Search Documents

By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"In natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the content of MoO3 varies from 2% to 10%. As a result, the flotability of seyrigite (scheelite with molybdenum) turns to be weaker. One seyrigite mine, which has been built for 3 years,still could not produce qualified seyrigite concentrate due to the weak flotability of seyrigite (Mo-bearing scheelite) in raw ore. In our experimental research, through adopting new seyrigite collector TA-3 and advanced mineral processing technology, the seyrigite concentrate with a grade of 65.62% WO3 at a recovery of 87.47% was obtained for the raw ore containing 0.19% WO3 and 0.074% Mo. By applying the new technical achievement, for the raw ore containing 0.272% WO3, the seyrigite concentrate assaying 68.03% WO3 with a recovery of 77.56% was obtained in industrial production.INTRODUCTIONIn natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the scheelite is changed to be seyrigite (Ca[(W,Mo)O4]) (Ma, Bian, & Wang, 2013). The content of MoO3 in seyrigite varies from 2% to 10% usually, the content of MoO3 in some of the seyrigite even reaches 34%. The flotability of seyrigite is weak (Zhang, 2007), and the seyrigite is difficult to be recovered by flotation with common collectors and regulators. One scheelite mine in Anhui China, which is a skarn type seyrigite mine, has not produced qualified concentrate yet since 3 years it has been built due to the limit of beneficiation technology. Therefore, it is necessary to conduct research on the collectors with high efficiency and developing advanced processing flow for this kind of ore."

Jan 1, 2016

Designing rigging systems for complex castings has been more of an art than a science. Foundrymen have used thumb rules based on past experience to develop working designs. Of late, attempts are being made to formalize the procedure through the use of rule based expert systems, process modeling and other tools. Designing risers is one of the challenges of the rigging system design. Once the riser location have been determined, an optimization technique coupled with a casting simulation code can be used to determine the optimum riser dimensions. The main drawback of using a finite element or a finite difference based process simulation code along with the optimization routine is that the computation time involved is too large. Such an approach, thus, is unrealistic for practical situations where different options have to be explored and conclusions drawn in a short period of time. This difficulty has been avoided in the present work. The optimization scheme has been coupled with a modulus based solution routine to optimize the riser dimensions. The modulus calculations provide a good and quick estimate of the freezing time at different points in the casting. A functional, obtained from these freezing time values, is minimized by altering the dimensions of the riser until an optimum shape is obtained. Some examples have been included to illustrate the utility of this technique.

Jan 1, 1994

By Jorge Alberto Soares Tenório, Denise Crocce Romano Espinosa, Amilton Barbosa Botelho Junior

A new step in the Bayer process has been used to recover NaOH and to reduce its content in red mud. After digestion, the residue is separated from the Bayer liquor and goes through press filters, which enables the recovery of NaOH and decreases the moisture content. It is well known that red mud is one of the most important sources of scandium. For this reason, the goal of this work was to characterize a Brazilian red mud (BRM) for scandium recovery. The sample was collected after the press filter system process. Analysis of energy-dispersive X-ray fluorescence (EDXRF), scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDS), and X-ray diffraction (XRD) was performed. Microwave digestion using an acid mixture was carried out to determine the concentration of the main elements. Fe2O3 represented 40% of the BRM, and the Sc concentration was 43 mg/kg. The SiO2 content was 24%, which is the highest value found in the literature, whereas the sodium concentration was the lowest. A literature review was carried out to compare results with BRM, as well as the current studies for recovery of scandium by the leaching/ion-exchange process. Scandium recovery using a leaching/ion exchange process may be possible with efficiency higher than 90%. The greatest challenge is the occurrence of silica gel formation during leaching.

Oct 19, 2020

By S. Swaroopa

Copper-chromium mixed oxides are widely used as catalyst for organic chemicals industry, NOx and CO oxidation, solid propellant etc. In the present investigation, one such spent Cu-Cr catalyst has been tested for recovering copper and chromium values through hydrometallurgical route. The spent catalyst used in this study contains about 42% Cu and 36% Cr. Phase analysis through XRD indicates that major phases are copper chromium oxide (CuCrO2) and copper chromate (CuCr2O4) while minor phase is copper oxide (Cu64O). SEM images show that high energy ball milling changes surface morphology significantly ? more regular shaped grains in unmilled samples changed to fine agglomerates. Surface area also changes significantly due to milling. Preliminary leaching experiments with NH3 and H2SO4 media using unmilled samples indicate that both the media are suitable for selective extraction of copper. About 55% copper recovery is achieved in 2 h using 1.2 M NH3 + 0.2M (NH4)2SO4 solution at 100°C. Increasing NH3 concentration or temperature does not improve the recovery significantly. Under the above conditions chromium, dissolution is insignificant (max. 2.24%). XRD analysis of the residue indicates that copper chromate fraction (CuCr2O4), which is a spinel structure, remains mostly intact. In sulphuric acid media at ambient temperature, 47% copper recovery is achieved with 7.5% (v/v) H2SO4 and maximum of 57% with the increase in acid concentration to 20%. However, 67% recovery is achieved by increasing the leaching temperature to 150°C. High energy ball milled samples show improved leaching efficiency. Under the leaching conditions of 7% H2SO4 (v/v), 2% pulp density, 80°C an unmilled sample yields 47% Cu recovery whereas 3h and 5h milled samples yield 65% and 90% Cu recovery respectively in 2h leaching time. Influence of temperature is also more pronounced in milled sample leaching in comparison to unmilled sample. Water leaching of alkali (NaOH) roasted milled sample carried out at 750°C for 2 h with 100% NaOH (w/w) resulted in 80% Cr recovery as compared to 37% Cr recovery using unmilled sample under the same conditions. Keywords: spent catalyst, copper, chromium, leaching, mechanical activation, roasting

Sep 1, 2012

By Bernard J. Steblay

Two instruments have been constructed that extend microseismic data collection and processing capability for Bureau of Mines research in rock burst, coal bounce and outburst, and roof fall monitoring. The first instrument is a 13-channel tape-triggering system. This system allows better utilization of instrumentation tape recorders by collecting data digitally, turning the tape on only when valid data are present, and increasing the dynamic range of the recorder by using digital data. A digital-to-analog converter is used to provide analog output of the recorded digital data. The instrument records a much larger time slice of transient events than do current commercial devices. The second instrument is a microseismic energy measurement device. This device uses recent developments In integrated circuits to overcome the dynamic range and accuracy limitations of previous instruments. The analog signal is converted to a digital one, and then high-speed multiplication techniques are used to square the amplitude value in real time and integrate it.

Jan 1, 1983

By Thomas Fraser

About 24 per cent of our total production of bituminous coal is used in industrial power plants. As regards fuel conservation, therefore, the recovery of unburned fuel from furnace refuse presents interesting possibilities. Considerable attention has been given to this problem in the past, but because of the comparatively low initial cost of power plant fuel in the pre-war period little progress, has been made in this direction in the United States. Because of the higher price of coal in Europe more attention has there been given to the problem. In Germany a process has been developed for separating unburned coal in refuse by using an electromagnetic separator In the United States the use of mechanical stokers enabled low-priced screenings of high ash content to be used, so that even with relatively high percentages of combustible material remaining in the refuse, the loss in money is not excessive. If the price of screenings returns to the pre-war level around $1.00 per ton the process proposed here will probably not be especially interesting, except where the freight charges are very high. However, if the price of delivered coal continues high, such a process should result in considerable saving. The cost of continuous operation of such a refuse treating plant should not exceed 75 cents per ton of fuel recovered.

Jan 1, 1921

By A. L. Engel

Many western ores containing ;old, silver, and copper can be mined and concentrated at a profit only when the recovery of those metals is high and treatment costs are low. Usually, ores containing easily dissolved copper minerals, or copper minerals that become soluble to some extent through oxidation during treatment, present a real problem in cyanidation. Copper cyanide compounds are formed that tend to 'precipitate and that cannot yield regenerated cyanide and metallic copper on contact with zinc. This results not only in some loss of copper through solution in cyanide, but in excessive consumption of cyanide above the amount required for the extraction of Gold and silver. Any moans, therefore, of minimizing the: loss of cyanide while at the same time effecting high recoveries of the several values contained in the ore is of wide interest. A sample of typical low-grade ore of gold, silver, and copper, containing copper-sulfide minerals, was obtained from the MacLaren Gold Mines Co., Cooke, Park County, Mont., for laboratory investigation by flotation and cyanidation.

Jan 1, 1950

MIM Holdings Limited has acquired a reputation for the successful application of R&D to develop break-through technologies for the mining industry. The Isa Process tank-house technology has been licensed to copper refineries throughout the world, and almost 40 per cent of the worldÆs copper is refined using this technology. Isasmelt copper and lead smelting technology is either in use, or is currently being installed, by eight companies in eight countries around the world. Jameson Cell technology is widely used in the coal mining industry and increasingly in the base-metal industry. The IsaMills developed at Mount Isa and McArthur River made it possible to develop the McArthur River and George Fisher orebodies. This paper will address the need for innovation and then discuss the development of the IsaMill and Isasmelt technologies. It will conclude with some comments about why MIM has been so successful in developing such technologies.

Jan 1, 2002

By R. Leiby

Prior to March 1992, the only component of the lead acid battery that was not recycled by East Penn Manufacturing Company was the sulfuric acid electrolyte. This acid was unusable in new batteries because the iron level was found to exceed new product specifications. The development of a liquid ion exchange process to remove the iron from the acid allows East Penn to currently recover over three million gallons of sulfuric acid annually. The process is based upon the use of an iron selective liquid ion exchange material or solvent to extract iron from the sulfuric acid electrolyte followed by regeneration of the solvent. Equilibrium and kinetic data for the extraction and regeneration steps were collected in order to scale up the process to commercial scale. An electrochemical process for the treatment of the acid used in the regeneration step was, also developed which significantly reduces the volume of strip acid required in the process.

Jan 1, 1995

By Jafar Safarian, Gabriella Tranell, Stine Espelien

Hydrometallurgical treatment of silicon is an effective process for the removal of metallic impurities for producing solar grade silicon feedstock. In the present research, the removal of impurities from silicon is studied through the addition of Mg into a commercial silicon, its solidi fication, and acid leaching. The effect of concentration of HCl, temperature and leaching duration on the removal of impurities are studied. It is shown that the impurities such as P, Fe, Al, Ti, Ca, …are effectively removed through the applied method and Mg improves the segregation and the removal of the impurities. Scanning electron microscopy examination of the samples indicates the disintegration and dissolution of Mg2Si phase in acid leaching which causes the chemical and physical removal of the impurities existing in the phases between the silicon grains. It is shown that the leaching process rate can be optimized through the control of the acid leaching conditions.

Mar 1, 2017

By F. W. Smith

To determine whether preheating coals before carbonization would improve the coking properties of the coals, particularly the weaker coking coals, 3 coals, 1 each from Illinois, Kentucky, and Pennsylvania, and a blend of the Illinois with a Pocahontas coal were preheated before testing for coking properties in the Bureau's BM-AGA pilot oven. The effects of preheating on the chemical and physical proper-ties of the coals and on the yields of carbonization products and strength of the coke produced from the preheated coals were determined, as were also the effects of bulk density, gaseous atmosphere, and residence time during preheating. Most benefit from preheating was found with weaker or oxidized coking coals, whereas the more strongly coking coals and blends showed little effect. Direct charging of preheated coal to the coke oven without cooling gave better coke, increased yield of tar, and decreased yield of gas. INTRODUCTION Although 94 percent of today's coal production comes from fields east of the Mississippi, the Eastern States have only about one-third of the Nation's recoverable reserves. West Virginia, which now produces more than any other State, has much smaller reserves than Utah, Colorado, and Wyoming.5/ However, the manufacture of iron and steel in Western States, which has increased greatly since World War I, is handicapped by the scarcity of high-grade coking coals, such as are plentiful in the Appalachian region. Unless a practical method of improving the cokemaking property of local coals is developed, ferrous metallurgical industries in the West must continue to use inferior coking coals and to pay high shipping charges for better coals.

Jan 1, 1958

By Charles W. Perry

The options of enhanced oil recovery, coal syncrude, and shale syncrude are compared by approximately equivalent economics. The physical constraints for the major enhanced oil recovery processes are described, followed by new estimates of cost. The range for all three options in terms of light syncrude equivalent are $22 to $40 per barrel in 1980 dollars.

Jan 1, 1982

By Kotaro Ogura

"The electrolysis process in which CO2 is selectively reduced to C2H4 at a three-phase(gas/solution/metal) interface on a copper-mesh electrode has been developed in a concentrated solution of potassium halide. At open-circuit potential, CO2 is captured on the electrode by being inserted into the double-layer consisting of halide anions specifically adsorbed and potassium cations which are located in the Helmholtz inner and outer layers, respectively. CO2 thus activated is subjected to the electrochemical reduction. In the early stage of reduction, CO2 is converted to formate radicals that are adsorbed on the electrode by taking the place of halide anions. The reductive coupling of these radicals results in the formation of intermediates such as -CH2C(O)- and CH2=CH-, and C2H4 is finally produced. The catalytic activity of the electrode process involving the insertion of CO2 into the double layer is not deteriorated at all during the electrolysis, and the continuous reduction of CO2 to C2H4 is possible with the addition of inorganic acid under the assistance of natural energy.Carbon dioxide is a serious pollutant released from fossil fuel power station, internal combustion and many industrial operations. The easy release of CO2 to the air has caused the global warming, and the technique which intends to curtail CO2 by pushing it back into the ground has been suggested. However, this problem should be greatly mitigated if CO2 can be converted to innocuous substances. Especially, the reuse of CO2 as fuels and chemicals is extremely effective not only for the mitigation of the global warming but also against the depletion of the fossil fuel reserves. Several processes for converting CO2 to valuable compounds have been proposed including hydrogenation over heterogeneous catalyst at high temperature and electrochemical and photochemical reduction. In the conversion and cutback processes of CO2, however, it is of importance that the process is feasible under mild conditions, because the secondary generation of CO2 is feared if high energy is required and supplied with a fossil fuel. In this meaning, the electrochemical reduction of CO2 taking place at room temperature, which is similar to photosynthesis, is promising. From the practical point of view, it is further necessary that the conversion rate is high enough and the product is satisfactorily valuable."

Jan 1, 2008

By S. Mao

Total station has been predominantly applied in stationary survey scenarios in construction. With the moving target tracking and point survey automation functions, a robotic total station (RTS) lends itself well to more dynamic applications. Nevertheless, a RTS unit is still unable to track multiple targets simultaneously or to survey a target point when the line-of-sight is temporarily unavailable. In this paper, we propose a methodology to synchronize and automate multiple RTS units intended to address dynamic tracking and surveying applications in the construction field. By using the application programming interface (API) from the manufacturer, we implement the proposed methodology and the prototype system integrates two RTS units in regard to space and time and communicates survey command instructions among RTS units through wireless networks. The two RTS units can be operated to survey the two ends of one swinging sling concurrently in order to retrieve the actual length of the sling within several millimeters accuracy. Besides, in applications where line-of-sight between a target object and one RTS unit cannot be guaranteed all the time, continuous surveying can be materialized by automatically delegating the task to another synchronized RTS unit with clear view of the target object. A field test was conducted to demonstrate the application of the proposed automation approach in which sling length was measured of a rigging framework used for lifting industrial modules. The testing results are presented and achievable accuracy and reliability are discussed. The proposed solution overcomes the limitations of global positioning system (GPS) and laser scanning and holds high potential to provide cost effective solutions to many dynamic field applications.

Aug 1, 2013

By Fred D. Wright

Some new equipment for drilling vertical holes, cleaning blast holes, hauling explosives, and conditioning Diesel exhaust gas has been developed. at the Bureau's Experimental Oil-Shale mine near Rifle, Colo, The equipment has application, not only in oil-shale mining, but in many of the country's underground mines in which room-and-pillar methods of mining are employed. This report presents the Bureau's experience in testing the following equipment in the Experimental Oil-Shale mine: 1. A four-drill benching jumbo for drilling 23-foot vertical blast holes 2. A jet borehole blower for efficient cleaning of deep, vertical blast holes. 3. An explosives truck equipped with two compartments to provide safe conveyance for dynamite and detonators. 4. A mobile, electric substation to provide switching equipment, low-voltage and overload protection, and transformer facilities to remote locations in the mine. 5. A chemical conditioner for scrubbing the exhaust gases from Diesel-powered equipment used in underground operations. 6. Other units of equipment which have been tested at the Experimental mine.

Jan 1, 1951

By R. A. Wildenboer, R. F. Sandenbergh

Rare earth elements (REE) are present at concentrations of approximately 0.36 % in phosphogypsum stacks located in Phalaborwa, South Africa. The REE are present in the phosphogypsum in solid solution in the gypsum and as fluorine and aluminium rich precipitates. Recovery of the REE offers opportunities for valorization and reducing the environmental impact of the phosphogypsum waste. This paper presents the results of investigations into the leaching behaviour of rare earth elements and other impurities from phosphogypsum using aqueous sulfuric acid. The effects of acid concentration, temperature, residence time, and the influence of impurities were evaluated for their impact on the solubility of rare earth elements in a sulfate medium. It was found that a significant fraction of the REE can be leached from the phosphogypsum in a range of conditions much less severe than traditional hard rock rare earth processing conditions. The REE were leached at a sulfuric acid concentration of 110 g/l, temperature of 30°C – 40°C and a residence time of approximately 8 hours.

Nov 6, 2024

By J Deraisme, P Epinoux, O Bertoli

"Société le Nickel exploits the Dôme lateritic nickel orebody at its Tiébaghi operations in New Caledonia. The site geology has an obvious bearing on recovery and metallurgical performance, with controls that are extremely complex at all scales, including lithology, oxydo-reduction conditions, mineralogy and multivariate geochemistry. In this context, establishing an adapted recoverable resource estimation method that is efficient and transparent proves an interesting challenge. The method must address the key notions of: support effect – the exploration data set can only warrant the estimation of large panels of 20 × 20 × 3 m3 that are much larger than the selective mining units (SMUs) of 5 × 5 × 3 m3 information effect – the selection at the production stage uses estimates based on information that is much denser than that available for mine planning.The problem is rendered more complex in this type of deposit by the fact that the additive variables used for the estimation (metal accumulation and ore tonnage) are not the ones used to establish the selection at the mining stage (ie the nickel grade of SMUs, which is the ratio of accumulation on tonnage). Eventually, the selection criteria not only involve Ni grades, but also other elements such as Al2O3, Fe2O3, MgO and SiO2.The solution presented in this paper is to construct an SMU multivariate simulation in the saprolitic horizon and construct an efficient post-processing aimed at producing multivariate recoverable resource estimates. The efficiency constraints imposed by the number of blocks to be simulated (1.5 million) lead to resorting to direct block simulations. The underlying multivariate discrete Gaussian model, which had its validity tested beforehand, is put to good use to mimic the selection process that happens at the mining stage by offering the ability to simulate a composite value located at random within each block.The paper also presents the application of a scenario reduction algorithm to pick a representative subset of a few simulations to help appraise the risk attached to the downstream (reserve optimisation and mine sequencing) phases of the project. The original version of the paper (see Deraisme, Bertoli and Epinoux, 2014) used an early version of the scenario reduction plug-in (named S2RM) built in Isatis® software, where measuring the distance between the initial set of scenarios and the reduced set was based on Ni only. The implementation presented here is for the second generation of S2RM, where measuring the distance between the initial and the reduced set of realisations is based on all study variables. The benefits of the measure adapted to the true multivariate nature of the problem are highlighted in this updated version of the paper.CITATION:Bertoli, O, Deraisme, J and Epinoux, P, 2014. Multivariate block simulations of a lateritic-type nickel deposit and post-processing of a representative subset, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 99–108 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 24, 2014

By Xiang-nan Zhu, Hao Zhang, Lin Li, Jun Qiu, Yue-xian Yu, Chun-chen Nie, Xian-jun Lyua

Waste printed circuit boards (WPCBs) are excellent metal resources. Mineralogical characteristics of different components in WPCBs were analysed in this study. Organic-enriched particles, fibreglass-enriched particles, associated particles and metal-enriched particles were obtained by density gradient method. Subsequently, the elemental composition, morphology, dissociation characteristics, functional group composition and phase composition of different components were analysed by X-ray fluorescence spectrometer (XRF), scanning electron microscopy and energy dispersive spectrometer (SEM+EDS), infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). Elemental analysis results show that Cu is mainly contained in metal-enriched particles. SEM+EDS analysis results demonstrate that ideal dissociation can be achieved when the WPCBs are broken to -1 mm. Organic matter particles are enriched with carbon and oxygen elements, while fibreglass particles and associated particles mainly contain Al and Si elements, verified by XRD analysis. FT-IR results show that hydrophilic and hydrophobic groups exist widely in all components, caused by widespread organic matter. This study reveals the important properties of different components in WPCBs, which is of great significance for the subsequent separation process. Key words: Waste printed circuit boards, mineralogical analysis, elemental composition, dissociation; phase analysis, functional group composition

Jan 1, 2020

By K. M. Connor, O&apos

Variations in overburden geology must be considered in applying subsidence prediction methodologies developed by the U.S. Bureau of Mines (USBM). To characterize rock mass overlying high-extraction coal mines, the USBM utilizes a computer spreadsheet program and modified Rock Mass Rating (RMR) system. The spreadsheet calculates an RMR based on a bed's engineering properties determined from core logs and laboratory tests. An in situ deformation modulus and a bending stiffness are computed for each bed. Stiffness-versus-depth plots identify groups of beds with similar stiffness. Large variations in stiffness between adjacent beds are considered significant horizontal discontinuities where slip is likely. Time domain reflectometry (TDR) is used to verify this hypothesis by measuring shear displacement along such discontinuities. A model of the overburden is built by assuming that a near-surface laminated beam exists above a transition zone in which large plastic slip occurs along horizontal discontinuities. Increasingly thicker groups of beds are modeled to determine the most probable beam thickness based on a comparison with measured deflection profiles. The inverse of maximum beam deflection is an index parameter known as "bridging potential," a single value that incorporates both overburden geology and mine geometry.

Jan 1, 2010