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By Xiaoyan Xiang, Wenqiang Yang, Wentang Xia

Magnesium aluminate spinel is widely used in the metallurgical industry as refractory material, however, natural magnesium aluminate spinel is rare and most of the magnesium aluminate spinel is synthetic. The traditional synthesis of magnesium aluminate spinel often needs high temperature, which leads to more energyconsumption. In this article, solid phase sintering process was employed to synthesize magnesium aluminate spinel, in which, magnesium and aluminum oxide were used as raw materials and magnesium and aluminum powder were used as composite additives. The mass ratio of magnesium and aluminum on the effect of synthesis of magnesium aluminate spinel and the characteristic of the synthesis at different temperature and time was discussed. Experiment found that the synthesis temperature was observably lowered when the addition of magnesium and aluminum was 2.0% and 1.0% respectively.

Jan 1, 2016

By A M. Nyembwe, A M. Garbers-Craig, R Cromarty

With the depletion of high-grade lump iron ore, concentrates have been identified as an alternative material for sinter making. Adding concentrates to the sinter mixture reduces sinter bed porosity and gas flow through the sinter bed. This will result in lower sinter strand productivity. A potential solution to this problem is to add concentrate in the form of micropellets. This study investigates the effect of concentrate and micropellet additions on the permeability of the sinter mixture. Permeability was measured on sinter mixtures containing ten to 40 per cent concentrates and micropellets at various moisture contents. The effect of concentrate and micropellet addition on the permeability–moisture relationship was examined. The results confirmed that the addition of concentrates into the sinter mix decreases the maximum permeability of the sinter bed. The incorporation of micropellets into the sinter mix reduced the permeability less than concentrate addition. The study also showed that the maximum permeability of sinter mixes containing concentrate is reached at the same moisture content as the sinter mixture without concentrate addition. For sinter mixes containing micropellets, additional water must be added to obtain maximum permeability. Parameters including the granule size, void fraction and angle of repose were also investigated to evaluate their effects on the sinter bed permeability.CITATION:Nyembwe, A M, Cromarty, R and Garbers-Craig, A M, 2015. Effect of concentrate and micropellet addition on iron ore sinter bed permeability, in Proceedings Iron Ore 2015, pp 69–76 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By W. G. Davenport

Chapter 13 evaluated the %02 in blast, industrial oxygen and oil requirements for smelting FeSrCuFeS2 concentrates~ This chapter examines high eu grade CU2S-CuFeS2 concentrates the same way.

Jan 1, 2001

By W. G. Davenport

The Cu content of industrial flash furnace concentrates varies considerably. It is usually around 30% Cu (Tables 2.1, 3.1) but it may be as high as 55% Cu and as low as 20% Cu. The mineralogy of flash furnace concentrates also varies. The most common Cu mineral is chalcopyrite (CuFeSz), but many concentrates contain bornite (CuSFeS4), chalcocite (CU2S), covellite (CuS) and even native copper (CUO). Pyrite (FeSz) :is also present in many concentrates. This chapter examines how concentrate composition affects flash smelting -with specific reference to 'low-Cu-grade' FeS2-CuFeSz concentrates. Chapter 14 does the same with 'high-Cu-grade' CuzS-CuFeSz?concentrates.

Jan 1, 2001

By Lei Zhang, Xianjun Lu1, Minjie Lian, Liyang Zheng

In order to investigate rheological behaviour of fine tailings backfill pastes, the fine iron ore tailings (size fraction of -0.074mm accounts for 70%) from Fuquan Mining Co., Ltd. of Sinosteel Corporation (Shandong, China) was investigated. The rheological parameters such as slump, viscosity and yield stress of the tailings pastes under different densities were measured in detail, and the effect of paste density on the rheological property and the relationships of different rheological parameters of the pastes were also discussed. According to the results, the rheological behaviour is in accordance with the pseudoplastic fluid in a wide range of paste densities (solid content, w/w) of 65% to 80% and the pastes turn to be Bingham fluids at higher shearing rates. Along with the increase of paste density, the slump drops gradually and the viscosity and shear stress increase gradually. However, the variation extent of the rheological parameters varies at different density ranges. According to the variation pattern of the rheological parameters at different paste densities, the flow ability of the pastes can be classified into three zones. The high fluidity zone was observed at the density range of 65%-69% where the rheological parameters vary slightly along with the paste density, the moderate fluidity zone was observed at the density range of 70%-76% where the rheological parameters vary significantly along with the paste density, and the low fluidity zone was observed at the density range of more than 76% where the rheological parameters vary sharply along with the paste density and the critical density for this sudden variation is about 76%. Furthermore, linear correlations of slump/viscosity and slump/yield stress were observed. It is possible to predict the viscosity and yield stress of the pastes based on the slump measurements.

Jan 1, 2014

By S. Korman, S. B. Tuwiner

Chalcocite flotation is affected by agitation intensity during conditioning. Sodium sulphide in minute quantity may activate or depress, depending on conditions. Oxygen is a depressant while oxygen and sulphide neutralize each other by re-action at the mineral surface. Diffusion across a stagnant film at the surface governs reaction rates, while film thickness is reduced upon increase of agitation intensity.

Jan 2, 1950

By T. C. Rao, N. Suresh, M. Vanangamudi

Experiments have been conducted on a 76¬mm water-only cyclone treating cowl below 2 mm size having different proportion of -0.075 mm fines. The effect of cone angle of the cyclone (compound cone) has been analyzed on water split, separation of -0.075 mm fines, separation of coarse solids, and on separation behavior of individual size ructions of the feed. It has been noted from the results that there exists a linear relationship between the flow rate of water in the feed and flow rate of water reporting to overflow stream. This relationship is independent of the cone angle and, with changes in the fines content in the feed, only the intercept of the straight varies, keeping the slope constant. Further, it has also been found that the percentage of fines below 0.075 mm reporting to the overflow is directly proportional to the percentage of feed wafer reporting to the overflow. This relationship is found to be independent of the cone angle and the fines in the feed. The performance of the water-only cyclone has been analyzed by plotting partition curves for different experimental conditions. In addition to this, the Rosin-Rammler equation has been fitted to the partition curves of the hulk feed and individual size-fractions. Tile analysis of the results has revealed that the specific gravity of separation increases with increase in the cone angle of the cyclone while it decreases with increase in percent fines present in the feed. Mathematical relationships have been developed to relate the variation in SG50 with cone angle and percent fines in the feed.

Jan 1, 1990

By Silitonga M

Generally, the acceptable parameter for predicting the intensity of ground vibration due to a blast is the amount of explo ive u ed and the distance from the explo ion. A eries of closely controlled tests were carried out and it was observed that the degree of confinement or burden of an explosive charge play an important role in the variation of the transmitted magnitude of the shock wave through the ground.The intensity of the shock wave increases with burial depth or with greater confinement of an explosion until a critical depth is reached.Beyond this critical depth, the magnitude of ground vibration remain constant. This is an important finding, which explains the anomalies between the expected level and the monitored ground vibration in a particular situation.

Jan 1, 1984

By Ali Altway, M. E. Tunison, T. W. Chapman

Simulations of various contactor configurations for simultaneous extraction or stripping of two metals reveal the dependence of conversion and selectivity on operating and design parameters A two-film mass transfer model is used to provide the rates in countercurrent column and stirred-tank cascade calculations Even in these mass-transfer-limited cases the stoichiometry of the extraction reactions introduces nonlinearities and interactions between the two metal transfer rates, but these can be represented In a suitable model One conclusion is that a countercurrent column should be considerably more efficient than a cascade of mixer-settlers of comparable size.

Jan 1, 1981

By Biao Zhou, Qian Li, Kuo-Chih Chou, Yi-Long Liang, Jie-Yu Zhang, Qun Luo

"In this work, the phase transformational behaviors and microstructural characteristics of 60Si2CrVAT spring steel were systematically investigated as a function of applied cooling rates in the range of 0.l-10°C/s. A quenching deformation dilatometer was used to austenize and quench. The dilatometric curves between length changes and temperature of samples suggest three characteristic stages could be identified as different ranges of cooling rates, which meets well with metallographic examination and the measured hardness results. As the cooling rate increases, the structure transformed from pearlite, granular bainite to finally martensite. The F + P and B zones are completely overlapping in continuous cooling transformation (CCI) curve, which indicates that this steel is difficult to become single bainite and shows good hardenability.IntroductionThe 60Si2CrVAT, a high-carbon low ally super-high strength steel developed from the ?OCT 60C2XFA and 60Si2MnA, is often used for coil spring of heavy vehicles and high-speed railway by hot deformation or cold deformation [1-3]. The addition of Si improves relaxation resistance significantly, through the refinement of tempered carbides as the result of the retardation of E -carbide conversion to cementite during tempering. Due to its deleterious effects on decarburization and toughness, the maxinJum content of Si has limited to 1.5 or 2.0% [4-5]. Additionally, V and Cr can improve sag resistance due to the precipitation of fine carbonitrides during hot rolling [6-7]. To best of our knowledge, the strengthening by precipitation of alloy carbides of Cr and V often referred to secondary hardening [8]."

Jan 1, 2013

By L. E. Veki, S. M. Luukkanen, J. P. Karvonen, J. O. Leppinen

Today there is a consensus that xanthate adsorption on sulfide minerals is primarily controlled by redox reactions occurring at specific potentials on these semi-conductive minerals. Consequently, it is possible to control xanthate adsorption by controlling electrochemical conditions in the system by using oxidizing and reducing agents. The scope of this study was to investigate the possibilities to increase the selectivity of Cu-Fe-Zn ore flotation by applying electrochemical control in the conditioning of the flotation feed. In this work, mild steel grinding in a nitrogen atmosphere was used as the basis to provide a negative starting potential and minimize the amount of oxidation products on sulfide mineral surfaces. To study how different potential levels affect flotation results, a controlled conditioning procedure was utilized maintaining potential at a desired level by titrating the pulp with air. Xanthate adsorption kinetics during conditioning was examined by taking pulp samples for spectrophotometric analysis and laboratory flotation tests were conducted for samples that underwent the controlled conditioning procedure in the potential range of -200mV to +200mV vs. SHE. A clear correlation was detected between chalcopyrite recovery and the potential during controlled conditioning indicating that there was a constant increase in chalcopyrite recovery when the potential was shifted to more anodic values. It is possible that utilizing potential control in the conditioning stage, a smelter grade copper concentrate can be achieved directly in rougher flotation without cleaning stages. Conditioning in favorable conditions had significant positive effects on flotation selectivity of chalcopyrite. The improvement in copper concentrate grade being predominantly caused by the depression of pyrite. By applying the controlled conditioning procedure pyrite recovery in rougher flotation was reduced even low as under 1%, while in the tests without controlled conditioning, pyrite recovery varied between 7.5 – 65.7%. The result of this work indicate that affecting collector adsorption by electrochemical control in the conditioning stage can provide significant improvement in sulfide mineral flotation and industrial applications could lead to decreased chemical consumption, reduced equipment and maintenance costs.

Jan 1, 2018

By M. Shriwas, F. Calizaya

"Controlled recirculation may be considered as a beneficial means in mines of cold climate, where heating of air is required, and in deep or extensive mines, where cooling of air is required. Controlled recirculation can be designed by proper sizing of the booster fans with respect to main fan. Intuitively, it seems that the buildup of methane at the face will cease when a steady state condition is attained, and also that, at that same time, the maximum concentration at the face will remain same as in the return air. This supposition is proved by mathematical analysis that considers uniform mixing of methane in air in successive cycles of recirculation. This study includes two scenarios to show the effect of controlled recirculation on methane concentration in a sample network. Firstly, when recirculation crosscut exists near the working face; secondly, when recirculation crosscut exists away from the working face. The later scenario shows lesser buildup of methane concentration than the former one. INTRODUCTION The controlled recirculation is designed purposefully to allow a partial fraction of used air that increases the air velocity due to increased quantity of air and consequently allows effective dilution of contaminants to improve local ventilation condition at the working face. It can be designed by proper sizing of booster fan with respect to main fan in a ventilation network. Controlled recirculation may be categorized as crosscut, in-line or combined system based upon the configuration of the booster fan locations in a district ventilation network. Research on controlled recirculation has shown numerous benefits of controlled recirculation especially in deep or extensive underground mines, where further heating or cooling is required (Calizaya 1990; McPherson 1993 and Jones, 1987). However, fear of buildup of concentration has misled the mining communities to view the controlled recirculation as a hazard and deprived the mining industry to derive benefits from recirculation. Intuitively, it seems that the buildup of methane at the face will cease when a steady state condition is attained, and also that, at that same time, the maximum concentration at the face will remain same as in the return air. This supposition is proved by mathematical analysis that considers uniform mixing of methane in air in successive cycles of recirculation. This study includes two scenarios to show the effect of controlled recirculation on methane concentration in a sample network. Firstly, when recirculation crosscut exists near the working face; secondly, when recirculation crosscut exists away from the working face. The later scenario result shows the less buildup of methane concentration than former scenario result."

Jan 1, 2016

By M. J. McPherson

The legislation that prohibits the recirculation of air in coal mines was formulated because of the fear that concentrations of airborne pollutants would rise to dangerous levels. This paper undertakes a simple analysis of the effects of a controlled recirculation system on the gas concentrations in headings. It is shown, through an algebraic formulation and a numerical example, that a properly planned system of controlled recirculation leads to a reduction in the maximum general body gas concentration that occurs in a heading.

Jan 1, 1988

By Andrzej Warczok

Intensive smelting of copper concentrate in Teniente Converter (CT) leads to the production of high grade matte and highly oxidized slag. Smelting slag is processed in Teniente vascular slag cleaning furnace. The slag composition and forms of copper affect the slag cleaning process and final copper content. Converting of high grade matte in Pierce-Smith converter faces some difficulties in proper slagging of iron oxides. Overblowing in copper making stage allows for slag liquidation but leads to high content of copper oxide in converter slag. Converter slag recycling into CT results in the increase of the participation of oxidic copper. Separate treatment of converter slag and its impact on the forms of copper in CT slag has been analyzed. Thermodynamic properties of a system and kinetic limitations pointed out the negative effect of converter slag recycling on the forms of copper and copper recovery in slag cleaning stage. Experimental results of slag cleaning tests in a crucible scale as well as microscopic examination of laboratory and industrial slag samples supported the above analysis and permitted to formulate recommendations of separate processing of converter slag. Keywords: copper, losses, slag, recycling

Jan 1, 2001

By Dagoberto Brandão Santos, Kairo de Barros Guimarães, Túlio Magno Füzessy de Melo

The effect of the cooling conditions on the microstructure and hardness of a Dual Phase hot-rolled steel 800 MPa strength was investigated. Simulations of the cooling conditions using a dilatometer were carried out from samples of a hot rolled coil with variations of the intermediary temperature from 620 to 740°C, isothermal holding time between 1 and 10 s and coiling temperature between 50 and 400°C. In addition, two CCT (Continuous Cooling Transformation) diagrams were developed to evaluate the effect of the isothermal holding time on the phase transformations of the remaining austenite. It was observed that the intermediary temperature has a strong influence on the kinetics of the phase transformation, as well as the isothermal holding time influences the amount of ferrite formed and, consequently, the final microstructure and hardness of the material. The coiling temperature did not cause significant changes in the amount and morphology of the ferrite, but a gradual replacement of martensite with bainite was observed, which, in addition to the self-tempering effect, contributed to the hardness reduction.

Oct 1, 2019

By F. Khomamizadeh

In this study the effect of solidification rate, T6 and T7 heat treatments on thermal fatigue resistance of A319 aluminum was investigated. Increasing of the solidification rate improved the thermal fatigue resistance of the alloy by refinement of the microstructure. The most sensible areas for thermal fatigue crack growth were the eutectic zones, T6 and T7 heat treatments improved the thermal fatigue resistance of the alloy by enhancing of the matrix resistance against the crack propagation. The slight reduction of the thermal fatigue resistance after T7 heat treatment is attributed to coarsening of the precipitates which reduces the matrix resistance.

Jan 1, 2005

By D. L. Martin, E. R. Parker

IN a previous paper, one of the authors observed that the rate of cooling from the anneal prior to testing greatly influenced the life of copper under sustained load at 200°C. Furnace-cooled bars of oxygen-free copper (with, and without silver) had a life four to twenty-five times that of the water-quenched specimens. The addition of 0.054 per cent silver to the oxygen-free copper increased the life at a stress of 20,000 lb. per sq. in. from about 2 hr. to 50 hr. Fractures in these bars were intercrystalline. An explanation was advanced to account for the profound influence of cooling rate on the rupture properties at 200°C. The suggestion offered was that at the high annealing temperature the minor constituents are distributed at random. By water quenching, this condition is maintained at room temperature, whereas furnace cooling permits some segregation at the grain boundaries. The higher concentration of the minor constituents in the grain boundaries results in a strengthening, so that a longer life at a given stress and temperature results. Small amounts of cadmium or manganese have also been found to increase the life of copper at 200°C., and to a much greater extent than silver .2 The increase in the long-time strength of copper resulting from small additions of cadmium or silver appears to be related, indirectly at least, to the higher softening temperatures of such alloys. The elements, such as silver or cadmium, which greatly increase the rupture life of copper also cause large increases in the softening temperature. As little as 0.05 per cent of cadmium or silver is sufficient to raise the softening temperature more than 100°.3,4 The effects of cooling rate and of minor constituents on the rupture properties are of considerable fundamental as well as practical interest; therefore a more detailed study of their nature was conducted and is reported in this paper. EXPERIMENTAL PROCEDURE Materials The materials studied in this investigation may conveniently be classified in two groups: one consisting of a wide variety of commercial coppers, and the other composed of special high-purity, laboratory-prepared coppers. The commercial materials were tested to determine whether or not the effect of cooling rate occurred with all coppers, whereas the high-purity coppers were investigated in order to establish a basis for evaluating the effect of minor constituents on the rupture properties. In Table I are given the analyses of the coppers tested. The samples I to 6 are commercial materials and were obtained for the most part from stock supplies.*

Jan 1, 1943

By Ari Jokilaakso, Junjie Shi, Zhuo Chen, Pekka Taskinen, Xiang Gao

The amount of copper flash smelting slag has increased during the recent years along with an increasing slag-to-metal ratio. During slag tapping, some copper sulfide is mechanically entrained. As a result, it is necessary to recover copper matte from the slag by suitable methods. At present, the most common way is slow, controlled cooling in a transfer ladle. However, research on the detailed effects of slow cooling and the function of slag modification is rare. This paper described experiments that were performed at different cooling rates (0.5, 1.5, 3, and 7 °C/min), with and without additive. A detailed characterization of the copper-rich phase and its particle size was subsequentlymade using SEM-EDSmicrographs and image analysis software.With a decrease in cooling rate, the particle size of the copper-rich matte phase became larger. The addition of gypsum and carbon as a slag modifier affected the size of the copper-rich phase slightly, and its chemical composition was modified compared with the experiments without additive.

Jul 31, 2020

By Jinsheng Wang, Zhixiong You, Xuewei Lv, Yu Zhang, Jie Dang

Electro-titania slag is generally used as the raw material for titanium dioxide production by sulfate process. The phase composition of titanium as well as their disseminated grain size have significant effect on the acidolysis of titanium. Anosovite is considered as the most favorable Ti-bearing phase due to its high acidolysis ef ficiency, while silicates and rutile are not soluble in concentrated sulfuric acid. Different cooling rates will play a significant effect on the phase structure and particle size, which directly affects the acidolysis ratio of titania slag. In this paper, the influence on acidolysis ratio of titania slag at different cooling rates was studied. The results revealed that slower cooling rate resulted in the formation of larger particle size and a comparatively higher acidolysis ratio was obtained. On the contrast, rapid cooling was disadvantageous to the leaching of titanium as the smaller particle size anosovite was wrapped by glass phases.

Mar 1, 2018

By Gülhan Özbayoglu, Yusuf Ziya Akgök

The effect of cooling rate on the flotation behaviour of copper slags of flash smelter plant in Samsun was investigated. Fresh molten slag was solidified in laboratory scale in three different ways. All the samples were characterized by chemical and mineralogical analyses. The chemical analyses showed that samples prepared from fresh slag had 0.9 to 1 % Cu with 40 % Fe and 30 to 32 % SO2. Old pit slag samples contained between 1 to 3% copper. Microphotographs showed that rapidly cooled slags showed fine size distributions, e.g. the copper grains in granulated slag had sizes in 1-2 microns. On the other hand, the size of copper grains in slowly cooled slags increased above 40 microns. Flotation tests carried out by using potassium amyl xanthate and Flotanol-C showed that slowly cooled slag reduced the copper losses in the tailing and improved the grade of concentrate. Under the light of laboratory investigation, the pit dimensions of Samsun Plant have been modified which resulted in a pronounced improvement of the grade and recovery of concentrate produced at Samsun slag flotation circuit.

Jan 1, 1995