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By Roorda H. J, R. R. Saddington, Curlook W

THE copper-nickel sulfide ore deposits of the International Nickel Company of Canada, Limited contain the minerals pyrrhotite, pentlandite, and chalcopyrite. In the extraction of the nickel, copper, and iron, much of the processing involves oxidation of the metals as well as sulfur. Roasting plays a predominant role at several stages in the operations which prepare the constituent metals for refining. Copper, nickel and iron concentrates of various grades, ranging from low-grade nickeliferous pyrrhotite to high-grade nickel sulfide, must be partially or completely oxidized. Figure 1 shows the main points at which roasting is conducted at INCO. Roasting experience at INCO dates back to the time when lump ore was partially roasted in heaps. It has progressed through single hearth roasters, sinter machines, multiple-hearth roasters, flash roasters, and more recently has centered on the development and utilization of fluid bed roasters. The primitive, slow, and inefficient method of heap

Jan 1, 1961

By W. S. Dyer

The lignite deposit at Onakawana on the Abitibi river is of particular interest at the present time, since the Ontario Government has recently decided to proceed with the extension of the Temiskaming and Northern Ontario railway to James bay. Forty-five miles of steel will be laid this year to the crossing of the Moose river. This will cross the lignite field. It has been known for many years that lignite occurred in the Moose River basin, but it was not until drilling was commenced at Blacksmith rapids (or Onakawana, as the camp is now known) in June, 1929, that a seam of economic thickness and extent was found. Early in 1929 the Ontario Legislature voted $25,000 for the carrying out of a drilling programme in the Moose River basin. This came as a culmination of two summers' exploratory work by the Geological Branch of the Ontario Department of Mines, and as the result of a report which said; in effect, that further information concerning the mineral resources of the basin could only be obtained by drilling, and that such a drilling programme was well worth while in order to establish once for all whether lignite, fire-clay, or oil or gas did or did not exist in economic quantities in the region.

Jan 1, 1930

By Fernández H. Carlos

Debido que el subproducto en la etapa de lixiviación de las calcinas de zinc, alcanza un 18% de plomo y 40% de plata en la refinería de Cajamarquilla, es necesario la recuperación de sus elementos valiosos a través de un procedimiento hidrometalúrgico donde se obtengan extracciones en plomo y plata del orden de 85% respectivamente. En este sentido, el texto señala la solubilidad del plomo y la plata en una solución con excesos de iones cloruros y así someter al residuo a una lixiviación ácido clorurante de altas temperaturas y con presencia de un agente oxidante. Una vez obtenida la solución, se divide el plomo y la plata por cementaciones sucesivas con polvo de zinc. Finalmente, se determina la factibilidad del procedimiento para la extracción de los elementos valiosos del residuo y se disminuye los costos de la refinación del zinc.

Nov 8, 1984

By J. E. Pahlman

Spontaneous oxidation and combustion of sulfides and resultant fires are serious problems in underground mines. The Bureau of Mines has con-ducted fundamental thermal gravimetric analysis (TGA) research to deter-mine the mechanisms and factors governing the rate of low-temperature pyrite oxidation, and to identify possible inhibitors to spontaneous oxidation and combustion. The mechanism of low-temperature pyrite oxidation was found to be topochemical, meaning that the oxidation process is controlled by the chemical reaction at the interface between pyrite (FeS2) and iron sulfate (FeS04)' An activation energy of 8.9 kcal/mol FeS2 was obtained for oxidation of minus 500-mesh pyrite in an atmosphere of 60 vol pct water vapor and 40 vol pct . Water-vapor content of the atmosphere was found to be the critical factor in the rate of spontaneous oxidation of pyrite, with a water-vapor content greater than 20 vol pct needed for accelerated oxidation. An atmosphere of pure oxygen resulted in negligible oxidation. The rate of pyrite oxidation is also greatly affected by the particle size of pyrite. Pyrite-oxidation rate increased drastically for particles less than 40 ~m. Room-temperature pyrophoric behavior was observed for freshly ground unoxidized pyrite (55 pct minus 5 ~m) upon exposure to air. Addition of water-adsorbing materials such as activated alumina (Alz03) decreased the rate of pyrite oxidation.

Jan 1, 1986

By Terri Jordan, Gregory Hempen, Thomas Keevin

Water-borne blast pressures from confined blasts were recorded as part of a submerged blasting program in Florida for channel deepening. The blasting was confined within the rock floor by stemming. Shot patterns of stemmed borings were recorded, as were two open-water shots. One hole of one shot was not confined properly, which allowed comparison of confined and a poorly confined larger charge weights per delay. The pressure data were intended to gain information on typical pressure measures from the rock removal program relative to impacts on marine organisms. Water-borne pressures from actual confined, rock-removal shots validate the hypothesis of lessened impacts to aquatic and marine biota.

Jan 1, 2007

By Samuel H. Dolbear

NOT WITHSTANDING the extremely low ebb of business activity, the nonmetallic industries have fared somewhat better than some other branches of mining. The average price level in nonmetallics, although far from satisfactory, has resisted any cataclysmic fall such as has been suffered by copper and other metals. Stocks, also, though too abundant, represent no corresponding overhang of the market, which should result, in some branches, in a more rapid recovery. Research work has continued in some industries with interesting developments.

Jan 1, 1933

By William J. Douglas

Critical path modeling (CPM) has been used widely as a tool to manage large-scale projects having many activities which are conducted in series or parallel. The construction industry is a regular user of critical path modeling as a planning tool. In this context, the method is used to provide an orderly schedule for all activities to forecast delays, slippages, and problem areas and to identify critical activities where resources should be directed. It also identifies others which have slack time, and provides information on the degrees of freedom and flexibility available in completing the project. The purpose of applying critical path modeling to an underground mining system is not primarily for scheduling, but as an analysis tool. In observing underground mining systems, it Is clear that repeated sequences of activities must take place for mining to proceed efficiently. Some of these activities must be sequential, while others be carried out in parallel. The fundamental difference between critical path modeling applied to mining versus a large-scale construction project are: (1) The activities in a mining system are cyclic in nature. (2) The location of the activity varies, and the entire process is not thought of as co-located, as is the case in a construction project. Another important aspect of the network development for mining systems is the degree of detail that is desired. One can be concerned with very macroscopic networks which represent, for example, an entire mine life cycle. Networks representing this problem would be more closely analogous to those of a large construction project. On the other hand, one might be interested in evaluating alternative ways of developing a property or of mining in a given section. More detailed networks representing the section activities are necessary to evaluate system parameters and their impact on long-term production.

Jan 1, 1978

By VIVEK KASHYAP, EVODY TSHIJIK KARUMB, PATRICK TAYLOR

Zinc ferrite is considered an integral phase of zinc residues as their presence can render the processing of zinc and critical metals difficult. It is a refractory phase, formed at high temperature in the presence of zinc (Zn) and iron (Fe) during oxidative roasting in zinc processing plants. Because it is refractory to efficient leaching, unreacted zinc ferrite gets concentrated in the final zinc residue, making it a viable source of zinc and indium extraction. The refractory nature of zinc ferrite makes the extraction of associated critical metals difficult. In order to explore a potential economic and carbon-neutral zinc ferrite processing technique, our previous study proposed the partial reduction of zinc ferrite followed by sulfuric acid leaching of the roasting product [1-3]. As demonstrated in our previous studies, partial reduction of zinc ferrite results in a mixture of ZnO, Fe3O4 and FeO, which can be further subjected to leaching for efficient extraction of zinc and critical metals such as gallium and indium.

Dec 1, 2022

By F K. Altuntov

The study presented in this paper is based on the Kiirunavaara underground mine located in the northern part of Sweden. The deposit is mined using the sublevel caving (SLC) mining method. This paper briefly reviews the alternative SLC layouts, as well as presents challenges for the application. In Kiirunavaara currently, the traditional SLC design is employed, however, continuous improvement of material transportation systems used in mines generates a need for investigation of the current and future production area layouts in sublevel caving mines. When identifying the potential benefits of the alternative production area layouts, the production targets and effects must be further investigated to understand the benefits and potential effects. In this study, several different layouts have been investigated and evaluated. The designs include different development configurations and orepass infrastructure moved further away from the orebody and still require further investigation.

Mar 29, 2023

By Z. Zhang, R. G. Reddy

The viscosities of industrial lead slags with various compositions were measured as a function of temperature. It was found that viscosities of lead slags decreased with increasing temperature, and the plots of ln(11) vs. 104tr followed a linear relation over the reported ranges of temperature. Using the data of this study and available other related data from the literature, a viscosity expression was developed as a function of composition and temperature. The calculated results using this viscosity expression are in good agreement with the measured data. The composition dependency of viscosity of lead slags is discussed.

Jan 1, 2000

By Edward A. McClatchie

A novel nondispersive electro-optical gas analyzer has been designed, fabricated and tested. The instrument is based on a pressure modulated absorption technique. Key features of this new gas analyzer technique include long-term zero and calibration stability. The technique was investigated for the gases carbon dioxide (CO2), carbon monoxide (CO), methane (CH4) and nitrogen dioxide (NO2). The delivered analyzer was capable of measuring the three species CO, CO2 and NO2. It is a compact (300 cu in) package, is battery powered and weighs 15 lbs. Some thirty readings of each gas may be made on a single battery charge.

Jan 1, 1980

By Krishna Parameswaran

This paper discusses sustainability considerations in primary copper smelting using selected examples of practices at ASARCO LLC, an integrated U.S. primary copper producer. Using the classic Brundtland Commission definition of sustainable development, i.e., “development that meets the needs of the present without compromising the ability of future generations to meet their own needs,” the paper discusses how copper mining and smelting practices can be made sustainable. The examples used to illustrate sustainability considerations include: (1) adoption of flash smelting; (2) emission reduction and process improvement associated with anode refining of blister copper and the converter retrofit project, and (3) preliminary research findings on alkali treatment of copper smelting slags and copper mine tailings.

By M. E. D. Raymont

"During the history of the sulphur industry there have been three distinct phases of production. Factors controlling supplies during these periods have shifted from demand for sulphur to demand for energy and a cleaner environment. The pattern of brimstone production is t raced through these phases and includes estimates of future supply; these indicate an involuntary excess production of some 20 million plus tons per year by 1980 unless some large-scale new uses are found. Traditional uses for sulphur, including fertilizer, chemicals, fibers, etc., are generally expanding slowly; how• ever, supply in ""by-product"" form alone will soon outstrip demand. The predicted oversupply situation can be corrected by the development of novel potential markets. Promising areas include construction materials, insulation and plastics, among others."

Jan 1, 1972

By Larry L. Anderson

Enormous quantities of organic wastes are produced each year in the United States. The total amount is in excess of 2 billion tons and at least 880 million tons of this is moisture- and ash-free organic material (dry organic solids), representing a potential energy source of significant magnitude that is not being utilized. Bureau of Mines scientists have developed methods for converting these wastes to convenient energy forms. This report itemizes and evaluates for the first time in detail the quantities and sources of moisture- and ash-free organic material contained in manure, urban refuse, industrial wastes, sewage solids, and agricultural wastes in the United States. Furthermore, estimates are presented for amounts of organic wastes collected or concentrated. The potential for fuel, either oil or gas, from both the total organic wastes generated and those collected or concentrated is also estimated.

Jan 1, 1972

By Nino Catalano, Meeok Kim, Gordon Chen

"The design of the below grade structure of Brigham Building for the Future (BBF) included three different areas to provide power generation and medical facilities as well as a parking garage. The three areas are divided and bounded by 3 foot thick slurry walls. Because each area has different depths and functions, the excavation and construction of the below grade structure presented considerable design challenges. The intricate sequence of excavation and construction between the areas was numerically simulated using a finite element analysis to assess the behavior of the slurry wall and the retained soil. The slurry wall and the related bracing system were modeled as a linear elastic beam and truss element respectively while the soil behavior was simulated using a hardening soil model. The interaction between slurry wall and soil was facilitated by the implementation of an interface element in the numerical model. The design of bracing system to adequately support the slurry walls during the excavation was done based on the envelope of the numerical responses in stage analysis. Predicted lateral displacements of slurry walls were later compared with the field measuring data. The comparison indicated a close agreement.INTRODUCTIONBrigham Building for the Future (BBF) is located in the Brigham and Women’s Longwood medical campus of Boston. The building will serve, once completed, as a biomedical research center and clinical facility to carry out a commitment by Brigham and Women’s Hospital to be the most technologically advanced facility in the country.The 11 story building will also feature a roof garden. The below grade portion of the building has a footprint of 265 feet wide and 210 feet long and is divided into three areas, a 6 stories garage, a cogeneration plant, and an imaging center. BBF was designed and constructed to achieve LEED Gold certification and will have high efficiency and improved sustainability as a medical facility. Ground breaking was in May, 2013. Below grade construction was completed in April, 2014 and the entire building will be finished in late 2016.As shown in Figure 1, the garage area has the largest foot print, 265 feet wide and 125 feet long. The lowest floor of the garage is located about 70 feet below grade. The co-generation plant is about 190 feet wide and 85 long and 50 feet deep. The imagining center is the smallest among three areas. It is 75 feet wide and 85 feet long and 22 feet deep. The areas are separated and bounded by 3 feet thick slurry walls.The perimeter and inner slurry walls were designed to support column loads from the above grade structures, lateral soil pressures and earthquake loads as per the building’s permanent condition and requirement. However the contractor was required to design the temporary bracing and the reinforcement for the slurry walls to resist construction stage loadings."

Jan 1, 2017

By E. C. Perkins, R. S. Lang, D. M. Taylor, H. Dolezal

The amenability of titaniferous slags and domestic mineral concentrates to chlorination was determined in a 6 - inch diameter fluidized bed chlorinator . Ilmenites from Valley County , Idaho ; Aiken , S.C ,; Trail Ridge , Fla .; and MacIntyre , N.Y .; and a titaniferous magnetite from Iron Mountain , Wyo . , were used in preparing the slags . The domestic minerals tested were an ilmenite concentrate from Valley County , Idaho , and a rutile concentrate from Magnet Cove , Ark . A high - grade Australian rutile was used as a standard for comparison . The impurity content of the slags and minerals tested , which was the most critical factor affecting their performance , was dependent on the geographical source of the material . All of the materials tested were amenable to chlorination in a fluidized bed although some required special operating conditions . Titanium extractions and chlorine utilization were over 90 percent for most of the slags and the Australian rutile . The Valley County , Idaho , ilmenite performed well in the reactor despite its 34 percent iron content .

Jan 1, 1963

By Hillary W. St. Clair

The reduction zone of the iron blast furnace is represented by a mathematical model of the chemical reactions and heat transfer that occurs between gas and solids during the deoxidation of iron oxide. The model consists of a set of equations and an algorithm whereby the equations may be solved to give the temperature and composition of gas and solids at any position in the reaction zone and at any time after a specified initial state. The model is applied to the special case in which ferric oxide is reduced by graphitic carbon and carbon monoxide produced by burning carbon in dry air. The rate of reduction, carbon consumption and maximum temperature are shown as functions of the temperature and rate of flow of the incoming reducing gas and external heat loss. The model of the reduction zone is the essential part of a general mathematical model for simulation of the iron blast furnace. The simulation model will serve as a research tool to be used in conjunction with an experimental or operating furnace. After the simulation model has been correlated with the real furnace, it is proposed that further experimentation be done mostly with the model. The real furnace will then be operated primarily to test and confirm the model.

Jan 1, 1967

This paper presents a theoretical investigation on the ionic equilibrium of Fe(III)?Ni(II)?H2SO4?H2O system. A non-ideal speciation model is developed to calculate the concentration distribution of iron and nickel species in a mixed ferric and nickel sulphate aqueous solution over the pH range from 0 to 4 and temperature from 25 to 100°C. A series of speciation diagrams for iron and nickel species is plotted with the effects of ionic strength and temperature on the equilibrium constants being taken into account. The ionic strength-dependent equilibrium constant is treated through a semi-empirical Vasil'eV equation, which is based on an extended Debye?Hückel theory. A Helgeson model is applied to extrapolate the equilibrium constant to elevated temperature. The ionic equilibrium reactions are described by a group of numerical equations containing the temperature and ionic strength-dependent equilibrium constants, which are solved by the Newton-Raphson method. The speciation model is also applied to estimate the hydrogen ion activities and corresponding pH values. The calculated pH values are in agreement with the experimentally measured pH, and are compared to literature data and pH values produced by the Visual MINTEQ® program (a computer code for the calculation of chemical equilibrium in natural aqueous system). This investigation provides a deep insight into the ionic equilibrium behavior of a mixed metal sulphate aqueous system which commonly occurs in hydrometallurgical processing. Keywords: speciation, chemical modelling, thermodynamics, iron, nickel

Sep 1, 2012

Proposed by outstanding electrochemist and electrometallurgist Prof. Raphael Agladze (191 1- 1989), process of copper and manganese co-electrowinning was enhanced to the pre- electrowinning stages: low,temperature co-leaching of copper and manganese containing materials, and to high-temperature co-roasting of the same materials with consecutive leaching. The report presents results of experimental investigations of the processes mentioned above, as well as results of thermodynamic investigations of co-roasting processes, and co- leaching processes computer modeling.

Jan 1, 1997

By T Niitti, J Turunen, P B, A Rinne

In todayÆs marketplace, with high metals prices, many operations are faced with the challenge of improving recovery in the particle size ranges which are normally difficult to recover. This presentation focuses on the various methods used to alter the flow dynamics in a mechanical flotation cell, thereby improving metallurgical results. Modern computational fluid dynamics (CFD) tools have been used in the design phase, with subsequent validation at the plant. Some of the validated variables include mixing profile, power draw and local air hold-up. This presentation underlines how modern CFD analysis can be used to screen and select different approaches before commencing costly trial-and-error experiments at plant scale. Two methods of affecting flow dynamics are discussed û firstly, by altering the geometry of the rotor-stator area and, secondly, by fitting additional features in the tank. The rotor-stator area can be modified to provide more concentrated turbulent kinetic energy or, respectively, to provide more pumping efficiency with less attrition. The tank can be fitted with various additional features, aimed to create different particle suspension profiles. The benefit of both methods is that they can be applied not only to newly installed flotation technology, but also to existing plant cells, thus enabling potential improvement in the mixing profiles, solids suspension, tank sanding and metallurgical performance. Results of several sitesÆ tests are discussed in terms of flow variables measurement as well as metallurgy. This paper demonstrates the effects of different flow dynamics on the mixing profiles and metallurgical results of existing mechanical flotation cells.

Jan 1, 2006