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By R. Bergstrom

The implementation of a Quality Management System (QMS) or an Environmental Management System (EMS) that conforms to the standards issued by the International Organisation for Standardisation (ISO) no longer needs to result in a bureaucratic nightmare supported by mounds of paperwork. In this sense, this paper describes the Quality Management System that was implemented and demonstrates how the technologies that were developed can be used to satisfy other similar requirements.

Aug 25, 2002

By S Mundell, A Atkins, S van de Water

Geoscientific information management enables the capture, management and delivery of the original geoscientific observations and measurements of the earth’s natural resources. However, original observations and measurements are worth nothing if the quality and integrity of the data can’t be guaranteed. Geoscientific information is one of the fundamental assets enabling miners to make confident and accurate business decisions, whether that is defining a resource model, performing reconciliation, delivering ore reserve reports or meeting environmental compliance requirements. Without access to reliable, validated or verified data it increases the risk of miners using incorrect information for reporting and compliance. Industry codes, such as JORC, or government regulations, such as environmental compliance requirements, must be adhered to and companies should be able to confidently report to these standards. Without having a robust information management framework in place, it becomes a challenge to make trustworthy decisions, report confidently and reduce the risk of non-compliance. As a key initiative, good data governance should form one part of a miner’s information management strategy. Within the mining industry it is common for companies to only consider technology tools as the key focus for compliance whereas a mature information management focus will additionally consider people and process. All three pillars are critical for a miner to have confidence in their data driven decisions. This paper discusses an industry framework for best-practice geoscientific information management based on the observations gathered from analysing data management practices within the mining industry. It focuses on how the three pillars of people, process and technology are crucial elements to improve operational decisions and ensure companies are compliant.

Nov 8, 2021

The optimum cut-off grade policy maximizes the net present value (NPV) of an open pit mining operation subject to the mining, processing, and refining capacity constraints. The traditional approaches to cut-off grade determination ignore the escalation of the economic parameters such as metal price and operating costs during life of an operation, and consequently lead to unrealistically higher values of the objective function. Further, the NPV of a mining operation declines due to the depletion of the available reserves, causing a decline in the optimum cut-off grade, i.e. higher cut-off grades in the early years of an operation and lower cut-off grades during the later years. Hence, low grade material mined in the earlier years may be stockpiled for processing during later years to offset the effect of escalating economic parameters on NPV. This paper demonstrates the combined impact of introducing economic parameters, escalation and stockpiling options into the cut-off grade optimization model. The model promises an enhancement in NPV as illustrated in a case study incorporating practical aspects of an open pit mining operation.

Jan 1, 2011

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

In this study, the dissolution behavior of copper and arsenic from five different copper concentrates containing 21-34.7 %wt. of Cu, 1.3-7.3 %wt. of As and 15.6-27.5 %wt. of Fe were investigated under high pressure oxidative leaching conditions. Leaching experiments were conducted using different leaching reagents such as ferric sulfate, sodium chloride, deionized water, sulfuric acid and ferric sulfate-sodium chloride mixture in order to compare the effectiveness of each on the dissolution of copper and arsenic from copper concentrates. The effects of ferric sulfate (0.1-1 mol/L), sodium chloride (0.1-0.5 mol/L) and leaching temperature (100-180C) were investigated under 1 MPa autoclave pressure , particle size >45 m, pulp density of 100 g/L, stirring speed of 750 rpm and leaching time of 60 min. Results showed that the most effective leaching reagents for the dissolution of copper are 0.34 M NaCl and a mixture of 0.1 M Fe2(SO4)3 - 0.34 M NaCl, in which As extraction did not exceed 7%. The copper concentration in the pregnant leach solution obtained after leaching using 0.1 M Fe2(SO4)3 - 0.34 M NaCl was 13-30 g/L, while the concentration of As and Fe were in a range between 0.3-1 g/L and 0.2-10 g/L at 160C. INTRODUCTION Copper sulfide minerals, such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and covellite (CuS) are used for the production of copper in mining and metallurgical industries worldwide. The conventional pyrometallurgical processing followed by electrorefining is a common process for the production of high purity copper (Moskalyk, & Alfantazi, 2003; Padilla, Aracena, & Ruiz, 2012). However, the degradation of copper content and an increase in the amount of metal impurities, especially arsenic (As), antimony (Sb) and bismuth (Bi) in copper concentrates cause serious problems to the production of copper and environmental pollution (Basha, Selvi, Ramasamy, & Chellammal, 2008; Long, Peng, & Bradshaw, 2012). Hydrometallurgical processes are used to recover metals from refractory ores, concentrates and tailings by leaching (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018). During the last decades, hydrometallurgical processing for the recovery of copper from enargite-bearing copper ores and concentrates has been extensively investigated due to its relatively more environmentally benign and less capital costs than the conventional pyrometallurgical processes (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018; Choubey, Lee, Kim, & Kim 2018). However, several issues facing the hydrometallurgical processing are incomplete extraction of copper associated with the coprecipitation of iron compounds, difficult stabilization of toxic impurities and production of a contaminated copper product (Dreisinger, 2003; Safarzadeh, Moats, & Miller, 2014). Hence, a number of studies have been conducted on the selective dissolution of copper from copper ores and concentrates or selective removal of arsenic leaving a clean copper residue using various leaching reagents or lixiviants (Safarzadeh, Moats, & Miller, 2014; Mihajlovic, Strbac, Zivkovic, Kovacevic, & Stehernic, 2007; Tongamp, Takasaki, & Shibayama, 2009). More extensive studies on the selective extraction of copper from enargite- bearing copper ores and concentrates are much needed to improve copper recovery.

Jan 1, 2019

By J. G. George

A brief review of the silver industry is presented to set the stage for the analysis of the distribution of silver production by source from various types of mines in Canada and of the changing relationship between the total output of silver and the total output of base metals. The decline in the average grade of the Canadian mines is also discussed and a trend for the future is proposed. The report then examines in broader aspects the world primary silver production and concludes, in the section on outlook, that the effective supply in primary silver will grow at a rate significantly lower than the growth rate expected for base metals. A cumulative deficit of some 900 million ounces is projected for the period 1975-1980 and a further deficit of some 1,100 million ounces if projected for the 1980-to-1985 period.

Jan 1, 1977

By E. Lee Bray

"Editor’s note: The editors thank those who make this annual issue possible. A special thank you goes out to the Industrial Minerals Annual Review editor, to the Industrial Minerals & Aggregates Division Technical Committee chair and vice chairs, and to the authors of the individual commodity profiles.Jim Norman, member SME, of Tetra Tech Geo, is the industrial minerals annual review editor. Edgar Blanco, member SME, of Freeport- McMoRan, is chair of the Industrial Minerals &Aggregates Division’s Technical Committee.The technical committee vice chairs include:• NickTushar Gupta and Sallie Gaillard, of the USGS, members SME, agricultural materials.• Abhishek Choudhuryand Xihui Yin, members SME, of Montana Tech and Kemira, repectively, ceramic and refractory materials.• Bobbi Strange and Riddhika Jain, members SME, of Outotec, Martin Marietta and Outotec, respectively, chemical raw materials.• Snehamoy Chatterjee, Alyssa Kendir and Alind Chandra, members SME, of BMT, Universityof Kentucky and Michigan Tech, respectively,construction aggregates.• Subham Verma, Gauran Soni and Freddy Sime, members SME, fillers and pigments.• Kaiwu Huang, Thomas Hilderbrand and Ricardo Santander members SME, of Virginia Tech, Thiele Kaolin and Carbo Ceramics, respectively, sorbents, filters and process aids.• Rhaghay Dubey and William Rapier, members SME, of Outotec and a consultant, respectively, specialty minerals.On behalf of ME readers, the editors thankTwo U.S. alumina refineries produced an estimated 1.5 Mt (1.65 million st) of alumina from imported bauxite in the United States in 2018. The 500-kt/a (550,000-stpy) refinery in Burnside, LA, owned by Almatis Inc. produced specialty alumina used in the abrasives, ceramics, chemical and refractory industries. The 1.2-Mt/a (1.32 million-stpy) refinery in Gramercy, LA, owned by Noranda Alumina LLC produced alumina mostly for use in aluminum smelters but also produced specialty alumina. An upgrade project at the Gramercy refinery to convert 200 kt/a (220,000 stpy) of capacity to produce more profitable specialty alumina was completed in the first half of 2018, and another project to increase capacity was started but a completion schedule was not available. The amount of new capacity was not disclosed, but it would be used to produce nonmetallurgical grade alumina. The 2.3-Mt/a (2.5 million-stpy) refinery in Point Comfort, TX, which was temporarily shut down in March 2016, remained closed throughout the year."

Jul 1, 2019

By H. Sekimoto, T. Matsuoka, K. Yasuhara, M. Ota, S. Akutagawa

A magnetic anisotropy sensor is used for nondestructive measurement of stress on surfaces of a ferromagnetic material, such as steel. The sensor is built on the principle of the magneto-strictive effect in which changes in magnetic permeability due to deformation of the material is measured in a nondestructive manner, which then can be translated into the absolute values of stresses existing on the surface. This technique was applied to measure stresses of H-beams used in tunnels. The results show that this method could be one of the promising technologies for non-destructive stress measurement for safe construction of underground structures. Une sonde magnétique anisotropique est utilisée pour des mesures non-destructives de stress sur la surface d' unmétal ferromagnétique, comme l'acier. La sonde est construite sur le principe de l'effet magnéto-strictif dans lequel les changements dans la perméabilité magnétique due à la déformation du metal est mesurée avec une manière non-destructive, qui peut être alors traduite en valeurs absolues des stress existants à la surface. Cette technique a été appliquée pour la mesure de stress des poutres en H utilisées dans les tunnels. Les résultats montrent que cette méthode peut être l'une des technologies promet tantes concernant les mesures non-destructives de stress pour des constructions sûres de strcutures souterraines. Ein magnetischer Anisotropie-Sensor wird für die zerstörungsfreie Messung von Spannungen an Oberflächenvon ferromagnetischen Materialien wie z.B. Stahl verwendet. Der Sensor kann Änderungen in der magnetischen Durchlässigkeit auf Grund von Verformungen des Materials erkennen, die dann in Absolutwerte der Spannungen an der Oberfläche umgerechnet werden können. Die Methode wurde auf Messung von Spannungenvon H-Balken in Tunnels angewendet. Ergebnisse zeigen, dass dies eine vielversprechende Methode für diezerstörungefreie Messung im Tiefbau ist.

Jan 1, 2003

By J C. Volkwein, A D. A Hansen, E Sarver, C Barrett

Ensuring that diesel particulate matter (DPM) levels in underground metal and non-metal mines are maintained below statutory limits is an essential requirement of mine ventilation systems. However, despite the cost of providing ventilation, air ventilation rates are usually based upon models, assumptions, or measurements integrated over long durations rather than actual need. Real-time measurement of DPM, interpreted in terms of mine activity schedules, can offer better ventilation management to keep DPM within regulated levels while controlling costs. This work presents data from three demonstration sites with in-mine applications of an environmental particulate sensor that measured black carbon (BC) as a surrogate for DPM.Aethalometers are a class of environmental monitors that measure the light absorbance of aerosol particles at several optical wavelengths. A model AE33 Aethalometer was operated in three separate mines for periods of two weeks, three months, and seven-plus months, and the data was reported in real time as a concentration of BC. Concentration of aromatic organic compounds, which can indicate other forms of combustion, was also reported. The data was used to:- measure the relative efficiency of a new scale-model DPM air scrubber- determine if ventilation could be reduced in a shotcrete loading facility without compromising air quality- evaluate diurnal and weekly DPM levels in a large-entry stone mine. Instrument data were displayed locally and stored for later downloading in all cases. In one mine, the instrument was connected to a local controller, and in another it was connected to the mine’s underground network so that DPM data was presented in real time to a display in the mine ventilation engineering office on the surface.The results showed that the air scrubber removes from 82 per cent to 95 per cent of the DPM; that DPM produced during shotcrete loading is only a minor part of overall DPM levels; and that wide variations in DPM levels exist in the limestone operation. The DPM monitor operated continuously for extended periods in these underground environments. The only maintenance required was the routine replacement of filter tape, typically on a two-week schedule. A sample diluter, which is currently being tested, could extend the intervals between filter changes. The real-time data output of the Aethalometer is appropriate for direct integration into ventilation-on-demand control systems.CITATION:Volkwein, J C, Barrett, C, Sarver, E and Hansen, A D A, 2017. Application of an environmental ‘black carbon’ particulate sensor for continuous measurement of DPM in three underground mines, in Proceedings Australian Mine Vent Conference 2017, pp 143–150 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By Shelby Z. Palya

"The Bureau of Mines was established in the public interest to conduct inquiries and scientific and technologic investigations concerning mining and the preparation, treatment, and utilization of mining-substances; to promote health and safety, in the mineral industries; to conserve Material resources , and prevent their waste; to further economic development; to increase efficiency in the mining, metallurgical, quarrying, and other Mineral industries; and to inquire into the economic conditions affecting those industries. The organic act of the Bureau, as amended by Congress and approved February 25, 1913, made it the province and duty of the Bureau to ""disseminate information concerning these subjects in such manner as will best carry out the purposes of this Act.""In accordance with this directive, the Bureau reports the findings of its research and investigations in its own series of publications and also in articles that appear in scientific, technical, and trade journals; in proceedings of conventions and seminars; in reference books; and in other non-Bureau publications. The number of these reports, the wide range of subjects they cover, and the variety of mediums in which they appear make the kind of list and index presented in this special publication both necessary and valuable. This issue describes reports and articles published during the period January 1, 1975, to December 31, 1979. It supplements the 50-year list of Bureau publications issued from July 1, 1910, to January 1, 1960; 2 the 50-year list, of articles by Bureau authors published outside the Bureau from July 1, 1910, to January 1, 1960; 3 the 5-year lists of publications and articles, from January 1, 1960, to December 31, 1964,, from January 1, .1965, to December 31, 1969,5 'and from January '1, 1970, to December 31, 1974; and the annual ,lists of Bureau publications and articles from January, 1 to December 31, 1975,7 from January 1, to December 31, 1976,8 from January 1 to December 31, 1977, and from January 1 to December 31, 1978."

Jan 1, 1981

By L. E. Eary, Andy Davis

The evolution of pit lake water quality depends on the lithology and hydrologic characteristics of the ultimate pit surface, the availability of buffering capacity in the wall rock vs. oxidizable sulfide content, the alkalinity of recharging groundwater and the evapo-concentrative characteristics of the system. This paper assesses the geochemistry of 11 existing pit lakes, ranging from the acid Red Hill and Berkeley pit lakes (pH 2.6 to 2.8) to the alkaline Yerington pit lake (pH 8.45). Predicted pit lake chemistry is similar to that in existing pits, with long-term chemistry lying on a geochemical continuum between end members that consist of influent calcium bicarbonate groundwater and naturally occurring sulfate-rich evaporite playa lakes.

Jan 1, 1998

By E. S. Moore

Although nickel was in use in alloys long before the Christian era, the metal was not discovered until 1751, when Cronstedt recognized it in niccolite from Sweden. The Chinese apparently used a nickel alloy, known as "pahfong" thousands of years ago and Persian coins dating farther back than 200 B.C. consist of a copper-nickel alloy similar to some of those now in use in coins. The pure metal was first prepared about 1775 and the metal was refined for commercial purposes some years later. The nickel industry did not attain much prominence until the ores in New Caledonia were discovered. Exports of ore from that country began in 1875 and since that date there has been an ever-increasing world output of nickel and a great expansion in the uses of the metal except during short periods of commercial and industrial depression. Previous to 1875, for a number of years, Norway was the chief producer, although the metal was mined also in Sweden, Finland, Italy, Germany, Austria, France, China, the United States and other countries. With the discovery of nickel deposits in the Sudbury district, Ontario, a new factor was introduced into the nickel industry and Sudbury has since become the overwhelmingly dominant feature in the world's nickel markets. Although nickel was first discovered in Canada as early as 1848 near the north shore of Lake Huron and nickel-copper sulfides were found in 1856 by surveyors working close to the present location of the important rnine at Creighton, in the Sudbury field, it was not until 1883 that any importance was attached to this field. In that year copper sulfide attracted attention where the main line of the Canadian Pacific railroad was being projected across Canada to the Pacific coast. Mining began near this discovery in 1889 but in the meantime operations had begun in 1886 in other parts of the field and by 1890 about 100,000 tons of ore had been raised. In the Sudbury field, as in Norway and at the old Lancaster Gap mine in Pennsylvania, the ore was first mined for its copper content and difficully in the refining of the copper led to the discovery of the important proportions of nickel in the ore. No. 3 property of the International Nickel Co., now known as the Frood, the greatest deposit in the

Jan 1, 1932

By Roger L. Beals, George A. Tweedy

I. INTRODUCTION. THE results of the cyanide-operations, given in detail in the following paper, show the progress that is being made at the Minas del Tajo. The old pan-amalgamation process, in operation up to and including 1905, while paying a profit on high-grade ores, was no longer able to treat profitably the ores in sight at that time, hence an alteration in the process was imperative. The success of this alteration is eloquently expressed by the following data Pan- Amalgamation. Cyanidation. 1905. 1907. 1903. Tons treated, . . 51,387 53,983 69,300 Value per ton (U. S. currency),. $10.75 $8.39 $8.28 Extraction, per cent., 65.00 88.50 S7.45 Extraction, per ton. .- $7.00 $7.4.; $7.24 Total cost, per ton treated, 6.50 4.311 4.01 Profit, per ton treated, . . 0.50 3.07 3.23.;

Feb 1, 1910

By Scott, Turner

IN 1933, the monetary metals were produced in a ratio of 6.7 oz. of silver to 1 oz. of gold, the lowest relatively for silver since the period from 1851 to 1865. At the beginning of that period, the virgin placers of California -and Australia began producing almost simultaneously; in consequence, there was an abrupt fall in the high silver side of the ratio that had prevailed through the centuries after America was discovered. The output from the Comstock and other silver-bearing lodes, located a decade after this influx of new gold began, soon restored the production ratio to its former proportion, that is, a relatively large weight of silver compared to gold.

Jan 1, 1934

By J. Leinart

As is readily apparent, the reliability of the early-stage costs estimated for any mining project are critical to the viability of that project. An estimate too high might leave a potentially profitable deposit undeveloped or worse yet, available to a competitor. One too low might waste investment dollars in a project not yet economically ripe. There are two aspects critical to any estimate: 1. The cost data used to represent the values of the wages, salaries, supplies, and equipment. 2. The design used to determine the engineering parameters upon which the above estimated values are based. Given that all of the information contained in Mining Cost Service is provided by suppliers, equipment manufacturers and mine operators, one wonders why there is any question as to the reliability of cost estimates developed using this information. Given that it is all actual (as opposed to statistically derived) data, where do the problems with estimate reliability lie and what is the impact of the data on that reliability? The following presents a series of analyses designed to assess the reliability of the cost estimating process. Both the actual cost data and the engineering parameters upon which they are based are examined in an attempt to quantify and understand the importance of each. While several sources of cost information are available (Means, Richardson, Primedia?s Equipment Watch, and individual suppliers and manufacturers), the following rely solely on data contained in InfoMine USA, Inc?s, Mining Cost Service and in its Sherpa Mine Cost Estimating Software.

Feb 27, 2013

By W. J. Kingwell

Where the equipment, technique and materials are available for the construction of large diameter rock socketted piles, this is frequently the most economical and environmentally acceptable method of supporting very large concentrated foundation loads in geoglogically appropriate areas. This paper outlines the current approaches in Australia to design and installation of large diameter rock socketted piles. The equipment and procedures described generally reflect those developed or used by Vibro-Pile (Aust.), a company which, while installing the usual range of driven and bored piles, specializes in the design and construction of large diameter rock socketted piles and possesses special expertise in drilling in high strength rock. A high capacity crane attached drill for large diameter drilling in rock is briefly described. Discussed in detail are the construction techniques employed and structural and geomechanical design methods adopted.

Jan 1, 1989

By Amado Yataco

El presente texto describe un cuadro comparativo sobre la producción minera comprendida entre el período de enero-febrero 2017 y 2016. En este se observa un déficit reiterativo en oro, plata, plomo y estaño y un menor avance en el cobre y zinc, dada la caída de producción metálica en Antamina. Así también se describe la caída de variación del PBI de oro, plata y plomo en febrero del presente año y la participación de cada metal en la generación del PBI minero. Finalmente se describen las exportaciones e importaciones y la evolución de los metales principales de la minería en los últimos siete meses.

May 1, 2017

By Sergio N. Monteiro

Polymeric composites reinforced with natural fibers are increasingly been used in several engineering applications, from automotive parts to building construction elements. In addition to the relatively low cost, the natural fibers are also appraised by their renewable and biodegradable characteristics. Fibers extracted from the crust of coconut fruits, also known as coir fibers have been investigated for a possible use in composite materials. In the present work, the coirfiber/polyester matrix interfacial strength was evaluated by means of pullout tests. The variation of the pullout tensile stress vs. the embedded coir fiber length permitted to determine the critical fiber length and, thus, to calculate the interfacial strength. Observations by SEM complemented the results from pullout tests, indicating that coir fibers have a potential for application aspolymeric composites that could replace conventional materials such as wooden and gypsumpanels.

Jan 1, 2006

Researchers, medical organizations, statisticians, and others often use data on the nature and rate of occurrence of occupational diseases in directing their efforts and plans. Very often this information is developed from the reports of the States which describe the nature of work¬men's compensation claims and awards and the frequency with which they are made. To be meaningful, the statis¬tical information must be viewed in the context of the State laws involved. There is considerable variation among the laws of the different States. The Bureau of Mines has responsibilities for protecting the health of persons employed in the mineral industries and for the development of useful mineral products. To assist the Bureau in the accomplishment of its objectives, this compilation has been undertaken. For the benefit of the mineral industries, and any others who may have a similar interest, this volume is made available. An earlier compilation of the Bureau of Mines on this subject was published in 1952.4 However, during the intervening years, sufficient changes have been made in State laws to warrant completely recompiling the information. This publication includes the laws of the States, the District of Columbia, Puerto Rico, and the Virgin Is¬lands through 1964. Only those portions of the workmen's compensation laws which apply to or as ' related to occupational diseases are presented, and in each case enacted additions to and deletions from the basic law have been incorporated into the text of the law, thus snak¬ing it unnecessary to search out the various amendments made each year.

Jan 1, 1967

By Enzo Palumbo, Joël P. T. Kapusta, François Larouche

In light of the rapid deployment of bottom blowing smelting in China over the last ten years, one has to wonder why it has taken the copper industry so long to adopt ultra-high oxygen enrichment via Savard-Lee type injectors. As early as 1976, Kellogg and Henderson suggested, in their landmark paper on energy usage in the copper industry, that ‘maximum use of oxygen enrichment of process air’ was one of seven ‘energy saving features’ for copper matte smelting and converting. Yet today, shrouded injection and high oxygen enrichment has not been implemented in copper bath smelting outside China and Vietnam. In this paper, the authors explore the reasons why bath smelting processes such as the Noranda Reactor and the Teniente Converter still operate around 40% oxygen enrichment, while the bottom blowing SKS/BBS process typically runs at 65 to 75% oxygen, with all three processes producing white metal. Are there fundamental metallurgical explanations for this striking difference beyond the long-standing skepticism towards high oxygen shrouded injection and its perceived high implementation cost?

Jan 1, 2015

By M. R. Pickus, I. W. Pickus

ORDINARILY age-hardening is thought of as being associated with a limited solubility of one metal in another. Much less has been written about the type of age-hardening that attends the formation of superstructures. Solid solutions generally have a disordered or random arrangement of atoms; that is to say, in a unit cell, such as that of the face-centered cubic lattice, there is no distinction between atomic sites. Atoms of a given metal may occupy cube corners or face centers. Under certain conditions, however, some alloys develop what is known as an ordered structure. In this case, cube corners would be occupied by only one type of atom and face centers by another type, Associated with this ordering process are many interesting changes in physical and electrical properties. Moreover, in many instances the alloys become susceptible to age-hardening. From the evidence now to be described, it appears that age-hardening in 14-carat gold alloys is due to the formation of both a super-structure and a precipitate. Alloys of the metals gold, silver and copper were known in antiquity. The available knowledge regarding their constitution has been ably summarized and extended by Sterner-Rainer,1 Janecke,2 Carter,3 Wise,4 and Coleman.5 Despite the long familiarity with these alloys and the numerous investigations of their properties that have been made, there is still much that remains unexplained. It has been known for a long time that the hardness of these alloys is closely related to the rate of cooling, Similar changes have been observed in the binary gold-copper system,6 one alloy of which corresponding to the formula Cu3Au, has been the subject of a careful and competent report by the English investigators, Sykes and Evans.7 They have established the fact that the shift of atoms from the ordered to the disordered condition takes place in some critical temperature range. At temperatures above the critical range the structure is random, and at temperatures below it the structure is ordered. No difference between these two structures is revealed by the microscope. Both have a face-centered cubic lattice and complete solubility, so that there is no evidence to suggest that the changes in properties are associated with a phase change, The more slowly the alloy is cooled, the higher is the degree to which the ordering process proceeds and the more marked is the increase in hardness. As experimental data were accumulated on 14-carat gold alloys, several contradictions arose. Certain observations tended to confirm the existence of a superstructure, while other observations seemed to be inconsistent with such a transformation. PRESENT INVESTIGATION As a focal point about which to develop this subject, it is expedient to consider first

Jan 1, 1943