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By J. Alberto Vázquez M.

A sensor employing yttria-stabilized zirconia (YSZ) was used to determine the oxygen activity of molten copper at laboratory scale at temperatures of 1200° and 1300 dc. The reference electrode was a Ni-NiO mixture. The amount of the deoxidizing agent (CU3P) ranged from I to 3% of the mass of copper. Thermodynamic analysis of the Cu-O-P liquid system was carried out to predict the required deoxidizing agent and the final composition of the molten copper. Both results, calculated and experimental, show that the oxygen removal is more efficient at lower temperatures. The kinetics of the deoxidizing reaction is very fast in the first minutes of the treatment. A metalography analysis of rapid cooled samples show the oxygen and phosphorus distribution

Jan 1, 2003

By G. F. Vander Voort

The accident at Unit No. 2 of the Three Mile Island nuclear reactor (TMI-2) on 28 March 1979 was the worst nuclear accident in US history and crippled the nuclear industry. An international Vessel Investigation Project was formed to assess the integrity of the vessel. However, it was not possible to remove specimens from the lower head until January?March 1990. Fourteen of the fifteen specimens removed by electrical discharge machining were from under the debris pile that accumulated on the lower head due to melting of approximately 19 000 kg (45%) of the core. Specimens were previously cut from the lower head of a cancelled reactor of very similar size and design destined for Midland, Michigan. These specimens were subjected to controlled heating cycles with peak temperatures from 800°C to 1100°C for periods of 1 to 100 minutes. The initial study qualitatively compared the structures in the 15 specimens from TMI-2 to the control specimens from the Midland lower head. The writer used the same specimens and employed microindentation hardness traverses, electron microprobe analysis, and selective etching followed by quantitative metallography (by image analysis) to obtain a far more detailed description of the thermal exposure experienced.

Jan 1, 2013

By M. Z. Rashad, H. A. El-Sageer

The intersections of numerous joint sets at the surface of tunnels of the Abu-Tartour project in Egypt create blocks of irregular shape and size in the rock mass. Although most of these blocks are unable to move into the free space of the tunnel, a few key blocks are capable of such movement. In addition, as soon as they move, some restrained blocks will be liberated. The aim of this work is to find the removable key blocks of the walls, floor, roof and corners of a portion of the tunnel under jointed surface rocks and then determine the best tunnel direction.

Jan 1, 1993

By P D. Katsabanis

The dynamic tensile strength of geomaterials is known to be highly dependent on the strain rate of the load applied. This is significant in applications where the material is subjected to shock waves and impact loading. This paper proposes the use of a simplified method to determine the dynamic tensile strength of hard brittle rocks using an explosively impacted version of the Hopkinson Pressure Bar. A compressive stress wave was propagated in a sample, representative of the material of interest, by detonating a small charge at one end of a cylindrical sample. The tension wave, generated upon reflection at the free face, causes spalling in brittle materials. Strains at four points in the specimen were continuously measured and the dynamic tensile strength was determined by applying the one-dimensional wave theory.

Jan 1, 2010

By Blair R. Benner, Ronald J. Roman

The rate of acid leaching of malachite from a sandstone ore was shown to be controlled by the diffusion of H+ ions through the host rock. The kinetics of the reaction can be expressed by a shrinking core model. Equations for calculating effective diffusivities from an "infinite" slab and a cylindrical core were derived. The effective diffusivity, of H+ ions in a sandstone ore was measured.

Jan 1, 1975

The purpose of this work is to determine the equilibrium-state of the aqueous-solution which is produced by the leaching processes, including natural weathering of pyrite minerals. The latter can lead to acid-mine-drainage (AMD). The ferric iron species (Fe3+) resulting from bacteria-catalysed oxidation of ferrous iron (Fe2+), in the presence of water and air, is known to bring about steady-dissolution of minerals chalcopyrite (CuFeS2), sphalerite (ZnS), pyrite (FeS2), and so forth. Good-aeration, relatively high-porosity and sufficient bacterial activity tend to promote leaching in waste-rock-dumps. The composition of the aqueous-phase that accumulates in the pore-space (or in open-pits) is of practical interest as it would strongly influence the leaching of both sulfide and non-sulfide minerals. Since the reactions among the various ionic species occur relatively fast, the solution-phase may be regarded as approaching a state of virtual-equilibrium and it is possible to determine by computation the respective concentrations of the many dissolved species. For the Cu-Fe-H-O-S system, these species may include: H+, Fe2+, Fe3+, Cu2+, HSO4-, SO42-, OH-, CuSO4o, H2O, Fe(OH)+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, Fe(SO4)+, Fe(HSO4)+, Fe(HSO4)2+, and Fe(SO4)2-. The aqueous-system which may be constituted from appropriate mole-quantities of H2SO4, FeSO4, Fe2(SO4)3, and CuSO4 is in fact the result of various natural processes (reactions) and due respect must be accorded to the extents of these reactions. The present model computes the equilibrium molalities of the foregoing ionic and neutral aqueous species, using the iterative equilibrium constant method that ensures strict-adherence to charge-balance and elemental molar-balance constraints. The dissolving sulfide-minerals (FeS2, CuFeS2) consume Fe2(SO4)3, H2O, and O2 and yield FeSO4, H2SO4, and CuSO4 while the aqueous-phase tends to become progressively acidic (declining pH) reflecting the gradual increase in the extents of sulfide-dissolution reactions. The equilibrium-state of the solution-phase is computed for specific set of values for the extents of respective reactions. The temperature and pressure of the system are 25¦ C (298.15 K) and 101.325 kPa (1.0 atm), respectively. The mica-like minerals such as the biotite [H2K(Mg,Fe)3Al(SiO4)3] tend to consume much of the H2SO4(aq), with the extracted K+, Mg2+, Fe2+ and Al3+ ionic species accumulating in the solution. The precipitation of the jarosites (potassium, hydronium, or ammonium) contributes to the removal of ferric and ferrous species from the solution-phase. In the present work, the emphasis is on predicting the compositions of the aqueous- and condensed-phases with advancing time or increasing æextent of reactionÆ. The results of such calculations are compared to published data on raw AMD (acid-mine-drainage).

Jan 1, 2008

By S. M. H. Ahmadi, K. Barani, F. Moradpouri, R. Ghaedrahmati

As exploration is time-consuming, costly, and risky, determination of the erosion surface of a metalliferous deposit before geophysical surveying and exploration drilling might be very helpful. Geochemical haloes can be used to determine whether the erosion surface is supra-ore or sub-ore and thus reduce the risk of exploration operations. The aim of this investigation is to determine the erosion surface of the North ROK porphyry deposit (NRPD) in northwestern British Columbia in Canada using linear productivity (LP), which is the content of an element defining the halo multiplied by the width of the halo. A total of 2045 soil samples from the B horizon were analysed using ICP-MS for 36 elements, including Cu, Mo, Pb, Zn, Au, As, Ag, Ni, Co, Fe, and Mn. The data-set was snalysed to obtain the statistical parameters and the elements Cu, Mo, Pb, and Zn were chosen to calculate the linear productivity and the total linear productivity. These four elements were modelled using probability plots to identify and separate subpopulations in terms of anomalous haloes and background, including the threshold values of each subpopulation. The results of the probability plot modelling and thresholds values were then used to map the distribution of each element in a GIS to calculate the linear productivity. The total linear productivity indicated that the erosion surface is supra-ore. Finally, a 3D orebody model of the Cu, Mo, Pb, and Zn distributions was constructed using borehole data and used to validate the results.

Feb 6, 2023

By R. A. Thomas, C. D. Litton

"The objective of this study was to develop a laboratory-scale method to rank the ignition and fire hazards of commonly used underground mine materials and to eliminate the need for expensive large-scale tests that are currently being used. A radiant panel apparatus was used to determine the relevant thermal characteristics of the materials: time to ignition, critical heat flux for ignition, heat of gasification, and mass loss rate. Three thermal parameters, TRP, TP1, and TP4, were derived from the data, then were developed and subsequently used to rank the combined ignition and fire hazards of the combustible materials from low hazard to high hazard. The results compared favorably with thermal and ignition hazards of similar materials reported in the literature and represent a simpler approach to quantifying these combustible hazards. INTRODUCTION The potential fire hazard from combustible mine materials is a major concern that can impact the safety of mine workers. Combustible materials tend to be solids and within this category there exist degrees of flammability and fire resistance. These materials may be readily ignitable or they may be able to withstand high temperatures and high heat fluxes. Presently, no simple methodology exists to assess these possible fire behaviors and quantify the resultant fire hazards. Thus, better knowledge of the thermal properties and chemical characteristics of combustible materials is of great importance to the safety of mine workers. Tewarson [1994] developed a methodology which he subsequently used to evaluate the ignition and fire resistant properties of combustible mine materials, but these efforts are more than 20 years old, and do not include many of the new materials used in mines today. The standard practice that has evolved for a combustible material to be approved by the Mine Safety and Health Administration for use in underground coal mines is to conduct extensive and costly large-scale experiments on each new material that is used in a particular mine operation. Results of such tests provide pass/fail answers to the questions of a material’s flammability or fire resistance, yet they provide little, if any, information that will lead to a better understanding of the basic mechanisms involved. Therefore, there is a need to quantify material flammability properties and to develop a methodology to rank the ignition and fire hazards of commonly used underground mine materials. During the heating and ignition stages of combustible materials, properties such as smolder susceptibility, minimum surface temperature for ignition, thermal conductivity, heat capacity, density, and heat of gasification are known to be important [Apte, 2006]. During the flaming stage, additional parameters, such as the heat of combustion, heat release rate, flame spread rate, yields of soot/smoke, and toxic gas production become more important as the flame is sustained and spreads. In very general terms, the heat flux incident on the surface of a solid combustible not only controls the rate of temperature increase of the local fuel surfaces, resulting in expulsion of fuel vapors that sustain the flaming process, but also the heating of other combustible surfaces that subsequently ignite and spread flame."

Jan 1, 2015

By R. A. Thomas, C. D. Litton

"The objective of this study was to develop a laboratory-scale method to rank the ignition and fire hazards of commonly used underground mine materials and to eliminate the need for the expensive large-scale tests that are currently being used. A radiant-panel apparatus was used to determine the materials’ relevant thermal characteristics: time to ignition, critical heat flux for ignition, heat of gasification, and mass-loss rate. Three thermal parameters, TRP, TP1 and TP4, were derived from the data, then developed and subsequently used to rank the combined ignition and fire hazards of the combustible materials from low hazard to high hazard. The results compared favorably with the thermal and ignition hazards of similar materials reported in the literature and support this approach as a simpler one for quantifying these combustible hazards. Resumen ¦ El objetivo de este estudio fue el desarrollo de un método a escala de laboratorio con el fin de clasificar los peligros de ignición y fuego de materiales comúnmente usados en minería subterránea y la eliminación las pruebas costosas y a gran escala que se realizan actualmente. Se usó un aparato de panel radiante con el fin de determinar las características térmicas relevantes de los materiales: tiempo de ignición, flujo de calor crítico para ignición, calor de gasificación y tasa de pérdida de masa. Se derivaron tres parámetros térmicos de los datos: TRP, TP1 y TP4, luego fueron desarrollados y subsecuentemente usados para clasificar los peligros combinados de ignición y fuego de materiales combustibles, de bajo riesgo a alto riesgo. Los resultados tuvieron una comparación favorable con los riesgo/peligro térmicos y de ignición de materiales similares reportados en la literatura y apoyan este enfoque como uno más simple para la cuantificación de estos riesgos combustibles"

Jan 1, 2015

By M Carr, K Williams, W Chen, J Plinke

The depletion of iron ore deposits at the face of the mine site dictates the necessity for the exploitation of formerly less attractive orebodies to meet the demand of the modern world. These orebodies will typically be found close to or even beneath the water table where an increasing clay and moisture content will result. Problematic iron ores, colloquially termed as ‘wet and sticky’ material (WSM), can have a significant impact in the material handling stream due to the expensive downtime of processing equipment, which is attributed to the inter-particle and boundary cohesion and adhesion forces of the bulk material.In order to gain a better understanding of the causes of poor handleability, experimental test methods to determine wall adhesion, and inter-particle adhesion within bulk materials were developed. Based on the combination of wall adhesion and inter-particle adhesion measurements, with traditional methods of assessing bulk material handleability, a new method to assess the potential of bulk materials to cause handling problems is proposed. This method reduces the multitude of factors leading to problematic behaviour to a handleability index (HI) [0,1], which is easily assessed and understood. The method is suitable for adhesive materials and applicable for a wide range of material flow, from gravity reclaim stockpiles to transfer chutes and carry back on conveyor belts.Additionally, this research presents an assessment of the HI derived by experimental testing of three iron ore samples. A clear understanding of the problematic behaviour of the iron ore samples is achieved with the use of dust extinction moisture (DEM) tests, which indicates the regions where problematic behaviour may be experienced on-site.CITATION:Carr, M, Plinke, J, Williams, K, Roberts, A and Chen, W, 2017. Determination of the handleability index of adhesive bulk materials, in Proceedings Iron Ore 2017, pp 503–510 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By P. Creevy, P. F. Mousset-Jones, G. Danko, A. D. S. Gillies

The surface heat transfer coefficient is measure of the rate of heat transfer from exposed rock surfaces to the ventilating air. Knowledge of its value is of particular importance to accurately simulate the early stages of rock cooling after the opening of an excavation. A number of theoretical formulae for the calculation of the coefficient are available for use in mine climate simulation. However, direct determination by in situ measurement is preferred. Instrumentation, which has been developed for in situ mine measurement, and experimental procedures involving measurement at varying air velocities, are described. In a major study covering four Australian underground mines, the system has been used to determine surface heat transfer coefficients. A direct relationship was clearly established between the measured surface heat transfer coefficient and air velocity. Comparison is made between experimental results and those previously measured or calculated by others. The relationship established can be described by an equation and holds for air velocities above 0.4 mls. The derived relationship was con- firmed at all mines tested and is independent of geology and tunnel dimensions found in modern mines.

Jan 1, 1991

By R. E. Gürtunca, D. J. Adams

Writen contribution by J.F.Curtls The subject mater of the paper is interesting in that, instead of 'numerical modeling based on elastic theory' being used for the prediction of energy release rate (ERR) in relation to various types of stope support, including backfil, use is made of stresses in the backfil in an atempt to corect the numerical modeling. Authors' reply to J. F. Curtis We thank Mr Curtis for his contribution to our paper. First of al, it should be emphasized that the object of the paper is not to address the validity of ERR as a tool for the assessment of seismic events or rockbursts, but to determine an in situ modulus for the rockmass with the aid of backfil measurements. Writen contribution by T.R. Stacey Although the authors of the above-mentioned paper have presented some good and interesting information, the title of the paper, and the recommendation that such an in situ modulis should be used for calculations of energy release rate (ERR), are viewed with some concern. The reasons for this concern are as follows. Authors' reply to T.R. Stacey Dr Stacey's comments on our paper are appreciated; we should like to address his concerns as follows.

Jan 1, 1991

By Eurípides do Amaral Vargas Jr., J. A. de Mello Franco

"It is frequently necessary to excavate a tunnel for Civil Engineering purposes, or wells for petroleum exploitation, in laminated rock mass like schists or phyllites or in highly foliated gneisses. The determination of the pre-existing in situ stresses is essential, in order to assure the stability of these excavations. In most cases, the pre-existing triaxial stress field is arbitrary in relation to the tunnel or well axis. For these rock masses the concept of Generalised Plane Strain can be correctly utilized.There are closed form solutions for the calculation of stresses in anisotropic rock masses under Generalised Plane Strain conditions (Lehknitskii, 1981 and Hong , 1994). Based on these analytical solutions, established for the cases of Generalised Plane Strain, a synthetic problem will be formulated: the theoretical in situ stress tensor acting on this rock mass will be determined, with the aid of Bayesian Inverse Problem Techniques, as developed by de Mello Franco (2009). Additionally, the reliability of results obtained will be evaluated, in accordance with the research performed by this author. INTRODUCTIONThe Inverse Problem Technique, as developed in the paper, is based on the definitions and concepts obtained from the current literature and used for the solution of Inverse Problems, but the innovation to be presented is the utilisation of Bayesian Techniques and the determination of the reliability of the results obtained. This will be shown in a synthetic example where the determination of the in situ stress tensor, from strain measurements in a drill hole is supposedly performed. It is assumed that this drill has its axis arbitrarily placed in relation to the rock mass. Generalised Plane Strain conditions will hold for use with problem. The equations of Beltrami – Mitchel, in agreement to Lekhnitskii (1981) and Ong (1994), will be used in this synthetic case, for calculating strains, hypothetically measured in the hole before the final excavations. Finally a synthetic example for the determination of the in situ stress in a fully anisotropic rock mass, based on Bayesian Techniques and its reliability, developed in de Mello Franco (2009) is presented."

Jan 1, 2015

By V. Sheikhzadeh, M. Saghaeian, N. Esmaeili, R. Hejazi, A. Dehghani Ahmadabadi

High Pressure Grinding Rolls (HPGR) are mostly used prior to pelletising processes to increase the specific surface area (SSA) of iron ore concentrate. For expressing SSA, the Blaine index is utilised as one of the most important dimensional properties of iron ore pellet feed. ISO 21283 is a standard test method that explains the manual of Blaine air-permeability apparatus for determination of this parameter. In this standard, the disaggregation method is based on passing the minus of 1 mm samples from the 0.150 mm sieve. The disaggregation process has an effective role on the results of Blaine airpermeability test especially for regrinding HPGR products. In this research, firstly the Blaine index of samples was measured without disaggregation. Following this, disaggregation was done by passing the minus of 1 mm samples through three sieves with different dimensions, 0.150, 0.090 and 0.045 mm, separately, and the Blaine index was calculated for each one. Finally, lab-mill with rubber balls, called Jar mill, was investigated as another option. Screen analysis and image analysis with SEM were performed to evaluate the effects of the sample's disaggregation on the size distribution and agglomeration of samples. The results showed that the disaggregation method with sieve size 0.150 mm, according to ISO 21283, was not applicable for HPGR products because the particles were still stuck together. In addition, the disaggregation method with the sieve size 0.045 mm or with Jar mill offered reasonable results. Keywords: Disaggregation, Blaine index, specific surface area, regrinding HPGR, ISO 21283, Jar mill

Jan 1, 2020

By J Edmund Hay

Previous work by the Bureau of Mines to develop a test for determining the initiating strength of commercial detonators has been modified and extended. Recently reported results by the Bureau used a homogeneous liquid explosive to avoid the complicating effects of inhomogeneities; however, due to the belief that there may be essential differences between the initiation mechanisms of simple liquids and multi-phase mixtures and the fact that almost all commercial explosives are in the latter category, the experiments have been modified accordingly. The acceptor explosive is now a mixture of explosive-grade ammonium nitrate (AN) prills, methanol (MeOH) and nitromethane (NM). An additional change has been the use of the United Nations (UN) cap sensitivity test configuration in which the detonation witness is the degree of compression of a lead block, which is a quantitative measure of the response of the explosive. Results indicate that this mixture has sufficient range of sensitivities to be useful in comparing the strength of commercial electric detonators.

Jan 1, 1993

By J Edmund Hay, T S. Bajpayee

The Bureau of Mines is developing a test to determine the initiating strength of commercial detonators. Various tests of "detonator strength" are in use, but many of them do not correlate well with each other, and so far, there is little evidence that any of them correlates well with the ability of detonators to initiate detonation in an explosive. Therefore, the Bureau decided to attempt a measurement of the ability of detonators to initiate detonation. To this end, an explosive mixture of adjustable sensitivity was developed. This mixture was nitromethane sensitized with ethylene diamine, the sensitivity being "fine-tuned" by the addition of nitropropane.

Jan 1, 1992

By J. Mark Gronseth

The instantaneous shut in pressure often times is not a well defined feature of pressure-time records from in situ stress determinations by hydraulic fracturing. As the applications of in situ stress data become more sophisticated, the grea5er the need for an unambiguous method with which to identify the instantaneous shut in pressure becomes. Controlled experiments suggest that the instantaneous shut in pressure should be equated with the pressure at the inflection point of the pressure-time record following shut in. A method for determining this value is presented. Often times the minimum instantaneous shut in pressure determined after several pressurization cycles is the best estimate of the stress acting perpendicular to the fracture plane.

Jan 1, 1982

By A. Bruynesteyn

The results of a 2 phase evaluation program designed to determine the amenability of an oxide ore from the Butte, Montana mine of the Anaconda Company to a sulfuric acid leach is presented. In the phase 1 preliminary evaluation, using roll tests and percolation leaching in small columns, it is shown that the ore is highly extractable at low acid consumption ratios. In the phase 2 confirmatory tests in large columns on l-l.5 tons of material, the amenability of the ore to the leaching process is proven and pregnant solution grade profiles from planned commercial heaps established.

Jan 1, 1978

By G. Deschênes

Following a successful investigation on the Central Zone sample, a cyanidation study was conducted on an ore sample from the AD-MW Zone of Clarence Stream Property, owned by Freewest Resources Canada, to develop a leaching strategy to extract gold. At a grade of 6.48 g/t, gold is present in the forms of aurostibite, free gold and electrum. The ore contains 4.3% berthierite/gudmundite, 1.3% pyrrhotite, 0.7% pyrite, 0.07% stibnite and 0.9% arsenopyrite. Similar to the Central Zone, the extraction of gold from the AD-MW Zone can be performed at atmospheric pressure, pH 10.5 and with a low concentration of cyanide. The grind size had no effect on gold extraction between a P80 of 28 to 71 µm. The oxygen and cyanide requirement significantly increased with a ?ner grind. Consequently, a very close control of cyanide addition is required to minimize passivation of gold. Lead nitrate, added in the pretreatment, increased the extraction of gold by 2.3%. Leaching at pH < 10 improved gold extraction but increased the cyanide consumption by 5%. Passivation of gold occurred when the pretreatment was longer than 2 hours. A longer pretreatment reduced the cyanide consumption by 5%. Mineralogical characterization of the leach residue with no gravity pretreatment prior to leaching indicated the presence of unleached gold grains and passivated gold grains. Removal of coarse gold by gravity increased the extraction by 2.8% (leach residue at 0.74 g/t Au). Increasing the DO to 16 ppm or the lead nitrate from 500 to 1,000 g/t increased the overall gold extraction to 90.4% (leach residue at 0.62 g/t), which is the maximum gold extraction obtained. The leaching parameters were 800 ppm NaCN, DO 16 ppm and pH 10.5 for a duration of 120 hours. The associated cyanide consumption was 4.0 kg/t. Gold leaching was not sensitive to cyanide concentration. Reducing the cyanide concentration to 250 ppm resulted in a gold extraction of 89.5% with a cyanide consumption of 2.6 kg/t.

Jan 1, 2009

By Lu S, Jiang Y

The conventional transportation system in open pit, a to u.* itc:,~> truck., to carry the ore along the ramps. Normally, the transportation distance increases greatly as mining progresses deeper. A new approach to overcome the above disadvantage is to adopt a buried roadway by which ores is transported by conveyors from the mining area to the outside dump in the shortest distance so that the production efficiency is greatly increased. Maintenance of the buried roadway in a good working condition is the key factor that determines the success or failure of the proposed approach. This includes the determination of support load, types and structures of support and other related supporting measures. The crucial problem here is to effectively control the load applied on the buried roadway in a certain range that the ordinary support can stand. Based on the theoretical analysis, numerical modelling and physical simulation testing using equivalent material, this paper studies effects on control of the support load by adopting certain measures, for instance reinforcing the surrounding rock and placing the extendable layer between the support and a rock mass. Furthermore, the influence of the dynamic load induced by the movement of heavy vehicles on the stability of the buried roadway is also investigated.

Jan 1, 1995