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By Toshiaki Akahoshi

Keywords: Wasted catalyst, Hydrodesulfurization, Ammonium vanadate, Ammonium molyb-date, Hydrometallurgical process. The fundamental reactions have been investigated in order to develop a hydrometallurgical process for recovery of molybdenum and vanadium from wasted catalysts generated in the hy-drotreating desulfurization of heavy oil. The principal steps of the process are a mild oxidation roasting of the waste catalysts at temperature around 500°C, leaching of the target metal components with dilute ammoniacal aqueous leachates, selective precipitation of vanadic acid, and ammonium molybdate precipitation. The selective recovery of vanadium as vanadic acid is successfully performed using ammonium sulfate as a salting-out agent. Recovery of ammonium molybdate is based on large dependence of solubility of ammonium molybdate in ammoniacal solutions upon temperature and ammonium salt concentration. In this process, the solution after recovery of vanadium and molybdenum is recycled to the leaching stage of the roasted materials, and the ammonium salts in the process liquor is in the repeated use. Employment of am-moniacal system makes it possible to operate the roasting at much lower temperature than that for the currently operating process.

Jan 1, 2005

By Sam Lo Grasso, Carlos Herranz Calvo, Stuart Warren, Ted Giesing, Charles Marchesano

Mott MacDonald and Project Management Advisors are providing Technical and Project Management services for San Diego County for the Courthouse Commons Project. The Courthouse Commons Project involves the redevelopment of three downtown blocks owned by San Diego County and construction of an Inmate Transfer Tunnel between the County Central Jail and the San Diego Central Court. The tunnel will be 327 feet long, crosses the San Diego Fault and is being constructed using the Sequential Excavation Method (SEM). This paper discusses the history and procure‑ ment strategy for the project, the technical aspects of the transfer tunnel and the con‑ struction progress of the tunnel to date.

Jun 13, 2021

By Z. W. Zhang, Songsong Xu, Jinhui Li, Yun Zou, Yu Zhao

High strength low alloy (HSLA) steels with high strength, high toughness, good corrosion resistance and weldability, can be widely used in shipbuilding, automobile, construction, bridging industry, etc. The microstructure evolution and mechanical properties can be influenced by thermomechanical processing. In this study, themomechanical processing is optimized to control the matrix microstructure and nano-scale precipitates in the matrix simultaneously. It is found that the low-temperature toughness and ductility of the steels are significantly the matrix microstructure during enhancing the strength by introducing the nano-scale precipitates. The effects of alloying elements on the microstructure evolution and nano-scale precipitation are also discussed.

Jan 1, 2016

By Mim Li, Huimin Lu, Lisha Yang

"CuInS2 thin films solar cells have drawn much attention for their low-cost, stability and high conversion efficiency. The electrodeposition of Cu-In precursor films, as the first step in making CuinS2 solar cells electrochemically in the air-and water-stable ionic liquid based on choline chloride/urea eutectic mixture has been investigated at constant potential. Compared with aqueous electrolytes, the large electrochemical window as well as the high thermal stability of this ionic liquid allow the direct electrodeposition of Cu-In precursor films. Then the precursor films were sulfuretted in a tube furnace at different sulfurization temperatures to optimize the films properties. The films obtained were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS).IntroductionCuInS2 is one of the most prospective absorber materials for low cost thin film solar cells, with a high conversion efficiency that exceeds 32% in terms of theory and nearly 13% in laboratory level [1-2]. In addition to its long-term stability, CuinS2 has a band gap energy Eg ranging from 1.3 to 1.55 eV and an optimal optical absorption coefficient reaching 105cm-1 [3-4]. CuinS2 thin films have been prepared by several methods such as spray pyrolysis [5-6], r.f.sputtering [7], vacuum evaporation [8-9] and electrodeposition. Comparing with vacuum methods, electrodeposition has lots of advantages such as less energy consumption, preparation big area thin film, stable system and enabling cheaper films.The electrodeposition of most technologically important metals has been shown to be possible from a wide range of ionic liquids. These ionic liquids are currently applied in a wide variety area. It is reported that the cell efficiency of chalcopyrite absorber layer (CIS, CISeS, and CIGS) via an electrodeposition route in laboratory condition has reached 11.3% [10]. Copper and indium alloy film is regarded as important precursor for the production of compound semiconductors with sulfur. The electrodeposition of the alloy film from room temperature ionic liquid (RTIL) has not been widely investigated. Only few alloy films, such as ZnTe, CdTe, GaAs and AlSb have been electrodeposited."

Jan 1, 2011

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By Adrian Dance

The Antamina orebody is a geologically complex, polymetallic skarn located in the Peruvian Andes. A range of copper and copper-zinc ores are campaigned separately through the concentrator producing copper and zinc concentrates as well as lead and molybdenum by-products. Ore type classification at Antamina is based on chemical assays; geological or lithological variations are not considered. Consequently, each ore type demonstrates a wide range of concentrator performance. Antamina is currently implementing a system to track ore movements from the shovel face to the concentrator. Relatively sophisticated models of the ROM and coarse ore stockpiles ahead of the mill will be used to account for the variable delay between mining and milling. One of the numerous benefits of ore tracking is the ability to directly associate the measured concentrator performance with a physical location in the orebody. Using existing mine planning software, three-dimensional models can be created of such performance measures as metal recovery, concentrate quality, operating cost and reagent consumption. Such a database of information allows the true value of different ore sources to be determined. The value of an ore source is conventionally measured as metal content (individual or combined ?equivalent?) with a cut-off grade applied to indicate some base level operating cost. However, the true value of an ore source should include dynamic factors like haulage cost, reagent use, smelter penalties and even prevailing metal prices. If an ore source is considered from all perspectives rather than simply its potential to deliver value, the concept of ?ore? becomes more flexible. Any ore source that reveals itself to be unprofitable can be eliminated from the mine plan or possibly blended with others to improve its value. The ability to predict mill performance ? and thereby profitability ? is a powerful tool. In an operation such as Antamina, where managing ore sources, campaigns and the delivery of a variety of concentrates in a narrow timeline to customers is a daily challenge, prediction is the key to success and improved efficiency.

May 1, 2003

By Ralph W. Edie

"IntroductionTHIS PAPER presents some analyses of diabases from a number of metallogenic provinces in Canada and the United States. It is intended as a contribution to the literature on the genesis of mineral deposits associated with diabase.As it has been in the past, opinion today on the origin of the cobaltnickel- native silver and associated pitchblende type of deposit is sharply divided. Some geologists hold that this type of deposit is in some way genetically related to intrusive diabase; others are of the opinion that the deposits are related to granite. The controversy, like others of a similar nature, probably will not be settled satisfactorily for many years to come, •but in the meantime it is recognized that, with respect to most deposits of the type referred to, altogether too few facts are known for accurate conclusions on genesis to be drawn. To contribute in a small way to factual data on this whole .problem, the writer analyzed diabase from several districts in Canada in which deposits of the aforementioned type occur. For comparative purposes, the copper, cobalt, and nickel content of diabase from Cornwall, Pennsylvania, and of norite from the Sudbury basin of Ontario, was also determined.Insofar as is known, none of the analytical work undertaken had been previously carried out."

Jan 1, 1953

Discussion following the presentation at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, included the author's introduction, written contributions by Bedson P.P., Gregory T.W.D. and Morgan J.D., oral contributions by Louis H., Greener T.Y. and Severs W., and the author's reply

Dec 1, 1916

By Wen Lan Chen

In the plant where the 800m diameter cyclone was tested, 500 STPH of 50m x 0 raw coal was pulped in a heavy medium tank and pumped originally to four 700mm heavy medium cyclones. For the test one of these units was replaced by an 800mm diameter cyclone with the subsequent feed pressure for both units sets at approximately 15.0 psi. Since this was a feed to zero plant, an appropriate bleed of heavy medium to the dilute medium circuit was established to en- sure that the cleaning of the 500m x 0.5mm raw coal would not be adversely affected by high levels of 0.5mm x 0 fine coal present in the heavy medium. The medium gravity measured varied between 1.41 and 1.43. During a three-hour test on June 10, 1983, the raw coal sample was collected from the feed belt while the clean coal and refuse samples were collected separately at proper locations along the product streams of the two different diameter cyclones. All of these samples were shipped to the laboratory for screen and sink- float analyses. The raw coal screen and ash analyses are shown in Table 1.

Jan 1, 1984

By Nixon J. C, Reynolds C

Three principal features of the ore at Captain's Flat, New South Wales, tend to complicate concentration of the valuable minerals, these being:1. The ore occurs in three more or less separate bodies which vary in texture and mineral ratios. Mining of constant proportions of the three sections, or adequate blending of the ore, is not fully effective, and consequently the flotation section is subjected to feedof varying texture.2. The mineral association in the heavily pyritic ore is extremely intimate. Composite particles exist even at 20 micron sizeI, and probably finer.3. The copper content of the ore averages_about 0,6%, which is high enough to justify recovery of the chalcopyrite in a separate concentrate. A review of the metallurgical history of the mine shows that this feature has been the cause of the several major changes in flowsheet of the flotation section since the commencement of milling.METALLURGICAL HISTORYThe mine started production in January 1939, at the rate of 250 tons per day of sulphide ore, assaying 0·68% Cu, 6·52% Pb, 10·8% Zn, and about 1 dwt. Au and 2 oz. Ag per ton.

Jan 1, 1952

By T. Vincent, J. Steele, C. Debrunner, M. Whitehorn

This paper presents current work on the development and use of stereovision for underground mining. Information on the calibration of the cameras and the feature-matching algorithm are presented. This system uses an intensity-based approach that evaluated correspondences along the epipolar line. Once features have been identified and their distance from the cameras computed, a three-dimensional map of the muck pile is developed. The approach used here uses a ray-tracing algorithm. This approach provides an uncertainty measure along with the elevation. A discussion of the use of this modelling information in the control of the LHD is included. Keywords: Robotics, automation, LHD, underground mining, vision sensing, task automation, tele-operation

Sep 1, 2001

By Jean-Christophe Ehrström, Fanny Mas

"A specific test set-up has been developed to study at the lab-scale the high-temperature behavior of aluminium alloys in conditions close to those experienced by thick plates during hot-rolling. A particular attention is paid to reproducing both the stress triaxiality and strain fields that exist in plate during rolling. In addition to standard ductility measurements by means of secondary tensile tests (STT), multi-step plane strain compression (PSC) tests have been performed to mimic hot-rolling pass schedules. Tool and sample geometries were adapted to allow low h/a ratios (h= average specimen thickness, a= tool width) and thus guarantee depressive stress conditions at the center of the specimen during most of the test. Such conditions resulting in porosity opening can then be used to investigate the impact of rolling conditions on damage evolution. The mechanical testing was combined with post-mortem high-resolution ultrasonic scans allowing to detect small amounts of damage and quantify its evolution as a function of processing parameters such as strain and temperature. The test set-up was validated on two 2050-type AlCuLi alloys with different susceptibilities to high temperature embrittlement.INTRODUCTION Aluminium thick plates are widely used in the aerospace industry, mainly as semi-products to be machined for internal structure parts of wings (spars, ribs) and fuselage (frame). The conversion route of such products always involves a hot-rolling step, the conditions of which (temperature, speed, pass schedule) have to be optimized to maximize both mechanical properties and final plate quality. This goal cannot always be efficiently achieved by full-scale industrial trials as (a) cost limits the number of possible test conditions and (b) it is often difficult to change one parameter alone. That is why there is a need for laboratory-scale tests able to mimic the rolling process in terms of temperature, strain rate, stress triaxiality and deformation. Most laboratory hot-rolling mills do not adequately simulate industrial processing routes, especially in terms of heat loss, deformation speed and rolling geometry (maximum roll gap vs. work roll diameter). Concerning thick plate, it is of interest to achieve both similar deformation and L/h ratio (L=arc of contact, h=mean gauge) per pass as the industrial schedule because they are simultaneously involved in damage evolution and void closure during hot forming processes (Saby, 2014)."

Jan 1, 2018

By Xiu-Xiang Tao

This study investigated bio-liquefaction of lignite and its model compounds of thymol, bezioc acid and quinoline by a fungus, Hypocrea lixii AH. It analyzed, during bio-liquefaction, enzyme activity of oxidase, LiP, Lac, MnP and polyphenol oxidase, and degradation products by UV-Vis, FTIR, 13C NMR and GC-MS. The results showed that the bio-liquefaction percentage (by mass) of lignite was up to 44.86 %. The bio-liquefaction products of lignite were mainly aniline, amide, ether, carboxylic acid ketone and ester. The aromatic ring number was 1-3 with an aromatic carbon ratio of 0.328, which indicated rings opening, bonds breaking and oxidation reaction. By considering with the enzyme activity analysis results, it showed that LiP and Lac catalyzed reactions to open aromatic cycles and to break bonds; esterase to break ester bond; and peroxidase in oxidation reaction.

Aug 1, 2013

By Justin Simmons, Michael Arnold, Bob Faulhaber

"In order to remodel an existing beach resort on the Gulf of Mexico, an existing three story structure, founded on stepped tapered piles, was to be replaced by a ten-story building with service rooms on a daylight basement level, conference rooms on the next levels and up-scale hotel rooms on the upper levels. The new building was founded on augered-cast-in-place (ACIP) piles. The pile caps and the basement required excavations between nine and fifteen feet (three to five meters) below ground surface.BAUER Foundations Corp. (BFC) successfully used Cutter Soil Mixing (CSM) to install the support of excavation walls. This technique allowed for the adjustment of the wall alignment during execution in order to avoid existing and new piles and other underground obstructions. Nearly 1600 – 16-inch (400 mm diameter) ACIP piles were installed to an average depth of 71.5 feet (22m) below ground surface (BGS) by BFC to support the new hotel structure. Initial grout overages in piles were excessively high and ground stability issues were encountered in some pile locations. By identifying specific areas of concern BFC was able to modify the approach to ACIP installation, effectively mitigating the ongoing risks and successfully completed the project.PROJECTMarriott Hotels began the $300 million renovation and upgrade of their Marco Island Marriott Beach Club Hotel in Marco Island, FL to JW Marriott status in May 2015. The renovation included the demolition of a portion of their existing hotel tower, and the construction of a new 10-story hotel tower consisting of 94 new guest rooms and a 10,000 SF (900 m2) ballroom, among other amenities. As is typical with hotel construction, time was of the essence. The schedule was the driving factor of this project as the owner had already booked events in their new ballroom starting in January of 2017.BFC provided the client with a deep foundation package that included the installation of 1562 Augered Cast-In-Place (ACIP) piles supporting the new tower, and the design and construction of approximately 36,500 SF (3,400 m2) of soil-mixed retaining wall for support of excavation (SoE)."

Jan 1, 2017

By Ryo Kawarabuki, Atsushi Shibayama, Masato Kosugi, Masanobu Fujita, Kohei Mitsuhashi

An investigation on improving copper and iron recovery by removal of organic carbon and carbonaceous gangue mineral through flotation was carried out. The ore contains chalcopyrite and bornite as valuable minerals, and dolomite and calcite as carbonaceous gangue minerals. The chemical composition of the ore indicates that grade of 2.08 and 5.37 mass% for copper and iron respectively, while carbon was 3.70 mass%. The total organic carbon in the feed was recorded as 2.02 mass%. The presence of these gangue minerals is detrimental to copper and iron recovery during flotation. Therefore a two stage flotation study was carried out to remove hydrophobic carbon and carbonaceous material from ore and to improve copper and iron recovery. The objective of the study was to find effective and selective flotation conditions which can eliminate gangue minerals from valuable minerals and improve quality (grade) and recovery of copper and iron. The obtained results could be used to develop a flotation circuit for recovering copper and iron from carbonaceous sulphide ores.

Mar 1, 2018

By J. W. Buch

IN THE FIELD of track haulage, interest has seemed to center on the question of larger mine cars both for handling material from loading point to shaft bottom or surface, and for shuttle service. Saving of time in car changing is obvious if larger cars are used. In addition, shorter trips result where car transportation is from face to opening without transfer. This also brings about side-track and equipment savings. Track shuttle service, using large automatic-dump cars (10 tons) between loading machines and trip loading point, has been a satisfactory solution for the operator who mechanizes a working mine regularly equipped with a large number of small mine cars. This development in track shuttle haulage, has made track installation and maintenance increasingly important, requiring closer supervision.

Jan 1, 1942

By Sheridan A. Glen

As the Federal government along with individual states continue to grapple with the job of refining a comprehensive energy policy, coal continually stands out as an energy source which heralds a combination of old and new capabilities like an energy planners prophecy, but which is plagued with serious environmental constraints. To determine what level of coal utilization is ultimately possible for states East of the Mississippi, whose high sulfur content coal presents the most paramount of challenges, one must consider product availability, via existing transportation modes, the developing industrial markets and the ability of coal to meet the challenge of becoming an environmentally acceptable fuel. Gasification is emerging as a form of utilization, which during the next twenty years stands a good chance of being able to meet the challenge of making coal an environmentally clean, easily transport-able and usable fuel. It can be argued that, of all the potential ways of utilizing high sulfur coal, coal gasification is perhaps the most expensive, the most financially risky and carries environmental liabilities of its own. Synthetic gas and oil markets will undeniably be a function of price and demand, which, for the purposes of this paper, I'm assuming will begin to merge in the late 1980's and into the 1990's. This is also presuming that public utility commissions will allow favorable price structure ruling so that gasified coal products can be rolled into their respective rate base, much the same as synthetic natural gas from petroleum by-products are currently being priced. The comparative economic markets of coal to gas pro-duct have plenty of time to mature. There is an approximate twelve-year lead time needed to bring coal gasification plants on line which will be able to compete in the market place for natural gas and oil customers.

Jan 1, 1977

By H. D. Hoskold

I. Instrument-Parts and Implements. Cross-hairs ; Stadia-measurement; Fineness of Graduation ; Cylindrical Gradu ation ; Nonius; Vernier ; One Vernier or two ; Leveling-Screws ; Troughton & Simms' Shifting Tripod-Head ; Hoskold's Shifting Tripod-Head; Hoskold's Extensible Tripod ; Electric Lamp ; Plumb-lines; Chain. II. Instruments. Compass (Mine-compaes of 1518, Compass of 1541, and Agricolals of 1556, Voig tel's Setz-compass, Circumferentor, Stanley's Hedley Dial, Compass on Tele scope, Hanging Compass, Lack of Precision) ; Plane-table; Octant and Quadrant; Theodolite and Transit (Evolution of the Theodolite, Scott's Tachymeter, Hoskold's Engineer's Theodolite, Angleometer, Precision of Mine-Theodolites). I. Instrument-Parts and Implements. Cross-Hairs.—Mr. Scott‡ says Lean's dial " might also have been provided with a diaphragm and cross-hairs; for Huygene discovered that any object placed in the common focus of the two lenses of a Kepler telescope (1611)- appeared as distinct and well defined as any distant body. Following this established theory, in 1669 Jean Picard, Marquis Malvasia and others crossed silken fibers in the mutual focus of their astronomical instruments." If by this Mr. Scott means that Huygens and Picard first devised and applied cross-hairs to the focus of the telescope, the writer cannot agree with him. Huygens did not describe " his telescope without tubes until 1684, in his Astroscopia Compendiaria."§ Moreover, it is recorded that the English astronomer, Gascoigne,?

Jan 1, 1902

By William G. Freeman

In comparison to many mineral commodities, barite has a low unit value. It is mined and sold in low volumes in high-grade (90-98% BaSO4) forms to basically one industry that uses approximately 75% of the free world production. Based upon the above criteria, all factors must be considered in determining if a barite deposit is economical; such as, the type of deposit, mining and milling methods required, transportation to the markets, tariffs, local political conditions, etc. In other words, barite mines are made--not found. The length of this paper precludes any indepth discussion of geology, mining and metallurgy of barite. Most of this information can be found in data already published, such as D. A. Brobst's bulletin1 on the Barite Resources of the United States.

Jan 1, 1971

By Yong Pan, Srivatsan Jayaraman Sridharan, Purushotham Tukkaraja

Block cave mining method poses unique ventilation challenges compared to other underground metal mining methods. This research study focuses on assessing the airflow behavior in regulated airflow distribution systems by developing a 1:100 scaled block cave experimental model and a numerical model. This study also investigated gas flow behavior under various airflow conditions. Based on our findings, we observed that reduction in particle size and porosity of caved materials, decrease in cave footprint, and closure of undercut drifts would increase cave airflow resistance. The increased airflow is found beneficial for gas dilution regardless of its source locations, while the regulated airflow distribution system might deteriorate gas dilution situation when the source is located in the extraction drifts.

May 12, 2022