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The present work is mainly focused on developing intermetallic inert anodes for aluminum electrolysis. The anode alloy based on Al-Ti-Cu system was prepared by casting, followed by the application of a protective coating. Behaviour of corrosion and the passivation under anodic condition was characterized using the electrochemical and microscopic techniques. The results obtained clearly demonstrate that the oxide coating can provide good corrosion resistance via surface passivation of alloy anodes, rendering them inert in cryolite melt.

Jan 1, 2006

By Roberto Parra

The wear and corrosion phenomena in the furnace lining of the ferrous and non ferrous pyrometallurgical processes are complex problems where chemical, interfacial and mechanical phenomena are presents. The characteristics of the processes determine the conditions to which these materials are submitted, where the thermal conditions reached during the operation is one of the most important parameter. Assuming that all the degradation phenomena are thermal activated, the rate of the different steps of the wear mechanism will depend on the thermal field in the lining. In view to apply the independent physicochemical knowledge of degradation mechanisms to the analysis and design of furnace lining the methodology of the Nodal Wear Model (NWM) was done. It combines the mathematical modelling of the heat transfer in the lining with the physicochemical control equation for the wear-corrosion phenomena. The NWM has been applied to different examples: theoretical analysis, laboratory scale test and industrial applications. We present in this paper the theoretical background of the model and two examples of applications: the sole of an electric furnace and the earth of a blast furnace.

Jan 1, 2006

By F. A. Guo

Ultrafine-grained surface layers were obtained by surface mechanical attrition treatment (SMAT) in copper and titanium samples. The thermal properties of the deformed layers were characterized using a scanning thermal microscopy (SThM) that allows thermal conductivity to be mapped down to the submicrometer scale. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a powerful tool for the thermal property and microstructural analysis of ultrafine-grained microstructures.

Jan 1, 2006

By H. C. Verakis

This paper summarizes blasting accident data for over a quarter of a century (1978-2004) for all types of surface and underground mining operations in the United States. Although many billions of pounds of explosives and blasting agent have been used by the mining industry, the accident safety record has improved significantly in the past 25 years. Over the past decade, approximately 5 billion pounds of explosives and blasting agents were used annually in the United States. Coal mining has been and continues to be the dominant user of blasting agents.

Jan 1, 2006

By L Mariani, G. Mendoza-Suarez

In this investigation, TiH2 powders were coated with copper and nickel by electroless plating to delay hydrogen evolution. Copper-coated samples were found to have a mixed acicular (2D growth) and cauliflower (3D growth) morphology whereas the nickel-coated samples had a cauliflower morphology. Examinations of the coated powder cross-sections revealed that the coating thickness ranges from 0.2 µm to 4 µm. Uncoated areas on the powder surface and coating flakes unattached to TiH2 particles suggest poor adhesion between the coating and the substrate. The phase transformation undergone by the TiH2 during dehydrogenation was studied in samples taken at intermediary points in the heating cycles and examined by XRD. The findings reveal that as the powder is heated from room temperature to 800°C, it changes from TiH1.971 to Tiu and to aTi. Differential Thermal Analysis (DTA) was performed to study the effects of the coatings on the temperature of hydrogen release. It was found that increasing the number of plating iterations, and therefore the thickness of the coating, creates a significant shift in the temperature of gas release.

Jan 1, 2006

By Shinroku Matsuzaki

Data the measurement sensor installed with spatial distribution on the blast furnace were successively accumulated online from the process computer to the database system over a long period. This is a new system that accurately considers the relation with the installation position of each sensor, and picture computerization of the measurement data was developed. The overall operation state of a blast furnace, which skilled operators can see in their mind?s eye, was objectively visualized as pictorial information.

Jan 1, 2006

Iron removal using biologically produced organic acids was investigated as a treatment option for the production of refractory grade bauxite. A leaching solution containing 98mM oxalic and 67mM citric acid was prepared from a sucrose medium using for fermentation the fungus Aspergillus niger. The leaching capacity of the metabolic product was tested on a bauxite sample containing 16-19% iron (as Fe2O3). Aerobic and anaerobic leaching tests were carried out at pH 3, 50°C and in the absence of light. Results indicated that more than 80% of total Fe can be removed from the ore, when the sample is finely ground and applying a two stage treatment. The presence of oxygen was seen to affect adversely the kinetics of the process, suggesting that leaching follows a reductive mechanism. Experiments that were carried out with different particle size fractions indicated that for obtaining efficient removal of iron particles should be finer than 0.63mm. Reduction of the operating temperature from 50 to 30°C caused a decrease in the rate of iron removal by more than 10 times.

Jan 1, 2006

By H. Kurokawa

Sumitomo Metal Mining decided to expand copper production capacity of Toyo Smelter and Refinery to cope with the recent copper demand growth in Asia, and to survive by reducing cost. The expansion plan is promoted to increase electrorefined copper production capacity from 270,000 metric tons in 2001 to 450,000 metric tons in 2007. The major changes in smelting section are introduction of the rotary steam dryer, renewal of the feeding system for flash furnace, improvement of the concentrate burner, modification of the flash furnace cooling materials, renewal of the slag cleaning furnace, modification of the flash furnace waste heat boiler, installment of a new converter furnace, enlargement of two anode furnaces. In addition, the gas cleaning system was upgraded and the second acid plant was installed. In the refinery section, the existing tank houses have been operated at high current density of 300A/m2 using the conventional starting sheet cathode technology and moreover a new tank house utilizing the permanent cathode technology was constructed. Although the copper production capacity has been increased, SO2 emission has been kept the lowest in the world through consideration of influence on the environment by expansion project.

Jan 1, 2006

By Ryosuke O. Suzuki

A combined process of electrolysis of CaO in the molten CaCl2 and of calciothermic reduction, so-called OS process, was applied to prepare metallic vanadium directly from V2O3. The fine metallic powder containing 1860 mass ppm oxygen was obtained using 0.5mol%CaO-CaCl2 melt for 10.8 ks at 1173 K. The oxygen level did not decrease further even when twice electricity was applied. Because the metallic vanadium could be electrochemically deoxidized to the level of 10 ppm oxygen from 1.48 %, the large amount of by-product, CaO, due to reduction and the large surface area of the fine particles are the reasons of high oxygen content in the reduced powder.

Jan 1, 2006

By David Kennedy, Noel Hsu, Miguel Araos

The use of bulk explosive for mining applications started in the 50’s. Since then millions of tons of that material have been transported by road. However during that time, there have been several road incidents involving them. This type of incident has forced the explosives manufacturers as well as regulatory organizations to look for a better classification of explosives in order to regulate the industry as well as to mitigate community concerns over the classification of mixtures of substances that are regarded as precursors to explosives.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

The object of this paper is to show in some detail the mining challenges that have been presented and overcome during the successful development of the main exhaust ventilation drive that will service the Ballarat East mine during its 20+ year lifespan. Topics to be discussed in this paper include the ground support regimes employed, the ground conditions encountered during construction, how the heading was recovered after falls of ground and the effectiveness of geotechnical probe drilling at Ballarat.

Jan 1, 2006

By Tom Goforth, Rongmao Zhou

The interest of seismologists in mining explosions has increased substantially with the construction of the International Monitoring System (IMS). The IMS supports the Comprehensive Nuclear Test-Ban Treaty by providing global data coverage from seismic, hydro acoustic, infrasonic, and radionuclide sensors that will detect a host of natural and man-made events at regional (<2000 km) distances. Ideally, the recorded data can be used to identify those events that have explosive characteristics and therefore might be clandestine nuclear tests. The regional observations assure the detection of mining explosions, and these must be properly identified to avoid false alarms of the monitoring system. Cooperation with the mining industry, including documentation of the firing programs, provides critical information necessary to characterize the seismograms.

Jan 1, 2006

By Vince Luongo

"INTRODUCTIONThe West Side Combined Sewer Overflow (CSO) Tunnel Project is located in Portland, Oregon and is part of the Willamette River CSO Control Project. The purpose of the West Side CSO Project is to reduce the frequency and volume of combined sewage overflows from the drainage areas on the west side of the Willamette River using the West Side CSO tunnel as a combined storage and conveyance facility. The sewage is then directed to the Pump Station on Swan Island, which is located on the east side of the Willamette River. From here the combined sewage is pumped through force mains that discharge into the existing Peninsular and Portsmouth tunnels.The West Side CSO tunnel has an inside diameter of 14-feet (4.27m) and is approximately 18,150-feet (5,532m) long. The tunnel slopes at a constant down gradient of 0.0018 from south to north over the entire length of its alignment.The tunnel passes beneath six existing bridges; Hawthorne Bridge, Morrison Bridge, Burnside Bridge, Steel Bridge, Broadway Bridge and Fremont Bridge. The general tunnel alignment follows beneath the Naito Parkway starting at Clay Street Shaft and connecting three other shafts on the west side of the Willamette River, Ankeny Shaft, Upshur Shaft and Nicolai Shaft. It then passes below the Willamette River and on to Swan Island to connect with the Confluent Shaft, which will combine flows from the West Side CSO and East Side CSO (not part of this contract) and then continues to the Pump Station Shaft.The Nicolai Shaft is the primary mining shaft from which two TBM’s were launched to construct the West Side CSO tunnel. The first TBM started mining south and terminated at the Clay Street Shaft. The second TBM started mining north below the Willamette River and terminated at the Swan Island Pump Station Shaft."

Jan 1, 2006

By Philip Dubbeling

Conventional dynamic sheetpiling techniques are ill-suited to urban development because of the emission of excessive noise and ground vibrations. Drilled shafts and slurry walls alleviate some of these environmental concerns but add additional problems due to large bulky machines, reliance on dusty concrete plants and urban trucking grief. To solve these problems, pre-fabricated sheetpiles are hydraulically jacked-in by reaction principle using a compact and lightweight press-in machine, a so called the "Silent Piler". Through scientific analysis, definition and systemization of press-in machines and methods, new construction concepts such as the one-step approach, implant structures, functional design and life cycle design have been developed to comply with new basic construction principles.

Jan 1, 2006

By N Hungerford, A Coote, S Doyle, D Henderson, F Della-Pasqua

A systematic, detailed airborne geophysical programme carried out in the Taupo Volcanic Region (TVR) in 2005 by Glass Earth NZ Ltd culminated in the identification of 21 epithermal gold targets. In this paper we present the follow up ground-truthing results from the first target drilled, Tahunaatara (TAH). &nbsp; The Tahunaatara target was identified by means of a multi-disciplinary integrated approach (ôdata interventionö) that defined and ranked the target as being highly prospective for epithermal gold mineralisation. A follow-up ground resistivity survey over the target area revealed the presence of a ôresistorö buried beneath an extensive cover of recent volcaniclastic material. Geochemical soil sampling carried out in conjunction with the resistivity survey yielded anomalous gold values. &nbsp; The host unit at TAH consists primarily of flow banded rhyolitic lavas, volcaniclastic deposits and tuffs of the Ohakuri Ignimbrite with small outcrops of silicified bedded breccias forming local topographic highs. Results from the first orientation drill hole show wide zones of intense silicification, clay alteration and mineralisation. Sulphide mineralisation is disseminated throughout the core in association with hydrothermal replacement and also occurs in association with quartz veins and infill in fractures (sulphide-only veinlets as opposed to quartz + sulphide veinlets). Textural evidence from drill core indicates that hydrothermal fluid flow was multi-staged with potential for multi-stage gold, and other elements. The presence of polymictic hydrothermal eruptive breccias indicates a hydrothermal vent system. &nbsp; Alteration varies from argillic to silicic, with pervasive adularia and vuggy silicification also present. Chlorite is minor and associated with quartz, illitic clay and adularia. Assay results currently available confirm the presence of anomalous gold values in association with zones of vuggy silica deposition and intense silicification.

Jan 1, 2006

By Michel Grenier, David A. Young, Brent Rubeli, Mahe Gangal

This work forms part of a study being conducted into the feasibility of constructing a prototype Load Haul Dump (LHD) vehicle for operation in underground Canadian mines. A series of in-laboratory assessments were performed to determine the relative contributions of a Deutz F4L912W (54 HP- conventional vehicle engine) and a Deutz F2L 2011 (31 HP hybrid vehicle engine) to diesel emissions concentration during mine transient duty cycles and steady-state operating modes respectively. Results indicate significant reductions in the quantity of gaseous and particulate emissions with the application of the hybrid system and a high-efficiency ceramic element filter. This paper describes the engine test protocols and the results of this laboratory study.

Jan 1, 2006

The desire for minimising impacts of mining activities on the environment, and in particular, water resources; is usually tempered by the costs and practicalities of implementing æbest practiceÆ measures. This paper briefly discusses the theoretical and practical options for water management for typical mines and quarries in a range of environments to assess if adverse impacts can be completely eliminated or at least be perceived as doing so. The regulatory requirements for water resources management are usually an essential part of mine planning and operations that can be a primary focus for all stakeholders. As such they can distract attention from implementing best practice in water management for the benefit of the environment and the community for altruistic reasons that have a long-term benefit for the mining industry as a whole. Cost-effective options for supply, demand and quality management of water that comply with basic regulatory requirements are readily available. Making a mine æinvisibleÆ in a practical sense, in terms of impacts on water resources would require eliminating potentially contaminated discharges, minimising demand, maximising reuse and recycling and putting back a healthy proportion of the clean water that is taken out of the natural environment for use in mine operations. This may sound simple enough and there are many well-known standard approaches that are usually applied. But which are the most effective, and who benefits? New approaches to water management are becoming more affordable and can benefit the bottom line as well as the environment, but can they make a mine ædisappearÆ? The perception of whether a mine is æinvisibleÆ in terms of its impacts on water resources is as important as the actions taken to try to achieve such an objective. The viewpoints and thresholds of perceptions of the different stakeholders are therefore relevant to how ævisibleÆ mining activities become.

Jan 1, 2006

By P Atkinson, M P. Simpson, J R. Kyle

BM37 is a bonanza-grade (&gt;30 ppm Au) ore shoot of the Maria Lode of the Karangahake adularia-sericite epithermal deposit in the southern Hauraki Goldfield. Samples from BM37 contain up to weight percent gold. The ore shoot is a vein that pinches and swells, but is typically tens of cm thick, and locally exceeds 0.5 m in true width. Gold occurs as irregular anhedral electrum grains that range up to 300 microns across and contain 38 to 59 wt&nbsp;per cent&nbsp;Au (ave. 52 wt per cent&nbsp;Au). Electrum occurs in sulphide-rich bands in association with pyrite, chalcopyrite, acanthite, galena, sphalerite, and local covellite. Lower grade samples contain local to rare mckinstryite [(Ag, Cu) 2S] and polybasite [(Ag, Cu) 16 (As, Sb) 2S11]. Pyrite from BM37 is nearly stoichiometric; it lacks the As that commonly occurs at up to percent levels in pyrite from other veins in the goldfield. Acanthite also contains low quantities of trace metals, and typically has less than 2.5 per cent&nbsp;Se. The vein shows complex textures. Bonanza grade sulphide-rich ginguro bands form discrete layers adjacent to the vein margins, and occur as breccia fragments encased by later massive to comb quartz with local quartz after platy calcite. Both the breccia fragments and ginguro bands are cross-cut by later quartz veins. Textures thus indicate that formation of the high-grade portions of BM37 resulted from one or more discrete events that differed markedly from the events that formed the bulk of the vein.

Jan 1, 2006

By G. Barrasso

REACH was proposed by the EU Commission in October 2003 and stands for the Registration Evaluation, Authorisation and Restriction of Chemicals. It requires that all substances identified as persistent, bio-accumulative and toxic, whether the risk of those chemicals being released is real or perceived, require registration prior to them being allowed to be imported into the European Union. An internal investigation by the metals industry indicates that almost all primary raw materials streams would be classified as hazardous due to the potential health or environmental hazard properties of one or more of their ingredients. REACH uses a wide definition for chemicals and metals and as such its implications greatly impact the entire supply chain of the metals industry. The process of registration would require the producer/ importer to produce a dossier. Initiatives along the same lines as the EU REACH are also coming up in other parts of the world. REACH requires registration of at least four substances manufactured by the aluminium industry: aluminium metal, including powder, aluminium oxide, and aluminium hydroxide. The proposed legislation permits the affected companies to band together to form a consortium to develop certain aspects of the registration application. The aluminium industry has established a consortium and testing is currently underway.

Jan 1, 2006