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By S Natsui, Y Goto, S Kawanishi, J Takahashi, H Nogami

The demand for copper increases yearly, and further improvements in copper smelting efficiency using flash furnaces are required. This study was conducted to understand and promote the interfacial reaction associated with the collision of silica flux and iron oxide particles, ie the formation reaction of fayalite slag, in the reaction shaft of the flash furnace. High-temperature microscopy was used to observe the reaction behaviour of a 2 mm granular SiO2 reagent in contact with micrometreorder- sized FeO reagents in situ. When the amount of FeO was lower than the stoichiometric amount with SiO2, the molten slag formed at the interface between FeO and SiO2 diffused into the SiO2 particle before dissolving the remaining FeO particles. It did not contribute to the subsequent reaction, and despite having the lowest amount of FeO among the samples in this study, many unreacted FeO particles remained on the surface of the samples after testing. On the other hand, under conditions with high FeO content and close to the eutectic composition of the FeO-SiO2 system, a liquid phase formed from low temperatures, gradually increasing in volume and eventually completely dissolving the 2 mm SiO2 grain. These results indicate that the early-stage slag is essential in increasing the interfacial area between FeO and SiO2 and facilitating the supply of FeO to SiO2. In other words, the FeO/SiO2 determines the amount of liquid phase and significantly influences the subsequent interfacial reaction rate between FeO and SiO2. Therefore, the local FeO/SiO2 of the particles falling down the reaction shaft should also be optimised to ensure early slag formation. Meanwhile, the time required for 2 mm SiO2 to complete the reaction for the temperature history employed in this study was significantly longer than the particle residence time in the reaction shaft. Further detailed investigation of the effects of silica flux particle size, composition, and reaction temperature on the reaction time will help find the conditions under which the reaction of silica flux can be completed in the reaction shaft. These kinetic approaches could contribute to future innovations in the copper smelting process using flash furnaces.

Jun 19, 2024

By C. Landolt

Inco's Copper Cliff Smelter Complex produces some 11 5,000 tonnes per year of nickel and 120,000 tonnes per year of copper. The Smelter flowsheet has changed a number of times over the years. The most recent changes were effected in the mid-1980's in response to new realities in metal markets and heightened awareness about the workplace environment. By 1994, the flowsheet will undergo yet another metamorphosis as part of Inco's SO2 Abatement Program. The paper discusses the improvements implemented during the 1980's and projects the processing in the Smelter through 1994.

Jan 1, 1993

The objective of the paper is to develop a material balance calculation procedure for a production unit involving two plants separated by a pipeline. The case study is taken from the oil sands industry. The raw sands are first mixed with water in a conditioning plant, then transported through a pipeline to an oil extraction plant. The combination of pipeline dimensions and nominal throughput creates a significant variable time lag between the two plants. As usual, mass balance calculations required for the evaluation of plant performance indicators, such as bitumen recovery, are inaccurate due to measurement errors. In addition, in the present case study, the time lag of the pipe creates an additional source of uncertainty, which may lead to misinterpretations and wrong decisions. Raw data are usually reconciled through steady-state mass balancing, to correct for measurement errors. However, because of the significant pipeline dynamic lag, standard steady-state daily mass balance may fail at giving an appropriate picture of the operations. The proposed solution to the data reconciliation problem includes the use of a pipeline plug-flow model in the mass balance calculation. To fulfil the industrial constraint that current data reconciliation must not modify past reconciled values, while still satisfying dynamic constraints, a daily one-step method, i.e. a unitary filter-ing horizon, is recommended. The method is illustrated with simulation data, and the results com-pared to those of standard data reconciliation methods.

Jan 1, 2014

By J. Jirestig

Poor grade iron ore, suffering from interlocked particles, is challenging for any process technology. Extensive grinding is required to attain liberation and to yield concentrates of desired grade. Fine particles are commonly very difficult to retrieve, resulting in value losses to tailings. In this paper, results from HGMS tests on fine to ultra fine hematite are reported. Special emphasis is put on slurry flow velocity. If hydrodynamic drag force, i.e. flow velocity is not controlled and kept constant during the feed and/or rinse phase, fine particles will not be captured and retained. Flow velocity control and constant flow during separation are achieved by discharge valves/slots and parallel magnetic flux and pulp flow configuration. In tests, increased slurry velocity from 178 to 268mm/s caused Fe-recovery to drop from 78 to 48%. Proving that flow velocity control is essential to optimise grade and recovery. HGMS tests at the Metso mineral laboratory on natural (weathered) hematite fines clearly show a large potential to recover valuables, currently lost to tailings. Even at particle size distributions as low as D80=35µm concentrate grades and recovery are very satisfying. Two samples, in-plant desliming rejects (D80=35µm and 50µm) where significantly upgraded and recovered, from 45,3% to 63,6% and 53,0% to 63,4% Fe, at 73,8% and 81,1% Fe-recovery respectively. Other types of in plant rejects, such as gravity separation or WHIMS tailings, also benefits from HGMS separation. Gravity separation reject, 55,8% Fe, at D80=500µm was tested, yielding a magnetic concentrate of 60,8% Fe at 50,7% Fe-recovery. The results indicated that the hematite was poorly liberated. HGMS separation was repeated after a regrind to D80 150µm, resulting in a magnetic concentrate of 62,8% Fe at 75,9% Fe-recovery. The tests prove that hematite, presently lost to tailings streams, can be recovered by HGMS and thereby significantly contribute to improved overall economy. Keywords: HGMS, magnetic separation, recovery of ultra-fine hematite, Indian hematite ores, hematite recovery from tailings

Sep 1, 2012

By T. E. W. Nind

"A short description of the chamber lift method for producing oil wells is followed by some comments on compressor requirements and gas utilization. A quantitative analysis of the process is presented and, based on this analysis, criteria are suggested for selecting wells for which this type of lift might be suitable. The analysis leads to the conclusions that chamber lift is an efficient producing mechanism for wells having very low productivity indices (say about 0.05 bbl/d/ p.s.i. or less), but that for such wells optimum utilization of injection gas cannot be attained. It is suggested that the gas injection time per cycle should be kept as low as possible, compatible with a small oil fallback volume, and that the cycle frequency should be in the range of 20-40 cycles/ day. For wells with productivity indices of 0.2 bbl/d/p.s.i. or higher, chamber lift is relatively inefficient; how-ever, if well allowables are low it may offer an attractive, low cost, alternative to gas lift or pumping."

Jan 1, 1960

By R. L. Lincoln

The effects of adding from 1 to 50 atomic percent (a/o) to vanadium were investigated by the Bureau of Mines. Properties studied included as-cast and annealed hardness, microstructure, fabricability at room temperature and elevated temperature, tensile strength, electrical resistivity, and oxidation resistance at 625° and 800° 2. Additions of small amounts of hafnium resulted in lessened as-cast hardness, decreased electrical resistivity, impaired roll- ability, increased oxidation resistance, and greater tensile strength. Larger amount of hafnium caused greater as-cast hardness, increased electrical resistivity, further impaired rollability, continued increase in oxidation resistance, and lessened tensile strength. INTRODUCTION The purpose of this study was to determine the effect of hafnium additions on the properties of vanadium and to learn if this binary alloy had any special or unusual properties. This investigation is a part of a larger research project in which new and expanded uses of vanadium are being sought. Domes tic vanadium is found frequently in combination with uranium, and because of the demand for uranium as a nuclear fuel, there now exists a surplus of vanadium-bearing minerals and vanadium pentoxide as a byproduct of uranium production. Primary principles of conservation demand that greater use be made of this readily available surplus; finding suitable metals to alloy with vanadium to enhance its properties is one way to increase its utilization. This report is the result of an investigation of the effects on the properties of vanadium when hafnium is added in amounts from 1 to 50 a/o.

Jan 1, 1962

By C. M. Anson

Introduction The prosperity of any country today is dependent upon the efficiency and growth of its primary steel industry. The ?march of the United States of America to its present commanding position in world affairs parallels the growth of its steel industry. The remarkable growth of that industry was possible only because bountiful providence endowed that country with adequate supplies of the raw materials necessary for steel making -coal and iron ore. If we accept this hypothesis, and surely we must, then to what extent can we envisage the future of our own country? This symposium deals with the most important of the raw materials required for steel making -iron ore. If we are blessed with a bountiful supply of iron ore, then surely a glorious future awaits only our taking advantage of that blessing. It is becoming increasingly evident that Canada has immense iron ore deposits. It is my privilege to make you acquainted with one of these, one that can only be classified as among the more important ore reserves in the world. I refer to the Wabana ore deposits in Newfoundland. Location These deposits lie under the floor? of Conception bay, off the east coast of Newfoundland. They consist of a series of beds which outcropped for a distance of about three miles on the northeastern shore of Bell Island, dipping at approximately 8° toward the northwest. This three-mile outcrop is the only key to the occurrence.

Jan 1, 1951

By Charles Prasky

The Bureau of Mines investigated the conversion of nonmagnetic iron minerals to magnetic form through reduction Toasting operations. The primary objective was to obtain a concentrate that could be used as a direct shipping material for blast furnace consumption. Crude iron materials from the Steep Rock Lakes, Ontario, area were prepared into a blend of 8 parts siliceous ore, 3 parts pyritic ore, and 1 part tailings. Experimental work included laboratory reduction roasting tests, two continuous 10-day campaigns, and one 12-hour test all in a 34-inch by 36¬-foot rotary kiln. The objective of the project was achieved in producing an iron concentrate containing about 66 percent iron with over 90 percent iron recovery. Desirable operating conditions were developed in the kiln but optimum process variables were not completely established.

Jan 1, 1969

By W. F. Watts

The U.S. Bureau of Mines has conducted research on methods to reduce and to measure diesel particulate matter (DPM) aerosols in underground coal mines. One objective of this report is to present findings from an investigation of the DPM reductions obtained by an engine-mounted integrated control system consisting of a dry system (DS) and a diesel particulate filter (DPF). Another objective is to present results from the usc of a size selective personal sampler to measure DPM concentrations in an underground coal mine. Bureau laboratory tests of the integrated dry system and diesel particulate filter (DS-DPF) have shown that DPM emissions can be reduced up to 97 pet with little change in gaseous emission concentrations. The DS-DPF is undergoing certification tests conducted by the Mine Safety and Health Administration (MSHA). Subsequent to passing all safety requirements, it will be tested in an underground coal mine. A baseline survey of DPM concentrations and aerosol size distributions in a cooperating mine was completed in August 1988. A prototype DPM personal sampler was tested during this survey. Based on results from this test, an improved unit has been developed. This unit is scheduled for extensive field testing by MSHA in 1989.

Jan 1, 1989

By Wojciech Masny, Andrzej Walentek

"The most common extraction method in Polish coal mines utilize pillars between adjacent longwall panels. This is mainly due to the significant depth and difficulties in maintaining stability of the gateroads. This paper presents measurements of entry convergence and range of the fracture zone around a gateroad measured with a borehole camera. The entry where the measurements were taken was located in a parallel entry separated from the gateroad by a 5-m- (16-ft-) wide pillar. The gateroad was located in a hard coal seam 900 m (2,952 ft) deep with a dip of 5°. The extraction method was longwall mining with caving and the mining height was about 3 m (10 ft).Furthermore, the ""in situ"" measurements were compared to the convergence forecast for the gateroad and fracture zone by means of numerical modeling conducted using the Phase2 Version X.X finite element program from Rocscience. The determination of the fractured zone around the openings is of great importance to successful mining practice, especially in support planning and design for longwall gateroads. Moreover, proper determination of the fractured rock zone is one of the basic elements in the process of planning the roof bolting for mine workings.INTRODUCTIONIn the Polish. hard coal mining sector, retreat longwall extraction is most commonly used (Prusek and Masny, 2007). This method is connected with the necessity to carry out a number of development operations during the first stage, including among others, driving of gateroads and a setup room.Currently, most Polish mines eliminate gateroads behind the extraction front, using the ""U"" ventilation system (Szlitzak et al., 2008). In such cases, one of the roads for the next longwall panel is driven along the caving goafs, leaving a protective pillar of some chosen width (Figure 1). The question regarding the width of the coal pillar is especially important to the stability of the gateroads that define the panel for the subsequent longwall. When analyzing the previous experience relating to this type of pillar (Junker, 2006; Rajwa, 2008; Stranzet et al., 1973; Betriebsempfehlung, 1982), one can state that there exist two solutions for the determination of its width."

Jan 1, 2010

By Albert L. Toenges, Theodore R. Jolley

"INTRODUCTION The construction of frame houses (fig. 1) in recent years instead of the conventional sod hut (igloo) (fig. 2) by the Eskimos in the villages along the Arctic Ocean has increased the demand for fuel in these villages. The frame houses, which are not insulated against extreme cold and are difficult to heat, are equipped with Goal stoves. The well-insulated sod huts were heated comfortably with whale-oil stoves. In some years whaling is Door, consequently there is a demand for solid fuel.The Eskimo villages usually are on the sand spits at the mouths of rivers and points of land near the best fishing and hunting grounds. These narrow necks of land usually are sand bars that are not underlain with coal, and coal must be transported to the villages. Lack of development of coal deposits in the Arctic has made it necessary to import coal from the States, generally from 'Washington, to supply these villages. This coal is imported by boat and is received once a year. Its cost is, high, and development of coal deposits in the Arctic to supply these native villages should result in a considerable saving to the Government-operated schools and hospitals as well as to the natives.Early traders attempted to establish coaling stations in the Arctic, and the Eskimos generally know where the coal deposits are situated. A. reconnaissance of a number of deposits in the Arctic was made in the summer of 1946 by engineers of the Coal Division, Fuels and Explosives Branch, Bureau of Mines, and this report describes the areas investigated and suggests plans for the development of some of these deposits."

Dec 1, 1947

By Anja Pfennig, Axel Kranzmann, Sabrina Schulze

The CCS technique involves the compression of emission gasses in deep geological layers. To guarantee the safety of the site, C02-corrosion of the injection pipe steels has to be given special attention when engineering CCS-sites. To get to know the corrosion behaviour samples of the heat treated steel 1.7225 42CrMo4, used for casing, and the stainless injectionpipe steel 1.4034 X46Cr13 were kept at T=60 °C and ambient pressure as well as p=lOO bar for 700 h - 8000 h in a C02-saturated synthetic aquifer environment similar to possible geological on-shore CCS-sites in the northern German Basin. The isothermal corrosion behaviour obtained by mass gain of the steels in the gas phase, the liquid phase and the intermediate phase gives surface corrosion rates around 0.1 to 0.8 mm/year at ambient pressure and much lower about 0.02 to 0.2 mm/year at 100 bar where the C02 is in its supercritical state. Severe pit corrosion with pit heights around 4.5 mm are only located on the 42CrMo4 steel. Main phase of the continuous complicated multi-layered carbonate/oxide structure is siderite F eC03 in both types of steel.

Jan 1, 2013

By W. A. Calhoun, M. M. Fine

"One of the most important wartime activities of the Bureau of Mines was the search for new sources of mineral necessary to the prosecution of the war. Part of that effort was in the form of metallurgical service extended to other government agencies engaged in purchasing and stock piling some of the more critical and strategic materials.Fluorite was one of the materials stock piled by the Metals Reserve Company. The fluorite was usually in the form of coarse metallurgical con¬centrate purchased in the United States and abroad. The material was stock¬piled to insure an adequate reserve of fluorite for the metallurgical industries. The domestic production of metallurgical fluorite containing a minimum effective calcium fluoride content of 55 percent,4/ however, gradually increased until production was at least equal to consumption. The stock-piled metallurgical fluorite, therefore, soon became a surplus commodity.On the other hand, the supply of acid-grade fluorite, containing a minimum of 97.5 percent calcium fluoride and n maximum of 1.5 percent silica,5/ was never entirely adequate. Increased consumption of acid-grade material in the aluminum, petroleum, and chemical industries kept that material on the critical list during the war.Under the circumstances, it was felt that a study of the possibility of producing acid-grade fluorite from the metallurgical stock piles would be of some benefit to the war effort. Consequently, samples of fluorite from several of the Metals Reserve Company stock piles were tested by the Bureau of Mines at the request of the War Production Board.Two groups of samples were submitted for testing. One consisted of metallurgical fluorite purchased from Mexico and stock-piled in the El Paso and Laredo, Texas, stock piles of the Metals Reserve Company. The second group of samples was from the stock piles at Gila, N. Mex.The sample submitted from the El Paso stock pile consisted of about 5,000 pounds of minus 4-inch material. Mineralogically, the sample consisted of fluorite contaminated by calcite, chert, quartz, and small amounts of iron and alumina. Although some of the fluorite was reasonably free from gangue at minus 1-inch, much of it remained locked in sizes as fine as 65-mesh.The Laredo sample was about 5,000 pounds of material from five different piles. The samples from each stock pile, A to E, inclusive, were analyzed separately to determine whether the grade of the material in the piles varied markedly. As there was little difference in the analyses, the samples were combined in proportion to the tonnage represented to make a composite sample for testing. The composite sample consisted of fluorite with small amounts of quartz, calcite, and barite. Most of the fluorite was the dark-colored, opaque variety. A small amount of iron-oxide staining was present, and traces of muscovite, clay, pyrite, and tourmaline were noted. The quartz was present as crystals in vugs, and as finely disseminated grains in the fluorite. The druzy quartz and the calcite were free at minus 10-mesh, but the disseminated grains, some of which were 1 to 15 microns in size, were not entirely free at minus 270-mesh. A petrographic estimate indicated that 65 percent of the silica was locked in the 150- to 200-mesh."

Jun 1, 1946

By James S. Browning

The Bureau of Mines conducted laboratory and small--scale continuous tests of weathered mica pegmatite ores from Hart County, Ga., to determine the technical feasibility of recovering commercial-grade mica concentrates by flotation. Two modifications of the Bureau-developed anionic-cationic method were used. In one method, sodium carbonate and calcium lignin sulfonate were used for pH control and quartz depression; this method yielded mica concentrates containing 98.5 percent mica with a recovery of 91.4 percent. In the other modification, lime and sodium silicate were used with the calcium lignin sulfonate; concentrates containing 98.9 percent mica with a recovery of 86 percent were obtained.

Jan 1, 1966

By Shilpa S. Haramkar, Bhaskar N. Thorat, Sachin V. Jadhav

The filtration of phosphogypsum is a ubiquitous step in the manufacturing of phosphoric acid. It is highly desired to achieve the minimum concentration of P2O5 in the phosphogypsum cake. This work is aimed at addressing P2O5 losses in phosphogypsum (PG) along with the recovery of P2O5 from slurry by using constant pressure filtration at 1 bar pressure. Laboratory tests were carried out in the phosphoric acid production plant situated in Paradeep, India. Recycled water source near acid plant (i.e., pond water) was used for cake washing to reduce the burden on fresh water stock. The findings indicated that pressure filtration offered the most effective P2O5 recovery (nearly 93.48%). The moisture was reduced to 14–16%, and watersoluble P2O5 in the gypsum cake was found to be negligible. A narrow particle size distribution was observed, which offered effective filterability with average cake resistance of 2.38 × 1010 m/kg, indicating a moderately separable cake.

Aug 23, 2023

By Frederick Bradley Henderson

This study was initiated to investigate the occurrence of cinnabar in the oxidation zones of some mercury sulfide deposits. Seven mines or mine districts were visited and samples were taken from both the oxidation and primary zones of these deposits in order to compare their mineralogies and assess Vie chemical changes that took place during oxidation. As a result of the study of these specimens, several limiting factors are suggested for the chemical environments and processes active in both the deposition and oxidation of mercury sulfide deposits. The Mt. Jackson mine, near Guerneville, California (location map, fig. 1), was studied in some detail and forms the basis of this paper. The mine has not heretofore been described in detail in the literature. The Mt. Jackson mine is considered typical of mercury sulfide deposits occurring at the faulted boundaries of serpentinite bodies and enclosing sediments. Such mines are common in the California and Oregon Coast Ranges? Specimens collected by the author from the New Idria and New Almaden districts, the Mt. Diablo, the Culver Bear, and the Buena Vista mines in California, and the Opalite district (Cordero and Bretz, mines) on the Oregon-Nevada border were studied for comparison with the Mt. Jackson samples. The mine description, maps and sketches were composed from field maps kindly provided by Francis Fredericks, consulting geologist to the Sonoma Quick-silver Mine Inc. during the author's visit in 1962. Additional information was obtained from the company maps and minor corrections and interpretations were added by the author.

Jan 1, 1965

By John C. Wilmot, Robert E. Brewer, Royce J. Smith

In March 2003, Phelps Dodge started up an innovative pressure leach facility for processing copper concentrates at the Bagdad mine in Arizona. This paper describes the development of the concentrate leaching plant at Bagdad and the operational results from start up to present. Optimization efforts and an approach to mineralogical modeling of the concentrate to calculate oxygen utilization are also presented.

Jan 1, 2004

By G. L. Oldright

In the previous study that has been made by the authors on smelting in the lead blast furnace,4 the furnace examined was one that operated under conditions that have been considered as more or less normal up to the present time. That is, although the furnace had in its charge a large portion of sinter, it also handled considerable quantities of naturally oxidized direct-smelting ore. Other ingredients, such as the limestone, were also added as fairly coarse material. The charges contained only about 24 per cent of lead. Until the changes incident to modern flotation began to take effect, many lead plants doing semicustom smelting in districts where competition was keen and much of the bonanza ore was exhausted were faced with the difficulty of obtaining enough lead to get a sufficient "lead fall" in the blast furnaces to clean the slag thoroughly and to separate it from the lead. A charge containing 24 per cent of lead would have been considered a very rich one by such smelters.

Jan 1, 1931

By G. L. Oldright

In the previous study that has been made by the authors on smelting in the lead blast furnace, the furnace examined was one that operated under conditions that have been considered as more or less normal up to the present time. That is although the furnace had in its charge a large portion of sinter, it also handled considerable quantities of naturally oxidized direct-smelting ore. Other ingredients, such as the limestone, were also added as fairly coarse material. The charges contained only about 24 per cent of lead. Until the changes incident to modern flotation began to take effect, many lead plants doing semicustom smelting in districts where competition was keen and much of the bonanza ore was exhausted were faced with the difficulty of obtaining enough lead to get a sufficient "lead fall" in the blast furnaces to clean the slag thoroughly and to separate it from the lead. A charge containing 24 per cent of lead would have been considered a very rich one by such smelters.

Jan 1, 1931

By Robert M. Weidenhammer

For years before the war, Coal had the reputation of being a sick industry. Currently it is operating at peak production and succeeding pretty well in keeping out of the red. But, says Mr. Weidenhammer, it will have a relapse as soon as the war ends unless (1) working capital can be built up; (2) it gets the support of the people and Congress; and (3) a truly long-range national fuel policy is formulated.

Jan 1, 1943