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By Djalma Souza, Felipe Perissé Duarte Lopes, Frederico Muylaert Margem, Sergio Neves Monteiro

The development of composite materials is a combination of distinct materials, with applications in various areas, such as: aerospace, automobile, etc. Regardingmechanicalresistance,composites reinforced with a dispersion phase in a fiber form is more relevant. The green idea is use composites with natural fibers instead offiberglass, especially in non-structural applications. The Fique fiber has occupying an important place at Colombian agricultural and agribusiness sectors. Epoxy matrix composites reinforced with 1–6 Fique fabric layers were tested and the results indicated that thetensile properties improve with increasing theamount of Fique fabric layers. The fiber/matrix interaction was analyzed by scanning electron microscopy.

Mar 1, 2018

By Leslie H. Sharp, Martin J. Gavin

"Introduction.Investigations of the oil shales of the State of Colorado were begun February 1, 1920, by the U. S. Bureau of Mines and the State of Colorado, under cooperative agreement entered into by the Bureau and the State, funds for which were provided by the State. The investigations are for the purpose of determining by large-scale Laboratory retorting tests, those conditions which will produce optimum yield of best quality products from Colorado shales. (For an outline of the work and description of the apparatus, see Gavin, Martin J., and Sharp, Leslie H., ""investigations of the Fundamentals of Oil-shale Retorting,"" Reports of Investigations, Bureau of Mines, July, 1920.)In the preliminary work which is usually required when a new material is being dealt with, certain physical and chemical constants of the shales being investigated, and their products, were determined; these data will be of much value not only to the thorough retorting tests now under way at Boulder, but to engineers who will design and construct oil-shale plants. While the figures presented in this report apply only to the shale used in the determinations, strictly speaking, the shale used was selected to represent, as well as possible, an average of the massive type of oil shale encountered in Colorado. The figures, therefore, can probably be applied with little danger of serious error to any massive Colorado oil shale which yields in the neighborhood of a barrel (42 gallons) of oil to the ton.This paper is based on a more complete article now being prepared in which experimental methods are explained in full, and complete experimental data. For the purpose of presenting the data with as delay as possible, it has been decided to anticipate the more complete article with the present report."

Aug 1, 1920

By D. L. Paulson

Electric furnace smelting of blister copper directly from copper precipitates (cement copper) was investigated by the Federal Bureau of Mines. Copper concentrations in five different lots of cement copper in the investigation ranged from 62.5 to 82.5 wt-pct. Laboratory-scale smelting tests were made in a 50-kva electric-arc furnace to establish the reductant and flux requirements. Best recoveries were realized by adding 60 pct of the carbon required to combine with the contained oxygen in the cement copper. Operating parameters established during the laboratory-scale smelting tests were used successfully in smelting 20 tons of cement copper during 12 pilot-scale tests in an 800-kva electric-arc furnace. Over 98 pct of the contained copper was recovered as blister-grade metal. The projected energy consumption for a commercial-size furnace was 380 kwhr per ton of cold charge.

Jan 1, 1978

By Regina Krachler, Herbert Ipser

"The principles of the derivation of statistical-thermodynamic models to interpret the compositional variation of thermodynamic properties in non-stoichiometric intermetallic compounds are discussed. Two types of models are distinguished: the Bragg-Williams type, where the total energy of the crystal is taken as the sum of the interaction energies of all nearest-neighbor pairs of atoms, and the Wagner-Schottky type, where the internal energy, the volume, and the vibrational entropy of the crystal are assumed to be linear functions of the numbers of atoms or vacancies on the different sublattices.A Wagner-Schottky type model is used for the description of two examples with different crystal structures:For B'-FeAl (with B2-structure) defect concentrations and their variation with composition are derived from the results of measurements of the aluminum vapor pressure; the resulting values are compared with results of other independent experimental methods.For Rh3~ (with an NiAs-derivative structure) the defect mechanism responsible for nonstoichiometry is worked out by application of a theoretical model to the results of tellurium vapor pressure measurements. In addition it is shown that the shape of the activity curve indicates a certain sequence of superstructures.In principle, there are no limitations to the application of statistical thermodynamics to experimental thermodynamic data as long as these are available with sufficient accuracy, and as long as it is ensured that the distribution of the point defects is truly random, i.e. that there are no aggregates of defects."

Jan 1, 1996

By C. K. Leith

OTHERS here are far better qualified than I to discuss some of the specific proposals for government regulation of the oil industry. I shall make no attempt to carry oil to Oklahoma. The question of public control, however, is inherent in other branches of the mineral industry in varying degrees, and my comments will be directed mainly toward some of the trends affecting the mineral industry as a whole, as a background for your more specific consideration of oil legislation. A proud American tradition has been the insistence on freedom of competition, on equality of economic opportunity, on a policy of laissez faire. Nowhere has this principle been given wider application than in the mineral industry. The mineral field has been open to all comers, and the job of mineral exploitation has naturally attracted daring and independent spirits. The laws governing conditions of discovery and development, as well as the anti- trust laws, have been devised to foster the spirit of private initiative. The result has been the building of a mineral industry on a scale never before approximated anywhere in the world. The impetus thus gained, the methods, the technique, the financial resources, have been projected be- yond our boundaries and have made the American mineral industry the purveyor to the world for many essential commodities and first in the exploitation of the world's minerals. Our habits of individual self-reliance and success are deeply ingrained, and there is hardly an individual in the entire mineral field who does not instinctively recoil fro111 the extension of collective control, whether public or private.

Jan 1, 1932

By Chaturvedula V. K

Pillar extraction carried out using various methods (split and lift, Wongawilli and Old Ben) involves the formation of narrow fenders (commonly 7 m of coal) formed by driving "splits" for lifting off with a continuous miner. The strata above a split and fender adjacent to the goaf consists of a cantilever beam (usually >3 m thick) that extends from the solid coal and bridges across the fender. Lifting off the fender from the split in safe conditions depends upon the bridging capability of the cantilever and the fender strength. The nature and competence of the immediate and near roof, the support capability of the coal fender and the presence of faults and or joints can adversely affect the bridging behaviour of the cantilever. Insufficient knowledge of these parameters can lead to extraction under dangerous conditions. Remnants of fenders ("stooks") also support the cantilever and their dimensions are critical to obtain regular caving and goaf falls. Stook area, goaf roof span and roof stand-up time after lifting can be related and only a relatively small increase in stook area of 10-15 m2 can lead to a significantly increased stand-up time, especially under a massive roof. Such conditions strongly influence the re- distribution of abutment stresses and can create increased outbye pillar loading. Based on detailed underground geotechnical investigations, it is concluded that strata caveability, roof cantilever behaviour, fender H:W ratio and remnant stook size are all critical parameters for successful and safe pillar extraction.

Jan 1, 1992

By G. O. Hiers

IN 1948 in the United States, 184,300 tons of lead was fabricated as coverings for electric power and communication cables. Such covering generally is called "sheathing" for the principal lengths of the cables, while the short lead encasements of the joints are called "sleeves." For the purpose of this paper, both lead sheathing and lead sleeving can fittingly be called lead tubing. In the United States in the same year, 34,262 tons of lead was consumed in making extruded lead pipes. Such pipe is employed frequently for water or chemical solution conveyance with gage pressures up to 100 psi. Consequently, the walls are thicker in ratio to diameter than is the case with the cable sheaths. For this discussion, lead pipes can be thought of as tubes or tubing. About 19 centuries ago, the Romans produced metallic lead of about 99.9 pct purity. Evidently this was cast in flat sheets of Y8-in. thickness, for instance. Such sheet of 10-ft lengths was bent around a removable core producing a tube somewhat oval in cross-section and with a typical internal diameter of, say, 3 in. This method of production necessitated a seam or longitudinal joint evidently made by casting the seam metal adherently. The seam metal, as analyzed recently, contains about 1 ½ pct Sn. Blow pipes were said to have been employed when the joint was made. Specimens of such pipe were found both in Italy and in the British Isles. It is believed the pipes conveyed water for drinking purposes and for baths. Numerous specimens are still in existence in a good state of preservation, due to lead's usual inertness in air or water. According to Claude E. Pearson,1 there were various stages in the evolution of lead extrusion presses for making tubes: I. First press by Joseph Bramah, 1797. 2-First successful press by Thomas Burr, 1820. 3-First bridge die press, J. and C. Hanson, 1837. In 1845, Wheatston and Crooke made the first lead sheathed electric cable. Flat lead strip was wound spirally around the insulated conductor. Overlapping edges of lead were soldered. Early cables were also made by pulling insulated conductors into 50-ft lengths of lead tube. Borel in France, and Wesselau are credited with devising the first presses for extruding lead sheaths directly on cables in 1879. In the United States, Eaton, in 188o, and Roberston, in 1885, introduced new presses of improved design. Following Cunningham's original idea of making lead traps and. bends in 1873, the presses apparently were improved and made successfully soon thereafter. Between the years 1930 and 1940, two continuous extrusion presses for lead were developed abroad. One apparently was originated by Dunsheath and made by the Henley Telegraph Works Co. The other was developed by the Pirelli-General Cable Co. CURRENT PRODUCTION In addition to the several descriptive chapters on lead extrusion in Pearson's book, the Metals Handbook2 recently described pipe, sheath, and collapsible tube production. The latter is by impact extrusion.

Jan 1, 1951

By Laurence Delisle, Aaron Finger

THE alloys formed by the addition of nickel to iron by convelltional metallurgical procedures show physical properties that differ widely from those of the individual metals. The effect of alloying on the mechanical properties is most pronounced in alloys containing between 15 and 25 per cent nickel. The tensile strength of an alloy containing, for example, 20 per cent nickel and 80 per cent iron (with 0.06 per cent carbon), in an annealed condition, is above 150,000 lb. per sq. in.? owing to a martensitic type of transformation, as compared with about 50,000 lb. per sq. in. for pure iron in the same condition. The object of this work was to determine whether the same beneficial alloying effect could be obtained in alloys of iron and nickel prepared by powder metallurgy technique. PROCEDURE Bars and pellets for tension and compression tests, respectively, were made. Two groups of specimens were prepared: (I) by cold-pressing the powders and sintering; (2) by cold-pressing the powders, sintering, repressing and resintering. Raw Materials Nickel powder supplied by Metals Disintegrating co., marked MD-151, was used. A typical analysis of this powder was as follows: sulphur, 0.040 per cent; copper, 0.18; iron, 0.23; manganese, 0.002; magnesium, 0.001 5 ; lead, 0.035; tin, 0.025 ; silicon, 0.08; chromium, 0.008. Electrolytic iron powder supplied by Plastic Metals Inc. was used. A representative chemical analysis for impurities other than gases, supplied by the vendor, gave the following results: carbon, 0.005 per cent; manganese, 0.002; silicon, 0.003; phosphorus, 0.001; sulphur, 0.004; nickel, 0.008. The fractions from these powders passing a 3 2 5-mesh sieve were reduced in hydrogen at 600°C. for one hour, to clean the surfaces of the particles. The reduced powders, slightly caked, were ground in a mortar and screened again through a 325- mesh sieve. Mixing The proper proportions of the powders were mixed overnight on rolls, in glass jars fitted with iron-wire baffles to break aggregates of particles that might form. Pressing All specimens were compacted on hydraulic presses. The pellets were compacted in a cylindrical die, ½ in. diameter. The ratio of thickness to the diameter of the pellets was maintained as nearly as possible at 0.9, as specifed for standard short compression pieces. The tensile bars were made by compacting 30 grams of powder. Their shape is shown in Fig. I. The compacting pressures for the pellets and the tensile bars were:

Jan 1, 1946

By Lawrence L. Davis

This paper describes current research by the Bureau of Mines to develop technology for improving efficiency and productivity in metal/ nonmetal mines. The research program addresses a wide variety of problems associated with each of the major categories of mining: underground mining, surface mining, in situ mining, and premining investigations. An overview of the Bureau's research activities is given with emphasis on underground mining. In particular, two innovative and promising concepts currently under development are described: a unique shaft sinking system that uses an impact hammer for rock fragmentation, and a low-profile, portable crusher for underground hard-rock applications.

Jan 1, 1979

By J. O. Merritt

The primary objective of this research program was to recommend ranges of minimum luminance for safety in underground metal and nonmetal mining. Visual tasks critical to safety were identified and rank-ordered. Realistic, full-scale, dynamic task simulations encompassing the most important visual components of the critical tasks were installed in a large simulated workspace. Five trained observers performed the six simulated mining tasks under varying levels of luminance. Over 13,000 measurements of visual task performance were used in developing minimum luminance recommendations for the on-foot underground worker and the mobile equipment operator.

Jan 1, 1983

By Jas. G. Ross

Introduction Asbestos, a mineral known and used in ancient times, has become an article of commerce only during the life of the older asbestos miners in Quebec. The diversified uses of this adaptable substance are now numbered by the hundreds. Wherever insulation or resistance to heat may be required, asbestos, either by itself or mixed with some other material, may be employed to advantage. Regarded as a curiosity for centuries, it is now in such common use that it is familiar to all. The demand for long fibre for use in the manufacture of textiles and brake-lining, and for shorter fibre for making shingles, paper, and insulation materials, serves to support the industry of mining asbestos-bearing rock and milling the fibre from it in Canada, South Africa, Russia, Cyprus, and the United States. The commercial use of asbestos dates only from 1876, in which year large deposits were discovered in the Province of Quebec, Canada. Prior to that year a small amount of long fibre amphibole asbestos was produced in Italy. Occurrence In Canada In the Eastern Townships of Quebec, along the line of the Quebec Central railway, is an area of serpentine rock. It extends westerly into Vermont and easterly to Gaspe. A part of it, the section from Danville to East Broughton, contains areas in which occur deposits of commercial asbestos fibre of the chrysotile variety. Pits have been opened on some of these deposits at Danville, Coleraine, Black Lake, Thetford Mines, Robertson, and East Broughton. Thetford is distant 68 miles from Quebec city, East Broughton lies 25 miles to the northeast of Thetford, while Danville is 45 miles to the southwest of Thetford.

Jan 1, 1927

By C. H. Li, R. J. Stokes, T. L. Johnson

The effect of alumina particles on the nucleation and growth of cracks through a silver- chloride matrzx has been investigated. It has been found possible to promote fibrous cracking in dispersion-strengthened silver, chloride under notch-impact conditions at temperatures at which silver chloride alone cleaves brittlely The modification) of fracture beIzavzor is thought to be due to the relaxation of hydrostatrc stress beneath a notch by the nucleation of cavities near alumina particles. In recent years, composite or dispersion-strengthened materials have been studied primarily to understand their high resistance to plastic flow particularly at elevated temperatures. Dislocation models have been developed with which it is possible to deduce with fair success the effects of interparticle distance, particle size, temperature, upon yielding and creep behavior.l-4 Much less attention has been paid to the fracture behavior of these materials (with the notable exception of common structural steels) and little is known experimentally about the manner in which inclusions affect the nucleation and growth of cracks through a matrix. Nevertheless a beginning has been made in connection with fibrous cracking in ductile matrices where inclusions appear to play an essential ro1e.5-7 During the severe localized plastic deformation which accompanies necking in a tensile test, cavities are believed to develop at inclusions; these cavities subsequently grow and coalesce by plastic flow until separation is complete. It is of interest to consider whether inclusions can affect fracture behavior under loading conditions which restrict the plasticity of the matrix itself (for example, cleavage under conditions of a high imposed strain rate at low temperatures). It is particularly interesting to study these effects in a solid which shows a spectrum of behavior ranging from fully ductile to semi-brittle behavior. Such a solid is silver chloride whose mechanical behavior depends sensitively upon temperature and strain rate.'," The present paper is concerned with a study of the influence of inclusions (in the form of alumina particles) on the fracture behavior of silver chloride loaded uniaxially at low strain rates at room temper- ature and also under notch impact conditions over a wide range of temperature. In particular, it will be shown that the alumina particles can exert a startling effect on the ductile-brittle transition temperature of notched silver chloride and that the magnitude and nature of the effect depends upon both the quantity of alumina and the shape of the alumina particles. 1. EXPERIMENTAL PROCEDURE 1.1 Materials Used. Silver chloride powder of analytical reagent (AR) quality having an average particle size 6 was supplied by the Mallinckrodt Chemical Works (st. Louis, MO.). Acid washed 900 mesh alumina powder, designated A38-900, was supplied by the Norton Co. (Cambridge, Mass.). This powder was added to silver chloride in two forms: a) the as-received condition in which the individual particles were of random irregular shape; their statistical average size was 7; b) in a condition in which each particle was spherically shaped by a fusion technique. In this case, the statistical average particle size determined with the optical microscope was approximately the same (about 5p) but electron micrographic evidence indicated that many ultra fine particles were present in the spheroidized powder. 1.2 Preparation of Composite Materials. Silver chloride-alumina composites containing 2.5, 5, and 15 pct by volume of alumina were produced by the extrusion of mechanically mixed powders blended in a ball mill for 24 hr at room temperature. The mixtures were compacted at 50,000 psi at room temperature in the form of billets 3/4 in. in diameter and 1 in. long which were then extruded with a 16:l reduction ratio at 370°C through a radius-type steel die having a 5 deg lead-in angle. An extrusion temperature of 370°C was selected to ensure that all composites had sufficient plasticity to be extruded. Apart from this general requirement, the choice was arbitrary. 1.3 Microstructure of Composites. Attempts were made to check the distribution of alumina metallo-graphically by polishing transverse and longitudinal sections of the extruded rod. Specimens were wet-ground to 600 emery paper and lapped successively with 5 and 0.25-p grades of diamond paste. They were etched for 10 sec in 10 pct sodium thiosulfate solution and lightly polished in concentrated ammonium hydroxide. The most effective way to render the alumina particles and grain boundaries visible was to radiate the surface with intense white light to decorate the grain boundaries and the particle-matrix interfaces photolytically.

Jan 1, 1962

By Alberto Terrones

En un mundo que cada vez se hace más pequeño, los países latinoamericanos deben buscar una alternativa que oriente su desarrollo y estructure sus economías hacia un mercado común. En ese sentido, es necesario conocer la producción minera y metalúrgica de los distintos países de la América Latina, así como examinar algunos de los proyectos mineros y metalúrgicos que se espera desarrollar a corto plazo con el fin de apreciar o valorar sus posibles repercusiones en las economías nacionales o subregionales. Por ello, el presente texto revisa el panorama actual de la industria minera y metalúrgica de América Latina y plantea mejorar la industria a través de establecer contacto directo con todas las instituciones de técpicos mineros y metalurgistas de los países latinoamericanos para intercambio de publicaciones, la estimulación de la organización de reuniones técnicas regionales y el diálogo de los problemas técnicos y económicos que afecten al desarrollo latinoamericano de la industria minero - metalúrgica.

Jul 1, 1967

By Chen-Ming Kuo, Esher Hsu

Energy recovery of livestock waste can not only reduce waste pollution but also generate renewable energy and further create economic bene fits. Currently, most of livestock waste in Taiwan is treated as waste without efficiently recycled. This paper aims to explore and evaluate the energy recovery of livestock waste in Taiwan and further provide policy suggestions. Study results show that small farming scale of livestock industry in Taiwan leads to a lower efficiency of biogas energy recovery. Besides, the environment with relative low price of electricity and high invest cost for power generation plant is hard to provide incentive for implementation of energy recovery which has further caused difficulty on policy promotion for renewable energy recovery of livestock waste in Taiwan. Policy reform with increasing FITs and differentiated purchasing rate for biogas power is suggested to stimulate energy recycling of livestock waste in Taiwan.

Mar 1, 2017

By B. L. Landrum, P. B. Crawford

The rise of a new laboratory model for studying tran-sient fluid flow problems, is described. The theory of he model is based on the analogy between the equa-ions which describe the flow of compressible fluids in porous media and the conduction of heal m solids. The "thermal model" is used to study the Iransient Pressure distributions during fluid displacement in five Standard well patterns. The studies indicate quantita-ively how die pressures change with lane at any poit in the reservoir. It was found that, in general, the equipressure contours are more radial about the wells early in the program than after steady-state conditions are established. In addition two studies of fractured five-spot patterns are presented to illustrate the opplicability of the model for a wide range of reservoir conditions. INTRODUCTION In reviewing the oil recovery techniques involving fluid displacement it was found that a very considerable quantity, if not all of the fluid within the pattern, mav be displaced (during a time-dependent or transient period rather than the usually applied steady-state conditions. Since the oil is displaced during a transient period, it was believed desirable to study the nature of the transients for several of the commonly used fluid displacement patterns. A literature review indicated fairly complete studies of the streamlines and isopotentials for steady-state: yet few data were available on the transient displacement process. Several simulated steady-state multiwell displacement programs were carefully mapped by Foster and Lodge on an electrical conducting sheet as early as 1875, hut the more recent work of Muskat provides the best source for steady-state phenomena having direct petroleum production applications. In order to study the transient phenomena a new lab-oratory model was developed which is based on the similarity of the equations that describe the flow of fluids and the conduction of heal. The equations describing heat flow were developed early in the nineteenth century. Regorous solutions tor most transient problems are in gcneral complex and usually limited to fairly restricted houndary conditions.2 the thermal model may be used to obtain approximate solutions for many transient problems without some of the restrictions required for analytical solution. The application of the analogy between heat conduc-. tion in solids. electrical flow and fluid flow, in a porous media has long been recognised. Techniques originally developed for the solution of heat conduction prol?lems have in many instances proved useful in ohtaining solutions to fluid flow prohlcms. Ir is not surpri5ing then that a heat conduction or thermal model might bf usefull in sludying transient fluid flow. As an example ol the problems suitable for the study with the thermal model, transient pressure distributions during fluid displacement programs are studied for the five-spot, line-drive, staggered line-diibe. seven-spot 211 two fractured patterns. A model was constructed of an iron plate of geometry similar to the reservoir patterns under study. The principle of mirror images as suggested by Bryan was employed in shaping the model. A temperature differential was obtained by soldering two sections of copper tubing to the plate at points analogous to the well location in the field. Hot and cold water was passed through the tubing. The temperature distribution, analogous to the pressure distribution in the field. was obtained a a function of time from thermocouplcs distributed over the plate.

By Lj. Obradovic

The aim of this paper is to study the feasibility of copper and gold recovery from the old flotation tailing dam at Bor, Serbia. Laboratory leaching experiments were carried out using a composite sample taken by drilling from 16 - 40 m depth. Different oxidation agents as FeCl3, Fe2(SO4)3 and H2O2 were used. An H2SO4 solution with a pH less than 3 was used for leaching. The influence of a number of parameters on the recovery of both elements as temperature, pH, duration of leaching and concentration of oxidation agents was also studied.

Jan 1, 2006

By W. R. Ingalls

In reviewing the history of the metallurgy of zinc, I shall pass hastily over what is only of antiquarian interest. That has been excellently treated by Dr. Bernhard Neumann in "Die Metalle" (1904) and has been described briefly in my "Production and Properties of Zinc" (1902), in my "Lead and Zinc in the United States " (1908), and in other metallurgical works of more or less the same date. In this present monograph, I have it in mind to confine myself mainly to technical practice, especially to that of the last 75 years, prior to which period advance was slow and of no great moment. The ancients made brass by the cementation process, i.e., embedding copper in a mixture of calamine and carbon and heating, whereby zinc oxide was reduced and zinc was vaporized and combined with the copper. Zinc was isolated by some of the alchemists, who named it and knew something of its properties, but made no use of it. Long before then, however, zinc was produced in India. Later it was produced in southern China. Possibly the Chinese obtained their knowledge from India. The Chinese in remote places still produce small quantities of zinc. I have seen photographs of their furnaces; or pots, for they hardly deserve the dignity of being called furnaces. I imagine that they are the same that were used centuries ago, for I cannot conceive of anything more primitive. Anyway, it is certain that the idea of a commercial production of zinc in Europe was imported from the Orient, where the metal was known in commerce as Speauter and Spiauter, whence speltrum and finally our term spelter. Tutanego and Tuteneague are other old names. Dr. Isaac Lawson went to China about 1730, expressly to discover the method of its production. What connection there was between Isaac Lawson and John Champion we do not know, but the latter obtained in 1739 a patent for a process of distillation downward and at some time between 1740 and 1743 erected a works at Bristol and actually began the manufacture of spelter. A production of 200 tons per annum is mentioned. In about the year 1766, Rishop Watson visited the Champion works and saw the process in operation, which previously had been

Jan 1, 1937

By Xinghai Lei, Nan Wang, Xiangyang Jin, Yuqi Ren, Yang Li

The upward mining method, as an effective mining method, is widely employed in close-multiple coal seams to extend the service life of coal mines and improve the recovery rate of residual coal resources. However, the upward mining feasibility of the upper coal seam is related to the height of caved zone of interlayer strata after lower coal seam extraction. Therefore, it is extremely important to determine the height of the caved zone after the lower coal seam. The No. 9 coal seam (upper coal seam) and the No. 12- 1 coal seam (lower coal seam) in the Qianjiaying coal mine are selected as the research object. The characteristics of the interlayer strata structure field, fracture field, and subsidence field are studied using UDEC numerical modeling, in which the height of the caved zone is gotten after the No. 12- 1 coal seam extraction. Furthermore, the height of the caved zone is verified by onsite detection of GPR and BTVI. In the numerical modeling, the height of the caved zone is 19.6 m. And the height of caved zone is 14.7 m and 15.4–21.2 m, respectively, by using the onsite detection of GPR and BTVI. The heights of the caved zone onsite detection results are consistent with the numerical modeling result. The No. 9 coal seam is always located above the caved zone after the No. 12- 1 coal seam extraction. Consequently, the upward mining of the No. 9 coal seam is feasible.

Jun 28, 2023

By K. Hanumantha Rao, A. Javadi Nooshabadi

"Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by chalcopyrite (CuFeS2), which is a copper iron sulfide mineral, during grinding, was investigated. It was observed that chalcopyrite generated H2O2 in pulp liquid during wet grinding and also in the solids when placed in water immediately after dry grinding. The generation of H2O2 during either wet or dry grinding was thought to be due to a reaction between chalcopyrite and water where the mineral surface is catalytically active in producing •OH free radicals by breaking down the water molecule. The effect of pH in the grinding medium or in the water in which solids are added immediately after dry grinding showed that the lower the pH value, the higher the H2O2 generation. When chalcopyrite and pyrite are mixed in different proportions, the formation of H2O2 was seen to increase with increasing pyrite fraction in the mixed composition. The results of H2O2 formation in pulp liquid of chalcopyrite and together with pyrite at different experimental conditions have been explained by Eh-pH diagrams of these minerals. This study highlights the necessity of revisiting the electrochemical and/or galvanic interaction mechanisms between the chalcopyrite and pyrite in terms of their flotation behavior.IntroductionHydrogen peroxide causes nonselective oxidation of sulfide minerals if present in pulp liquid. Oxidation of sulfide minerals takes place when they are exposed to atmosphere and during the grinding process when the particle size is reduced for flotation. The oxidation of chalcopyrite leads to iron dissolution from the particle surface and from a metal-deficient, sulfur-rich surface (Fairthorne et al., 1997). Other studies report the formation of iron hydroxide on the surface with the metal ion dislodged on the surface (Buckley and Woods, 1984; Chander, 1991). The chemical reactions for the oxidation of chalcopyrite in alkaline and in acidic solutions with the addition of oxidants, such as oxygen or hydrogen peroxide, are shown in Eqs. (1) and (2), respectively (Shi and Fornasiero, 2010)."

Jan 1, 2015

By Ingvar Ymén, Anders Sandc, Jan Rosenkranzc, Lisa Malma, Ann-Sofi Kindstedt Danielssonb

The understanding of particle surface properties is essential for the study and evaluation of froth flotation phenomena, particularly in the investigation of various chemical or reagent effects. Dynamic Vapor Sorption (DVS) is a method used for the analysis of surface properties of powders for instance in the pharmaceutical industry. To the knowledge of the authors, it has however not been used before in applications related to mineral processing. The DVS technique involves measurement of the water uptake of a relatively small amount of sample as a function of the relative humidity (% RH) in a temperature-controlled environment. The purpose of this work was to evaluate the method and investigate how it can complement existing techniques for surface characterization in mineral processing. Four samples (feed, CuPb concentrate, Cu concentrate and Pb concentrate) from the Cu – Pb flotation process in the Garpenberg concentrator, Sweden, were analyzed by DVS and the traditional capillary absorption technique (Washburn capillary rise). This enabled comparison between the two methods and evaluation of their respective advantages and disadvantages. Both methods give the expected ranking of the hydrophobicity for CuPb concentrate, Cu concentrate and Pb concentrate, but a discrepancy was observed for the feed. Washburn gave a value for the contact angle which was in the same range as for the CuPb concentrate, whereas DVS gave a value for the moisture uptake which was much higher than for the CuPb concentrate. Thus, DVS ranks all samples correctly, but with an unexpectedly high value for the feed whereas Washburn gives good ranking for three samples out of four. Potential reasons for the discrepancies are discussed.

Jan 1, 2018