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By J de Cuyper, S. R. Rao, J. Leja, K. S. Moon, W. Freyberger

A prolonged grinding of sulphide ores in steel mills appears harmful to flotation recovery and selectivity whenever xanthates are used as collectors. Particles finer than about 10um show a pronounced decrease in floatability. A supposition was made that the cause of the reduction in floatability of ground sulphides is the presence of metallic iron abraded during grinding and deposited on the ground particles. Electro- chemical measurements were made of mixed potentials developed by different sulphide-mineral electrodes (galena, chalcopyrite, pyrite, marmatite, pyrrhotite) in xanthate solutions, without a direct con- tact or in contact with a metallic iron electrode. These measurements showed that without a galvanic contact between the sulphide and the iron, the values of mixed potentials were in the vicinity of the xanthate/dixanthogen redax potential. When contact with iron was established, the mixed potentials shifted towards the more negative reducing or cathodic values, The shift was greater the higher was the ratio of the surface areas: iron electrode to sulphide electrode. Further, the shift in mixed potentials was greater the more reducing were the conditions on the sulphide electrode. Chemical analysis of reaction products produced on the surfaces of sulphides and in the bulk solution showed that less thiosulphate was formed in all of the sulphide-xanthate systems and that more elemental sulphur was detect-

Jan 1, 1976

By H. Ipek

Industrial grinding machines used in the mineral processing industries are mostly of the tumbling mill type. These mills exist in various types: ball, rod, pebble, autogenous, and semi-autogenous. Balls and rods are traditionally media shapes used in the tumbling mills. In resent years, as an alternative to balls, grinding charges with various shapes are being used. Cylpebs are slightly tapered cylindrical grinding charges with length equaling diameter, and all the edges being radiused. Cylpebs of equal diameter and length have 50% greater surface area and 45% greater weight than balls of the same material. In addition, they have 9% higher bulk density than steel balls, or 12% higher bulk density than cast balls. An important advantage of cylpebs over balls is that cylpebs produce narrower granulometric distribution due to their shapes. However, some discrepancies were found in the literature regarding the milling performance of cylpebs in comparison with balls (Chi, 2004). In recent studies, Chi (2004) has provided detailed information on cylpebs and has compared these to balls in relation to media mass, size distribution, surface area, and input specific energy. Ipek (2006) has investigated the effects of cylpebs and balls with equal mass and surface area on the breakage rate of quartz, using cylpebs and balls separately. Similarly, Lameck and Moys (2006) have investigated the effects of balls and worn balls on breakage rate of material using worn balls as grinding environment. However, no study has attempted to investigate the effects of grinding environment other than balls on the brekage distribution. As indicated by Prasher (1987), the breakage distribution function is independent of the following variables in ball mills: hold-up (Mika et al., 1967; Kelsall et al. 1969), mill speed and ball load (Herbst and Fuerstenau, 1972), media load and ball density (Kelsall et al., 1973), mill diameter (Malghan and Fuerstenau, 1976), and powder charge (Shoji et al. 1980). The aim of the present paper is to compare the effects of cylpebs and balls on the breakage distribution function of quartz with respect to same mass and same surface area. BACKGROUND Comminution as a rate process is called kinetic approach. Studies on the kinetic approach are reviewed by Oner (2001). Oner states that grinding kinetics are based on studies by Kolmogorov in 1941 and that Robert (1950) is the first to suggest this approach. Later, Melzak, Loeveday, and Reid have improved the grinding kinetics equation; and, Austin and Lynch have conducted two basic studies on the analytical solutions of these equations. Considering the results of studies comparing the size reduction mechanisms, it has been accepted that breakage constitutes of two operations. These two basic operations, first defined by Epstein (1948), are those of selection of material for breakage and the distribution of breakage material to particle sizes smaller than the initial size (Lynch, 1977). Epstein defined the two operations as: ? Pn(y), the probability of breakage of a particle size in the nth step of the breakage process. ? F(x,y), the cumulative distributions by weight of particles of size x<y arising from the breakage of a unit mass of a size y. Probability of breakage is called a selection or a breakage-rate function (Si). Characteristics size distribution after breakage is called a breakage distribution or appearance function (Bi,j). Due to the difficulties in representing particle size distributions mathematically and constantly, the batch equation based on particle size fraction is suggested. Thus, as is the case in breakage distribution and specific rate of breakage, the breakage parameters were defined by batch grinding experiments conducted in laboratories (Oner, 2001). When effective breakage occurs in the mill, the breakage of material with single feed size fraction usually fits first order grinding kinetics and the specific rate of breakage values can be calculated through the slope of semi-log plot. The values of the breakage distributions are deduced from the size distributions at short grinding times where there is mainly size 1 material breaking and only small amount of smaller sizes to rebreak (Austin et. al., 1984). B values can be calculated by using BII. [ ] where j is the top size of the charge, Pi(t) is the cumulative percent undersize of i th size interval at the short grinding time which gives no more than about 30% broken out of the top size interval. Cumulative primary breakage distribution, Bi,j, is also defined in an empirical form by [ ] where xi is the top size and Bi,j is the weight fraction of primary breakage products. The parameters F, ? and ß define the size distribution of the material being ground. On plotting size versus Bi,j on log scale, the slope of the lower portion of the curve gives the value of ?, the slope of the upper portion of the curve gives the value of ß, and F is the intercept as in Fig.1. [ ]

Jan 1, 2009

By M. Saghaeian, R. Hejazi, Sheikhzadeh. V., A. Abazarpoor

"The morphology of iron ore concentrate particles is known to influence several properties of iron ore pellets, including drop number, compression strength, and reduction properties. This study aimed to determine why grinding methods and particle morphology influence green pellet properties. Particle morphology can be directly related to the grinding method: ball mill (BM) or high pressure grinding roll (HPGR). In this research, two iron ore concentrates, namely Gol-e-gohar and Ardakan, were ground by a BM and HPGR to produce a suitable Blaine value for pelletizing (nearly 1,900 cm2/g). Morphological features of particles were subsequently investigated by sieving and cyclone sizing for particle size distribution, the Brunauer-Emmett-Teller (BET) and Blaine methods for specific surface area (SSA) and scanning electron microscopy (SEM) for the evaluation of shape descriptors. It was concluded that HPGR resulted in generating a greater proportion of fine particles compared to ball milling. The BET results showed that the SSA of HPGR pellet feed was higher than that from the BM due to a greater proportion of cracks, indents and bulges and the creation of new fracture surfaces. SEM images processed by ImageJ software indicated that particles ground by the BM tended to be more rounded and less elongated than HPGR particles because of the breakage model of each method. To show the effect of morphology on the green pellet quality, green pelletizing was performed in a pilot pelletizing disc. The HPGR pellet feed had a higher drop number in comparison to the BM pellet feed, due to the angular and rough shape of the particles.INTRODUCTIONThe demand for fine or ultra-fine particles as feed material for ceramics, composite materials, and mineral processing is on the rise (Kotake, Kuboki, Kiya, & Kanda, 2011). The final concentrate of iron ore processing plants (filter cake) has a size range roughly between 0 and 300 µm, depending on the liberation of Fe containing particles (Meyer, 1980). In general, to produce a suitable pellet feed of appropriate quality, Blaine numbers of 1800–2000 cm2/g should be achieved (Van der meer, 2015)."

Jan 1, 2016

By Wantae Kim, Hoon Lee, Kwanho Kim, Sangbae Kim

Mechanochemical activation of starting minerals and their effect on the solid-phase synthesis and properties of ceramics with lower thermal expansion coefficient was examined. The mineral mixture, pyrophyllite-gibbsite-lithium carbonate, was prepared for the synthesis of ?-eucryptite (Li2O•Al2O3•2SiO2). Dry grinding using a planetary ball mill promoted the amorphization of the starting mixtures. XRD and FT-IR results showed that the crystallization of the target materials occurred from the ground mixtures by calcination. The crystallization of them increased with increment of grinding time and calcination temperature. In the synthesis, the trace of undesired phases such as quartz and cristobalite once formed during calcination at the temperature range from 750 to 850 °C almost disappeared and monophase ?-eucryptite was formed in the ground mixture at 950 °C. The lowest liner thermal expansion coefficient (TEC) of ?-eucryptite prepared was -2.5x10-6•°C-1. The thermal expansion behavior characteristics of the calcined

Jan 1, 2014

By Bern Klein, Randy Blaskovich, Reem Roufail

"Morphology is a tool that is rarely used for mineral breakage mechanism evaluation. Ground particles are typically assessed for their size distribution. They are also visually analyzed using image analysis. However, image analysis is not a comprehensive evaluation of the particle surface texture. It evaluates particle’s size parameters such as area, diameter, and perimeter amongst other features. On the other hand, morphology analysis takes the particle assessment to another level of detail. Morphology analysis evaluates particles’ roundness, elongation and angularity that would indicate the degree of roughness of the particle. According to Roufail and Klein (2009), rougher surfaces are generated due to breakage along grain boundaries – intergranular breakage. Mill operation, particularly mill speed, dictates the dynamics in the mill. Stirred mills are known to break the particles via abrasion under standard operation. However, if the dynamics of the grinding media in the mill are changed, the particles could be more exposed to impact and compression loading that would lead to a different mode of breakage.In this paper, the effect of material properties and mill operating conditions on particle morphology will be studied. Hard non-sulfide versus soft sulfide minerals are compared, namely quartz and galena, respectively. Extreme mill speeds are tested covering the range of 1000 to 2000 rpm for a 4-litre Netzsch (ISA) mill. In addition to particle size distribution, micro-analysis is executed in the form of morphological analysis using a tested manual roughness point counting technique.INTRODUCTIONGrinding in general and stirred milling in particular are processes that are used to break particles to liberate metal-bearing minerals for further separation downstream. The energy required to achieve the target particle size versus maximum possible liberation has been studied intensively and it is usually the breaking point for the grinding system chosen in a process flowsheet. Operating conditions are dictated by the energy consumption. Becker et al. (2001) related different forms of energy such as input, specific, volume/mass specific energies to stress intensities and final product fineness. Other research studies focused on energy input in a stirred mill (Zheng, Harris and Somasundaran, 1996)."

Jan 1, 2011

By L. L. Chasko, D. W. Alexander

Researchers from the National Institute for Occupational Safety and Health’s Office of Mine Safety and Health Research conducted an assessment of the effects that ground control mesh might have on rock and float coal dust distribution in a coal mine. The increased use of mesh to control roof and rib spall introduces additional elevated surfaces on which rock or coal dust can collect. It is possible to increase the potential for dust explosion propagation if any float coal dust is not adequately inerted. In addition, the mesh may interfere with the collection of representative dust samples when using the pan-and-brush sampling method developed by the U.S. Bureau of Mines and used by the Mine Safety and Health Administration for band sampling. This study estimates the additional coal or rock dust that could accumulate on mesh and develops a means to collect representative dust samples from meshed entries.

Jan 1, 2014

By L. L. Chasko, D. W. Alexander

Los investigadores del National Institute for Occupational Safety and Health’s Office of Mine Safety and Health Research han evaluado los efectos que la malla de control de suelos podría tener en la distribución de polvo flotante de roca y carbón en minas de carbón. El creciente uso de mallas para controlar el desconchado o caída de material del techo y las vigas introduce superficies elevadas adicionales para recolectar el polvo de roca o de carbón. Es posible que el potencial para la propagación de explosión del polvo se incremente si el polvo flotante de carbón no es convertido en inerte de manera adecuada. Adicionalmente, la malla podría interferir con la recolección de muestras representativas de polvo cuando se usa el método de recipiente y brocha desarrollado por la U.S. Bureau of Mines y usada por la Mine Safety and Health Administration para muestreo de banda. Este estudia hace una estimación del polvo de roca o carbón adicional que pudiera acumularse en la malla y desarrolla un método para recolectar muestras de polvo representativas atrapado en las mallas.

Jan 1, 2014

By R. K. Rath

Adsorption, electrokinetic and flotation studies were carried out. The maximum density of adsorption of guar gum was obtained at pH 7.5 on sphalerite and at pH 11.5 on galena. Flotation recovery of sphalerite was reduced only marginally by the presence of guar gum in the pH range investigated, whereas recovery of galena was reduced to about 20% at pH 12. Differential flotation tests on binary mixtures indicated that 10 ppm of guar gum can depress galena and separate it from sphalerite at around pH 12.1. Co-precipitation tests confirmed the formation of a metal ion-guar gum complex in the bulk solution, suggesting that this is the precursor to adsorption. The adsorption isotherms for both minerals followed Langmuirian behaviour, but adsorption of guar gum on galena was significantly higher than on sphalerite and dissolution tests indicated that the concentration of Pb ions released from galena was an order of magnitude greater than that of Zn ions dissolved from sphalerite

Jun 21, 1905

Effect of Hardwater on Selective Flocculation of Diasporic-Bauxite

Sep 13, 2010

By Clarence Merritt

STAINLESS iron, as mild stainless steel is usually called, an alloy ranging from 11.50 to 15.00 per cent chromium with carbon under 0.12 per cent, has been considered to be not appreciably affected in respect to corrosion resistance by heat treatment. This metal, while one of the most widely used of the "straight" chromium stainless alloys, has failed in many applications because of insufficient information regarding heat treatment. These failures have been attributed to many possible causes from an inherent lack of resistance to corrosion and misapplication to mysterious electrolytic effects or comparatively minute non-metallic inclusions. Many uses for a steel with such excellent physical properties is are latent in this alloy have been lost on account of corrosion failures which could have been avoided by applying proper heat treatment. The alloy has not received the recognition or attention it should because of the fact that&apos; the details of its metallurgical behavior were not thoroughly understood. Response to heat treatment of the steel is well known as regards tensile properties, 1,2 but its application has been for improvement in tensile characteristics or on account of machining considerations rather than for corrosion prevention. The potential user of this steel has not been clearly advised in papers, either technical or commercial, that have been written about it in the last 10 years or more, of particular features that are of prime importance in developing the excellent properties of this metal. The data to be presented in this paper are concerned mainly with the effect of heat treatment on the corrosion resistance, but a study has also been made of the concurrent microstructural changes and an explanation developed for the phenomena revealed, as well as a correlation to the other physical properties-hardness, tensile characteristics and impact strength. Stainless steel, largely used for cutlery purposes, an alloy of approximately 13.00 per cent Cr with 0.30 per cent C, must be hardened and the surface prepared by polishing or pickling for best resistance to staining and corrosion.3 Monypenny reports that a loss of hardness is

Jan 1, 1932

By E. Dalgaard

During linear friction welding of titanium alloy Ti-5A1-5V-5Mo-3Cr (Ti-5553), the weld zone exhibits beta (B) grain refinement and alpha (a) phase depletion that have the combined effect of deteriorating the mechanical performance of the weldment. In this work, linear friction welded Ti-5553 was subjected to pre- and post- weld heat treatments in order to determine the conditions under which a phase depletion could be mitigated in the weld zone and thermomechanically affected zone (TMAZ). The mechanical response of the welded samples to the heat treatments was determined by performing tensile testing at room temperature. While the pre-weld heat treatments had no significant effect, the post-weld heat treatments were instrumental in restoring the strength of the starting (heat-treated) material.

Jan 1, 2011

By S. K. Shaha, W. Kasprzak, D. L. Chen, J. Friedman, F. Czerwinski

The role of solutionizing conditions within the T6 heat treatment of the cast Al-Si-Cu-Mg alloy with micro-additions of Zr-Ti-V was assessed in terms of their influence on microstructure and mechanical properties. As a solution treatment, a single step process at 485 and 510oC and a two-step process at 510 and 525oC for varying time intervals from 0.5 to 9 h, were examined. In all cases, solution treatment was followed by isothermal aging at 150oC for 100 h. The microstructural analysis showed that the solution treatment changed the eutectic silicon morphology from needle-like, present after casting, to spherical shape in the T6 state and that the extent of changes was strongly influenced by temperature and time. The Cu- and Mg-rich phases completely dissolved during solution treatment while the Fe-containing phase, Al8Si6Mg3Fe, remained partially in the microstructure. The Ti, V and Zr containing phases, Al13Si2Ti3Zr and Al3Si26FeTiV10, present in as-cast state, were partially dissolved during solution treatment, reducing their size by 10 - 48%. The studied alloy reached the maximum ultimate tensile strength of 335 MPa and yield stress of 303 MPa for two-step solutionizing with a total time of 4.5 h. It is concluded that the two-step solution treatment resulted in higher tensile properties than the single-step process.

Jan 1, 2015

By B. Egeberg

IN A previous paper1 the authors dealt with the physical properties of cold-rolled and heat-treated Britannia metal of the approximate composition Sn, 91 per cent., Sb, 7 per cent. and Cu, 2 per cent. It was found that cold rolling to more than 50 per cent. reduction produced a continuous softening of the metal when measured by the Brinell machine, whereas the Shore instrument indicated increased hardness; that the strength of the material followed the Brinell hardness and that the metal therefore became weaker the more it was cold-rolled; and further, it was found that hardness and strength could be largely restored to the cold-rolled metal by "baking" for about one hour at any temperature, between 200° and 450° F., the melting point. The higher the baking temperature, the more effective was the heat treatment as far as increased hardness was concerned. It seemed to be of little importance whether the metal was soaked or not at the baking temperature for a great length of time and the rate of cooling seemed to be immaterial. The present paper deals with the same alloy and more particularly with the resistance towards various forms of stress - tensile, bend and deep drawing. The metallography of Britannia metal has in part also been covered and an explanation attempted for the abnormal behavior of this alloy.

Jan 1, 1929

By G. Morin, S. Amira, F. Chiesa, B. Duchesne

"The effect of heat treatment on the stress corrosion cracking (SCC) resistance of A206 aluminum alloy was studied using the breaking load test according to ASTM G139 standard. This method uses the residual strength measurement from tensile test specimens previously stressed axially while exposed to the 3.5% NaCl alternate immersion test according to ASTM G44 standard. The residual strength after exposure is used as a measure of SCC degradation. The performed heat treatments were conventional natural aging T4 and artificial over-aging T7 tempers in addition to artificial aging T6 temper added for purpose of comparison. These tests showed that A206-T4 has a good resistance to SCC at pre-loads up to 100 MPa while A206-T7 was prone to SCC for pre-loads of 0 and 50 MPa, and showed total loss of ductility for pre-load of 100 MPa. Both A206-T4 and A206-T7 pre-loaded at 150 MPa showed poor resistance to SCC. A206-T6 showed the worst susceptibility to SCC as it lost all mechanical resistance at the end of the alternate exposure to 3.5% NaCl solution, even without any applied pre-load. Metallographic analyses showed that the resistance of A206 alloy to SCC is mainly affected by the transition from pitting to intergranular corrosion attack. The initiation and the propagation of intergranular corrosion attack might be assisted by high stress concentrations in the pits, particularly for pre-loads higher than 100 MPa. The transition from pitting to intergranular corrosion can also be promoted by hydrogen evolution from growing pits, which supports crack propagation by hydrogen embrittlement.INTRODUCTIONA206 aluminum-copper casting alloy offers ones of the best mechanical properties among the aluminum foundry alloys. This alloy belongs to the 206 alloy family developed in 1970s as an alternative to the highly resistant and ductile but more expensive Ag containing 201 alloy (Tiryakioglu, 2009). A206 showed also good low cycle fatigue strength (Sigworth, 2002). These properties made A206 alloy a strong candidate for some vehicles lightweighting applications. In spite of its interesting properties cited above, A206 alloy was rarely used in critical applications due to its tendency for hot tearing and stress corrosion cracking (SCC). Studies of A206 hot tearing behavior showed that this tendency can be reduced by improving castability and by grain refinement (Sigworth, 2002). The optimisation of the casting design can also prevent the tendency toward hot tearing. The SCC of aluminum-copper alloys arises from their susceptibility to localised corrosion, especially in chloride containing media. The localised corrosion in Al-Cu alloys is caused mainly by their heterogeneous microstructure, where the presence of many phases leads to the formation of micro-galvanic coupling with the matrix. However, most of the studies aimed at investigate the SCC of Al-Cu alloys concerned the wrought ones, especially the AA2024 alloy tempered in the T3 (or derivative) condition and few studies concerned the 206 and cast alloys in general (Alexopoulos, 2009 and 2016; Campestrini, 2000; Vogt, 1998; Talamantes-Silva, 2008; Zhang, 2003). Jean et al. (Jean, 2009) studied the effect of heat treatment on SCC behavior of B206 alloy using alternate immersion technique and grain boundary attack method and did not find direct correlation between the two methods. Another study showed that aging of 206 alloy may make a casting susceptible to SCC (Sigworth, 2002). However, these studies did not provide detailed information about the mechanisms of SCC of 206 alloy, as well as the effect of the stress intensity. The present work investigates the effect heat treatments and the stress intensity on the morphology of the corrosion attack and the SCC behavior A206 aluminum alloy. This study uses the breaking load test according to ASTM G139. This test utilizes direct tensile specimens and was developed to give a more quantitative measure of the SCC performance of resistant aluminum"

Jan 1, 2016

By M. M. Kim

As-electrogalvanized coatings of pure Zn, Zn-11% Fe, and Zn-18% Fe coatings were characterized in terms of initial crystal structure and surface morphology. Samples were then subjected to heat treatments simulating the paint bake cycle of automobile manufacturers. Surface morphology changes were correlated with the process variables, and crystallo.graphic changes were interpreted by mapping heat treatment routes on the Fe-Zn phase diagram. The morphology of pure zinc electrogalvanized coatings with heat treatment from platelets to smeared platelets. The zn-11% Fe coating changes with heat treatment from tetrahedral nodules to a mixture of round and tetrahedral nodules, with the Zn-:18% Fe coating always having round nodules. Regarding crystal structure, a critical transformation time can be defined at any selected temperature, below which the crystal structure does not change. This temperature is related to iron content.

Jan 1, 1990

By Haofeng Xie, Lijun Peng, Xujun Mi, Xue Feng, Xiangqian Yin, Zhen Yang, Guojie Huang

The Cu/Al composite wires have been widely used in cable industry. Especially in the development of aerospace, the light weight character of wires is particularly important. The wires are fabricated by a drawing process and heat treatment. Mechanical and electrical properties are measured and analyzed. The bending behavior is studied by scanning electron microscope. INTRODUCTION Cu/Al composite is a typical bimetallic composite that has been used in plenty of fields such as automobile and aerospace. The composite has the advantages of excellent conductivity as well as low weight, which cannot be obtained from single copper or aluminum. Industrial products of Cu/Al composite include Cu/Al composite joints (Uscinowicz, R., 2013), Cu/Al bimetallic sheets (Li, X. et al., 2011), Cu/Al flat bar (Wu, Y. & Liu, X. & Xie, J., 2014) and CCA wires (Ahmed N., 1978). CCA wires refer to the composite wires that copper layer concentrically coated on the surface of aluminum core conductor, implementing solid combination of two metals on the interface and forming an integral. At present, the aircraft cable generally use copper or copper alloy conductor, which makes the wire in the aircraft occupy a considerable proportion due to the large density of copper. Therefore, the use of Cu/Al composite wires instead of copper wires for weight loss, is of great significance to the development of aerospace technology industry. Heat treatment is an indispensable procedure to improve plasticity during cold working process, which is of great importance to preparation of wires (Wang, Q. et al., 2008). During the heat treatment, the Intermetallic Compounds (IMCs) are inevitable formed at the contact area of Cu/Al due to the occurrence of diffusion (Lee, S. et al., 2012). According to the results of former researchers, kinds of IMCs were discovered. Antoine Gueydan (2014) identified the formation of three IMCs (Al2Cu, AlCu, and Al4Cu9) at the interface between copper and aluminum after thermal aging. IMCs have a significant effect to the properties of Cu/Al wires. Bending performance is a vital property for the actual application of wires. The brittle IMCs may create a stress concentration that can cause crack initiation during bending process. This work focus on the mechanical properties of Cu/Al composite wires after heat treatment. The effect of various annealing condition on mechanical and electrical properties are studied, in order to find the appropriate annealing conditions, which produce optimal combination properties of Cu/Al clad composite wires. Bending fracture of composite wires is discussed by morphology observation.

Jan 1, 2019

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By Onder Guney, Erdem Demirkesenm

"In this study, the crystallization behavior and thermal expansion coefficient of a lithium disilicate (LS2) based glass-ceramic derived from SiO2-Li02-AhO3-K2O-ZrO2 system was investigated by using x-ray diffraction (XRD), high temperature x-ray diffraction (HTXRD), differential thermal analysis (DTA) and dilatometer techniques. Analytical reagent grade chemicals were chosen as raw materials for preparing glass batches. Nucleation and crystal growth heat treatments were planned according to DTA results. The amounts of the amorphous and crystalline phases developed during the heat treatments were determined by quantitative XRD. XRD results of crystallized samples showed simultaneous formation of lithium silicate (LS) and quartz in the early stage of the crystallization followed by formation of lithium disilicate (LS2) at higher temperatures. The thermal expansion coefficients of glassceramics were also measured depending on the applied heat treatments.IntroductionSignificant developments occurred in all ceramic materials provide the fabrication of high quality dental implants [1]. Glass ceramic based dental restorations like dental inlays, crowns, bridges and veneers are becoming increasingly popular with their reliable and durable performance [2,3]. In addition to their advanced functional properties, glass ceramic implants especially lithium disilicate glass ceramics also face the esthetics expectations of patients and dentists and in this way they are starting to take the place of metal based restorations today [1,3,4,5]. Lithium disilicate glass-ceramics derived from multicomponent glass systems have some superior mechanical and optical properties comparable to natural teeth [ 6]. In restorative dentistry, mechanical characteristics of biomaterials play very crucial role in order to resist the masticatory forces occurred during biting and chewing [7] According to three point bending test results of Roland, flexural strength of the lithium disilicate glass-ceramics were 400±40 MPa and their fracture toughness (K1c) are approximately 3,3 MPa m112 [2,6]. In addition to high mechanical strength, aesthetic appearance is another important prerequisite as material for dental restorative applications. Translucency and light transmission of the LS2 glass ceramics mimic enamel. Moreover, opacity of the material can also be adjusted depending on the restoration types [2,6, 7]. These superior properties of the LS2 glass ceramics are directly related with chemical composition of the base glasses and controlled crystallization heat treatments [ 4, 7]. The aim of the present work is to determine the effect of heat treatment schedules on the crystallization behavior and thermal expansion of the LS2 glass-ceramics."

Jan 1, 2011

By Matthew S. Hall

Gold/iron oxide catalysts have been prepared and their catalytic performance evaluated for low temperature CO oxidation. The method and temperature used to dry the sample has a significant effect on their catalytic activity. Analysis by TEM revealed the catalysts contained Au particles, although catalysts with high and low activity did not always differ in their microstructure as evidenced by TEM. Catalysts were characterised using XPS and the difference between the Au(4d) and C(1s) binding energies measured; in general the greater the difference, the higher the catalytic activity of the material.

Oct 1, 2003

By Kazutami Imai

Effects of heavy metal ions on the growth and the activities of iron and sulfur oxidation of Thiobacillus ferrooxidans were investigated. Mercuric, silver, and stannous ions inhibited both of the growth and the iron- oxidizing enzyme system of the bacterium. On the other hand, uranyl ion inhibited the growth, but it gave almost no effect on the iron-oxidizing enzyme system. The inhibitory effect of uranyl sulfate on the growth of the bacterium is intensified on lowering the cultivating &apos; temperature from 28 ºC to 7 ºC. In the concentration of 10-3M, cadmium and copper ions inhibited colloidal sulfur-oxidizing activity of the cells 69 and 52 %, respectively, though they did not inhibit the iron-oxidizing activity at all in the concentration. On the contrary, stannous chloride did not givr any effect on the sulfur-oxidizing activity of the cells, though it inhibited the iron-oxidizing activity 55 % in the concentration of 10-3M. Several differences were observed among the cytochrome systems of cell-free extracts of the cells grown on iron and on sulfur.

Jan 1, 1976