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By Dachun Liu, Xutao Guo, Wenlong Jiang, Baoqiang Xu, Bin Yang, Yong Deng, Heng Xiong

Typical copper dross, the byproduct of lead bullion pyrometallurgical refining for copper removal, mainly contains Pb, Cu, S, As, Sb and Sn etc. In traditional treatment process, copper dross is transformed to be copper matte by smelting with iron scarp and iron pyrite. Here, a new treatment process of converting-vacuum distillation (CVD) was proposed and investigated. Based on this concept, the converting process was tentatively investigated in this paper. The results of element distribution of converting samples showed the sample has three layers. The upper layer is mainly sulfides of lead and copper, the middle layer is mainly copper arsenide, and the lower layer is lead arsenide and crude lead. On the condition of oxygen flow rate 400 ml/min, the converting temperature 1000 °C, the holding time 1 h, the converting time 10 min, the lead copper alloy containing 0.17% S was obtained.

Mar 1, 2018

By Gordon Lovegrove, Jeffrey Leob, Dwayne Tannant

It has long been known that the combination of aluminum (AL) powder to ammonium nitrate (AN) / fuel oil (FO) can greatly enhance fragmentation or ultimately reduce the number of blast holes in a pattern. Decades of research have meticulously provided optimal AL:AN:FO ratios showing dramatic increases in energy output levels, yet widespread use of aluminized ANFO (ALANFO) has yet to replace the use of ANFO in the blasting world today. This may be due to the perception that the upfront, increased cost of materials deters the selection of this advantageously modified explosive. Researchers have explored this question and promote ALANFO by pledge of massive reductions in day-to-day operational costs. However, in these analyses there is a complete disregard for the external costs of the material; the environmental effects and sustainability considerations of the product. A holistic social cost-benefit analysis of ALANFO shows that an admittedly high-cost explosive does indeed provide an output which contains a wealth of operational savings in typical blast patterns. However, the immediate, on-site costs and savings do not define the limitations of this analysis. A complete comparison of the externalities including the environmental and sustainability considerations of the aluminum by-product life-cycle, and the environmental impacts of both the refinement of ammonium nitrate prills and the acquisition of sufficient fuel oil are also assessed. A savings of $216,000 / year through the use of ALANFO in one particular case study was recalculated to an increase in drilling and blasting costs of $188,000 when the external costs of aluminum, ammonium nitrate, and fuel oil are included analysis. The results of this analysis are intended to improve contractors? selection of explosives by providing additional societal and environmental factors into the equation, in preparation for an exponential global shift to greener business operations, while allowing them to remain competitive.

Jan 1, 2011

By R Battison, R Duggan, S Esen, K Henley, P Dare-Bryan

Increased catch bench crest loss has been observed in recent years at Barrick’s Cowal Gold Mine situated in central New South Wales, Australia. A project was initiated to diagnose the cause of the crest loss, and evaluate ways to limit its effect on final walls.A range of different blast measurement techniques were utilised to evaluate the progressive damage caused to catch berms by presplit, production and trim blasts. Techniques employed included; single point vibration measurement, cross-hole seismic analysis, precision berm surveys, horizontal p-wave velocity measurements, crest loss volume calculation and water level changes between blasts.Blast measurements showed that the majority of damage to the catch berm was caused by the presplit blasts, which registered vibrations greater than 700 mm/s at 5 m behind the presplit line. As a result, considerable changes were made to the blast designs after a series of computer simulations via mechanistic blast modelling (MBM). The uncharged presplit collar was increased from 2 m to 4 m, and every second hole was left uncharged. Vibration modelling using a multiple seed wave (MSW) model was used to optimise trim blast delay timing. Burden relief was changed from 16 ms/m to 27 ms/m using one hole firing per 4 ms time window, and the initiation angle was changed from shallow to steep. These changes in the presplit loading and trim timing helped reduce catch bench crest loss by 1–2 m.Trim shots using a high strength bulk emulsion explosive were also identified as contributors to berm damage after analysis of blast monitoring and MBM modelling. The modelling study resulted in the generation of alternative blast designs to minimise the crest loss, including the use of low-density/low-velocity of detonation (VOD) bulk explosive product (Flexigel™ Advantage) in trim pattern designs. This was trialled on the Northern and Eastern pit walls to evaluate the damage to catch berms on final walls. The trials demonstrated that berm vibration was reduced significantly; fragmentation was similar (or slightly blockier) compared to the fragmentation using the old blast designs; displacement of the berm was reduced, so increased catch bench widths were attained. This paper summarises the trials, and presents a summary of the crest loss to date.CITATION:Battison, R, Esen, S, Duggan, R, Henley, K and Dare-Bryan, P, 2015. Reducing crest loss at Barrick Cowal Gold Mine, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 189–202 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Montaser S. EL Salmawy, Takahide Wakamatsu, Eishi Kusaka

"The effect of ethoxylation of long chain alcohols on the quartz and feldspar flotation behaviors was investigated for surfactants of the octylphenol polyoxyethylene family. The tests were carried out with an average of 7.5 (Triton X 114), 9.5 (Triton X 100), 30 (Triton X305), 40 (Triton X 405) and 70 (TritonX 705) oxyethylene units. Electrokinetic and flotation studies on quartz have shown that at low pH values, quartz could be floated with polyoxyethylene octytlphenols. The possible mode of adsorption of these nonionic surfactants may be suggested to be due to hydrogen bonding between the oxygen of ether and hydrogen in the free hydroxyl groups on quartz surface. It was anticipated that the selectivity between quartz and microcline would decrease as oxyethylenic chain length increases.Electrokinetic methods were used to elucidate the mechanism of surfactants adsorption and to correlate these findings with the optimum flotation conditions. The polymeric surfactants would reduce the negative values of zeta potential of quartz while the reverse is true for feldspar. After treatment of microcline with HCl, its electrokinetic behavior in the presence of Tritons X surfactants became similar to that of quartz.The obtained results would suggest that separation of quartz from feldspar using nonionic surfactants of octylphenoletoxylated alcohols having shorter oxyethylenic chain length at low pH could be achieved"

Jan 1, 2003

By G Morgan, C Kemp

In December 2010, a trial of borehole radar technology was conducted to test the usefulness of the technique in better refining the position and geometry of narrow vein orebodies away from the primary data sources of drilling and mapping of development excavations. This paper summarises the reasons why the technique was applied, describes the testing methods selected and summarises the outcomes of the trial.Poor reconciliations of recovered metal from a section of an orebody at Jundee mine site, Western Australia, led to an investigation that identified insufficient understanding of the geometry of a narrow vein orebody as a potential cause. This orebody was situated between mapped development excavations and away from surrounding drill holes. Borehole radar was identified as a possible technique that could supply information on vein location and continuity away from other data sources allowing more accurate orebody modelling and subsequent stope optimisation.A borehole radar instrument (10 - 100 MHz frequency) was inserted into pairs of purpose-drilled boreholes on either side of relatively well-constrained mineralisation and the radar reflection data was collected. This process was repeated in five locations across the mine to represent the most common geological settings, lithologies and orebody varieties encountered at Jundee to determine the suitability of applying the technique in each of these settings. Collected, processed and interpreted radar data was compared to other geology data collected independently for verification and interpretation.Conclusions drawn from the analysis were that the technique could effectively determine the following features of the mineralised veins in the majority of test environments: geometry of veins, magnitude of offsets where structures intersect and orientations of planar structures with short strike length. The technique was very useful in selecting the appropriate structural interpretation where available data could lead to multiple, equally likely, interpretations.CITATION:Kemp, C and Morgan, G, 2012. Using borehole radar to refine orebody interpretations in a narrow vein gold deposit, in Proceedings Narrow Vein Mining 2012 , pp 121-130 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By S. Constantinides

"A major use for many of the rare earths is in permanent magnets. While alternate technologies are in research or already exist, rare earth magnets are unlikely to be supplanted as a major input to clean technologies and high efficiency consumer and industrial devices. We’ll examine where and how the magnet rare earths are utilized and the size of the market. Market growth forecasts based on global markets will be presented. A brief explanation of materials research in the US completes the material.INTRODUCTIONRare earth magnets, first commercialized c.1969, have become essential for a wide range of consumer, industrial and military devices. They are used in the speakers and vibrator motors of cell phones. Rare earth magnets spin the hard discs within the drives and rare earth magnet voice coil motors position the read/write head over the spinning platter. Rare earth magnets are the heart of motors and generators used on airplanes – they are smaller and lighter weight than alternative materials/devices. Now rare earth permanent magnets are being introduced into electric vehicles and wind power generation.Rare earth minerals are difficult to extract from the ores and to separate from one another. The increase in use of rare earth magnets has placed a severe strain on established sources of supply. The establishment of new mines and processing facilities is costly and requires upwards of 15 years to become productive. The combination of rapid rise in use of rare earth minerals coupled with supply shortages has caused rapid price increases and threat of non-delivery of product. The result of this disruptive situation has been a profound response at several levels: corporate, industry-wide and governmental. Let’s learn more about why rare earth magnets are so important to modern society."

Jan 1, 2012

By Luis de Montreul

El conocimiento de los controles mineralógicos, tipos de ocurrencias y otras características mineralógicas de los depósitos auríferos permite plantear una adecuada exploración geológica-minera y seleccionar un óptimo tratamiento metalúrgico. Por ello, se busca establecer la relación entro el oro y determinados minerales metálicos y no metálicos para obtener una mejor recuperación de este elemento valioso. En ese sentido, el presente texto presenta ejemplos de controles mineralógicos en seis yacimientos aurífero de cinco Fajas mineralizadas del Perú.

Jul 1, 1987

By R. S. Dean

This report, the third of a series of annual reports of the Metallurgical Division to be released in this form, covers the fiscal year July 1, 1936, to June 30, 1937. The technological work of the division is performed by sections. Thus, an efficient organization is provided to prosecute the various problems under investigation, and a logical system is set up for presenting the material contained in this report.

Jan 1, 1937

By A Parbhakar-Fox, B G. Lottermoser, N Fox

"Determining the deportment of economic and environmentally significant elements in sulfidic mine materials (eg ore, gangue and waste) requires the use of advanced microanalytical techniques, including electron microprobe analysis (EMPA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Sulfidic boulders were sampled from an acid rock drainage impacted ephemeral stream adjacent to historical copper-silver workings at Baal Gammon, northern Queensland. The abundance and deportment of a range of trace elements and precious metals were analysed in these samples. Whilst many of these elements represent a potential environmental risk if leached from sulfidic rocks into streams in the surficial environment, significantly some of these elements (eg In, Sb and Co) represent specialised metals that are currently considered to be in critical supply.Sulfidic waste rock material at Baal Gammon is dominated by chalcopyrite, arsenopyrite, pyrrhotite and pyrite. Microanalytical investigations revealed that chalcopyrite contains significant quantities of In, Sn, Ag and Zn either substituted directly into the crystal lattice or occurring as discrete sphalerite and stannite inclusions. Arsenopyrite, which may comprise more than 50 per cent of some boulders, is notably enriched in Sb, Co and Ni but also contains inclusions of sphalerite, chalcopyrite and stannite. In contrast, pyrrhotite contains no trace elements of economic significance, but instead represents a likely contributor to acid generation during oxidation in the surficial environment. Trace metals (eg In, Sb, Co, Ni, Zn) are liberated during sulfide oxidation of these boulders in the surficial environment, generating a metal-rich, low-pH leachate.Fe-oxides precipitated as rinds on the surface of these boulders under low pH conditions also contain abundant As, Bi, Sn, Cu and Zn. Abandoned or historical mines represent potential sources of metalliferous drainage that poses potential environmental risks to water and habitats. However, sulfide-rich historical waste rock, stockpiles and processed waste (eg tailings) at abandoned mines may also represent significant sources of critical (eg indium) or other significant metals (eg Sn) that if liberated economically could improve environmental conditions in and around abandoned and historical mines.CITATION:Fox, N, Parbhakar-Fox, A and Lottermoser, B G, 2016. Critical and Deleterious Metal Deportment in Sulfidic Waste Rocks, Baal Gammon, North Queensland, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 173–182 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By K. G. Davis, P. Fryzuk

A study has been made of the effect of undercooling on the grain structure and solute distribution in small ingots of pure bismuth and of a 100 ppm Ag in bismuth alloy. Autoradiographic evidence shows that in undercooled melts a network of dendrites is formed throughout the melt immediately after nu-cleation. At large undercoolings the dendrites are very thin and closely spaced. The origin of the observed grain morphology can be explained on the basis of information about the mode of solidification revealed by the impurity substructure. WHILE a great number of studies of nucleation in undercooled molten metals have been made, comparatively little attention has been given to the mode of solidification from melts with large undercool- ings. Colligan and Bayles1 and Walker2 have measured the rate of advance of the solid-liquid interface in undercooled nickel melts, but the morphology of the solidifying material remained a matter of speculation. Fehling and Scheil3 have described the grain structure in ingots formed from undercooled melts of nickel, palladium, and copper, and a series of Ni-Cu and Ni-Pd alloys. At small undercoolings, equiaxed structures are observed, the grain diameter tending to increase as the temperature of nucleation is lowered. At greater undercoolings, a columnar structure is developed, while with still further undercooling there is a smaller grain size incorporating rather coarse subgrains. All-bright and Colligan4 examined the grain structure shown by ingots solidified from melts of nickel and of Ni-Ag alloy at an undercooling of 105°C, and concluded that considerable grain growth had taken place after solidification. The object of the present work is to correlate the mode of solidification from undercooled melts with both the grain structure and impurity segregation, using tracers to examine the latter.

Jan 1, 1965

By F. Habashi

"A short account will be presented on the extraction of rare earths from monazite sand, bastnasite ore, and phosphate rock of igneous origin. This includes mineral beneficiation, leaching methods, fractional crystallization [of historical interest], ion exchange, solvent extraction, precipitation from solution, and reduction to metals. INTRODUCTIONOriginally, the term rare earths was only used for the oxides, R2O3, which are similar to one other in their chemical and physical properties and are therefore difficult to separate. Within the rare earth group, the elements scandium, yttrium, and lanthanum differ in their atomic structure from the elements cerium to lutetium (the lanthanides, Ln). Scandium occupies a special position with respect to this classification and its other properties, and therefore does not belong to either of these groups. The rare earth elements always occur in nature in association with each other. The isolation of groups of rare earth elements or of individual elements requires costly separation and fractionation processes owing to the great similarity of the chemical and physical properties of their compounds, which explains why the history of their discovery has extended over such a long period.The word “rare”, when used to describe this group of elements, originates from the fact it was thought that these elements could only be isolated from very rare minerals. Considering their abundance in the Earth’s crust, the term rare is now inappropriate. These elements are lithophilic and are therefore concentrated in oxidic compounds such as carbonates, silicates, titano-tantalo-niobates, and phosphates.The abundance of the rare earth elements taken together is quite considerable. Cerium, the most common rare earth, is more abundant than cobalt. Yttrium is more abundant than lead, whereas Lu and Tm are as abundant as Sb, Hg, Bi, and Ag. For all practical purposes promethium does not occur in nature. It forms only in nuclear reactors."

Jan 1, 2012

By M. Rahman, P. C. Kapur

The fixed-time locked-cycle grinding test is employed to simulate the industrial closed grinding circuit on the laboratory scale. A mathematical algorithm for 'cyclewise' computer simulation of the locked-cycle test has been derived and used to study an idealised laboratory-scale model of a closed ball-mill circuit. The agreement between simulated and experimental results is reasonably good, except when the grinding times are relatively long

Dec 1, 1971

By Feng Wang, Guojing Shi, Yangyang Xie, Zizong Zhu, Qiang Wu

The coal chars from northwestern part of China are characterized with high reactivity and low strength after reaction. Four type of coke-making coals selected from northwestern part of China were studied by proximate analysis, ultimate analysis, vitrinite reflectance analysis, and FTIR with curve-fitting analysis to obtain information on their chemical composition and chemical structure. The results show that the studied coals have relatively high values of final contraction of coke residue index (x) and relatively low values of maximum thickness of plastic layer (y) and average vitrinite reflectance. Based on the curve-fitting analysis of FTIR spectra, the aliphatic carbon (Cal), the aromatic carbon (Car), and the molecular structural parameters such as CH2/CH3, fa, Hal/Har, and (R/C)u are determined. The results of curve-fitting analysis indicate that the studied coals are characterized by a large amount of oxygen-containing functional groups and aliphatic side chains.

Mar 1, 2018

By W. P. Haynes

To evaluate the potential use of battery-powered vehicles, the Bureau of Mines studied the performance of a battery-powered truck propelled by a 9.6 kw dc motor in considerable detail under various driving conditions. Some of the factors investigated were: Gear ratios, payload (1,468 lb maximum), road grade, stops made per mile, and charging time. With the exception of some difficulty with brush wear, operation and maintenance of the truck was generally trouble-free. On range tests carrying an 868-lb payload a distance of about 50 miles at an average speed of about 19 mph in normal driving, the Bureau's battery-powered truck averaged 1.6 to 1.9 miles per ac kwhr input. Stop-and-go tests indicated that prospects for the use of battery-powered trucks in house delivery service within city limits are good; performance of the Bureau truck was sufficiently high for that type of service. The estimated power cost of 2.65 cents per mile while making 10 stops per mile was attractively low from the standpoint of fuel costs.

Jan 1, 1967

By John P. Coughlin

The Bureau of fines has tested a portable microseismic processor recorder at the Galena Mine, Wallace, ID, both in an environmentally controlled enclosure and, with minimal protection, in a working area of the mine. In both trials the device demonstrated effective and reliable data acquisition capabilities.

Jan 1, 1985

By Kuo En Chang

Many rare earth - transition metal (RE-TM) compounds absorb/desorb hydrogen reversibly at room temperature and atmospheric pressure. For LaNi5 which is used as a battery material, the electrochemical nature of this process is well known. In the case of Nd-Fe-B which has found wide application as a powerful permanent magnet, the absorption of hydrogen has both significant advantages and disadvantages. However, a fundamental understanding of the hydrogenation process at ambient temperatures and its effect on subsequent corrosion behavior is currently lacking. This paper reports the results of the hydrogenation of NdFeB two alloys, (NdDy)15Fe78.3A10.7B6 and (NdDy)15Fe67Co5V4A12B7, which are compared with that of LaNi5. Results show that hydrogenation can be accomplished by either electrochemical methods or immersion in dilute sulfuric acid. For the latter method, the change in lattice parameter indicates that the level of hydrogen absorbed by the NdFeB particles corresponds fairly closely to an overall composition of Nd2Fe14BH2.7. Cyclic electrochemical charge/discharge experiments show that the maximum hydrogen discharge capacities of the NdFeB, NdFeB-Co-V, and LaNi5 are 40, 60, and 210 mA?h?g-1, respectively. Anodic potentiodynamic polarization measurements and calculated values of icon reveal that absorbed hydrogen in NdFeB-Co-V and the NdFeB may lead to significant increases in corrosion rates.

Jan 1, 1995

By S. A., Taylor

IT is very difficult to arrive at exact figures for the cost of maintaining excess capacity of coal mines, but we can approximate the various items. To do this, I will take the Pittsburgh district of Pennsylvania and the other districts can be compared to this one. I believe we can take the depreciation item of plant ac- count as a whole and discount it over a period of 20 years; while this is high for some items it is low for others and I believe it is not far from a safe basis. This equals 5 per cent per year, and this depreciation will take place about as rapidly when not in use as when in operation. A fair value in the Pittsburgh district to- day for plant and houses is close to $4 per ton per annum. At 5 per cent this will equal 20 cents per ton per year. The item of keeping the mine in condition, free from water, etc., will be close to an average of 2y2 cents per ton per annum.

Jan 1, 1928

By Roy J. Greenfield

The overall purpose of this research was to improve the understanding of how the post disaster seismic location system works, what determines the signal size, what is the character of the seismic noise, how well the system can detect blows from a trapped miner, and how well the source of the blows can be located. Based on an improved understanding of the system, improvements were suggested in the seismic subarray configuration, and in the system deployment procedures. An important part of this research was to become familiar with the seismic system operation and to work with the Westinghouse Electric Corporation and MSHA personnel to modify and improve the system. To accomplish this we participated in the planning, execution, and data analysis for a number of seismic field tests. Several in-mine field tests were conducted. From these tests the capabilities of an in-mine seismic system were analyzed and specifications were made for designing an operational in-mine system. Several portions of the work done on this grant were covered in previous reports. In particular the capabilities or the presently operational surface based seismic location system has been thoroughly documented by Durkin and Greenfield (1981). Portions of the location procedures and effects of mine openings on seismic signals have also previously been published. These portions or the work will only be summarized in this final report.

Jan 1, 1982

By H. L. Lovall

Huge banks of preparation plant refuse and other non¬saleable materials have accumulated over the years in all major United States coal producing areas. These banks, esthetically and commercially undesirable, can cause air and water pollution and land reclamation and mineral conservation problems for the industry and nearby communities Although some refuse banks have been reworked to recover saleable coal, all remain and accumulation continues. Even those previously processed continue as potential hazards. Among the several problems created by refuse banks, in situ combustion is most treacherous. Of the millions of tons of major accumulations, there are at least 450 refuse banks on, fire at this time Attempts to extinguish such fires are costly, impractical and generally unfruitful. Studies are in progress to evaluate the potential of processing such materials to eliminate the combustion capability and to yield usable fuel and nonfuel products. Aspects of the study now in. development for coal refuse include: (a) evaluation of characteristics (size, sink-float, ash, sulfur and calorific value) of the coal refuse materials which are known to be highly variable, (b) development of an ignition test having significance for in situ conditions, (c) study of processing capabilities (comminution for liberation, pilot plant washing tests), and (d) investigation of potentially significant properties of fuel and nonfuel products which could be altered to enhance their market potential.. Among the latter products are lightweight aggregate, fill for mine slushing operations, construction, etc: Plans are to extend the studies to include the design, erection, and test processing of refuse with a transportable plant,; which could provide basic economic and product utilization data from several locations

Jan 1, 1964

By William Martinez

El presente trabajo presenta alternativas indirectas para la exploración de depósitos de pórfidos de cobre (DPC), en los dos arcos magmáticos desarrollados entre Arequipa y Tacna. Estos dos arcos están representados por la Formación Guaneros y los batolitos de Punta Coles e Ilo, con edades Jurásico a Cretáceo inferior, y El Grupo Toquepala con el Batolito de Yarabamba de edad Cretáceo a Paleoceno. El análisis tectónico, aeromagnético y geoquímico de estos dos arcos, evidencia posibles áreas favorables al emplazamiento de cuerpos ígneos que puedan haber originado yacimientos económicos. De forma que se busca reevaluar los conceptos geológicos en tectonomagmatismo para la exploración de pórfidos de cobre, así como el desarrollo de ideas conceptuales a nivel regional de los patrones magmáticos y estructurales especialmente entre Perú y Chile y contribuir la exploración de Porfidos de Cobre desde el punto de vista geoquímico y tectónico.

Sep 14, 2009