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By F. Sime, X. Wang, J. D. Miller, T. Akinseye, S. Assemi, L. Pan

Respirable coal mine dust (RCMD) is a complex mixture of carbonaceous and mineral particles with a variation in size and shape. Accumulation of RCMD in the lungs of underground coal miners results in severe respiratory damage and ultimately progressive pneumoconiosis known as the black lung disease. The occurrence of the black lung disease dropped to a low of 2.1% in 1990s but has increased to 3.1% in 2000s [1], prompting more research on coal mine dust mitigation. In addition to surveying the impact of new mining technologies on the size of generated dust and exposure measurement, a comprehensive characterization of physico-chemical properties of RCMD particles are essential for a better understanding of the adverse health effects of coal mine dust. Such vital factors include particle size, surface charge, morphology, composition, and agglomeration state. The respirable fraction of RCMD, has been designated as particles < 10 μm in diameter, and almost all studies on the RCMD toxicity have focused on micron-sized particles. However, recent toxicological studies have shown that nanoparticles (particles with one dimension less than 100 nm) can have a magnified toxicity compared to the larger particles with the same chemistry [2]. Nanoparticles have a much higher specific surface area compared to the same mass of larger particles and are thus more reactive. Most micron-size particles can be cleared by the body’s defense mechanism. However, inhaled nanoparticles can easily deposit in all regions of the respiratory tract and can translocate to vital organs. [2].

Mar 2, 2022

By P. L. M. Wong, N. W. Johnson

Surface analysis by X-Ray Photoelectron Spectroscopy (XPS) of samples taken from the galena flotation section of the Hilton Concentrator of Mount Isa Mines Limited are presented. Flotation rate and pulp chemical data taken during the sampling period are also presented and discussed. Surface analysis suggested that, under normal operating conditions, an overlayer of precipitated calcium sulfate existed at the surface of the sulfide minerals. In particular, there was a decrease in the surface concentration of calcium sulfate for the concentrate samples relative to that occurring on the tailing samples. This suggests that the flotation process was selective against minerals which have calcium sulfate predominating at the surface. Heterocoagulation of hydrophilic calcium sulfate on to the galena surface considerably reduced galena flotation rate. Methods to control calcium sulfate precipitation, which include sodium carbonate treatment of the pulp, are also discussed. Sur- face analysis results of samples taken from the Hilton Concentrator during sodium carbonate addition to the grinding circuit are also presented. This shows clear evidence for the removal of calcium sulfate from the mineral surfaces without concomitant surface precipitation of calcium carbonate. Reasons for the apparent dispersion of precipitated calcium carbonate are discussed. Galena flotation rate was increased by the addition of sodium carbonate apparently due to the removal of interfering calcium sulfate.

Jan 1, 1995

By R. D. Hamilton, W. J. Miles

In 1987, the International Agency for Research on Cancer designated crystalline silica as a 2A probable carcinogen. As a result, crystalline silica is regulated under the Hazard Communication Standard as a probable carcinogen at a concentration of 0.1% or greater in the workplace. Crystalline silica will be listed as "reasonably anticipated to be a carcinogen" by the National Toxicological Program. This designation of crystalline silica as a probable carcinogen has created major issues for the mineral and chemical producer, including labeling, hazard communications, marketing a material with potential hazard exposure, and potential liability. The State of California also regulates crystalline silica under Proposition 65 in products as a carcinogen, based upon the IARC determination that it is a probable carcinogen. More federal and state regulations are anticipated as a result of the IARC classification of crystalline silica and its subsequent federal regulation. Respirable crystalline silica has been regulated as a hazardous dust for many years by OSHA. This regulation was initiated to prevent silicosis, another occupational disease. OSHA has established monitoring devices for determining the concentration of airborne respirable silica in order to measure exposure to this substance. The accurate determination of the crystalline silica content is critical to dealing with these health risks and regulations. In the past, crystalline silica was considered to be safe and, because of its ubiquitous nature, little effort was made to determine or quantify its presence in most materials. The Hazard Communication Standard requires that a1l products containing 0.1% or greater crystalline silica must be properly labeled for this material and its hazard. Unfortunately, the 0.1% threshold was not chosen on the basis of established analytical capabilities for crystalline silica, but results from general limits for potentially carcinogenic chemicals and substances. Numerous methods have been developed for the determination of crystalline silica in a variety of products. However, these methods are not generally applicable since they must be specific for silica in any of its crystalline states and not just for total silica content. Chemical tests for silica are not difficult and quite accurate at the 0.1% level; however, in addition to its crystalline phases, it occurs in amorphous phases and in a wide variety of crystalline and amorphous silicates. In general, there is little correlation between total silica content and crystalline silica.

Jan 1, 1991

By Gift Makusha

Surface subsidence associated with coal mining activities in the Mpumalanga Province of South Africa changes the natural environment in several ways, and current challenges for mining companies include rehabilitation of the natural environment and the prevention of further degradation. To monitor the spatial and temporal evolution of surface subsidence, traditional fieldbased monitoring approaches such as GPS and spirit leveling are employed at a number of locations. However, the resulting measurements are point-based, and frequent revisitations are necessary to map the evolution of surface subsidence basins over time. To address these limitations, differential interferograms derived from repeat-pass satellite-borne synthetic aperture radar (SAR) systems were tested for their ability to measure and monitor surface deformation. The SAR data was captured by the European ERS-1 and ERS-2 satellite and covered a timeframe between 2008- 09-15 and 2008-09-15. The resulting interferograms revealed several features indicative of surface subsidence. Ground truth data confirmed the presence of a subsidence basin, detected using differential interferometry techniques during the 35-day period between April 12, 2008 and May 17, 2008; a maximum vertical deformation of 3.2 cm (1.3 in) was recorded. Interferometric monitoring revealed an eastward migration of the subsidence basin between June 2, 2008 and September 15, 2008 with an additional 4.7 cm (1.9 in) of subsidence observed. This migration coincides with the advance of the working face of the mine during this period. Finite element modeling will be performed in order to model the rates and evolution of surface subsidence haloes as underground mining advances. These presented results demonstrate the ability of interferometric synthetic aperture radar techniques to measure surface subsidence as well as the monitoring of the evolution of subsidence basins over time. This implies that the technique could be included, together with traditional field-based surveying techniques, in an operational monitoring system. With knowledge on deformation rates and subsidence basin evolution, informed decisions on current and future infrastructure development can be made and remedial actions and prevention strategies can be formulated for the problems associated with environmental degradation.

Jan 1, 2011

By J. A. Herbst, C Lo. Y, Z. Rogovin

The identification and quantification of incipient overload conditions in mills have recently been found to be very significant in the design of tumbling grinding mills. To investigate these phenomena, a series of experiments was conducted in a Plexiglas mill operated in both dry and wet modes. For on-stream measurement of the mill charge weight, volumetric filling, dynamic angle of repose, and mill power, an electronic system was developed. The mill was filled to various levels with 19.1-mm (3/4-in.) ceramic balls as grinding media. As feed material, grindable limestone or 3.2-mm (1/8-in.) nongrinding ceramic balls were fed at various steady-state rates to determine the incipient overload conditions. The prediction of overload has apparently been reduced to predicting the feed rate that results in 50% mill filling.

Jan 1, 1988

By K. Raht

LEAD poisoning is perhaps the oldest and, until recent years, the most misunderstood of all industrial diseases. Hippocrates appears to have recognized a relationship in the colic experienced by a patient who worked with metals, and the ancient literature is filled with references to the colics and &apos;dry bellyaches&apos;. The colic and other sequalæ following drinking of lead-bearing waters and, particularly, wines has excited possibly more comment in the older medical literature than any other ætological factor. It was not until1656, when Stockhusen definitely connected the colic of the workmen with the fumes given off in the process, that the true danger to those working with lead was recognized. Unfortunately, something over 200 years elapsed before industry took any note of Stockhusen&apos;s discovery; it remained for Legge and Goodly and investigators of the early 1900&apos;s to forcibly educate their profession and industry to the manner in which lead gained entrance to the body. The work of Legge and Goodly was published in 1912 and the clearness with which these investigators presented the scientific data which they had accumulated will mark this volume as perhaps the first and most important contribution to our modern knowledge of the subject. It also ushered in a period when, in the short space of thirty years, lead poisoning has been reduced from one of the most baffiing and widespread o industrial diseases to one which can be anticipated and controlled. The next great contribution came in 1926 with the publication of the work of the Harvard group. Here, for the first time, was the physiological behaviour of lead laid bare, and it is to the discoveries of these authors that we owe our modern treatment of lead poisoning.

Jan 1, 1941

By Guerney P. J

A suspension of finely powdered ferrosilicon in water is the dense medium used in the gravity upgrading of iron ore, diamonds and other minerals. Ferrosilicon can he lost in the plant through corrosion. The greatest corrosion losses occur when

Jan 1, 1997

By Stephen L. Chryssoulis

The detection and quantification of invisible gold by microbeam techniques is discussed. Ion probe microanalysis is used to quantify the gold content of individual sulphide, sulpharsenide and oxide particles with a detection limit of 0.2 ppmw (g/t). The proton microprobe is used to determine the gold concentration of gangue minerals with a detection limit of 2 - 4 ppm. Using these techniques complete mineralogical balances for gold are obtained to assist in the process selection and optimization. A total of twenty gold and gold-bearing ores have been examined. Selected examples are presented.

Jan 1, 1990

By A. M. Blount

In 1983, a final ruling of the U.S. Occupational Health and Safety Administration (OSHA) specified that chemicals containing >0.1 % of a carcinogenic substance or > 1 % of a substance hazardous to health must be labelled. Amphiboles of the fibrous or asbestos-type must be quantified at levels of 0. I % whereas the status of non-fibrous types is not finally determined at this time. Tremolite and actinolite can possibly be measured to 0.1 % by XRD, but anthophyllite cannot be so measured. Recently the International Agency for Cancer Research (IARC) has designated quartz as a suspected carcinogen, and its quantity must be measured to the 0.1 % level. Thus, it has become Increasingly important to be able to detect and quantify minerals in bulk samples down to low or "trace" levels. It has been found that minerals needing to be quantified can often be concentrated by microcentrifuge and counted by means of polarized-light microscopy. For example, amphiboles in talc samples can be separated by using a heavy liquid (thallium formate-malonate) of density 2.810. Talc floats, and amphiboles sink. After centrifuging, the denser particles are removed from the bottom with a Pasteur pipette and placed in a clean centrifuge tube. Distilled water is added to the tube containing the denser minerals and the tube centrifuged again. After several washings with distilled water, the sample is removed along with a drop of water to a clean glass slide. A drop of 1 .584 refractive index liquid and a cover glass are placed over the dried sample. The slide is scanned for particles greater than 5 um in length and having an aspect ratio greater than 1:3. These are checked for refractive index, sign of elongation and extinction angle to differentiate them from talc particles on edge and other minerals. Amphiboles have all indices greater than 1.584, and talc has all indices equal to or lower than this value. Alternately the heavies at the bottom of the centrifuge tube can be filtered through a nucleopore filter. After the filter has been washed with distilled water and dried, a 1.584 refractive index liquid renders the filter transparent in two of the four extinction positions so that a count of amphibole particles can be made directly on the filter. The refractive index-density method which is so useful for talc powders should be equally useful for other nonsoluble industrial minerals.

Jan 1, 1989

By Curtis Clement

Williamson & Associates, Inc. has developed a marine mineral exploration tool using an induced polarization technology (IP) under license from the US Geological Survey. Developed by Jeff Wynn at the USGS, this method has gone through several prototyping stages and is now in commercial use to map offshore ilmenite deposits. Preliminary results of a recent resource mapping program are discussed as well as potential applications in the detection and quantification of other minerals in marine sediments.

By Theodore James Kurela

Analysis of adverse technical issues has traditionally relied on a snapshot of the state of the operation complemented with both the melt shop’s archived data and eyewitness accounts of adverse events. The GrafTech ArchiTech System is helping EAF shops solve problems faster by combining continuous analysis of information with statistically based alerts of process deviations. After one year of system implementation, a number of cases have been detected and communicated to melt shops worldwide. The objective of this paper is to examine a few of these cases; the early detection, statistical analysis, deviation reporting and the resulting countermeasures implemented.

Aug 17, 2017

When xanthates or dithiophosphates are used as collectors in sulphide ore flotation, adsorbed species may be identified by gas chromatography of the volatile products formed during low temperature pyrolysis. For collector additions ,as low as 20 g/tonne of ore, pyrolysis of the flotation products usually gives&apos; an olefin directly related to the particular xanthate or Aerofloat reagent used. The method is able to provide valuable qualitative and quantitative data relating to the extent of collector adsorption and the resulting changes in the hydrophilic or hydrophobic nature of the mineral surface.

Jan 1, 1974

By H. Reginald Hardy, Y. S. Kim

Recent studies of inelastic behavior and acoustic emission in geologic materials further validate the concept that such materials may be considered to consist of an elastic media containing an array of pores and cracks. In the present paper this concept is investigated further by experiments in which the mechanical behavior of a number of geologic materials were studied in detail at low stress levels using ultrasonic pulse methods. Experiments were carried out on cylindrical test specimens of Indiana Limestone, Tennessee Sand- stone and Barre Granite under relatively low confining pressures (0-5000 psi). Analysis of data from these experiments indicated that there existed a low-level critical stress at which there appeared to be a transition in the mechanical behavior of the material. Under triaxial stress, results indicated that the differential critical stress was relatively independent of confining pressure, i.e., the mechanism responsible for the transition in mechanical behavior was governed by a maximum shear stress criteria.

Jan 1, 1971

By D. Butler

Subsurface density changes can be detected by very precise surface gravity measurements. A feasibility study, combined with field experience using modern instruments, will indicate the probability of success. In addition to projected anomaly parameters, surface conditions that effect the survey precision must be evaluated. Examples with excavated zones at 9 m (30 ft) of depth and [+] 22 microgal error are compared to the same model at 30 m (98 ft) of depth. The figures illustrate anomaly detectability. The survey error is a function of surface topography and lateral density variation in the very near surface.

Jan 1, 1990

By Shu Yan

The high resolution resistivity method (HRRM) is developed specifically for detecting underground cavities and tunnels. HRRM has a special feature in that it can recognize and cancel static shift, which makes it different &om the high density resistivity method (HDRM). In searching for various means for detecting underground cavities, we found that the detecting depth of the transient electromagnetic field method (EM) depends mainly on the measurement duration, not the loop area. In addition, TEM can also be used to locate the high-resistivity bodies. In order to use them for local working site conditions, we combine HRRM with TEM to become a combined electromagnetic method. Since the late 1980&apos;s this method has been used to locate abandoned mines and air passages and burning centers of mine fires with great success. This paper cites case studies for which this technique was successfully used.

Jan 1, 2005

By Š. Šachlová, T. Lokajícek, M. Petružálek, T. Svitek, A. Štastná

During the past 20 years, alkali silicate reaction (ASR) as a cause of concrete deterioration has been studied by a wide range of experimental methods such as microstructural and macrostructural analysis, bulk chemical analysis, X-ray and neutron diffraction analysis, etc. All of these data are compared with expansion values of mortar bars (following ASTM standard C 1260). Recent studies indicate the useful application of non-destructive methods with the aim of better reflecting mechanical properties and the degree of deterioration of real concrete. Ultrasonic testing methods (including ultrasonic pulse velocity UPV) are widely used to determine material mechanical properties and the changes induced by a variety of mechanical or chemical processes. However, only a few laboratory studies of ASR focused on ultrasonic testing of mortar bars. Due to this fact, a heating chamber was designed and constructed to enable ultrasonic sounding of mortar bar specimens while stored in accelerating solution. Regular ultrasonic sounding of mortar bars reveals significant dependence of ultrasonic data such as longitudinal P-wave velocity, signal energy, signal amplitude and signal frequency on mortar bar storage time. Ultrasonic data were subjected to time domain as well as frequency domain analysis. Different storage conditions were used to determine the effect of ASR on ultrasonic parameters. Mortar bars, prepared in the same manner with one type of aggregate, were stored in cold or warm water or in an accelerating warm medium. Ultrasonic data accurately reflects the differences in hardening and deterioration of tested mortar bars due to different storage conditions. Ultrasonic results showed very good correlation with the results of ASTM standard expansion tests and much higher sensitivity to ASR-induced concrete deterioration. Expansion tests showed 1% measured length differences in comparison with up to 80% resolution of ultrasonic data. The ultrasonic testing proved to be a suitable laboratory method for investigating ASR-related processes and could lead to an improvement of standard testing procedures.

Jan 1, 2015

By E. Niehuis, J. Y. Kim, H. G. Cramer, S. L. Chryssoulis, K. G. Stowe, C. Bendel

TOF-SIMS was used to detect, identify from parent molecular ions and determine the relative concentrations of collectors sorbed on the surface of mineral particles in concentrate and tailings samples from three Canadian concentrators. In the Kidd Creek Zn circuit, sphalerite lost to tailings carried on average a quarter of the amount of isobutyl xanthate present on that recovered to Zn concentrate; amyl xanthate, which is not reported as added to the circuit, was also detected on floated sphalerite and pyrite. At Brunswick, sphalerite particles lost to the scavenger tailings had ten times less amyl xanthate and isobutyl xanthate than those recovered to the Zn final concentrate, while both xanthates were detected on sphalerite floated to the Cu-Pb cleaner circuit. At Matagami, significantly more isopropyl xanthate and isopropyl dithiophosphate were detected on sphalerite recovered to the final Zn concentrate than on that lost to the Zn rougher tailings

Dec 1, 1995

By Ken G. Stowe, Stephen L. Chryssoulis, Christian Bendel, Joe Y. Kim, Ewald Niehuis

"TOF-SIMS (Time-of-flight secondary ion mass spectrometry) was used to detect collectors sorbed onto the surface of mineral particles in concentrate and tailings samples from the Brunswick, Matagami and Kidd Creek concentrators. This technique uses ion beams from either Cs or Ga sources to sputter the particle surface, a method which reduces fractionation of the collector molecule during sampling.In the Brunswick Zn circuit, sphalerite particles lost to the scavenger tails had less amyl xanthate and isobutyl xanthate compared to sphalerite recovered to the Zn final concentrate. Xanthates were detected on the surface of sphalerite particles floating to the CuPb final concentrate.At Matagami, significantly more isopropyl xanthate and isobutyl dithiophosphate were detected on sphalerite recovered to the Zn final concentrate, compared to sphalerite lost in the Zn rougher tails.In the Zn circuit of Kidd Creek, sphalerite lost to the tails had on average ten times less xanthate compared to sphalerite recovered into the Zn final concentrate. Xanthate was also detected on the floated pyrite particles. In addition to isobutyl xanthate, amyl xanthate was also detected on the floated sphalerite and pyrite particles.This preliminary investigation has (a) demonstrated the ability of TOF-SIMS to detect individual collectors on particle surfaces from plant samples and (b) shown that TOF- SIMS is an excellent tool, complimentary to TOF-LIMS, in establishing the surface chemistry of minerals as related to mineral processing."

Jan 1, 1995

By Hector Carreon

Due to elevated temperatures, excessive stresses and severed corrosion conditions, turbine engine components are subject to creep processes that limit the components life such as a turbine bucket. The failure mechanism of a turbine bucket is related primarily to creep and corrosion and secondarily to thermal fatigue. As a result, it is desirable to assess the current condition of such turbine component. By using eddy current images, it was shown that the eddy current technique could be used to monitor creep damage in a nickel base super-alloy. The eddy current results also show a significative variation in the electrical conductivity on the creep damage zone with respect to the background zone in nickel-base super-alloy samples. In addition, the absolute thermoelectric power coefficient show also a strong dependence associated with creep damage in nickel base super-alloy samples using a copper hot tip reference. The eddy current and thermoelectric power techniques seems to show promise as nondestructive evaluation tools for monitoring the level of creep damage in metallic alloys.

Jan 1, 2010

By Ankit Jha, Sudarshan Rajagopal, Purushotham Tukkaraja

Geologic structures are one of the crucial parameters in blast design. Structural geology and rock properties influence drilling patterns, blast layout, and initiation systems. A comprehensive understanding of structural characteristics is essential to achieve the desired blasting objectives. This paper aims to identify geologic features in a bench using images obtained from the drone. Images obtained from mine site are annotated for geological features such as faults and joints. Semantic segmentation of images is achieved using an encoder and decoder structure available in the machine-learning pipeline. The encoder consists of initial convolution and pooling layers to capture essential features of the geology and rock patterns from two-dimensional RGB images. Batch normalization is used to put all the features on the same scale. These images are then inputted as training data for the machine-learning algorithm. Machine learning model is trained on sub-section of interest to achieve reasonable accuracy. Initially, 1000 best annotations were used to train the model and additional samples were added later to achieve more accuracy and avoid iteration of machine learning model in wrong convergence. After the model achieves reasonable accuracy, it is used to recognize geological features on new data. Geological features identified on the new data can be used by the blasting crew in blast design and keeps the geological maps updated that can help the geotechnical team.