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By D. C. Lynch

While a sizable amount of data exist as to the activity and distribution of minor elements between matte and metal, there has been no unifying theory presented delineating the form of dissolution of these elements in molten sulfides. In order to alleviate that deficiency the literature concerning the behavior of As, Sb, Bi and Pb in mattes is reviewed. Models present in the literature, regarding the thermochemical behavior of minor elements, are tested, and new models are presented and evaluated using thermodynamic theory. The results of those analyses are used to predict optimum conditions for the volatilization of minor elements. The dearth of data on the behavior of minor elements in nickel mattes requires that this review focus on copper- iron mattes. An effort is made, however, to utilize basic knowledge regarding nickel sulfides and the interaction of nickel with the minor elements to predict the behavior of those elements in nickel-copper and nickel-iron mattes.

Jan 1, 1993

By R. P. Vinson

The Bureau of Mines conducted a series of tests to determine how well the Bendix BDX 60, the Gilian HFS 113U, the MSA Fixt-Flo, and the Spectrex PAS-3000 dust sampling pumps control the flow rate at 2 L/min. These tests were performed because users need to know the performance characteristics of sampling pumps to select the pump that best satisfies their sampling requirements. Long-term (6- to 8-h) flow stability at various backpressures was examined in relation to the flow control tolerance of ±5% of the flow, the level imposed by Federal regulations; four of the five Bendix pumps did not meet the criterion for this test, which was passed by all other pumps tested. Flow control recovery times were measured at transient backpressures; all pumps evaluated met the criterion for this test. The low-flow indicators of the sampling pumps were tested; only two Bendix pumps and one Gilian pump met the criterion of indicating a flow change greater than ±5%. In the pulsation flow measurement test all of the pumps passed, with pulsating flows greater than 20 Hz. The Bureau also evaluated the manuals accompanying the sampling pumps. All were judged adequate except the Spectrex manual, which was judged poor.

Jan 1, 1985

Cutter roof failure, a ground control problem that frequently results in massive roof failure, is common in coal mines of the Northern Appala-chian Coal Basin, causing delays in production and posing a safety hazard to mine personnel. The Bureau of Mines is conducting research on the causes of cutter roof failure to gain a basis from which to predict and prevent its occurrence, and to support such roof when failure occurs or is imminent. Research conducted at the Greenwich Collieries North and South Mines, in central Pennsylvania revealed a correlation between the presence of clastic dikes and formation of cutter roof failure. The research con-sisted of in-mine mapping of geologic and deformational features, rock pressure monitoring, core recovery and evaluation, and in situ stress measurement. It was found that roof failure increased in areas where the occurrence of clastic dikes was most frequent, especially where two or more clastic dikes intersect. Staggering of crosscuts prevented the extension of cutters and deterred the occurrence of large falls extending over several break-throughs. In addition, trusses and cribbing were effective in stabilizing clastic dikes and inhibiting the development of cutter roof failure when employed immediately or shortly after mining.

Jan 1, 1987

By Nirander M. Safaya

Revegetation success on surface mined lands is dependent upon the nature of the plant growth media. Soil physical and chemical properties dictate the needs for specific reclamation and subsequent management practices. Field experiments were conducted at six coal mine sites in Oliver and Mercer Counties, North Dakota to determine the subsequent effects of a single application of selected amendments on spoil and topsoils over the five year period, 1974-1978. Considerable variations in the physical and chemical properties were found in mine spoils from site to site. The texture of spoils ranged from sandy clay loamy at North Beulah I to loamy at Glenharold, and from sandy loamy at North Beulah 3 and South Beulah sites to loamy sands at the Center site. The pH of the sites ranged from 6.5 at South Beulah to 8.2 at North Beulah 3. In many cases, the pH values of mine spoils were not significantly different from the topsoils. The electrical conductivity (ECe) did not exceed 6 mmhos cm-1 at the test sites even though in other studies much higher values were recorded in the same vicinity. The spoils from Glenharold and North Beulah test sites can be classed as moderately saline, and those from Center and South Beulah as non-saline. The sodium adsorption ratios (SAR) varied from less than 1 to 32, with highest values in the spoils of North Beulah 3 followed by Glenharold; all other sites were nonsodic. Lowest SAR values (less than 1) were found in the topsoiled sites at South Beulah and Center. Spoils of North Beulah 3 test site were highly calcareous, followed by North Beulah 2 and Glenharold. Center mine spoils which were the least calcareous of the test sites, showed the calcium carbonate equivalent three times higher than that of the topsoil. The average calcium concentrations in the spoils of North Beulah 3 and South Beulah test sites were -13 and 14 me 100g -l while at North Beulah 2 and Glenharold test sites 25 and 22 me 100-1-1 were recorded, respectively. The overall magnesium concentrations ranged from an average of 4 to 16 me 100g 1. Sodium concentrations in all sites never exceeded 10 me 100g-1. Phosphorus concentrations on the average at North Beulah 1, North Beulah 2, and Center were 10.2, 4.6, and 22.2 µg g -1 spoil, respectively. Concentrations of potassium ranged from 200 ppm at South Beulah site to more than 375 pp in at the Glenharold site. High concentrations of sulfates (239-2778 µg g-1) seem to contribute to the salinity in these spoils. Chloride concentrations of spoils were low and never exceeded 40 µg g-1 spoil. Based on established critical levels of deficiency for micronutrients in agricultural soils, it seems that none of these were deficient. However, controlled environment experiments did reveal increased plant growth responses when some micronutrients were added to the mine spoils. Treatment effects were highly site specific depending on the nature of the soil/spoil characteristics and, of course, the properties of the various treatments. While slack coal amendment to the spoils at North Beulah 2 site affected significant increases in a large number of variables (both major and trace elements), amendment of the topsoils at the South Beulah test site with leonardite resulted in significant decreases in a number of variables, particularly trace elements. Spoils at Glenharold and North Beulah 3 demonstrated the fewest significant changes due to amendments. Calcium, magnesium, strontium, organic matter and nitrogen were consistently increased from site to site with the addition of lignitic materials. Other spoil/topsoil physical and chemical properties (30 variables) as affected by amendments and time are discussed.

Jan 1, 1982

By R. Benito

This paper describes the development of a life-of-mine schedule (LOM) for one of the world's largest known sedimentary copper-cobalt districts located in the Katanga Province, Democratic Republic of Congo (DRC). A particular feature of the Tenke Fungurume LOM schedule is the considerable number of pits/phases for scheduling, each competing to provide the best ore available to a capacity-constrained process facility. This paper discusses the LOM scheduling objectives and constraints, data preprocessing steps such as ore binning, block aggregation and clustering analysis as a scheduling aid, the mine scheduling approach and results and conclusions. Mining Engineering, 2011, Vol. 63, No. 8, pp. 39-47. Official publication of the Society for Mining, Metallurgy and Exploration, Inc.

Jan 1, 2011

By Hsing Kuang Lin

Ferric chloride leaching w.as applied to a complex sulfide ore from Tok, Alaska to dissolve zinc, lead, silver and copper. Gold in the leaching residue, as well as in the ore, is found to be refractory to the conventional cyanidation process. Roasting, pressure oxidation and elemental sulfur removal followed by cyanidation were tested to improve gold dissolution. Also tested were thiourea leaching and high-pressure cyanidation. The readsorption of dissolved gold by carbonaceous matter in the chloride leaching residue was analyzed. Based on the experimental results, factors causing difficulty of gold dissolution from the leaching residue are discussed.

Jan 1, 1989

By K. K. Kershner

Sulfide ore concentrates containing cobalt, nickel, copper, lead, and iron were salt roasted and leached on a laboratory scale. More than 95 percent of the cobalt, nickel, and copper was recovered. Heating patterns for salt roasting different concentrates were established. More cobalt, nickel, and copper were recovered from a bulk concentrate composed of a mixture of copper concentrate and iron concentrate. This mixture corresponded roughly with the mixture of these materials in stockpiles in southeastern Missouri. A temperature range of 375° to 400° C. was best for salt roasting. Metal chlorides were leached at a pH of 1 from chloridized charges of concentrates, Although the amounts of cobalt, nickel, and copper extracted were high, the amount of iron dissolved simultaneously interfered with subsequent separation and recovery of these metals. The amount of dissolved iron was reduced substantially by steam treating chloridized charges of bulk concentrate at 300° C. In this way, the ratios of cobalt, nickel, and copper to iron in leach liquors permitted satisfactory separation and recovery of these metals. INTRODUCTION The Federal Bureau of Mines is experimenting with chloridizing reactions.4 5 6 7/ Salt roasting of sulfide ores and concentrates, or their calcines, to form metal chlorides has certain advantages. Chlorides of

Jan 1, 1961

By T. C. Page

The Yarnell gold depoSit, located in the Weaver mining district of Yavapai County, Arizona is found within a structurally controlled, hydrothermally altered zone that occurs within a 1700 Ma granodioritic intrusive. Both potassic and sericitically altered rock that occur around and above the low-angle northeast striking Yarnell fault are known to host economic gold mineralization; a wider envelope of weakly-propylitic alterred rock also occurs in this area. During mineralization, strong sericitization accompanied several stages of quartz ± adularia veining, stockwork formation, and localized silicification and potassic replacement, in association with deposition of specularite, pyrite (now oxidized), and gold. The footwall of the fault is also sericitically altered but poorly mineralized. Mineralization along the Yarnell fault continues both northeast and southwest from the main deposit although the thickness of the zone and associated alteration envelope diminish away from the orebody. A sample of undeformed illite taken from the Yarnell fault zone was K/Ar dated at 69 ± 1.6 Ma; this date reflects a minimum age for both mineralization and latest movement on the fault. Gold mineralization is accompanied by modest increases in Ag, As, Cu, and Mo content. Both CO2-and H20-rich fluid inclusions were studied and suggest mesothermal pressures and temperatures of formation for the deposit.

Jan 1, 1992

By G. W. McMahon

Following the Sago Mine accident, the U.S. Mine Safety and Health Administration (MSHA) asked the U.S. Army Engineer Research and Development Center to study several possible methane explosion scenarios in the Sago coal mine. The study used a 0.3-m (1-ft) resolution map of the mine to produce a 3-dimensional (3 D) model of a portion of the mine, including the sealed area where the explosion occurred. An advanced 3 D computational fluid dynamics (CFD) code was used to calculate the explosion pressures within the sealed area, on the mine seals and in nearby regions of the mine. Based on the best available information on methane concentrations and assumptions on homogeneity and on layering and mix composition, three separate initial conditions of methane-air concentrations and location were studied. This paper discusses the CFD modeling technique, the results of the calculations, the challenges of conducting this type of modeling and the advantages and limitations of CFD modeling of accident investigations of mine explosions.

Jul 1, 2010

By A Bax, G Wardell-Johnson, W P. Staunton, J McGrath, J J. Eksteen

Since 2001, the AMIRA P420 gold processing technology project series has been studying the recovery of gold using gravity devices, with particular emphasis on the centrifugal units, Knelson and Falcon concentrators. The work has entailed the surveying of operating gravity circuits in Australia, Africa and North and South America.This paper reviews some of the results and lessons of these studies, including common circuit operating and design factors, which limit gravity recovery; pointers towards effective modelling of gravity circuits; and the contribution of gravity to overall gold recovery.CITATION:Wardell-Johnson, G, Bax, A, Staunton, W P, McGrath, J and Eksteen, J J, 2013. A decade of gravity gold recovery, in Proceedings World Gold 2013 , pp 225-232 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By V. I. Lakshmanan

The demand for elements such as nickel, cobalt, titanium and gold in various applications has increased significantly. Innovation to recover these elements now plays a major role in metallurgical processes as established technologies have challenges in treating the types of ores that are available while meeting the increasingly stricter environmental regulations. Alternative chloride based processes have been developed that can be used to recover the value elements from the available feed stocks with potentially lower environmental impact. Chloride-based hydrometallurgical processes have several advantages, including higher leachability of complex ores/tailings and relative stability of chloro-complexes of the metals. Process Research ORTECH Inc. (PRO) has developed mixed-chloride process flowsheets, where innovative solvent extraction process steps are used for the separation of nickel, cobalt, titanium and gold from their respective chloride solutions. This paper will discuss the potential aqueous chloro-chemistry of these metals and separation reaction mechanisms involved in the solvent extraction process.

By J. B. Hiskey

The principle oxide minerals of molybdenum are wulfenite (PbMoO4), ferrimolybdite (Fe2(MOO 4)3.nH2O), powellite (CaMoO4), and ilsemannite (Mo304). Wulfenite is found in Arizona, New Mexico, Nevada, Utah, California, and Montana. It is also found in the states of Sonora and Chihuahua, Mexico. Prior to 1915 wulfenite ores were the primary source of molybdenum. The solubility of wulfenite in hot sodium sulfide was first noted by Bonardi(1) during attempts to sulfidize wulfenite material prior to flotation. He identified lead sulfide and soluble sodium molybdate as reaction products. Bacon (2) sulfidized wulfenite in preparation for flotation and by X-ray analysis found the reaction product to be lead sulfide. Holmes(3) made an extensive investigation of the extraction of molybdenum from wulfenite concentrates by leaching. Nearly 100% molybdenum extraction was possible from -100 mesh samples leached for 15 min with 10% sodium sulfide solution at room temperature. Molybdenum extraction from -100 mesh samples after leaching 30 min at a temperature of 45°C using 2, 4, and 6% sodium sulfide was about 32, 79, and 98% respectively. The extraction showed little sensitivity to time, temperature, or particle size using 10" sodium sulfide solution.

Jan 1, 1976

By Harry V. Makar

As part of a continuing research program for conserving domestic mineral resources, the Bureau of Mines is investigating new and improved scrap identification techniques to improve sorted mixed scrap purity. This report focuses on various classes of wrought and cast copper alloys produced with recycled scrap. Based on a survey of the literature, principal alloys, such as the brasses and bronzes, are examined with respect to impurity elements and their effects on metallurgical behavior. Effects of elements such as lead, antimony, iron, chromium, and aluminum are discussed. The metallurgical effects described include hot shortness, fire cracking, and undesirable phase transformations.

Jan 1, 1985

By W. A. Gow, G. M. Ritcey, M. C. Campbell

"Uranium is a unique commodity. It is both a metal and a fuel, It has both commercial and military uses. It yields ""clean energy "" but presents environmental concerns. All of these factors have an impact on the commerce of uranium.Being a metal, uranium is extracted from ore like many other metallic minerals. As a fuel, it is subject to the vagaries of energy commodity market forces. The history of uranium in the first nuclear weapons has led to nation al governments carefully controlling production and sale of uranium. The spectre of radioactive contamination of the environment adds further to the public concern over the disposal of low-level radioactive wastes from uranium processing and use.There have been a number of excellent reviews on the commercial aspects of the uranium industry. In this discussion, these aspects will be briefly summarized to provide a general picture of the strengths of the Canadian uranium industry and the pressures to which it is being subjected currently. The principal thrust of this paper will be to outline Canada's resource strength and to identify some factors which will affect Canada's ability to continue holding a sizeable share of the world uranium market."

Jan 1, 1985

By Jiahua Pan, Yanxiong Mei, Shuqin Liu, Rongfu Pei

Growth characteristics of Co-rich crusts from the Western Pacific have been approached. The thick crust shows 3 structural layers: compact upper layer, porous middle layer, and compact lower layer. The middle and lower layers have obviously different microscopic structure, color, and luster. Preliminary study of Calcareous nanofossils in one crust shows that the crust began to grow since Paleogene. The porous middle layer was formed from late Miocene to late Pliocene (Ca. 0.5 ~ 11.9Ma) and the compact lower layer was formed from late Paleocene to late Oligocene (Ca. 56.3 ~ 23.2Ma). The sedimentary hiatus of a 14.26Ma was observed between the middle and lower layers. The boundary between them to be Oligocene/Miocene (O/M) shows an important message on growth age.

By L. Garner McDonald

The U.S. Bureau of Mines tangentially impacted potential coal-cutter bit shank materials against sandstone to investigate the potential of the materials to ignite natural gas by a friction-generated hot streak. The shank material samples were mounted in a 24-in, 550-lb flywheel, which was rotated at surface speeds of 400 to 900 sfpm. The sandstone was advanced toward the rotating flywheel at feed rates of 1 mil per impact. The atmosphere mixture was 7 vol pct natural gas in air. Three grades of polycarbonate resin, an ultra-high-molecular weight polyethylene, and a zinc alloy (ZA27) were among the potential materials. None of these materials caused ignition of the methane at any of the three test speeds (400, 600, and 900 sfpm), but the above materials do not have sufficient strength to hold a carbide tip during coal cutting. Of the materials having sufficient strength to hold a carbide tip, three nickel-based alloys proved less likely to cause a natural gas ignition than did iron-based alloys such as 4340 (a commonly used shank material for coal cutters).

Jan 1, 2010

By L. Garner McDonald

The U.S. Bureau of Mines, under contract to the U.S. Department of Energy, investigated the erosive-wear properties of seven commercial alloys with potential applications as valves for coal-conversion plants. A dry particle, jet-erosion apparatus was used to determine the wear of seven materials: 316 and 440-C stainless steels, K-68, K-701, and K-801 cemented tungsten carbides, HC-250 white cast iron, and Haynes 6B. The alumina abrasive entrained in the nitrogen gas jet had particle sizes of 27 or 50 µm, the abrasive velocities were 55 to 170 m/s, and the particle impingement angles were 15° to 90°. The maximum specific wear for ductile materials was found to occur at impingement angles of 15° to 30°, and the minimum specific wear occurred at 60° to 90°. For the brittle materials, maximum specific wear occurred at impingement angles of 50° to 85° and minimum specific wear was at the lowest angles. As the velocity and erosive particle size increased, the specific wear increased. The specific wear was related to the velocity by the power function WocAVn, where n was 1.8 to 3.9 for ductile materials and 1.8 to 3.6 for brittle materials.

Jan 1, 2010

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

By Hillary W. St. Clair

Mining activity began in colonial times with ironmaking operations scattered along the eastern seaboard. Iron furnaces and forges manufactured iron implements from bog iron ores using charcoal from the extensive forests as a fuel. Lead ores were mined in the Mississippi Valley and copper ores in the Lake Superior region. However, the real beginning of the American mining industry did not occur until the 19th century. The history of American mining is organized around three epochal events. The first was the discovery of gold in California in 1848, which marked the beginning of a period of apprenticeship in mining and metallurgical techniques. The second was the discovery of the fabulous Comstock Lode in western Nevada in 1859, which expanded mining throughout the Far West and led to large-scale underground mining and the development of smelting techniques for lead, silver, and copper ores. The third event was the building of a transcontinental rail-road system after the Civil War, which brought about the consolidation of the industry from a large number of independent mines, mills, and smelters into integrated operations run by large corporations. Thus developed the mining industry that today supplies the energy and critical materials for the great-est industrial complex the world has known.

Jan 1, 1977

By N Jeannee, L Rattmann, M W. N Buxton, A deJong, K Nienhaus, A Soares, P Graham, A Korre, J Benndorf, D Buttgereit

The flow of information, and consequently the decision-making along the chain of mining from exploration to beneficiation, typically occurs in a discontinuous fashion over long timespans. In addition, due to the uncertain nature of the knowledge about deposits and the inherent spatial distribution of material characteristics, actual production performance often deviates from expectations. Reconciliation exercises to adjust mineral resource and reserve models and planning assumptions are performed with timely lags of weeks, months or even years.The key concept of real-time mining promotes a change in paradigm from discontinuous intermittent process monitoring to a continuous process and quality management system in the resource extraction process. The framework includes a real-time feedback control loop that rapidly links online data acquired during extraction at the mining face, material handling and processing with a sequentially updatable resource model. This will allow near real-time optimisation of decisions related to long-term planning, short-term sequencing and production control.The proposed framework integrates the following building blocks in a holistic manner: automated sensor-based material characterisationonline machine performance measurementsunderground navigation and positioningunderground mining system simulation and optimisation of planning decisionsupdating techniques for resource/reserve models.This paper introduces the real-time mining concept and the building blocks and provides a review of the state-of-the-art. Technological readiness of necessary building blocks is assessed, and critical gaps for further technology development are identified. The value added is illustrated by means of a case study.CITATION:Benndorf, J, Buxton, M W N, Nienhaus, K, Rattmann, L, Korre, A, Soares, A, deJong, A, Jeannee, N, Graham, P, Buttgereit, D, Gehlen, S, Eijkelkamp, F, Mischo, H, Sandtke, M and Wilsnack, T, 2015. Real-time mining – moving towards continuous process management in mineral resource extraction, in Proceedings Third International Future Mining Conference, pp 37–46 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015