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By Bruna de Camargo Lemos

O objetivo deste trabalho compreende a realização da síntese de SnO2 dopado com aditivo Sr2 contendo diferentes quantidades molares de SrO (X)SnO2+(1-X)SrO, em que o cátion Sr2+ foi introduzido através do nitrato de estrôncio variando de 5 à 50 % em mol para uma mistura tanto em meio aquoso quanto em meio alcoólico, seguida da calcinação do pó resultante que é feita à 700°C com uma taxa de 10°C/min. Análises de caracterização como difração de raios X, área específica, calorimetria exploratória, picnometria a gás e determinação do ponto isoelétrico das suspensões aquosas foram realizadas de modo a verificar qual o agente dispersante mais apropriado para as características ácido-básicos da suspensão em questão. A partir deste determinar o potencial zeta do composto estudado através da eletroforese. Compostos intermediários a base de estanato de estanho foram identificados, e a deposição por eletroforese foi realizada com sucesso, uma vez que foi possível obter uma suspensão estável a partir dos pós cerâmicos produzidos.

Aug 16, 2017

By A. Hultgren, G. Phragmén

Page Outline of Progress of Knowledge and Theories about Gas Evolution in Steel Ingots. and Its Influence on Crystallization and Segregation................ 134 Object of Present Investigation........................................... 148 Theoretical Discussion of Process of Solidification........................... 149 Gas Given Off from Rimming Steel during Solidification................... 149 Equilibrium Diagram of the Iron-carbon-oxygen Alloys................... 151 Solidification of Pure Iron-carbon-oxygen Alloys.......................... 157 Solidification when Carbon Monoxide Is Given Off at Constant Pressure... 157 Solidification when Gas Evolution Is Suppressed....................... 158 Schematic Application on Solidification of Rimming-steel Ingots.......... 159 Influence of Manganese, Sulphur and Phosphorus......................... 160 Experimental work..................................................... 162 Liquid Steel and the Mold Gas......................................... 162 Ingots Investigated and Methods Used.................................. 165 Ingot structure....................................................... 174 Structure of Rim Zone.............................................. 174 Structure of Core................................................... 181 Structures Obtained under Special Conditions of Freezing................ 182 Distribution of Metalloids............................................. 187 Other Observations Made............................................. 192 General Discussion of Solidification Process................................. 195 Condition of Liquid Steel before Casting................................. 195 Rimming Period...................................................... 202 Composition of Rim Zone............................................. 225 Freezing after Top Is Closed........................................... 228 Slag Inclusions and Ingot Scum........................................ 234 Reaction between Gas in Blowholes and Surrounding Solid Steel during Cooling 235 Summary.............................................................. 237 Appendix—Preparation and Etching of Ingot Sections....................... 238 References............................................................. 239 In 1934, Jernkontoret (The Swedish Ironmasters' Association) appointed a committee for the study of the structure of rimming-steel ingots and the various phenomena associated with their solidification. The members of the committee, including those who have joined it later, have been: I. Bohm, B. D. Enlund, B. Kalling, M. Tigerschiöld, S. Wohlfahrt and the authors. The present paper‡ is a somewhat

Jan 1, 1939

By G. Phragmén, A. Hultgren

Page Outline of Progress of Knowledge and Theories about Gas Evolution in Steel Ingots. and Its Influence on Crystallization and Segregation................ 134 Object of Present Investigation........................................... 148 Theoretical Discussion of Process of Solidification........................... 149 Gas Given Off from Rimming Steel during Solidification................... 149 Equilibrium Diagram of the Iron-carbon-oxygen Alloys................... 151 Solidification of Pure Iron-carbon-oxygen Alloys.......................... 157 Solidification when Carbon Monoxide Is Given Off at Constant Pressure... 157 Solidification when Gas Evolution Is Suppressed....................... 158 Schematic Application on Solidification of Rimming-steel Ingots.......... 159 Influence of Manganese, Sulphur and Phosphorus......................... 160 Experimental work..................................................... 162 Liquid Steel and the Mold Gas......................................... 162 Ingots Investigated and Methods Used.................................. 165 Ingot structure....................................................... 174 Structure of Rim Zone.............................................. 174 Structure of Core................................................... 181 Structures Obtained under Special Conditions of Freezing................ 182 Distribution of Metalloids............................................. 187 Other Observations Made............................................. 192 General Discussion of Solidification Process................................. 195 Condition of Liquid Steel before Casting................................. 195 Rimming Period...................................................... 202 Composition of Rim Zone............................................. 225 Freezing after Top Is Closed........................................... 228 Slag Inclusions and Ingot Scum........................................ 234 Reaction between Gas in Blowholes and Surrounding Solid Steel during Cooling 235 Summary.............................................................. 237 Appendix—Preparation and Etching of Ingot Sections....................... 238 References............................................................. 239 In 1934, Jernkontoret (The Swedish Ironmasters' Association) appointed a committee for the study of the structure of rimming-steel ingots and the various phenomena associated with their solidification. The members of the committee, including those who have joined it later, have been: I. Bohm, B. D. Enlund, B. Kalling, M. Tigerschiöld, S. Wohlfahrt and the authors. The present paper‡ is a somewhat

Jan 1, 1939

By RENARDIR PEIXOTO MACIEL JUNIOR

A importância do desenvolvimento sustentável, tendo como base um ambiente saudável para as gerações futuras, leva a se pensar em como as organizações poderiam desenvolver materiais menos danosos ao ambiente com boas propriedades e pelo menor custo. A proposta de aproveitamento de fibras vegetais para utilização em desenvolvimento de compósitos de matriz polimérica reforçados pelas mesmas é a motivação da pesquisa visando obter um compósito com melhores propriedades mecânicas e químicas do que sua matéria prima. Por virtude da importância do desenvolvimento desses materiais, a caracterização mecânica da fibra, da matriz e, finalmente, do compósito através de ensaios destrutivos e não destrutivos é fundamental para estudo de sua aplicação. Após a obtenção dos dados, percebeu-se que a adição das fibras melhorou as propriedades mecânicas do compósito resultante. Mostrando, portanto, resultados promissores para o desenvolvimento desses materiais, promovendo assim um material mais barato e de melhor propriedade mecânica, além de uma alta leveza. Em suma, os resultados estão de acordo com o esperado, impulsionando assim um melhor estudo desses materiais, por exemplo, realizando outros ensaios, como ensaios de impacto.

Oct 30, 2017

The paper deals with the importance of design, and of codes of practice, in ensuring safe working conditions in mines. The design principles involved in the design process are dealt with, and the importance of a logical design process is emphasized. The links between the requirements for developing a code of practice, embodied in the existing guidelines for the preparation of such a code, and the design principles and process are considered in some detail. Finally, suggestions are included which may provide improvements to the code and hence, ultimately, lead to further improvement in safe working conditions.

Jan 1, 2003

By Afonso Garcez de Azevedo

As primeiras argamassas utilizadas em construções pelo homem continham em sua composição, materiais argilosos. Porém, por ser um material com muitas cargas elétricas livres, as argilas reagem constantemente com a água, ocasionando grande variação linear que acaba causando fissuração nas argamassas feitas com esse material. Assim, para solucionar esse problema, passou-se a utilizar cal hidratada no lugar dos materiais argilosos. Dessa maneira, mesmo não sendo composta por argila, a argamassa mantém sua trabalhabilidade. Nesse cenário, o presente trabalho teve como objetivo balancear estequiometricamente a cal hidratada e as argilas estudadas, para utilizar essas quantidades em argamassas para revestimento, barateando assim o material. Para encontrar esse balanceamento estequiométrico calculou-se a massa molar para um mol de cal hidratada e para um mol teórico de argila. Assim foram estipuladas algumas proporções possíveis de balanceamento da equação de reação cal+argila. Além disso, foram confeccionados corpos de prova, variando as quantidades de argila e cal, para realização de ensaios de capilaridade, a fim de comprovar a eficácia dos resultados encontrados no balanceamento teórico.

Oct 30, 2017

By Heitor Cristo Clem de Oliveira

O objetivo deste trabalho é estudar a reação de dessulfuração, envolvidas no processo de pré-tratamento de ferro-gusa. A princípio, as misturas utilizadas foram caracterizadas e estudadas através do software de termodinâmica computacional (FactSage 7.1). Em seguida, os resultados obtidos através do estudo termodinâmico computacional foram comparados com aqueles obtidos mediante os testes experimentais a 1400°C. As misturas dessulfurantes tiveram como base a CaO com três tipos de fundentes, fluorita, sodalita e barrilha, além da utilização de alumínio como elemento desoxidante. Os testes experimentais permitiram identificar que a adição de 0,1% em massa de alumínio no gusa, eleva a taxa de remoção de enxofre principalmente no instantes iniciais do processo. Com a utilização da termodinâmica computacional pode-se mostrar que a reação de dessulfuração no ferro-gusa é exotérmica para os teores de silício encontrados no processo. Além disso, a termodinâmica computacional também contribui, em alguns casos, para a análise de compostos sólidos que podem se formar na escória e limitar as reações de dessulfuração.

Oct 30, 2017

By Wainer da Silveira e Silva, Marco Antonio Teixeira, Robisom Damasceno Calado, Carlos Alberto Chaves, Tone Takayama Filho

A preocupação com o adequado tratamento de resíduos industriais surgiu com o conceito de desenvolvimento sustentável criado pelo Clube de Roma e contribuiu para o uso racional dos recursos naturais ao longo dos últimos 50 anos. A preocupação com a produção responsável e uso judicioso de recursos naturais priorizou a reciclagem de materiais na agenda das empresas, tornando-se numa atividade de alta relevância, vital para a sustentabilidade econômica e ambiental. Este trabalho aborda os aspectos técnicos, econômicos e ambientais da reciclagem de resíduos contendo zinco através do estudo de caso de reciclagem de resíduos gerados no processo de fabricação de aço em Forno Elétrico, denominado pó de Aciaria Elétrica (PAE). A indústria ainda está em busca de tecnologias para redução da geração e reciclagem desse resíduo. A relevância do estudo está na utilização da Análise Hierárquica de Processo (AHP) para avaliação e seleção da melhor alternativa, entre várias, para tratamento e reciclagem do PAE. Como resultado, demonstrou-se a eficácia do uso da metodologia no empreendimento de reciclagem de resíduos contendo zinco implantado pela Votorantim, em Juiz de Fora, Minas Gerais.

Nov 12, 2019

By Hideo Ando, Yuka Satou, Tatsuya Ishitake

Whole-body vibration occurs when the body is supported on a surface which is vibrating. Occupational exposures to whole-body vibration mainly occurs in the transportation industry, but also in association with other industrial process. Epidemiological studies have frequently indicated an elevated health risk for the spine in workers exposed to whole-body vibration. With regarding to train or bus operators, a fall of drivers’ wakefulness level because of fatigue is often pointed out. This decrease in wakefulness results in an increase of the occurrence of accidents. However, a study of how whole-body vibration affects people's level of wakefulness has not been done. To test the hypothesis that exposure to whole-body vibration has a certain effects on level of wakefulness, the change of a subjective wakefulness level and changes of electroencephalogram (EEG) were observed under experimental exposure to short-term whole-body vibration. Methods Subjects are ten healthy male university students, with an average age of 20.7 ± 1.8 years old, and they are all nonsmokers. Using the equipment (CV-300, AKASHI) of whole-body vibration generator, we consider an exposure environment of actual driver work, so that set the frequency and the acceleration level as 10 Hz and 0.6ms-2 r.m.s.. The subjects were exposed to whole-body vibration in the seated position and exposure time was fixed for 12 minutes. Subjective wakefulness level was evaluated using the questionnaire of VASS (Visual Analog Sleepiness Scale) and KSS (The Kwansei Gakuin Sleepiness Scale). For the electroencephalogram (EEG) measurement, it was equipped with the electrodes based on the International ten-twenty electrode system (C3-A2, O1-A2, O2-A1). EEG activity in the alpha frequency band (8 – 12 Hz) is one of the most typical physiological indicator which represent the transition from wakefulness to sleepiness. AAT (Alpha Attenuation Test) which repeats three times each opened and closed eye for 1 minute was performed in a seating position with directions of the researcher in the beginning, in the middle and in the end of exposure to whole-body vibration. For analysis, power spectral analysis was conducted over the last 6 min of EEG, and wakefulness levels were defined as the ratio of mean alpha power during eyes closed versus eyes opened. The laboratory was kept at room temperature (21 ± 1.0 degrees C), humidity was 50 ± 5%, noise level was 63.6 dB (A) eq, and illumination 510 lx. Each experiment was started around 10:00 am to minimize the effect of biorhythm.

Jan 6, 2006

By G. L. Smith

As the Platinum mining industry expands in the Eastern Limb of the Bushveld Complex it is increasingly evident that a major constraint to development is a lack of appropriate infrastructure. Of critical concern are water resources and spatial development / infrastructure. This paper identifies the context for infrastructure development in the Eastern Limb and two solutions that have evolved in the areas of water supply and spatial development. INTRODUCTION In an economics context, infrastructure is considered to be the structural elements of an economy which allow for the production of goods and services, without themselves being part of the production process. Despite the lack of a specific definition, infrastructure has largely become understood as to comprise road and rail transport systems, public transport systems, airports, public educational facilities, water supply and water resources, wastewater management, solid waste treatment and disposal, electric power generation and transmission, telecommunications and hazardous waste management systems. Critically it is important to understand that infrastructure not only comprises these physical elements but also the operating procedures, management practices and developmental policies that facilitate the effective utilization and development of the infrastructure in response to societal demand.

Jan 1, 2008

By A. Karadogan, G. Tuncer, A. Kahriman, S. Gorgun

This paper presents the results of ground vibration measurements induced by blasting operations at five different sites located close to the residential areas. Within the scope of this study, ground vibration components were measured for all blast events over a long period of time in order to predict peak particle velocity and determine the slope of the attenuation curve for five sites. During the study, while the parameters of scaled distance were being recorded carefully, suitable monitors for all blast events of five blasting sites measured the ground vibration components. At the end of evaluation of the data pairs, an empirical relation, which gives an average line at 95% confidence level, and upper bound 95% prediction line with a good correlation coefficient was established and suggested for each site

Jan 1, 2003

By Johne Jesus Mol Peixoto

No modelamento matemático do reator RH, a penetração do gás no líquido na perna de subida é o fator chave para determinar a distribuição do gás injetado e obter uma previsão confiável da taxa de circulação do líquido entre a câmara de vácuo e a panela. Neste trabalho, através de simulações numéricas via CFX, investigou-se o efeito das forças de arrasto, de sustentação, de lubrificação da parede, dispersão turbulenta e de massa virtual. A distribuição do gás na perna de subida e os valores de taxa de circulação previstos via CFX foram validados com resultados de modelo físico. A melhor predição da penetração do gás e da taxa de circulação foi obtida na simulação com incorporação da força de massa virtual e da força de sustentação, cujos coeficientes foram iguais a 0,3 e 0,1, respectivamente. A força de lubrificação deve ser utilizada para evitar o acúmulo de gás próximo às paredes da perna, mas possui efeito desprezível sobre a taxa de circulação. Os resultados dos modelos físico e matemático se ajustaram com a equação de Kuwabara para taxa de circulação.

Oct 30, 2017

By S. Kim Juniper

"This presentation aims to serve as a primer on conservation, research and regulatory organizations interested in the environmental impact of deep-sea mining. It will also consider a recent, early-stage proposal for an experimental SMS mining operation aimed at increasing our understanding of mining impacts and ecosystem recovery.Over the past 5 years, as deep-sea mining has been moving closer to reality, it has attracted growing attention from deep-sea biologists, conservation groups and operators of deep-sea research vehicles and observing systems. Several new international research organizations have emerged that have a direct interest in deep-sea biodiversity conservation, and the environmental impact of ocean mining. These include INDEEP, which evolved from the 10-year Census of Marine Life program, the Deep Ocean Stewardship Initiative that has recently hosted several high profile international meetings, and the VentBase forum of academics, industry and regulators that aims to develop environmental best practices and informational documents for all stakeholders involved in Seafloor Massive Sulphide (SMS) mining. InterRidge, currently hosted by China, represents a decades old partnership of deep-sea biologists and economic geologists who discovered the more than 100 known hydrothermal vent fields and SMS deposits on midocean ridges and in other settings of seafloor volcanism. In 2012 InterRidge formed an industry liaison group to examine how the mid-ocean ridge researcher community could contribute to the development of environmentally responsible practices for the exploration and exploitation of SMS deposits. While initial meetings with industry were promising, InterRidge members are currently debating the relative merits of sharing exploration know-how and understanding of vent ecosystems with industry, against the need to maintain their independence as stewards of deep-sea ecosystems."

Sep 1, 2014

By Yoneji Kanoh, Masahiko Ohtsuka

In Japanese tunneling history, it has commonly been accepted that the long-round driving is difficult due to the complicated geological condition. Therefore, the maximum past record has been less than 3 m per round. A new record of advance was established in the 99 m2 headrace tunnel of Imaichi Water Power Station Project with an advance of 239.5 m in a month by drilling 3.9 m deep blast holes. The geology of the headrace tunnel composed of pyroxine andesite (ie. 960-1770 kg/cm2, VP3.1-4.3 km/s) which had several clay seams and open cracks and was moderately weathered. Automatic shotcrete machine was used for shotcreting. Rock support was specified according to the N.A.T.M. with each different rock type. The contractor achieved a remarkable tunneling advance not earlier experienced in Japan.

Jan 1, 1983

By V. L. Ketellapper

This paper discusses the technical issues and stakeholder collaborative processes which resulted in achieving a balance between the reclamation of abandoned mine sites, providing affordable housing, and preservation of open space at the French Gulch Site. Through this process, it was discovered that mine site reclamation would need to be conducted in conjunction with two priorities for community sustainable development: providing affordable housing for locals who work in the resort town of Breckenridge, and open space preservation. It was found that conducting these activities concurrently would result in providing resources necessary to complete mine site reclamation. The first phase of the affordable housing development is almost completed. This development resulted in redevelopment of mining impacted lands and was recognized by the U.S. Environmental Protection Agency (EPA) with a National Smart Growth Award in 2002.Negotiations are also underway to preserve the remaining 1,800 acres of land held by the mining company as open space. This transaction will in turn provide resources to address water quality issues associated with mine discharges.

Jan 1, 2004

By Paula Maria Gomes Cunha Leão

Um modelo matemático tridimensional, via software Fluent 14.0, de modo a descrever o fluxo, em regime transiente e isotérmico dos fluidos escória e nitrogênio, foi utilizado para avaliar o comportamento de slag splashing em um convertedor a oxigênio com o propósito de reparar as regiões desgastadas do revestimento de trabalho deste reator. Para um dado padrão de sopro foi investigou-se o efeito de parâmetros tais como temperatura, densidade, viscosidade e tensão interfacial. Os resultados são comparados com dados de projeção disponíveis na literatura.

Aug 16, 2017

By José Dimas de Arruda

O conhecimento do campo de fluxo dentro do molde de lingotamento contínuo pode oferecer uma oportunidade de se melhorar a limpidez interna do produto. Modelagem física, aplicação da técnica PIV juntamente com a modelagem matemática via Ansys Fluent foram empregadas para avaliar a distribuição de velocidades na região de interface metal escória num molde de lingotamento de placas. Os resultados foram analisados com base em critérios de estabilidade da interface metal – escória disponíveis na literatura e ressaltam o papel do empuxo e tensão interfacial.

Aug 16, 2017

By Loyslene Rabelo Fernandes

Esse trabalho experimental apresenta os resultados preliminares da lixiviação de placas de circuito eletrônico de microcomputadores sucatados visando a extração de cobre, além da recuperação daquelas espécies através de precipitação por neutralização do licor de lixiviação. As placas foram desmontadas, fragmentadas em pedaços menores, onde passaram por uma incineração no forno mufla, moídas por moagem manual, onde depois sofreram ataque com ácido clorídrico e ácido sulfúrico. Também houve o processo de eletrodeposição com as laminas de cobre encontradas na moagem manual, onde apresentou 14% de cobre depositado.

Oct 30, 2017

By O. Alonso-Gonzalez, F. Nava-Alonso, A. Uribe-Salas, C. Jimenez-Velasco

"Most of the gold produced worldwide is still obtained by cyanidation, in spite of the difficulties encountered in the processing of some gold ores such as the dissolution of copper-bearing minerals in cyanide solutions. The leached copper forms complexes with cyanide and causes several operating problems, which have led to the development of copper removal/recovery processes, among them the industrially accepted SART process (sulfidization, acidification, recycling and thickening). Although the SART process is in use in gold production plants around the world, new challenges are appearing with the continuous varying of the mineralogy of ores (such as higher copper grades, changing the solution composition and complexity). The optimal SART operating conditions for a specific solution are not the same when the composition of the solution changes; consequently, the efficiency of this process can decrease.The present study is a thermodynamic approach, corroborated by laboratory experiments, to explain how the main variables of the process affect the efficiency of copper precipitation as cuprous sulfide (Cu2S). The variables considered were pH value, copper concentration, cyanide/copper molar ratio and sulfur/copper molar ratio, all of which werevaried within the limits encountered in typical cyanidation solutions presenting the problem of copper.It was found that the variable that most affects the efficiency of the process was the pH value, since poor or no control of it can cause cuprous sulfide redissolution. The S/Cu molar ratio is also important: raising this ratio increases copper removal, but high ratios will also cause sulfide and cyanide losses. The effect of changing the CN/Cu molar ratio was negligible between 4 and 8. For a solution containing 300 mg/L copper and 490 mg/L cyanide, copper removal as high as 98.8% can be obtained with the addition of 0.6 moles of sulfide per mole of copper at pH = 6.IntroductionThe main process for gold production is cyanidation, because it is the most economical and efficient process so far. Precious-metal leaching occurs when the ore is placed in contact with a dilute alkaline cyanide solution. The dissociation of cyanide salts provides free cyanide ions, which allow the formation of the aurocyanide complex Au(CN)2 -. This complex can be retrieved from the solution by adsorption on activated carbon or by zinc precipitation. Although the use of cyanide represents an issue to health and the environment, there are technologies for its management and treatment that can be easily applied. Furthermore, it is a low-cost process compared with other methods that are available or under development."

Jan 1, 2015

By Géssica Padilha de Souza

Nos dias atuais, tem-se uma busca incessante por materiais que atendam às solicitações de trabalho exigidas, mas que possuam um baixo custo de fabricação. Diante disso, esse trabalho tem por objetivo o endurecimento do aço AISI 1140, que foi normalizado, temperado com resfriamento em salmoura e seguido de revenimento, com posterior caracterização metalográfica e ensaio de dureza HRC. Através desses tratamentos, foi possível aumentar significativamente a dureza do aço em questão, além das modificações nas fases da microestrutura e consequentemente, de suas propriedades.

Aug 16, 2017