was achieved with 50 g/L Al at pH 2.8, while successful stripping required 1 M H2SO4. Competitive interactions between complexing aluminium and cobalt species were observed when contacting with CYANEX 272 at a pH < 4. Equipment design analysis for a targeted separation efficiency of 87% dictated the necessity of two mixer stages and a settler measuring 1.5 m × 1.5 m × 6.0 m (height × width × length). This settler would ensure sufficient residence time for gravity separation at a flow rate of 10 m3/h.

May 27, 2025