Search Documents

By James R. Hein

Rodriguez Seamount, located 150 km off the central California coast at the base of the continental slope, was studied using the ROV Tiburon aboard MBARI?s R/V Western Flyer, October 13-16, 2003. Fe-Mn crust and rock samples were collected along the SW flank of the seamount at water depths from 700 to 2100 m; bottom-water dissolved oxygen content (O2) and temperature were determined at each sample site. Fifty-three samples of bulk crusts, crust layers, and surface scrapes (~0.5 mm) were analyzed for 59 elements. Data allow for the correlation of crust compositions with precisely known water depths and seawater O2 measured at the actual site of sample collection. This is the first detailed study of Fe-Mn crust compositions in a region of strong continental-margin upwelling. Compared to open-ocean seamount Fe-Mn crusts, Rodriguez crusts have significantly higher (2-6 fold) mean concentrations of Fe (26.9%), Al (1.65%), Si (13.0%), Cr (82 ppm), Th (64 ppm), and Ag (1.7 ppm); and significantly lower (2-8 fold) mean concentrations of Ca, P, Bi, Co, Cu, Ni, Tl, and especially Te (8.2 times lower). All but one Fe/Mn ratio are >1 compared to <1 ratios for open-ocean crusts. O2 contents (0.35-2.03 ml/L) are nearly perfectly corrected with water depth and elements correlated with one are correlated with the other. The Fe-Mn surface scrapes represent 60-450 ka (mean 150 ka) of growth, whereas the dissolved oxygen contents of seawater represent an instant in time. Assuming that the entire sample set was affected uniformly by oceanographic changes, we suggest that correlation of elements with O2 may reflect oceanographic processes. O2 has a negative correlation with P, V, As, Fe, U, Be, Pb, Cr, Mg, Y, Bi, Te, and REEs (except Ce) and a positive correlation with aluminosilicate-hosted elements (Al, K, Rb, Cs). This later relationship is related solely to water depth, indicating that detritus shed down the seamount slopes accumulates in greater abundances in deeper-water crusts. Si/Al ratios indicate that the detritus includes a large component of biosilica produced by upwelling-mediated high productivity. These observations are supported by positive correlations of aluminosilicate-hosted elements with crust growth rates (range 1.2-13.0 mm/Myr). In contrast, other elements (Sr, Co, Mn, Mg, Te, As, Mo, V, W, U, Ti, Ni, REEs, etc.) are negatively correlated with growth rates. Growth rate has a weak positive correlation with O2. These compositional characteristics indicate that even though low-O2 seawater acts as a reservoir for Mn and associated elements and produces slow growth rates, which would allow for the concentration of elements and surface oxidation processes to occur, the high rate of input of detritus and high bioproductivity ameliorate the strong concentration of most metals. This dilution is significantly enhanced by the doubling of FeOOH in the crusts--the main cause of the generally high growth rates compared to open-ocean crusts. The high growth rates limit the oxidation of Co, Tl, and especially Te on the crust surface, which is reflected by their relatively low concentrations. Within the range of oxygen contents measured, O2 has less of an influence on crust chemistry than does the availability and incorporation of FeOOH and detritus.

Jan 1, 2004

By Tom Treleaven, Andrew Williams

The town of Greenwich, CT, an exclusive suburb of New York City awarded several contracts for the installation of sanitary sewer in the North Mianus section of town. The Valley Road section was the most challenging from a rock excavation standpoint. The cut was up to 14 ft (4.25m), with adjacent utilities [20 in. (500mm) water, 6 in. (150mm) water and 8 in. (200mm) gas] located to within 5 ft. (1.5m) of the proposed sewer trench. Rock types varied but were ultra metamorphic in nature, ranging from quartzites, granite gneiss and various types of migmatities.

Jan 1, 2004

By C. J. Badenhorst

The primary focus of management today is safety, or preventing negative, generally irreversible, events of acute duration. The outcomes of safety-related events are usually visible and can evoke strong emotions if the results are severe. Experts now see that occupational illness and disease also result in significant emotional and financial toll to workers, their families and communities, and to their employers. Effective health and safety management must include acknowledging the importance of occupational health hazards and the proportionate application of resources to address those issues. Improvement in workplace conditions and decrease or elimination of illness and disability are due to actions within the workplace and result from the implementation of risk prevention and control measures. However, success may only be visible months or years later and may require interventions that have to be maintained over prolonged periods. This demands continuous, co-ordinated effort to ensure sustainability of diverse occupational health programmes and the relevant management systems. Too often occupational health is not seen as being part of the general management of business, but rather the function of a medical practitioner somewhere off site in a clinic. Integration of occupational health management systems with other management systems within an organization is essential for its success.

Jan 1, 2004

By D. Oyler

The National Institute for Occupational Safety and Health’s(NIOSH) Pittsburgh Research Laboratory (PRL), RAG Pennsylvania and Strata Control Technologies of Australia have collaborated to conduct an extensive study of roof bolt strata interaction at the Emerald mine in Southwestern Pennsylvania. The primary goal of the project was to obtain detailed data on the interaction between the mine roof and the support elements for use in modeling studies. The study site was a longwall tailgate subjected to high horizontal stress. Three arrays of instruments were installed at the site, one in the tail-gate entry and two in an adjacent crosscut. Pumpable concrete cribs were present in the tailgate array, and cable bolts were installed in one of the crosscut arrays. The instruments included mechanical and sonic extensometers for measuring roof movement, instrumented roof bolts, and three-dimensional roof stress cells. The study was ultimately successful in determining the magnitude of the horizontal stress concentration, the height of roof failure and the roof failure sequence, and the loading history of the primary roof supports.

Jan 1, 2004

By Donald Bruce

The three types of specifications which are used for micropile work are: ? Performance Specifications: The contractor is permitted control over certain design and/or construction procedures but must demonstrate to the owner through testing and/or certification that the final product meets the specified performance criteria. This method allows and encourages the contractor to provide a competitive and/or innovative micropile design within the framework of the overall design requirements. The responsibilities for the work are shared between the owner and the contractor. ? Open Specifications: These leave the scope and design of the installation up to the micropile contractor. This method is the most common for securing bids on temporary micropile work. The responsibility for design and performance is clearly placed on the contractor. Open specifications are not recommended for permanent applications. This method allows the contractor to select the most economical micropile system. ? Prescriptive Specification: The Owner describes specific procedures that must be followed, but which may not necessarily describe the objective of the work. When prescriptive specifications are used, the owner is responsible for the proper performance of the system. The contractor is responsible for satisfying the details of the specifications. Performance specifications are the most common and best reflect the challenges and interests of micropile technology and applications.

Jan 1, 2004

By T. Tamura

It is known that the CaO-FetO-P2O5slag system has a wide liquid miscibility gap at steelmaking temperatures and this two-liquid slag phase has many advantages such as high activities of both FetO and CaO and high amount of P2O5. The phosphorus distribution ratio between the two-liquid slag and molten steel was confirmed to be higher than that between CaOsat.-FetO-P2O5slag and molten steel. The two-liquid slag may be useful for dephosphorization of molten steel and reduction of slag volume. Furthermore, the phase equilibrium of two-liquid CaO-FetO-P2O5slagsaturated with MgO was measured to determine the applicability of the two-liquid slag to dephosphorization in steelmaking process. Keywords: slag, refractories, solid solution, two-liquid phase, dephosphorization, steelmaking, phase equilibrium.

Jan 1, 2004

By G. Piegols, J. A. Lombardi

Substantial volumes of cyanide are consumed in precious metals mining due to the purposeful destruction of base metal cyanide complexes and free cyanide to meet surface discharge regulations. This destruction of cyanide resource runs counter to the prevailing social ethic of resource conservation wherein cyanide recovery-and-reuse is considered a more socially responsible cyanide use pattern than systematic cyanide destruction. HW Process Technologies, Inc. (HWPT) has developed membrane based methods for the recovery of cyanide from barren solution as a means to reduce cyanide waste. The HWPT Engineered Membrane Separation (EMS™) system uses state-of-the-art spiral wound membrane elements that are engineered specifically for the treatment of high pH cyanide process solutions. The membranes fully reject WAD CN, SAD CN and most minor metals, and partially reject SCN, Free CN and precious metal cyanide from a high clarity barren solution feed to a small volume EMS™ “concentrate” stream. The EMS™ “concentrate” stream is returned to the process. The large percentage of the EMS™ process feed exits the system as cyanide lean EMS™ “permeate.” The EMS™ permeate, after residual cyanide destruction, polishing, and pH adjustment, is, thereafter, typically suitable for discharge. Separately, the HWPT EMS™-PLS method of cyanide recycling is an internal plant cyanide recovery step that removes base metal cyanides from a pregnant leach solution to a small volume EMSTM concentrate stream. The concentrate stream is then typically processed further for the recovery of metals and recovery-recycling of cyanide. The method makes it economically practical to recover gold from Merrill-Crowe or car-bon plant “fouling” solutions, e.g., those with greater than 400 ppm Cu, as might result from the use of the EMS™ method wherein EMS™ concentrate is constantly thrown back into the mine leach solution pool as part of the free cyanide recycle process, or as might result from the single-pass leach treatment of high copper content ores or concentrates. The EMS™ cyanide recovery method for barren solution treatment is shown to be “economic” for the treatment of clear solutions at the approximately 200 ppm total cyanide level (CNT), and for slurries at the approximately 400 ppm total cyanide level, where economic is defined as a 2 year EMS™ plant payback. The EMS™ plant payback calculation includes the beneficial monetary impacts of gold and free cyanide recycling and the avoided operating cost of cyanide destruction.• The cyanide recovery plant payback period is reduced further when the avoided capital costs for cyanide destruction (EMS™ permeate “clear solution CN destruction polish” only required) and/or metals precipitation are considered.

Jan 1, 2004

By Frank Mucciardi, Hujun Zhao, Pietro Navarra

"A heat pipe is a device having a very high effective thermal conductivity in which two-phase flow and heat transfer takes place. Recent research at McGill University has led to a new type of heat pipe that contains a flow modifier. This improvement has enabled the device to operate at the high heat fluxes encountered in the metallurgical industry.This paper summarizes the progress made to describe the fluid flow in the evaporator section of a McGill heat pipe with the goal of understanding how the flow modifier configuration is linked to the film boiling and dry-out limitations. A separated flow model, an instability analysis, a lift-off model and an energy balance model are used to calculate the theoretical CHF with varying flow modifier configurations and operation conditions. A summary of the current work to relate the flow modifier to the dry-out limitation is also given.Determining how the flow modifier affects both the film boiling and dry-out limitation will give insight into improving the flow modifier design so as to extend the operational range of McGill heat pipes in terms of maximum heat flux and heat load capabilities.IntroductionThe McGill heat pipe is a specialized two-phase heat exchanger developed for several metallurgical applications where temperatures and heat fluxes are typically close to or beyond the maximum safe range of conventional cooling technology.Over the last few years, several breakthroughs have brought this device beyond the proof-of concept stage and a series of industrial trials have been performed with success. These trials include two oxygen injection applications for the ferrous and non-ferrous industry [l], and two light metals permanent-mould casting applications [2,3]. Current projects include a blast furnace copper taphole cooling application [4], a copper smelting application and a thermal analysis probe application."

Jan 1, 2004

By J. S. Stachulak, K. A. Mackinnon

This paper deals with specifying and evaluating fans for mine ventilation projects. Topics such as fan and equipment design life, operating points, and operating conditions are discussed. Common operating problems, such as vibration, parallel operation, mechanical failure, erosion, corrosion, and deficient fan performance are covered. Apart from identifying the potential operating problems, likely causes and suggested remedies are given. Fan type, fan accessories, and likely system effects and fan testing are discussed. Suggestions on what should be covered when evaluating different fan options and proposals and suggestions on the verification of supplier claims and guarantees, including cost of operation, the evaluation of initial capital cost, estimate on maintenance costs, and likely replacement expenditure over the life of the fans. In addition, fan reliability, operational flexibility, suggested construction details and fan vendor past history and experience are reviewed.

Jan 1, 2004

According to the Directive 93/15/EEC, given on 5th of April 1993, all the commercial explosives placed on the market and transfered in European Union and EFTA countries have to be certified and contain the CE-marking. Before the products can be awarded by the CE-marking they have to fulfil the Essential Safety Requirements (ESR) of Appendix 1 of the Directive. From the beginning of last year the commercial explosives could not have been be sold in Europian Union countries without the CE-marking. The legitimacy of the Directive 93/15/EEC encompasses High Explosives, Detonating Cords, Safety Fuses, Gun Propellants and Detonators. At the moment in Europe, there are seven Notified Bodies (NB) working in the field of commercial explosives. They are in Spain (LOM), Germany (BAM), France (INERES), England (HSL), Netherlands (TNO-PML), Sweden (SP) and in Finland (PvTT). The Swedish SP has qualifications only for the detonators and the Finnish PvTT for High explosives, Detonating cords, Safety Fuses and Gun Propellants, but not for the detonators. The role of the NB is to work as a third independent body between the client and the manufacturer testing, studying and certifying explosives by the commission of the manufacturer. The Notified Bodies are operating independently competing the clients, the explosives manufactures.

Jan 1, 2004

By F. Bonnet, J. Lehmann, H. Gaye

A review of thermodynamic information and models of slags, including associated software when available, is presented. The pertinence and accuracy of these models is discussed by comparison of their predictions for various slag thermodynamic properties with the available experimental data. Practical industrial applications will be illustrated by a literature review of the dephosphorization process of ferromanganese alloys and by the description of Ti behavior during silico-manganese alloys production. This latter example will show how the thermodynamic models have been used to propose a flotation treatment at low temperature to enhance TiC removal.

Jan 1, 2004

By G. Forté, R. Girard

The Alcan Bayer Process Experimental Centre (BEC) is an essential development tool for the Bauxite & Alumina researchers at the Alcan Arvida Research and Development Centre in Jonquiere, Quebec. Between the laboratory tests and the industrial prototypes or the industrial applications, the BEC is a key element for technology transfers. The Bayer process is the extraction of aluminium oxide (or alumina) from the bauxite ore. The Bayer Experimental Centre&apos;s history and flowsheet are presented. The major pieces of equipment are described. Safety and design considerations are presented. Finally, examples of applications, double digestion and pressure decantation, are briefly described.

Jan 1, 2004

By R. Guimarães, L. Silva, J. Milboume

The São Bento concentrator was built by Gencor in 1985 to treat refractory gold-bearing flotation concentrate. The plant was the first commercial application of pressure oxidation for refractory gold ore following about a year after the first use of pressure oxidation on a whole ore at Homestake&apos;s McLaughlin operation in California. Ore from the Sao Bento mine is remarkably consistent in gold grade and arsenic and sulphide concentration as is typical in banded iron formations (BIF) (l). Gold content is approximately 9 g/t with approximately 30 - 40% free milling. The balance is associated with arsenopyrite and pyrrhotite. An expansion of both process facility and mine was undertaken between 1996 and 1998, raising the treatment capacity from 32,000 t/mo to 45,000 t/mo.

Jan 1, 2004

By T Leach, I Pringle

The Bowdens Silver Deposit is a low sulfidation epithermal silver-base metal deposit that has formed on the northern margin of a hydrothermal system within air-fall breccias, ignimbrites and crystal tuffs of rhyolitic composition. The deposit lies near the north-eastern margin of the Lachlan Fold Belt and the rhyolitic host rocks are of Early Permian age. The silver mineralisation occurs as flat-lying zones of disseminations and silicic fracture-filling within the Rylstone Volcanics and is closely associated with sulfides of iron, arsenic, lead and zinc. High-grade silver mineralisation is also found in steeply-dipping fracture zones which host banded sulfide veins. Studies of the alteration products indicate that high temperature fluids, flowing from south of the current project area, resulted in quartz (¦adularia) û illite/sericite alteration. Cool, low pH steam-heated waters on the northern and eastern margins of the prospect area resulted in siderite û smectite-illite clay û Fe-carbonate û marcasite û kaolinite alteration. Mixing of the two fluid types resulted in the deposition of iron and base metal sulfides, a decrease in both sulfur activity and pH of the mineralising fluid, and subsequent silver mineralisation.

Jan 1, 2004

Anhydrite-based dam constructions, which have been implemented successfully in other geological formations, were investigated with regard to their suitability in salt mines. The laboratory investigations show that anhydrite-based building materials with suitable additives bind safely in spite of the high temperatures in salt mines which normally pre-vent hydration. The dependence of the compressive strength, swelling behavior, porosity and permeability upon the choice and ratio of binding material components and additives was determined. Based on the results of these investigations, a pilot-scale experiment was carried out at the GSF Research Mine Asse (Germany) using a mixture suitable for the prevailing conditions

Jan 1, 2004

By W. Song, C. Richards, B. Q. Li

"This paper presents a two-phase flow numerical model for spouting gas-particle flow reactors used in chemical vapor deposition processes for manufacturing heart valves and other biomedical implants. The model is developed based on the Eulerian-Eulerian formulation of gas-particle flows, with the k-e engineering model modified with the presence of particles for the description of turbulent gas flows. In parallel with the numerical model development, physical models are set up, where the particle image velocimetry is used for visualizing the particle flows and spout shapes and heights and optical probes are used to measure the particle velocities. The numerical model predictions are compared reasonably well with the experimental measurements.IntroductionVarious biomedical implant components, such as bone joints, dental components and heart valves, are coated with bio-compatible thin films by chemical vapor deposition in particle-laden chemical reactors [l-5]. In these reactors fine particles are used as packing and supporting media. During the coating operation, these packed particles are fluidized by an upward gas jet from the nozzle, reach a certain height and fall back on the top of an annulus region. These recirculating particles are mainly for levitating the implant components (usually one or two in a reactor at one time) so that every portion of them is equally exposed to the gaseous atmosphere. An equal exposure is critical for forming a uniform, mechanically strong and corrosion-resistant coating on implants. Plant experience shows that the quality of the coating is directly related to a stream of operating parameters such as temperature, particle size and loading, and gas flow rates [6]. Optimization of these operating parameters for improved reactor performance depends crucially upon our fundamental understanding of the physics governing the gas-particle flow, heat, and mass transfer phenomena taking place in these reactors."

Jan 1, 2004

By Francis Kendorski

One of the most dangerous events in underground coal mining is unexpectedly encountering water inrushes from undetected abandoned mines in the same seam. The surest and most confident method is probe drilling either from the mine or from the surface. However, drilling is expensive and may even miss the suspected mine voids entirely by drilling through pillars. Many operators rely upon one or more of several remote sensing techniques for detecting mine voids. However, mine "voids" often are not air- or water-filled open cavities, but are collapsed, rubble-filled chimneyed columns in the strata. Geophysical techniques, such as seismic reflection and refraction, electrical resistivity, magnetics, ground-penetrating radar, and others, often assume a continuous or fractured rock mass that has varying properties which provide the signatures that allow discrimination of one strata from another, or of strata from voids. However, a rubble-filled cavity has rock block-to-rock block contact throughout its volume and can still respond as a continuous rock mass with the rock blocks allowing signal transmission or mass detection, rather than a void space. Hydraulically, a rubble-filled cavity is essentially as transmissive to water as an open mine void. Thus, the problem of detecting a mine void with confidence is significantly compounded.

Jan 1, 2004

By R. Schmidt

The computational fluid dynamics (CFD) technique was used to analyze and optimize the design of the dynamic air classifier integral to Raymond® Bowl Mills. Flow patterns and particle behaviors were modeled in the RB Bowl Mill equipped with various classifier designs. These CFD simulations resulted in the development of a hybrid turbine classifier that has now been field-tested, yielding significant improvements to both mill throughput and product size distribution. This paper demonstrates the viability of CFD as a tool for air classifier design and as a technique that can be extrapolated for use with other pulverizer and classifier arrangements.

Jan 1, 2004

By Walter Curlook

An improved process of hydrometallurgical treatment of laterite ores of the limonitic type for the recovery of nickel and cobalt using sulphuric acid has been developed and patented [I]. The major improvement is brought about by recycling a significant portion of the "mother liquor" emanating from the pressure leaching reaction back to the feed preparation stage thereby substituting for all or at least a major proportion of the fresh water that must be added. The amount of process effluent waters is correspondingly reduced. Concomitantly with the major savings in fresh water requirements, a degree of reduction in new sulphuric acid requirements is effected, along with a savings in limestone and lime required for subsequent neutralizations. Keywords: Acid pressure leaching; Nickel laterites

Jan 1, 2004

By Yoshimasa Funakawa, Kazuhiro Seto, Akio Kobayashi

A new hot rolled high strength steel consisting of ferrite matrix and nanometer¬sized precipitates was developed. The ultra fine precipitates were identified as TiMoC2, and the strengthening by the precipitates was evaluated more than 300MPa in case of TS/800MPa grade steel. Due to the strengthening effect of the ultra fine precipitates, alloy elements for solid solution hardening can be reduced. It is notable that the steel shows very high yield strength (730MPa in case of TS/800MPa) and very high local elongation leading to excellent stretch flange formability at the same time. The mechanical properties of the steel are attractive for chassis parts and structural parts of auto body. The steel has been produced commercially, and applied to the parts successfully.

Jan 1, 2004