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By J D. Grobler

In the heavy minerals industry wet high intensity magnetic separators (WHIMS) are widely applied for primary magnetic separation of magnetic minerals and non-magnetic minerals. This piece of equipment is well known for its robustness to handle a wide range of feed conditions and still produce stable product qualities and yields. A heavy mineral production plant aimed to increase production through their WHIMS plant containing 11 duties and 26 units. Instead of adding new units an alternative approach was followed to firstly maximise the efficiency of the current circuit and secondly to consider possible reconfiguration of the circuit to produce additional product tons for minimal capital investment. In order to characterise the current circuit’s efficiency, identify pockets of excellence and determine the areas for improvement the whole circuit was surveyed several times and mineral mass balances were drawn up.This paper aims to: discuss the modelling process of the WHIMS circuit,explain the calibration and validation process followed to ensure the accuracy, anddemonstrate the sensitivity analysis performed on the different options. From this analysis an efficiency criteria was developed to compare different circuit configurations that enabled the production plant personnel to make an informed decision on the way forward.

Oct 5, 2011

By J Ledgerwood

Namakwa Sands is a mineral processing company based on the West Coast of South Africa and is solely owned by Exxaro Resources Limited. Mineral ore is mined and processed, concentrated and both chemical and mechanically upgraded before being sent for electrostatic and magnetic separation units. The final high value mineral products report as Zircon, Rutile and Ilmenite.The recovery of non-magnetic material is largely dependent upon a number of factors, including but not limited to dew point, ambient temperature, feed rate, mineral size distribution, specific gravity and mineral content in head feed. One important limiting factor to recovery in typical dry mill operations is the particle size distribution of the feed. Variance in the particle size has catastrophic consequences for recovery. This is the reason for this study. Until recently large variances in non-magnetic production were viewed to be a function of machine operation. This view was later rejected with the feed size distribution determined as the major driver of low recoveries, for Namakwa Sands orebody 50 per cent variance in particle size distribution can be noticed within one day. This is because of the successive mining blending techniques employed.The predicament is that the two modes were so closely placed together that recovery of a single mode is almost impossible without the consequence of greatly reducing recovery. The second mode was found at 125 µm while the first was at 90 µm. Interestingly, for the mentioned feed type a cumulative size distribution of a unimodal feed type is almost exactly the same as for a bimodal size distribution. Thus a plot of cumulative size distribution will show no difference due to the modes being so close together. This is the reason why this phenomenon was not noticed before.The study also found that, using an high tension roll (HTR) or rare earth roll, a fine stream with a single mode at 90 µm versus a coarse stream with a single mode at 150 µm would yield completely different results interms of yields. Larger conductive particles are thrown from the roll while small particles loose charge faster (entrainment). Results in terms of the bimodal size distribution show that even though 25 per cent of the feed type is greater than 150 µm the yields followed a similar pattern to that of the coarse particles rather than that of the majority (75 per cent) fine particles. This confirms what was published by M Ziemski and P N Holtham in 2005 on charge decay rates; they mentioned that particle bed effects played a major role in recovery.

Oct 5, 2011

By D McCoy

Titanium feedstocks are the building blocks of the titanium value chain. They can be mined directly, as is the case for ilmenite, leucoxene and rutile, or manufactured from ilmenite by extracting various quantities of non-TiO2 components from the ore by chemical and/or thermal processes.While feedstocks can be grouped into categories of materials with similar characteristics, they are essentially unique products from very different mining locations around the world. In fact, no two feedstocks are exactly the same. As such, the variations between the available feedstocks, in combination with the permutations in processing technologies to turn the feedstocks into titanium pigment or metal, mean that choices between feedstocks are specific to the location in which they are utilised.In this paper, the authors examine the key requirements of titanium feedstocks to the TiO2 pigment and metal sectors. Apart from the well known differences between feedstock choices for the sulfate and chloride process, the more opaque considerations in feedstock sourcing are examined.

Oct 5, 2011

By A Sadough Vanini

In this paper large deformation of smart functionally graded beams with initial imperfection and under thermal loadings is considered. Smart beam consist of two types of layers. One layer is made from functionally graded materials and a layer or a set of layers from active materials that usually is made from piezoelectric materials that are bounded on the surfaces of beam. An active controller is used for controlling the deformation and stress in functionally graded layer of beam. A simple Euler- Bernoulli beam theory is used for analyzing of beam. In functionally graded layer the material property vary continuously through the thickness direction and power law model is used for the variation of elastic modulus, heat expansion and heat conduction coefficients. Poisson ratio is assumed to be constant in functionally graded layer. The effects of varying the power law constants and the Gain of controller is considered here. The results are reduced and compared with smart functionally graded beam without initial imperfections.

Oct 1, 2011

By Wencheng Gao

An attractive way to beneficiate magnesium chloride and aluminum chloride is to prepare Mg-Al spinel, an excellent refractory material. Mg4Al2(OH)14?3H2O, the precursor of spinel, can be prepared using a co-precipitate method from aqueous MgCl2-AlCl3 solutions. The co-precipitation process of magnesium-aluminum from acidified chloride solutions by using NaOH or NH4OH as base neutralization agent was studied. Co-precipitation was conducted from different mixed solutions ? at initial CAl=0.0625M and Mg/Al molar ratio from 0.5 to 10, the temperature range from 30 to 90 °C. The effect of other parameters, including base type, method of base addition, base addition rate, aging time, background electrolyte and concentration were also investigated. The co-precipitation process was monitored by potentionmetric(pH) measurements. The experimental pH curves were characterized by two platforms separated by a steep jump in pH at Mg/Al molar ratio 0.5~6. The first platform was centered at about a pH of 3.8 and the pH of second platform was varied with different conditions. When the Mg/Al molar ratio was up to 6~10, the first platform in pH was almost disappeared. Furthermore, the shapes of pH curves were also affected by base type, base addition rate and method of base addition. Experimental results showed that the first platform in pH was connected with Al precipitation, and the second platform was involved with Mg. The final co-precipitates were characterized by XRD, TGA-DTA, particle size analysis, SEM and TEM. We found both Mg/Al molar ratio and temperature proved to be the key parameters controlling the formation of Mg4Al2(OH)14?3H2O phase. At solution Mg/Al ratio=0.5~4, the main precipitate phase was Bayerite (Al(OH)3) admixed with Mg4Al2(OH)14?3H2O; at Mg/Al ratio=4~6, the main phase was Mg4Al2(OH)14?3H2O admixed with some Mg(OH)2; while from Mg/Al ratio=6~10, the systems were mixtures of Mg(OH)2 and Mg4Al2(OH)14?3H2O.

Oct 1, 2011

By S. A. Sadough vanini

In this paper the influence of temperature on the flow behavior and rheological characteristics of an A356 alloy in the semi-solid state using backward extrusion process are studied experimentally and numerically. Simulation process is done by dynamic explicit in ABAQUS software for each forming condition. A cooling slope treatment was employed in order to obtain a non-dendritic microstructure. Experiments were performed in 5 temperatures and 4 different wall thicknesses. In the low forming speeds, liquid fraction had time to escape from solid phase forward the samples? wall. This condition was the main reason for the segregation phenomenon seen in the base and walls. Viscosities were determined using the force-displacement graphs obtained form back-extrusion tests. As observed experimentally, in a constant temperature, increase of shear rate resulted in decrease of alloy viscosity exponentially. Raising the temperature increases the liquid fraction hence reduces the semi-solid alloy viscosity. The results of experimental and simulation are compared and there is a good adaptation.

Oct 1, 2011

By S. Rash Ahmadi

Welding is highly reliable and efficient metal joining process. In welding the metal adjacent to the weld joint is subjected to severe thermal conditions. As a result, complex changes in metallurgical structure occur in this region. These changes in structure depend on the material and the temperature history experienced. Friction stir welding (FSW) is relatively a new welding process in which, heat is generated by friction between the tool and the workpiece. The amount of heat conducted into the workpiece determines the quality of weld, residual stress and distortion of the workpiece. The objective of the current work is to study the transient temperature in a friction stir welding. So, a three dimensional transient analytical model is used to study the thermal distribution during the welding. Heat input from the tool shoulder alone is considered in the model. The process parameters like axial load, welding speed and tool rotational speed, used in actual FSW process are taken to build the model. This analytical model is very useful for select the optimized affected parameters in friction stir welding. The model illustrates the comprehensive equation including actual affected parameters in FSW and it can be used for different materials. In addition to the above the thermal history finds application in design of welding tools.

Oct 1, 2011

By S. A. Sadough vanini

In this paper, Stress-Strain-Temperature relations for Shape Memory Alloys are studied. Temperature effects on Shape Memory Alloys are different from those related to ordinary materials. In ordinary materials, elastic characteristics can be assumed to be constant in low temperature ranges, and only the deflection arising from temperature changes could be added to the elastic defection. As long as two phases of austenite and martensite could be present in Shape Memory Alloys simultaneously, elastic modulus follows temperature and temperature gradient. In continue a smart actuator is investigated considering a homogeneous cantilever beam. Beam bending is established by using shape memory wires. An initial strain is imposed to shape memory wires in a low temperature, and then, they are installed in the outer surface of the beam. Therefore, since the temperature is imposed in these wires and they cannot have free recovery strain, the compressive recovery stress will be produced in the outer surface. This will result in a deflection in axial direction of the beam. At first, beam deflection is calculated on the basis of theoretical relations and solving the relevant differential equations. Afterwards, experimental tests are performed on an elastomeric beam equipped with shape memory wires. When a voltage is applied, a temperature rise will occur in the wires; then, this temperature rise causes a deflection in the beam. Finally, the theoretical and experimental results? comparison indicates a good conformity. One capability of this actuator is its high flexibility, and by controlling the inlet current, the end-beam deflection can be controlled.

Oct 1, 2011

By B. Farabi Khoshmehr

In the present study the effect of Silicate Sodium oxidation agent concentration and Plasma Electrolytic Oxidation (PEO) treatment time were investigated on properties of oxide layer on Aluminum alloy. The phase composition and surface morphology of PEO films were evaluated through x-ray diffraction (XRD) and scanning electron microscopy (SEM). Pin on Plate abrasive machine were used to investigate of were resistance of coating. The results showed that oxide layer which formed on Aluminum surface consist of high temperature a- Al?O? and ?- Al?O? phases. The diffraction peak intensity and percentage of these phases were increased by increasing silicate sodium concentration. Microscopic studies revealed a porous surface for PEO coating. This was affected by silicate sodium concentration and oxidation time. The wear test results showed that the weight loss of PEO coating was reduced due to improvement of their wear resistance.

Oct 1, 2011

By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By Sadough vanini Ali

Hot deformation behavior of functionally graded steel (FGS) was investigated via conducting hot compression tests at different temperatures and strain rates. Functionally graded steels consist of ferrite, austenite, bainite and martensite layers that are made by diffusion of alloy elements during the melting process. The zenerhollomon parameter has been used to describe the flow stress variations as a function of temperatures and strain rates. The parameter values for all the layers via using the boundary conditions was determined based on composite graded behaviors. Furthermore by applying the rule of phase mixtures, the whole strain rate applied on composite would be the sum of layers strain rates considering the layers volume fraction, while the layers have the same stress. Consequently the composite flow stress for each strain rate and temperature was determined.

Oct 1, 2011

By Saeid Akhavan

Accumulative roll bonding (ARB) is a severe plastic deformation process for achieving ultrafine grains in metallic sheets without changing the sample dimensions. In this study, ARB process was carried out on 5083 aluminum alloy sheets up to 6 cycles. In this process, the surfaces of the strips to be joined are roughened and cleaned and then stacked. After stacking, the specimen is roll-bonded by rolling using a 50% reduction. The rolled specimen is cut into two halves, and the above-mentioned procedure is repeated for several times. Microstructural characterizations were analyzed by transmition electron microscopy (TEM). Tension and Vickers hardness tests were performed on produced sheets for evaluating their mechanical properties. In order to clarify the failure mode, fracture surfaces after tensile tests were observed by scanning electron microscopy (SEM). The results indicated that at the early stages of ARB process, grains were subdivided by deformation induced boundaries. After several ARB cycles, lamellar structure elongated in the rolling direction contains lamellar boundaries was formed. With increasing the strain, mean spacing of lamellar boundaries decreased. Finally, continuous recrystallization resulted in a microstructure covered with small recrystallized grains with an average diameter below 100 nm at the end of four cycle. The tensile strength and hardness of the 6 cycle ARB processed 5083 aluminum alloy sheet increased about two and three times of the initial values, respectively. Results indicated conformity between mechanical evolutions and microstructural changes during ARB process. Fracture surfaces observations showed that failure mode in ARB processed aluminum is shear ductile rupture with elongated small dimples.

Oct 1, 2011

By D. Asefi

A new method to detect microstructural features such as recovery and recrystallization as well as cold rolling reduction in low carbon steels was developed based on magnetic hysteresis loop measurement. To this aim, a hysteresis loop measuring apparatus, specifically designed and assembled for plate samples was employed. It is shown that maximum field (Hmax) of hysteresis loop, measured at constant maximum flux density (Bmax) of 0.5T, is an adequatemagnetic property to monitor different stages of changing microstructures during annealing.

Oct 1, 2011

By S. Rash Ahmadi

One of the most important elements in power plants is rotors and repairing the damaged rotors is very important in view point of economics. One of the most complicated problems in power plants is increasing of stiffness of the turbine rotors. This problem which occurs mainly due to thermal shock or rubbing makes to exit damaged rotor from service. These elements can be repaired effectively by heat treatment methods. Tempering heat treatment is the most common solution for straightening of damaged rotors but it requires having good knowledge about heat treatment parameters (temperature and time) and their affects on fundamental properties of rotors. In this article, a suitable method is introduced in order to modify the increased stiffness in journal part of rotors due to martensite transformation, using heat treatment tempering process.

Oct 1, 2011

By Sadough vanini Ali

Charpy impact energy of functionally graded steels produced by electroslag remelting in crack divider configuration has been modeled in various strain rates. It has been well known that majority of materials indicate different behaviors under different strain rates and temperatures. Therefore, modifying the elastic-plastic model considering the effects of strain rates and temperature gives us an acceptable prediction of these composites behaviors in impact test. In this investigation, graded steel was divided in to several layers in which the layers have the same strains under the impact. Constitutive equation describing the flow stress variations as a function of strain rates and temperatures, have been used to express the stressstrain behavior of layers. The parameter values of constitutive equation determined for all the layers via using the boundary conditions based on composite graded behaviors which were the characterized ferrite, austenite, bainite and martensitte phases. Consequently by applying the rule of phase mixtures and ascribing the impact energy of each layer to the area of stress-strain curve of the same layer, the whole impact energy of composite is the sum of layers impact energy with considering the layers volume fraction.

Oct 1, 2011

By F. Hosseini

Shaping of metals by thixoforming relies on the unusual flow behavior of semisolid slurries containing nondendritic solid phase. The Flow behavior of metallic alloys containing both solid and liquid phases is investigated in the low solid fraction range (, 55%). This behavior depends on both the solid fraction and the shear rate. Four different shear rates is applied using back extrusion technique and flow stress versus true strain in different solid fraction is compared. It is well accepted that the flow stress s of alloys in their semi-solid state obeys to a thixotropic behavior, due to agglomeration and dissagglomeration phenomena during forming. The load-displacement curves produced from the tests may show an initial peak, believed to originate from a skeletal structure which rapidly breaks down under shear. Apparent viscosity obtained from this method is compared with other works and the proper power law of pseudo plastic state is introduced.

Oct 1, 2011

By A. Sadough vanini A. Kami

In this paper, effects of different ageing treatments on the mechanical properties, microstructure and formability of 7075 aluminum alloy have been studied. Forming limit diagrams of the alloy have been obtained for four ageing conditions including T6, OA1, OA2 and O. For this purpose, combination of uniaxial tensile tests and the Erichsen cupping tests with different sizes and shapes of sheet specimens have been performed after each ageing treatment. The highest formability and the lowest formability have been observed at samples with O and T6 ageing treatments, respectively. Also, investigation of precipitated microstructures showed that the size of precipitation particles has a significant effect on the formability of the alloy. Formability improves with coarsening of precipitation particles.

Oct 1, 2011

By A. A. Nourbakhsha

The main application of refractories based on andalusite in ferrous metallurgy are in air heaters of blast furnaces, mobile mixers, and hot-metal transfer, pig iron ladle, steel-casting, and intermediate ladles. Three specific properties of andalusite are very interesting for the production of high-quality shaped and unshaped mullite refractories: being free of water, its crystal a remains stable without changing its density or volume after firing and therefore has no internal porosity .Graphite additives due to its great wetting ability play an important role in raising the property of refractory bodies. In order to improve properties of andalusite graphite bodies, oxidant agent for increasing in hot strength and oxidation resistance can not be avoided. In this research, firstly 8 pig iron ladles from ESC(esfahan Steel company) with different conditions selected and monitored during usage to determine of main factors affecting on corrosion of refractories. Results showed that tap to tap time, undischarged pig iron ,penetrated pig iron are the main ones.Literature studies showed that the graphite addition help to thermal shock resistance and liquid penetration(steel,pig iron) effect. In this research particle size distribution of aggregates containing andalusite and graphite determined by andreazen equation. Then different mixes with different percentage of graphite,Si, FeSi, SiC prepared by uniaxially pressing under 1500kgf/cm2 pressure by adding 4%wt novalak resin and 0.4%wt HMTA as hardner. Samples fired at 1100-1500oC under reduction atmosphere. According to specific standards density, porosity and CCS measured. Analytical tests such as XRD, SEM were carried out on sample selected from point of view of mechanical properties at different temperatures. Results showed that optimized amount of Si and Fe-Si for _-SiC formation in body is 4 and 6 %wt respectively at 1500OC. XRD and SEM analysis on sample with Fe-Si additives showed no destructive phase through the matrix, also SiC additives not only increase oxidation resistance but also no effect on thermo-mechanical properties.

Oct 1, 2011

By Mohammad Mehdi Salarirad

Fouling of activated carbon by different organic species is a great concern in carbon in pulp and carbon in leach circuits. The rate of gold adsorption onto activated carbon from synthetic gold solutions which contained different amounts of potassium ethyl xanthate (PEX), potassium isobutyl xanthate (PIBX), and methyl isobutyl carbinol (MIBC) were evaluated through batch adsorption tests. The results of these experiments showed that the gold sorption rate rapidly decreases by increasing the concentration of collectors including PIBX and PEX up to 20 mg/L and at higher concentrations, the kinetic rate constant (i.e., k value) gradually leveled off to 53 h-1 for PIBX, which is 46% lower than the 99 h-1 for PEX. At low concentrations of up to 15 mg/L of MIBC, a gradual decrease of the rate constant was observed, while at higher concentrations, the decrease was found to be more pronounced. The gold loading capacity and the rate of gold adsorption onto activated carbon from a gold cyanidation pulp in the presence of flotation reagents were also evaluated. The results of these experiments showed that the flotation reagents have no significant effect on the gold loading capacity of activated carbon at prolong adsorption period, meanwhile the rate of gold adsorption continuously decreases by increasing the concentration of flotation reagents in the leaching solution.

Oct 1, 2011

By A. A. Nourbakhsha

During the last few years, low cement castable refractories found more application in industry, because of good low and high temperature mechanical properties.In the case of alumina based castables ,usually fume silica or reactive alumina are used as superfines in the matrix to form mullite at high temperature which depends to source of alumina . Mullite network formation improves the hot mechanical properties and thermal shock resistance of bodies. The mullitisation of andalusite (so called primary mullite) also produces a certain amount of rich silica glass, part of it being expelled out of the grain. This phenomenon restrict the application of andalusite low cement castable in pig iron ladle. In this research, firstly 8 pig iron ladles from ESC(esfahan Steel company) with different conditions selected and monitored during usage to determine of main factors affecting on corrosion of refractories. Results showed that tap to tap time and undischarged pig iron are the main ones.Therefore monolithic refractories such as castables which increase thermal shock resistance could be substituted. Regarding to ternary phase diagram of Al2O3-SiO2-CaO ,fumed silica was selected as fine particle.After optimization of particle size distribution by using of modified andreasen equation and rehological properties ,different mixture were composed with andalusite ,fume silica, reactive alumina,secar 71 ,SiC and kyanite.All aggregates system components were mixed dry for 1 min in hobart mixer .After water addition wet mixing was continued until getting flowing about 4 min.The ready mixes were poured in the moulds of of 25mm X 25mm X 140mm with vibrations .After demoulding the samples were cured for 24 hrs and dried at 110OC/18hrsand then fired at 1100-1500OC. Physical ,mechanical ,phase analysis(XRD) and microstructure studies (SEM)were carried out according to ASTM standards. Results showed that by addition of kyanite ,more mullite phase formed through the matrix but,because of expansion occured during this phase transformoration, some cracks formed and mechanical properties decreased.By SiC addition the silica film on the surface of SiC lead to improvement of mechanical properties at high temperature

Oct 1, 2011