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By Miguel Cochachi, Wilson Chavez, Germán Sovero

El presente trabajo está enfocado en recuperar los metales como plata y plomo de las escorias, mediante el proceso metalúrgico de lixiviación ácida/super ácida y flotación. Estas escorias son pasivos ambientales generados en los años 80’s, JS Consulting en el área de investigación metalúrgica desarrollo el proceso de lixiviación y flotación para lograr recuperar la Ag y Pb de las escorias y de esta manera darle valor en el mercado de dicho material que no tenía valor. Los resultados obtenidos fueron muy favorables, en la lixiviación de las escorias se logro separar hierro, silice, zinc, cobre de la plata y plomo, estos dos últimos elementos quedaron en el solido logrando una concentración comercialmente en el mercado.

Sep 29, 2023

By Frank D. Adams

The Island of Ceylon, which is one of the most beautiful possessions of the British Empire, has been an abode of man from the very earliest times. The Veddhas, a wild tribe of some 4500 people still living in the fastnesses of the jungle in east central portion of the island, are believed to represent a remnant of the oldest inhabitants of which we have any actual knowledge, but in the caves in which they live there are found the stone axes and other implements of Palaeolithic people who represent the first race of men who inhabited our globe, and of whom they may be, for all that is known, the direct descendants. About the fifth century before Christ there came the Aryan invaders, apparently from the north of India, who drove the Veddhas into the remote fastnesses of the jungle and developed the remarkable Singhalese civilization whose high character is demonstrated by the remarkable and very extensive system of irrigation works which they built up, and through which they made the island wonderfully productive. Great cities arose, some of which are believed to have had a population of over a million souls and whose temples and public buildings show that the people were accomplished architects and sculptors.

Jan 1, 1926

By T. A. Sullivan

High-purity vanadium metal was prepared by electrorefining commercial vanadium in a molten sodium bromide, potassium bromide, and vanadium dibromide electrolyte. Variables investigated were operating temperature, current densities, electrolyte composition, and condition of the anode. The purity of the refined metal was in the range of 99.95 percent vana-dium. Iron and oxygen in the 50- to 250-ppm range were the only major impurities. Metal with hardness numbers of 50 to 60 in the Rockwell F scale was prepared from feed material with a Rockwell B hardness of 90. The arc-melted metal was highly ductile and could be cold-worked into sheet or foil.

Jan 1, 1965

I HAVE now traversed for you in the small and fragile bark of my writing all the shores of the deep and spacious sea embracing the uses of material fires, drawn on by my own desire to enrich you with more learning and with the procedures of these things, as much as to satisfy your demands. Having through the grace of God arrived at the appointed end of my voyage and neither knowing nor perceiving a way of going farther, I had decided to furl the [167] sails and cast die heavy anchors into the water in order to enjoy in tranquillity respite from my sailing, when I was warned by my pilot that before I could disembark I should turn my glance backward and reexamine my work in detail to see if there were any part that had by chance remained undescribed in the obscurity of silence. When I did this there immediately appeared in my mind's eye the many sublimates and smoky tinctures that had been made by the burning and most powerful fire of love. I need not say that I knew of it in far-off countries or from the knowledge of others, but I knew it in my own breast and as my very own and can therefore surely esteem it as hotter than all the other fires that the world calls by that name. Although today its sparks and living flames are spent because of my cold and hoary season, nevertheless it is true that the memory of acts of love of long ago still remains with some smoke and warmth. Therefore, since in this work of mine I wish to describe for you the effects and powers of fires, I should logically have spoken of this before any of the others, because of its actual nearness and the great acquaintance I had with it. But since I have had the glance of my intentions directed at distant things, I have behaved as one does who does not see where he places his feet because he is looking at the sky, or as one who thinks about the affairs of others and forgets his own. But now I do not wish to pass over this thing and I wish to correct my error, particularly in order to provide a happier ending to my written work than by remaining among the horrible uproar of guns, powder, and saltpeter, which would be a harsher ending than speaking of love. Never-

Jan 1, 1942

By Jack O. Jones

The Furnish mine, Caharrus County, W. C., was operated intermittently until 1905 as a gold mine. Scheelite was discovered by A. L. Mash in the mine dumps of the Furniss and Phoenix mines, and he later informed the Bureau of Mines of his discovery. The Bureau of Mines, in two projects at the deposit in 1948 and in drilled 12 holes totaling 1,706.6 feet, examined and sampled the underground workings, excavated by bulldozer and hand, 3,155 linear feet of trenches and collected numerous samples for assay. The best scheelite shown; was found in the underground exposure of the Furniss mine.

Jan 1, 1950

By Tianzu Yang, Weifeng Liu, Lin Chen, Xinxin Fu, Shuai Rao, DUCHAO ZHANG

It is well known that the gold ores containing a high content of arsenic and antimony are very refractory. In this paper, the adverse effect of antimony on the extraction of gold by pretreatment-cyanide leaching was discussed in detail. Moreover, these processes of removing and recovering antimony from alkaline sodium sulfide or hydrochloric acid systems were introduced. Last bu not the least, a novel cleaning technology for recovering antimony from refractory gold ores was proposed. Antimony was dissolved into the solution with sodium sulfide and sodium hydroxide as leaching agents. And then pressure oxidation technology was applied to prepare sodium pyroantimonate from sodium thioantimonite solutions. This process is more promising owing to its high removal ratio of antimony, low production cost and environment friendly, which provides a positive guidance for the extraction of antimony from antimonial refractory gold ores.

Mar 1, 2017

By Albert G. Zima

THE conservation of strategic materials during war rime gives rise to many problems not commonly encountered in times of peace. During normal times, when world trade is unrestricted, we are apt to become lavish to a point of extravagance in our use of those materials which, during rime of war, become scarce owing to inadequate transportation and production facilities or because the enemy may be in position to control sources of supply. It becomes necessary, then, to enforce rationing of available sup-plies, and in some cases, where such supplies are wholly inadequate, we find we must resort to the use of substitute materials. We are now confronted with such a problem to an extent never before experienced, with the result that many of the commodities upon which our civilization depended are now either shut off completely or, because of the heavy demand occasioned by war production, are not available in sufficient quantities to meet requirements predicated on peace-time standards and manufacturing methods. It has become necessary, therefore, to make many changes, some of them very drastic indeed, to enable us to carry on our war effort effectively. This? discussion will deal briefly with one phase of this problem, namely, the conservation of alloys required in the making of steels necessary for war production. In line with a request from the War Production Board, the Technical Committee on Alloy Steels of the American Iron and Steel Institute made a study of experimental steels embodying the !east amount of alloying constituents, with the objective in mind of substituting these steels wherever possible for the standard alloy steels used heretofore. This study embraced the following phases: (1) The availability of silicon and manganese; (2) The average quantity of alloying elements recoverable from scrap; (3) The effect of increases in manganese and silicon contents on the general properties of steel; ( 4) The elements and ranges of elements which might be used to duplicate the hardenability of the steels now in use; (5) The effect of combining several elements in small quantities upon the properties of steel at various hardness and strength levels; (6) A determination as to whether or not the steels selected would suffice for general application. Working on this basis, the Committee arranged for the manufacture of several heats of steels containing various combinations of different amounts of such elements as silicon, manganese, chromium, nickel, and molybdenum. The steels thus produced were compared by hardenability tests.

Jan 1, 1943

By N. Skopak, C. Aimone-Martin, J. Redyke, B. O. Meins

PipeBlast is a spreadsheet-based calculator based on research conducted by Southwest Research Institute (SwRI), used by the pipeline industry to determine if proposed blasting planned near existing pipelines can be safely executed. The two factors determining “safe” are blast-induced pipe wall hoop stresses and predicted peak particle velocity (PPV) at the pipeline. Although methodology used to predict hoop stresses is somewhat sound, predicted PPV amplitudes are highly exaggerated based on inappropriate attenuation models developed using spherical explosive charges of limited charge weights, placed in soil adjacent to model pipelines that do not represent rock blasting. Hence, pipeline companies readily reject well-design blasts and limit scaled distances far beyond what is reasonable and cost-effective to pipeline owners. Full-scale trench blasting in rock was conducted near a 24in (711mm) diameter operating API 5L X70 grade steel pipeline in Texas to compare PipeBlast model predictions with a Ground Strain Model (GSM) based on field measurements of ground motions on the surface and at the pipeline springline. Results of the GSM were compared with pipeline strains measured using wire gauges mounted on the Springline. The comparative results showed that a site-specific velocity propagation model provided good estimates of ground strains that are replicated on the pipeline walls in terms of hoop and longitudinal strains. Trench blasting 28ft (8.5m) from the pipeline produced ground motions of 7.6in/s (193mm/s). At this ground motion amplitude, the factor of safety defined as the allowable stress divided by the combined operating and blasting hoop stresses was reduce from 3.04 in the absence of blasting to 2.98. This paper explains the research and findings on which PipeBlast is based and presents an alternative approach to predicting blast-induced pipe wall stresses based on site-specific velocity propagation measurements and a ground strain model.

Jan 1, 2024

By R. S. Dean

The development of metallurgical processes may be divided into periods : First , the discovery of a basic reaction which brings about the production of the desired product from the available raw material ; second , a long stage of mechanical development during which little or no attention is paid to the reaction itself ; and third , a careful study of the reaction . Most metallurgical processes are to -day approaching the end of the second period . This we may illustrate by the steel process . The reaction of carbon with iron ore to produce pig iron and the subsequent refinement of the pig iron by an oxidation reaction is very old . Development in modern times has been almost entirely mechanical , the development of the blast furnace , furnace , the Bessemer process , the Siemens process , and even the Aston process for wrought iron being mechanical improvements almost entirely . Metallurgy is now entering a phase where the reactions are being considered . The question of how far can they be made to proceed is being repeatedly asked . As mechanical processes are improved , we approach a limit to which our basic reactions can be pushed which is determined by the nature of the reactions themselves . We want to know : How far can iron be decarbonized by iron oxide ? How low can the oxygen of copper be reduced by any given reaction? How efficiently can the fuel in a zinc reduction process be used ? The demand for purer metals and lower production costs has forced these and similar questions upon us . How are we to answer them ? The determination of these equilibria or end points of metallurgical reactions by direct means is fraught with difficulty because here we must overcome mechanical difficulties which too often become the limiting factors even in the laboratory and we do nottherefore get the actual limit to which the reaction itself may be carried . Further , there are so many reactions of metallurgical materials that to survey each separately is a job to give pause to any experimenter or group of experimenters .

Dec 1, 1930

By L. M. Pidgeon, W. Curlock

FREE energies of formation of zinc sulfide and magnesium sulfide had previously been estimated to an accuracy of ± 5.0 kcal per g mol. In the present work, these values were determined experimentally. As the determinations of the free energies of formation of zinc sulfide and magnesium sulfide presented different problems, separate experimental procedures were employed for each. ZINC SULFIDE It is difficult to measure the free energy of formation of either zinc sulfide or magnesium sulfide by measuring their decomposition pressures directly, as they are very stable compounds. An attempt was made by Jellinek and zakowski3 to study the equilibrium. zns(s) + H2(g) = Zn(g) + H2S(g) [I] They passed hydrogen over zinc sulfide and analyzed the gases leaving the reaction zone for H2S. They were unable to determine the true partial pressures of the H2S by this method, as some of the H2S on being cooled from the reaction temperature, reacted with the zinc in the gas to produce ZnS. Consequently, they were unable to establish any true equilibrium data for reaction [I]. More recently,' the equilibria ZnS(sphaledte) + Fe (s) — FeS(s) + Zn(g) [2] and ZnS(sphalerite) + 2Cu(s) — Cu2S(S) + Zn (g) [3] were studied. As the standard free energy of formation of Cu2S is known to * 3.0 kcal, and of FeS to ± 1.0 kcal, it should be possible upon performing equilibrium studies on reactions [2] and [3] to deduce the standard free energy of formation of ZnS (sphalerite). However, as both of these equilibria involve 2 solid sulfides, and as it is possible for these sulfides to dissolve in one another, it is necessary first to ascertain the activities of the various sulfides in these solid phases.

Jan 1, 1959

By V. I. Lakshmanan, R. Roy

Base metals and PGMs are currently recovered from sulfide concentrates using pyrometallurgical processes. These processes suffer from several limitations such as being capital intensive, scaling problems, S02 emissions and long delay in value recognition. Alternative hydrometallurgical technologies have so far not been successful and currently total pressure oxidation and partial pressure oxidation hydrometallurgical technologies are being evaluated. Process Research ORTECH has developed a unique hydrometallurgical process to recover base metals and precious metals using mixed chloride technology. In a first stage leach, base metals are recovered and elemental sulfur is liberated from hydrogen sulfide formed during this leaching stage. During second stage leach, precious metals are recovered using proven separation technologies. Some of the advantages of the process are the recovery of elemental sulfur from sulfide sulfur, recycle of the chloride lixiviant thereby eliminating effluent treatment steps and use of excess energy from the Claus reactor for the pyrohydrolysis step.

Jan 1, 2011

By Ian Wark

IT has been shown1 that in the absence of heavy metal salts, the nature of the alkali used to promote differential flotation-whether caustic soda, lime or sodium carbonate-is unimportant. The hydroxyl ion is the active depressant upon which differentiation depends, and the pH value determines whether a film of collector forms on any given mineral surface. Even when sodium cyanide is used in conjunction with alkalies, it is the pH value and not the nature of the alkali or its concentration that is important, for upon the pH value alone depends the fraction of the added sodium cyanide that is present as cyanide ion, which is the true depressant. When heavy metal salts become dissolved from partly oxidized ores, or are added intentionally as activators, conditions are different, and metallurgists have found that lime and sodium carbonate do not give identical results, even when added in amounts sufficient to produce the same pH value. In the few instances in which we had attempted to confirm this view, we had failed to do so, for, with nothing to guide us, we had inadvertently chosen solutions that gave contact curves of a "stand-ard type," which correspond to conditions of ready floatability. Now, however, we find that, in the presence of copper salts, and within a restricted range of reagent concentrations, the nature of the anions present is important, and that sodium carbonate does influence the results, apart from the usual effect due to its influence on pH value. With the recognition of this anion effect, and with the control of temperature already introduced,' it appears that the factors of major importance in connection with this set of reagents have been taken into consideration, and that the results obtained and the conclusions drawn from contact tests will be of more immediate value to the operator.

Jan 1, 1939

By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By M. M. C. Lima, L. C. S. Solimani, M. A. Quintela

Galvanized steel scrap is recycled to B OF converters where zinc escapes from the bath and is captured by the gas control system, appearing in BOF sludge. As BOF sludge contain high iron content, it could be recycled, but due to its zinc content, it is disposed in landfills. In this study techniques were evaluated for zinc layer removal from scrap by sulfuric acid leaching. The effects of coating weight, temperature, time and sulfuric acid concentration were evaluated for three different galvanized scrap. The results showed that the behavior of each galvanized scrap was different. Nevertheless zinc removal efficiency was more than 80% with low dissolved iron in the leached solution.

Jan 1, 2011

By D G. Rantucci

Organic carbon is a major ore contaminant at MMG’s Century mine. This carbonaceous matter is associated with shale hosted sphalerite mineralisation. It occurs as elongated lamellae and as inclusions in porous sphalerite aggregates which are fine grained and difficult to liberate from sphalerite. The carbon prefloat circuit was designed to remove the liberated organic carbon in order to mitigate excessive reagent consumption, contamination of the lead and zinc concentrates and poor flotation performance in the primary zinc circuit. The consequence of organic carbon removal is that sphalerite and galena minerals are lost to the prefloat concentrate. A Jameson Cell was installed in late 2005 as a prefloat cleaner cell. Operational experience showed that the cell became capacity limited during periods of high amounts of organic carbon in the feed and was subsequently bypassed.Reactive style operating strategies were implemented to manage the effects of insufficient organic carbon removal by the prefloat circuit but due to the relatively large circuit residence time, upstream changes meant hours before the downstream circuits were stabilised following a disturbance from excess carbon.This paper describes the modifications and testwork undertaken to enable the Jameson Cell to be operated during periods of high organic carbon in the float feed and the implementation of process control initiatives to proactively remove the required prefloat mass from the float feed to eliminate the reactive style operating strategy.The process control modifications centred on dynamically targeting a prefloat mass recovery determined by an equation relating the carbon to zinc ratio to the carbon prefloat mass as a percentage of the float feed. The equation was developed by analysing historical data. These improvements served to optimise the prefloat circuit and consequently stabilise the downstream lead and zinc circuits.

Aug 8, 2011

La voladura es la herramienta económica más efectiva para fragmentar y mover rocas. Sin embargo, no puede ser empleado cuando un patron de voladura mal diseñado, ya que se genera un descontrol sobre la energía liberada. En este sentido, el presente texto describe el empleo de la prospección fotogramétrica estéreo y los sistemas de prospección de pozos en una operación de voladura en la cantera brasileña Incopel.

Apr 1, 2013

By Guo Chen, Jin Chen, Jinhui Peng

"In this paper, the methods of life cycle assessment for microwave hot air systems, and the concept of green degree were proposed. Greenness evaluation index, evaluation system and evaluation model of microwave hot air systems were established. Also, life cycle assessment processing based on these ideas was introduced. Analytic hierarchy process and fuzzy decision- making method were utilized to establish and solve the greenness evaluation of assessment model, while the scores of green degree in microwave hot air systems were obtained. The results show that Life cycle assessment can be applied effectively and efficiently to the microwave hot air systems.IntroductionHot air systems are an important industrial operation condition, which is used to provide high temperature air for materials processing. Nowadays, high temperature airs are manufactured by the conventional heating processes, in which some ceramic materials are used as heating materials. However, these processes pollute the environment. Therefore, to explore new method to produce high temperature air with low energy consumption and less environment pollution are necessary.Microwaves are now being used in various technological and scientific fields in order to heat dielectric materials [1]. Microwaves irradiation has been explored in materials processing in recent years [2-3]. The main advantage of using microwave heating is that the treatment time can be considerably reduced, which in many cases represents a reduction in the energy consumption as well. Since there is energy absorption but no heat conduction, the heating is very rapid and highly efficient, resulting in energy savings and the shortened processing time [2, 4]. Compared with conventional heating techniques, the additional advantage of using microwave irradiation is that microwave irradiation achieves both internal and uniform heating [5-7]. In addition, it is more convenient to control the microwave irradiation processing, because of no direct contact between the heating source and heated materials with less equipment size and waste [2, 8-9]. Life cycle assessment is used and accepted methods for the evaluation of the environmental impacts of products or systems [10]. Recently, many appropriate evaluation methods have been developed for life cycle assessment [11-12]. These proposed methods usually are employed for the evaluating product and analyzing results [13]. Among them, the analytic hierarchy process and the fuzzy comprehensive evaluation stand out as a popular method utilized in many fields [14-16]. Analytic hierarchy process and fuzzy comprehensive evaluation are a combination of mathematical and statistical technique that is useful for analyzing the effects of several independent assessment aspects on the system goal without the need of the predetermined relationship between the objective function and the assessment aspects [17-19]."

Jan 1, 2013

By Harlowe Hardinge, R. C. Ferguson

Laboratory and plant data covering 12 different operations show that lower than "standard" ball mill speeds increase grinding efficiency. In the case of high pulp-level mills, the gain is so great that the increase in capital cost of the larger lower speed mill will pay for itself in less than a year's time.

Jan 1, 1950

The following is an incomplete list of members and guests who called at Institute headquarters during the period Sept. 10, 19188 to Oct. 10, 1918. Thomas J. Adams, Rahway, N. J. A. N. Mackay, London, England. Henry M. Ami, Washington, D. C. A. W. MacNichol, San Francisco, Cal. Chester Atkinson, Peru, South America. Ernest Marquardt, Casper, Wyo. Bennett R. Bates, Berkeley, Cal. Lieut. S. A. Mewhirter, Denver, Colo. Robert S. Botsford, Petrograd, Russia. William A. Nelson, Nashville, Tenn. Juan Felix Brandes, Santa Barbara, Cal. Robert W. Olinger, Bahia, Brazil, So. G. A. Collins, Seattle, Wash. Amer. C. V. Corless, Coniston, Ont., Canada. G. Preumont, La Paz, Bolivia, So. Amer. F. T. Eddingfield, Washington, D. C. William H. Rettie, Yonkers, N. Y. C. Mason Farnham, Barre Plains, Mass. . Julius Segall, Minneapolis, Minn. F. N. Flynn, Trail, B. C., Canada. Robert Y. Seip, Franklin, N. J. Duncan D. Forbes, Humboldt, Ariz. H. M. Schleicher, Boston, Mass. Alexandre Gouvy, Paris, France. Chester Steinem, Ft. Monroe, Va. Henry G. Granger, Cartagena, Colombia, A. L. Sweetser, Pittsburgh, Pa. So. Amer. . H: E. Treichler, Creighton Mine, Ont., E. Harms, El Paso, Tex. Canada. Alfred G. Heggem, Tulsa, Okla. Frank A. W. Tullock, Yumbo, Colombia, H. B. Henegar, Mascot Tenn. So. Amer. A. M. Kivari, Denver, Edward I. Williams, Ft. Monroe, Va. T. M. Kniffin, Brookline, Mass. Alfred W. G. Wilson, Ottawa, Canada. Charles Lehman, London, England. Donald H. McLaughlin, Camp Meade,Md. C. E. Addams, who recently resigned as general manager for the Arizona Hercules Copper Co., has leased the Ray silver-lead property three miles from Ray, Ariz. Bennett R. Bates has resigned his position as general superintendent of the Cubo Mining & Milling Co., in order that he may take the examination for an officer of engineers.

Jan 11, 1918

By R. Viljoen, K. Manns

"The mining industry instinctively follows rule-of-thumb design velocities often based on very simplistic theoretical “economic velocity” optimization calculations to determine airway sizes. Although these are important building blocks in ventilation planning it should be recognized that mines are far more complex and various, often opposing factors, are at play. Therefore, it is important that each ventilation situation be analyzed on a case-by-case basis to determine the best-fit solution for an operation. The ventilation design process should not necessarily be constrained by theoretical optimal economic velocities that become rules-of-thumb. In some cases, this could lead to unrealistic infrastructure requirements and exorbitant capital expenditure. This type of design often lacks corporate support leading to a scenario where no ventilation upgrades are implemented. Economic velocities typically consider the cost of power, development costs and operational risk. These typical rules-of-thumb work reasonably well as a starting off point when considering feasibility of greenfield projects. For established mines that are looking at expansion these rules may not be appropriate due to capital expenditure constraints or geotechnical ground conditions. The theoretical optimum should be reviewed in the case of an established mine where existing infrastructure could perhaps be maximized. For example, the geotechnical risk of large diameter raises at depth may require multiple small diameter raise to maintain the theoretical economic velocity. If a mine has a life of less than 5 years, then the cost of power is an insignificant proportion of the total owning cost. For these mines, operating the ventilation raises at an increased velocity to avoid a complicated and expensive capital upgrade might be the more appropriate option, even though it opposes the traditional rules-of-thumb. Mines which are capital constrained may be better off accepting a higher operating cost for the interim or settle for minor infrastructure upgrades rather than run the risk of the entire ventilation upgrade not being approved at all. This paper explores a number of examples derived from case studies undertaken by the authors for several deep mechanized mining projects in Australasia. The examples explore conditions under which higher than the economic norm would be applicable."

Jan 1, 2019