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"Hematite pellets were electro-deoxidized to iron in molten sodium hydroxide to produce iron containing about 10-wt % oxygen. The anodic reaction was the evolution of oxygen on an inert nickel anode. Before the electrochemical reaction, there is a reaction between sodium hydroxide and ferric oxide to form sodium ferrite and, in order to compensate for the reduction in sodium oxide content, 1 wt % sodium oxide is added to the melt. In a laboratory cell, the cell voltage was 1.7 V with a current density of 5000 A m-2, a current efficiency of 90% and an energy consumption of 2.8 kWh kg-1.Introduction The iron and steel industry contributes about 2.3 bn tonnes/annum of the carbon dioxide to the atmosphere, which is about 10% of the total, and some believe that, in order to prevent a catastrophic rise in the earth’s temperature, carbon dioxide emissions must be reduced by 50% come 2050. However, by 2050, it is likely that the iron and steel industry would have grown significantly so that the production may have risen to 2 or 3 bn tonnes/year so in order to meet the 50 % reduction on today’s figure, the carbon dioxide may have to be reduced to 25% or less, which is a very demanding requirement. There are probably three ways of reducing the carbon dioxide output:1. By capture and sequestration, but this may be technically very demanding.2. Reduction using hydrogen in place of carbon."

Jan 1, 2009

By E. R. Palowitch

This report stems from a study by the Bureau of Mines of the possibility of reducing coal filter-cake moisture by applying radiant heat directly to the filter cake while under vacuum during the drying phase of the filter cycle. One disk of a 4-foot-diameter vacuum filter was equipped with gas-fired radiant-heat generators and the effect of radiant heating on the moisture content of a variety of filter cakes was studied. The results of this investigation show that this process can best be described as a filter aid capable of increasing the effectiveness of conventional filtration approximately 6 percentage points of moisture. The operating cost of removing water by this method is somewhat lower than the average operating cost of thermal drying and is considerably cheaper when the total cost is considered. Removal of water from coal that has been wet-cleaned is an important part of the overall coal preparation process. Water is a contaminant, and it is foolish to wash coal to reduce its ash content and add inert water in the process. In some instances the removal of water is actually more important than the removal of ash-forming minerals; its weight adds to the cost of transportation, and its evaporation during burning or carbonizing absorbs useful heat. Fine coal that contains more than about 10 percent moisture is notoriously difficult to handle. A problem thus exists for which there are sound practical and economic reasons to seek a solution.

Jan 1, 1961

By Xuan Cheng

The electrochemistry of sulfide mineral flotation is reviewed with particular emphasis on galvanic interaction among minerals and grinding media, and its relevance to flotation of complex sulfide ores is discussed. Surface alteration due to galvanic interactions among chalcopyrite, pyrrhotite and mild steel is analyzed in terms of voltammetric and chronoamperometric studies on individual minerals and through galvanic current measurements in 2- and 3- electrode combinations. The results are related to laboratory flotation behaviors of chalcopyrite-pyrrhotite mixtures simulating copper-nickel bearing Duluth gabbro.

Jan 1, 1993

By Courtney A. Young

All cyanide species are considered toxic and can be found predominantly in industrial effluents generated by metallurgical operations. For example, cyanide's strong affinity for metals makes it favorable as an agent for metal finishing and treatment and as a lixivant for metal leaching, particularly gold. These technologies are environmentally sound but require safeguards to prevent water contamination. Various methods of cyanide remediation by separation and destruction are available, but certain methods are more effective than others depending on the cyanide species being remediated. Photolytic destruction is regarded as the one technique that is independent of the cyanide species involved. The destruction of various cyanide species by several photolytic techniques has been investigated for the past few years. A literature survey suggests heterogeneous photocatalysis with anatase (TiO,) should behave similarly to homogeneous photolysis with hydrogen peroxide (H,O,) since proposed reaction mechanisms for both processes involve hydroxyl radicals. However, experimental evidence on a suite of cyanide species suggests otherwise. A new mechanism for the photocatalytic destruction of cyanides, especially SAD species, is therefore proposed.

Jan 1, 1998

By Oliver Bowles

Limestone is the most widely used of all racks and is essential to a great many industries, including tae building trades, highway construction, metallurgy, agriculture, end many chemical and manufacturing enterprises. It occurs in some form in every State and is produced in thousands of quarries. Production in 1930 exceeded 134,000,000 tons. It has more numerous and more diversified uses than any other rock. This paper is designed to furnish general information on the various branches of limestone quarrying and their economic importance. Brief reference is made to dimension stone, and a more complete discussion follows of the uses, requisite qualities, quarry methods, grid processes of preparation of crushed and broken limestone. Footnote references serve to guide the reader to more detailed information.

Jan 1, 1933

By G. M. Hughes, R. W. Dunn

"AbstractCurrently installed an analogue instrumentation devices at Sherritt 's Ruttan Concentrator control. and/ or measure mill tonnages, grind, pH, density , some reagent and slurry flows, and cell levels. On-stream analysis is used to assay the main process streams. The history of development of process control is reviewed from startup to the present stage of selection of a process control computer. A pragmatic approach has been taken to process control to ensure compatibility with the needs and resources of Ruttan. Emphasis is made of the need to have the mill performing well from a mechanical and instrumentation point of view and to have opera tor acceptance of the computer through training. Plans for the computer phase to achieve these objectives are outlined.IntroductionTHE COPPER-ZINC OREBODY at Ruttan Lake was discovered by Sherritt exploration personnel in 1969 and by mid-1973 a 10,000-tpd mine and concentrator were in operation. After a typical startup period , the major mechanical problems in the crusher and concentrator have been resolved. Metallurgical performance is now up to standards forecast in the feasibility study.The cost of the original instrumentation installations, including an on- stream analyzer, was about one million dollars or 4% of the cost of the milling complex. Although there was no intention of using a process control computer until the plant was operating smoothly, it was understood that all instrumentation was compatible with .a computer, but this did not prove to be correct. This paper cover s the development of the instrumentation loops to date and the control strategies that will eventually be implemented through a process control computer."

Jan 1, 1977

By Michael J. McGuire

Rostoker, Inc. has developed a process to smelt solid hazardous/non-hazardous inorganic wastes. Near seven hundred experiments were performed. Actual industrial wastes as well as reagent grade chemicals were used. By mixing a multiplicity of these wastes to proper formulations, then furnacing them, it was determined that saleable end products could be reclaimed; metal, fume and slag. The slag, due to its siliceous structure was tested to be leach resistant (40 CFR). This formed the essence of our patent, #5,180,421 "Method and Apparatus for Recovering Useful Products from Waste Streams". What is unique is that a HTMR (High Temperature Metal Recovery) process has been developed that can treat a multiplicity of wastes within the same furnace. The discussion will include a list of waste streams we have treated, details of proper waste formulation and experimental results.

Jan 1, 1994

By C. Sampaio, C. Petter, M. Veras

"INTRODUCTION Use of sensor technology applied to the gravimetric beneficiation is intended for the selective preconcentration or separation of various minerals. Sensor Based Sorting (SBS) uses sensors to identify the particles and separate them by a mechanical process (flap) or pneumatic ejection valves (Wotruba et al. 2014). The principle of the SBS technology to separate mineral particles consists of three phases which cover feed,detection and separation. (killmann, 2009 Apud nienhaus et al. 2014). The applicability of the technique in an early stage of beneficiation enables free particles and poor grade to be a part of the process. The mass of tailings to be processed can be removed at the initial stage to save energy, water and equipment maintenance (Wotruba et al. 2014). Lindner (2010) suggested that the use of SBS technology would only will be possible if there exsists an electromagnetic interaction in all the wave spectra interacting with the solid ore. The interaction of electromagnetic waves depends directly on the characteristics of the material. The material receives a spectrum of electromagnetic waves by irradiation and this results in a reduced wavelength with differing types radiation such as fluorescence, reflection, remission, absorption, transmission and transmission. The frequency of the wave spectrum varies between 1000 and 1020Hz, illustrated by the data in Figure 1, which shows that each type of sensor emits a wavelength inversely proportional to the frequency ranging from 10-11pm to 104km, and the frequency that varies between EHz 103 and 1020kHz. The difference between the electromagnetic spectrum variations can only be visible to the human eye at wavelengths with intervals between 380nm and 780nm (Wotruba et al. 2014). One of the main advantages of operating with imaging sensors is the versatility of the images which can take on zero, one, two or three dimensions shown below as a point, a line, an area or a spatial image, as illustrated in Figure 2. According to Schubert (1988), to separate a mineral particle it is necessary to follow the characteristics of mineralogy, physics and chemistry with or without use of water. The use of new technologies can help reduce operating costs and improve utilization of mineral resources."

Jan 1, 2016

By Yaxiong Wang, Yong Li, Yuedong Wu, Haigang Dong, Jiachun Zhao

A roasting-leaching process has been developed for concentrating platinum group metals (PGM) from a PGM-containing ferroalloy. The optimized roasting conditions used a NaOH-to-ferroalloy mass ratio of 1.2 at 600 °C for 2 h. The roasted product mainly comprised Na4SiO4, NaFeO2 and Fe2O3. The iron oxide and sodium silicate associated with the roasted product were leached in water and dilute sulfuric acid solution, while the PGM was concentrated in the acid-leached residue. A PGM concentration of 23.4% was obtained with assaying, and the concentration factor of PGM from the ferroalloy to PGM concentration was greater than 9.

Jun 14, 2021

By John B. Gayle

During studies of the various methods for determining and specifying the factors that indicate whether a particular coke is better or worse than other cokes for metallurgical uses, questions arose as to the precision of screen-analysis tests on coke. Although the usual index of precision, the standard deviation of the test result, gives a measure of the precision of these data, the experimental determination of the standard deviation for a particular set of conditions requires tests on a large number of duplicate samples. Because this procedure necessaily involves a great deal of labor, an equation for predicting standard deviations from theoretical considerations has been developed. Results predicted with this equation agree satisfactorily with the experimental values and are applicable to tests on coal, coke, gravel, and other bulk materials.

Jan 1, 1952

By C. R. Machado

Sossego Mine was the first Vale SAG mill operation to process copper-gold ore. It is located in the state of Para, in the south-eastern Amazon region of Brazil. In the first six years of continuous operation, Vale investigated different alternatives for improving circuit performance by investigating operating conditions, mainly focusing on the SAG mill. Today, after a steady increase over five years the annual production rate seems to have stabilized. It is hoped this work will show how the SAG operating practice have been perfected with time and as new data are collected. Historical data of mill grind-outs and crash stops helped create operation curves depending on the ball charge volume and total charge volume. Also noted were impacts on throughput due to the effect of reducing liner weight and the ore type characteristics.

Jan 1, 2012

By Enrique Toledo G

Dado que la vanguardia tecnológica en la perforación y transporte subterráneo minera es cada vez mayor, se hace necesario que las labores mineras se adecúen al funcionamiento del sistema. En este sentido, el método tradicional de cuadros de madera en la minería subterránea sin rieles quedó desplazado, surgiendo alternativas modernas como el empleo de arcos metálicos revestidos con concreto armado, el bulonado con diferentes tipos de pernos de roca y la aplicación del Sholcrete. Entre estos últimos, la mina Cobriza ha desarrollado un nuevo método de sostenimiento denominado "Shot Fer", el cual satisface el desarrollo de las labores mineras, asegura la estabilidad permanente de las labores subterráneas en terreno deleznable, disminuye los altos costos unitarios en el sostenimiento de las labores subterráneas y garantiza la seguridad contra los accidentes que pueda sufrir el personal que trabaja en la perforación y en las operaciones de sostenimiento.

Nov 8, 1984

By M. S. Tsai

Recovery of uranium from wet-process phosphoric acid is a newly developed source of uranium. Many processes have been developed but the OPAP (octylphenyl acid phosphate) process is still the valuable one because the OPAP reagent compound has the high extraction ,power and cheap cost. The OPAP process was already studied by murthy(1) in 1970 and its complete process flow sheet was first fulfilled by F.T. Hurst(2) in 1974. WCFC(3) (western Co-op Fertilizer Ltd.) in cooperation with ESI (Earth Science Inc.) set up the OPAP uranium recovery pilot plant in Canada in 1978. We have studied the OPAP process since 1974 and first improved the OPAP extractant by proper adjustment of the DOPAP/MOPAP mole ratio with CH3OH-H20 method, resulting in shortening the phase separation time and avoiding the precipitation occurrence in our process. Second, we utilize the reduction and oxidation occurring by DC power supply on either side of the membrane to achieve the extraction and stripping at the same time. An improved OPAP process in which high recovery yield of uranium and acid uncontaminated by iron has been developed in our laboratory.

Jan 1, 1982

By Wallace W. Roepke

Four bit designs, two conical and two radial, were tested in coal against a 60° conical reference bit to obtain data on orthogonal cutting forces and primary respirable dust generation. One conical and one radial design were modified by the Bureau of Mines for these tests. Results were mixed: One radial bit used substantially lower overall cutting forces and specific energy than the other bits and was the only cutter lower on energy and most forces than the standard 60° bit. How-ever, it generated more specific and total dust than any other bit. The four bits were also tested for incendivity, with a 90° plumb-bob bit as the reference. The frictional ignition tests were designed to simulate both trimming top rock and cutting such rock during advance on-sump. Results of these tests were also mixed. The radial bits were substantially less incendive than the reference bit and caused no ignitions in either top trimming or sump modes. Only the modified mushroom-tipped conical bit caused ignitions. Bits similar to this modified design should not be used on drum-type miners in gassy mine areas; in-stead, the other types of bits tested should be used to reduce ignition potential to a minimum.

Jan 1, 1983

By M. H. Kline

The Scarlet mine, in Randolph County, N. C., was operated on a small scale at intervals from 1899 to 1915, but no records of the quantity of ore produced are available. J. I. Moore unwatered the mine in March 1948, and Bureau of Mines' engineers examined the underground workings. Several assays checked previous sampling of the mine and indicated a small but comparatively high-grade copper-zinc deposit. The high metal content of the veins and the possibility of developing additional reserves prompted the Bureau of-Mines to drill three holes, totaling 530 feet, at the deposit during March and April 1948. Drilling disclosed that the mineralized vein did not extend over 300 feet along the strike and is probably limited in depth to the contact with the granite mylonite.

Jan 1, 1949

By Y. Q. He

The dynamic behaviors of the air bubbles in the dense gas-solid fluidized bed have a significant effect on the performance of dry coal separation. The combined method of experimental measurement and numerical simulation were conducted to conduct the research of the mean diameters and rising velocities of the bubbles in the fluidized bed. The calculation models of mean diameter and rising velocity of the single bubble were proposed. The results indicate that the models of the mean diameter raised by Rowe (1976) and the rising velocity raised in this work could be used to predict the bubble dynamic parameters in gas-solid fluidized bed. With the Geldart B type of magnetite powder as the medium solids and while the gas velocity of 1.5Umf=U=2.2Umf, the mean bubble diameter along the bed height is 36mm<Db<45mm, and the mean rising velocity of the single bubble is distributed in 40~65cm/s. The results of experimental measurement, numerical simulation and model predication provide well agreements finally. Based on the uniform fluctuations of air bubbles diameters and their rising velocities, the separation experiments of 50~6mm dry coal using the mixture of 0.3~0.15mm magnetite powder and <1mm fine coal as medium solids were carried out. The results show that the probable error, E is 0.06, which indicates a good separation performance by using the gas-solid fluidized bed. Keywords: dense gas-solid fluidized bed, bubble dynamic behaviors, numerical simulation, separation performance

Sep 1, 2012

By M Zengerer

The Basil Cu/Co deposit comprises a 26.5 Mt Inferred Resource of copper and cobalt, grading 0.57?per cent Cu and 0.05 per cent Co. It lies in the Harts Range, Central Australia, within the Riddock Amphibolite of the Irindina Province. Analysis of drilling within the mineralised zone of the deposit determined a spatial association between pyrrhotite with high magnetic susceptibility and chalcopyrite, following a strong magnetic trend as determined from airborne geophysics. A study was commissioned to examine if geophysical inversion could predict the distribution of sulfide mineralisation based on pyrrhotite from drill hole intersections, as well as predicting further mineralisation at depth or in the vicinity of the deposit. Petrophysical and geostatistical analysis of drilling susceptibility and mineralisation provided a basis of property distribution inside the model. This was followed by 3D geological modelling of mineralisation based on domain kriging of drill hole susceptibility sensitivity testing of signal to source depth, and distribution was performed using 3D forward modelling. Stochastic inversion generated alternative 3D geological models, which were tested for behaviour and adherence to observed drilling data and geostatistical limitations using GeoModeller software. Predicted mineralisation distribution was compared with conventional geostatistical modelling and found to be in agreement in planar behaviour but exhibiting possibly isoclinally folded trends, with reliability increasing closer to the surface. Predictions of mineralisation at greater depth and beneath weaker anomalies were more diffuse due to small model cell size having limited influence on the signal at depth.The Blackbush uranium deposit comprises a 64.5 Mt Inferred Resource, grading 230 ppm U in the Pirie Basin south of Whyalla, South Australia. It directly overlies the radiogenic Samphire Granite and is considered a tertiary unconformity deposit. Sensitivity modelling was performed using high-resolution ground gravity to see if a deposit signature could be detected using gravity. This required 3D implicit modelling of the geology and mineralisation from drill hole data and characterisation of an associated physical property model using domain kriging in GeoModeller. Density models relied on exploiting an observed relationship between logged density and measured uranium oxide percentage. The residual gravity response of the background geology model identified the location of the uranium deposit. Stochastic inversion of the litho/property 3D model has refined the known distribution of uranium from drilling and provided structural insights into the deposit.These projects have become excellent case studies for exploiting the relationship between mineralisation and potential fields and for testing the applicability of using domain kriging of properties determined from drilling to build robust 3D geological models for stochastic geophysical inversion, leading to robust methods for exploration targeting and mineral deposit prediction.CITATION:Zengerer, M, 2014. Use of geostatistically-constrained potential field inversion and downhole drilling to predict distribution of sulfide and uranium mineralisation, in Proceedings Ninth International Mining Geology Conference 2014 , pp 281–290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Iwu GO, Almond DP, Joasoo _

The gravimetric integral Knudsen effusion method was used to measure cadmium activity values in binary liquid In-Cd alloys in the range 523 to 573 K. The activity measurements together with other studies from the literature indicate that special bonding conditions exist in the melts near a composition corresponding to InCd3. Sound velocities in In-Cd melts were also measured using a precision pulse-echo over- lap method in the range 404 to 953 K. The frac- tional deviation of experimental and ideal isentropic compressibilities at 623K shows a functional dependence on composition with a pronounced maximum near the composition 75 at.%.

Jan 1, 1980

By A. E. M. Warner, I. E. Hills, C. L. Harris

Since the late Dr. Keith Brimacombe, et al, performed tests at the now-closed Asarco Tacoma smelter and the Inco Copper Cliff Smelter on Peirce-Smith copper converters almost thirty years ago, many Pyro-metallurgists have investigated using the technology. To the best of the authors knowledge, except for shrouded tuyere technologies using substantial oxygen enrichments, the core idea of using high pressure air injection has not been implemented anywhere in the world. This paper reviews the fundamentals of this technology and summarizes the basic economic considerations. It also presents the circumstances of where and when high-pressure injection might be justified.

Jan 1, 2007

By J. Githiria, D. Wachira

The conventional truck and shovel haulage system has become expensive to operate in most mines due to current strict environmental conditions, increase in depth and size of open-pit mines, increase in labour costs, and fuel costs. These factors have motivated the search for alternative material haulage options in open-pit mines. In-pit crushing and conveying (IPCC) system has been regarded as a plausible alternative in material haulage systems. However, usage of IPCC has been limited to a few mines due to limited knowledge of IPCC performance, and other technical factors of the system. This paper investigates, and evaluates the productivity performance of four types of IPCC systems (fixed, semi-fixed, semi-mobile, and fully mobile IPCCs) using mine productivity index (MPi). Using a model developed by MATLAB, the MPi for the four systems is computed using input variables such as availability, utilisation, performance and number of trucks and shovels in a limestone quarry. The mine productivity index for fixed, semi-fixed, semi-mobile, and fully mobile IPCC is obtained as 67.13%, 69.02%, 70.52%, and 71.52% respectively. In conclusion, the fully mobile in-pit crushing and conveying system is the most appropriate IPCC in the quarry, due to its better productivity performance compared to the other three IPCC systems and the truck and shovel system currently in use.

Sep 1, 2021