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By K. A. Natarajan, S. Usha Padukone

"An industrial waste liquor having high sulfate concentrations was subjected to biological treatment using the sulfate-reducing bacteria (SRB) Desulfovibrio desulfuricans. Toxicity levels of different sulfate, cobalt and nickel concentrations toward growth of the SRB with respect to biological sulfate reduction kinetics was initially established. Optimum sulfate concentration to promote SRB growth amounted to 0.8 - 1 g/L. The strain of D. desulfuricans used in this study initially tolerated up to 4 -5 g/L of sulfate or 50 mg/L of cobalt and nickel, while its tolerance could be further enhanced through adaptation by serial subculturing in the presence of increasing concentrations of sulfate, cobalt and nickel. From the waste liquor, more than 70% of sulfate and 95% of cobalt and nickel could be precipitated as sulfides, using a preadapted strain of D. desulfuricans. Probable mechanisms involving biological sulfide precipitation and metal adsorption onto precipitates and bacterial cells are discussed.IntroductionIndustrial effluents from hydrometallurgical and mineral processing operations often contain high sulfate and metal concentrations posing significant disposal problems, which require urgent solution to avoid serious environmental contamination. In such waste liquors, sulfate and heavy metals such as cobalt, nickel, zinc and iron originate from the chemical or biological oxidation of exposed sulfide minerals. Reduction of sulfate and precipitation of toxic metal ions from industrial wastes is essential from the viewpoint of environmentally acceptable waste disposal and recovery of associated strategic metals.Many of these heavy metals are essential for metabolic activity of bacterial cells at low levels. But they exert toxic effects at concentrations encountered in polluted water. Removal of toxic metals through biological reduction of sulfates from industrial waste waters have been practiced for several decades. Metal remediation through common physicochemical techniques such as oxidation-reduction, chemical precipitation, filtration, electrochemical treatment, evaporation, ion exchange and reverse osmosis processes is expensive and not suitable in the case of voluminous effluents containing complexing organic matter and low metal concentrations. Further, strong and contaminating reagents are used for desorption, resulting in toxic sludge and secondary environmental pollution. Biotechnological approaches can be more efficient and cost effective for detoxification of such effluents. Biotreatment/ bioremoval offers several advantages over conventional chemical and physical treatment technologies, especially for diluted and mixed contaminants. Biological detoxification, which involves the use of microbes to detoxify and degrade environmental contaminants, has received increasing attention in recent years (Iwamoto and Nasu, 2001). In addition, valuable metals can be recovered from metal sulfide sludge (Boonstra et al., 1999)."

Jan 1, 2015

By L. Lichty, R Bhappu, R. Rowan, G. Ramadorai

Treatment of refractory gold ores containing arsenic have always presented a major problem in their processing to recover the contained precious metal values. The major difficulties are concerned with lower recoveries, production of hazardous fumes, effluents and residues. Because of'these arsenic related problems, many otherwise economically attractive precious metal deposits and dumps all over the world are not exploited. In recent years, treatment processee for refractory gold ores and concentrates have been explored and a few commercial operations employing roasting or pressure leaching have resulted. Roasting has limitations due to environmental constraints related to off gases. Pressure leaching involving high temperatures (180% to 200%) and pressures (400 psi) is accompanied by high capital and operating costs. An alternate route to roasting for treating pyrite and arsenopyrite ores and concentrates ia the "lime-oxygen hydromet" process carried out at a moderate temperature (100%) and pressure (100 psi). A simplified process for treating such arsenic containing ores and concentrates utilizing low temperature and pressure oxidation is presented. This low cost treatment with compressed air and lime renders arsenic as an inert component in the residue, meeting all the requirements of the EPA Toxicity Test. The precious metal values are then extracted from the autoclaved residue by standard cyanidation. This paper discusses this new development.

Jan 1, 1990

By Joel L. Morrison

The preparation of coal-water slurry fuel (CWSF) has the potential to be a commercially viable technology for the coal industry. The technology base required to prepare stable CWSF using grinding circuits has been developed over the past decade and is now being applied to the preparation of CWSF from wet coal fines which are generated during coal beneficiation. When preparing CWSF, the optimum CWSF formulation must be determined to ensure that the fuel will be stable while having acceptable atomization and combustion properties, and the production run must be monitored closely to ensure that the CWSF quality is maintained. This paper describes the CWSF formulation process, CWSF preparation circuits, and some of typical problems encountered in, and solutions to, the transportation and storage of CWSF.

Jan 1, 1993

By David S. Young

All pigments and extenders or fillers whether organic or inorganic fall into the following broad general classes: I. Colored II.-White III. Black IV. Metallic A pigment- is any particulate matter that is essentially insoluble and chemically unaffected by the media into which it is dispersed. According to this very broad definition, colored pigments, white pigments, fillers, extenders, and functional pigments would all be included. The particulate size range would also be quite broad ranging from very fine colloidal particles (~0.01µ) to relatively coarse particles (~100.0µ). This broad definition is usually subdivided into more practical divisions which tend to relate the classification of the pigment to its primary function in the system in which it is used. Hence, the word extender implies that its major purpose may be to extend the system.

Jan 1, 1985

By Rudolph H. Jacobson

The leaching of heaps or sub-marginal waste ore dumps as it is practiced throughout the Southwest as well as other parts of the world, is the major method of secondary recovery of copper. In 1970, twenty percent of all domestic copper was produced by dump leaching operations (l). In recent years, this method has been successfully extended on a limited scale, for the recovery of uranium from low-grade ores (2). It is inevitable that this technique will be increasingly employed in metal production to satisfy the insatiable demand of our mineral based society. Although dump and heap leaching has been used effectively for some time (3) , its application has been more of an art than a science. Therefore, it is essential that we learn about the important factors and parameters affecting this versatile process so that we may make increasing use of this technique in the future. The dump or heap leaching process encompasses the preparation of ore for-subsequent inplace leaching, the flow of solutions and ionic species through porous rock masses, the leaching of minerals with inexpensive and, if possible, regenerable lixiviants under prevailing conditions of the inplace environment, and the recovery of metals from the pregnant liquors. It is evident that this comprehensive scope of dump or heap leaching falls under the realm of interdisciplinary science and engineering requiring the application of the principles of physics, mineral engineering, hydrology, computer modeling, operations research, economics, and allied disciplines. An exhaustive study of the phenomenology of a leach dump or heap requires detailed knowledge of the simultaneous interaction of'

Jan 1, 1972

By Kate Willa Brown Requist, Eric Lutz, Moe Momayez

As air quality sensor networks become increasingly popular in underground coal mines, it is important to generate paradigms for the application of the collected data. To date, air quality sensing has been primarily used as an early warning system for hazardous air conditions. Using data collected from a network of sensors in a US underground coal mine, we have created multiple visualization methods to show the interactions of carbon monoxide evolution with ventilation airflow. These visualization methods can allow for further analysis of the source of contaminant, as well as better data resolution across the area of concern within the mine. By utilizing univariate spatial interpolations, we present methods for identifying the movement of carbon monoxide at one-minute intervals. The resulting visualizations display the evolution of carbon monoxide concentration across a sizeable study area over a period of 14 minutes.

Jun 25, 2023

By P. B. Altringer

The Bureau of Mines conducted laboratory tests to develop a process for recovering a marketable grade of tungsten from the brine of Searles Lake, Calif. The brine contains only 56 parts per million of tungsten (70 ppm WO3). Using ion exchange resins synthesized by Bureau chemists, 98 percent of the tungsten was extracted from the brine and 92 percent of the tungsten vas recovered as a marketable iron-tungsten concentrate containing 44 percent tungsten as tungsten trioxide. Although major technical problems have largely been resolved, research is progressing to escalate testing in a process investigation unit to provide more reliable data for an economic appraisal.

Jan 1, 1978

By John G. Holmes

The generation of low cost power is but one phase of the TVA program for regional development. During the 36 years since TVA began, growth in its generation of electric power has necessitated a shift from a predominantly hydroelectric power system to a combination steam and hydroelectric system. The addition of steam-electric power plants to TVA's generating system was necessitated by the rapid increase in the traditional and defense demands for electric power in the 80,000-square-mile area served by TVA, the need to firm up the hydroelectric power, and the fact that all available sites for sizeable hydroelectric projects had been developed. At present TVA owns and operates 40 power plants--29 hydroelectric and 11 steam-electric plants. The total generating capacity of the hydroelectric plants is 3,105,430 kw, and the capacity of the steam plants is 13,951,135 kw. This provides a total generating capacity of 17,056,565 kw for the plants operated by TVA. Individual capacity of the 112 hydroelectric units ranges from 10,000 to 67,500 kw, and the individual capacity of the steam-electric units now in operation ranges from 60,000 to 950,000 kw. In addition to this generating capacity, TVA distributes the power from 6 U. S. Army Corps of Engineers hydroelectric plants on the Cumberland River. These plants contribute an additional 725,000 kw. Also, under an agreement with the Aluminum Company of America, TVA directs the stream flows and generation of their 423,715-kw system on Tennessee River tributaries and shares with Alcoa in the increased generation resulting from this coordinated operation.

Jan 1, 1969

By M. J. Laurila

On-line analyzers have made possible the use of Fuzzy Logic Control (FLC) for local control applications in coal preparation plants. This includes FLC control of complete circuits such as heavy media vessels, cyclones and froth flotation. These circuits can be controlled in real time in a feedback control loop with an on-line analyzer. Control strategies can be readily developed using Statistical Process Control (SPC) techniques which are first applied off-line in manual mode through the use of control charts and then this process is brought on-line using FLC in conjunction with an on-line analyzer to fully automate the circuit. This paper outlines the types of control strategies employed and presents examples of automatic verses manual control.

Jan 1, 1997

By E. B. Kroeger

Spoil instability has been a problem at a coal mine in interior Alaska. Parameters such as original site topography, groundwater conditions, material properties, spoil-pile geometry, geology, permafrost, natural slope instability, changing weather conditions, and dense, near-surface vegetation have interacted to produce unstable slopes. Several failure modes have been identified including deep seated earth block slides, bimodal earth flows, and solifluction. Thawing of permafrost also created conditions where sliding of spoil along the interface separating the spoil and the natural ground surface occurred when the cohesion and the friction angle of that zone was reduced to zero and below 15?respectively.

Jan 1, 1992

By R. R. Klimpel

This paper demonstrates, using the results of an unusually complete industrial test sequence, what the various interactions are between grind size, collector dosage, and frother type. While particle size is universally acknowledged to be important in optimizing industrial copper sulfide rougher flotation circuits, many of the various interactions that do occur at the industrial level with particle size are still being identified and/or quantified. This study also presents, in a consistent manner, the changes in flotation kinetics that occur as a function of particle size, in a typical industrial circuit along with some insights as to how flotation operators can optimize rougher circuit performance.

Jan 1, 1993

By M. C. Williams

The solution of the dynamic population balance model (PBM) of a closed grinding network consisting of a mill, sump, and cyclone is problematic. The fact that the dynamic PBM model equation solution to the Inverse Problem for grinding systems is degenerate or underspecified is demonstrated. Two numerical solution approaches to the Inverse Problem are used. These are: 1) providing additional constraints on breakage selection functions or 2) performing the Arbiter-Bhrany (or other) normalization of the selection functions. Actual experimental anthracite batch grinding data is used to demonstrate the non-unique functionality of the batch dynamic mill selection and breakage functions for a real physical system. The Levenberg-Marquardt algorithm for systems of constrained non-linear equations is used to solve the batch dynamic PBM grinding equations to obtain the grinding selection and breakage rate functions. Different solutions to the same PBM transport equations are provided. The mill, sump and hydrocyclone were modeled as a CSTR operating at various retention times. Batch dynamic PBM data was used to provide the mill kinetic and breakage selection function data. Two different solutions were obtained depending on the numerical solution approach. The severity of the non-uniqueness problem for dynamic grinding is demonstrated. Each solution approach to a dynamic PBM with transport, while giving the same prediction for a single batch grinding time, gives different solutions or predictions for mill composition for other grinding times. This fact makes dynamic nodal analysis and control problematic. The fact that the constraint solution approach gives a solution may suggest that normalization for closed networks is not necessary. Differences in solutions to the PBM cannot be excused away by inaccuracies in the data used to model the grinding phenomenon.

Jan 1, 1995

By H. Dho

The role of sodium silicate in the anionic flotation of a Florida phosphate ore was investigated using laboratory continuous flotation tests, frothability tests and SEM observations. In the absence of sodium silicate, Ca++ promoted the unwanted activation of quartz by forming calcium bearing precipitates. The addition of sodium silicate enhanced the flotation efficiency through: (1) the removal of impurity minerals and calcium-bearing. precipitates from quartz surfaces by dispersion, (2) drier and more persistent froths stabilized by oily droplets containing calcium silicate precipitates, and (3) higher specific flotation rates of phosphate relative to quartz, leading to faster flotation rates and increased selectivity of separation.

Jan 1, 1990

By J. R. Henke

Dewatering wells producing iron-rich water experience rapid declines in yield and drawdown due to the formation of ferric (Fe +) hydroxide deposits in well screen, pump intake and riser pipe. Precipitation is caused by a combination of dewatering-promoted iron oxidation and iron-oxidizing bacteria. Physical and chemical well rehabilitation techniques, as well as alternative well construction and well development techniques designed to minimize well clogging, were evaluated in this study. The addition of acid downhole feed systems to dewatering wells prone to iron encrustation can, in some cases, prolong their operational lives up to 500 percent that of unacidified wells.

Jan 1, 1989

By William J. Robinson

What is the cummulative rate of recovery of copper from a sulfide leach dump? This is one of the most frequently asked questions today. We, in the industry, ask it of each other when we meet; however, the technical answers may vary from "I don't know" to 'quite good" from people within the same company. Management also poses this question because it plays a vital role in our planning for future production. The answer is difficult because of the many variables between different operations such as physical construction of the dump, topography of the original site, characteristics of dump material, mineralization, water application, etc. Each has a bearing on the rate of recovery. OPERATIONAL DATA Our method of water distribution is unique in that each dump is drilled to allow physical injection of water into the dump. The in¬jection holes are drilled vertically, on 251 centers, from the surface of the dump. Normally, the holes are drilled 40' deep and cased with 4" PVC perforated pipe.. The pipe is perforated at one-foot intervals with four V diameter holes at 901 spacing on the pipe circumference. We formerly alternated shallow holes (20'-40') with deep holes (80'-l80') in an effort to cover the entire dump and hasten oxidation. The shallow hole depth varied according to the compaction thickness. The deep hole depth varied according to the height of the dump and the original ground profile, We prefer to have the deep holes end 20'-30' above the original ground level. This generally allows us to penetrate the coarse material at the bottom of the dump. We had to discontinue the deep holes_ in order to cover more dump area in a shorter period of time to meet increased production requirements.

Jan 1, 1972

By S. Tafazoli, D. Cooper, I. Bell, S. Nouranian, B. Sameti, M. Ramezani

"Image-based rock fragmentation sensing in mines and quarries includes an important rock boundary delineation step, commonly referred to as rock segmentation. This paper presents an artificial intelligence-based solution to this challenge. The proposed technique encodes prior knowledge of previously analyzed images into mathematical/statistical models. Human-labeled images are used as inputs to train neural networks through an optimization process. The networks can then be used in real time for rock delineation. To build the models, special deep artificial neural networks are used as a pixel classifier. The proposed classifier labels each pixel (edge, rock or fine) by analyzing a plurality of pixels within the image. Advances in machine learning allow the network to contain many parameters. The increased number of parameters is a strong factor in the classifier’s ability to correctly classify each pixel. Deep learning-based segmentation, combined with 3D imaging followed by post processing, provides a unified fragmentation sensing solution. Results from automatic segmentation are compared to human labeled segmentation using the percentage passing curves for 64 rock images. INTRODUCTION Mines and quarries can see significant productivity and performance benefits by controlling material sizes (McKee, Chitmobo, & Morrell, 1995; Sellers & Gumede, 2012). During the past decade, image-based fragmentation analysis has been applied to estimate rock size distributions in order to optimize procedures in mines and quarries. Using a roving camera and operator assisted analysis Maerz, Franklin, and Coursen (1987) measured the size distribution of the blasted rock and eliminated the need for manual sieve analysis. Since then, many others have introduced automated and manual methods for fragmentation analysis and improved upon existing approaches (Girdner, Kemeny, Srikant, & McGill, 1996; Smith & Kemeny, 1993; Palangio, Palangio, & Maerz, 2005; Tafazoli & Ziraknejad, 2009; Raina, 2013). In image-based fragmentation, rock boundaries are identified in the image, and an image scaling is applied to transform rock pixel sizes into real world dimensions. Usually geometric references, such as regularly shaped objects (discs and basketballs) (Siddigui, Ali Shah, & Behan, 2009), or the known size of an excavator bucket (Zeng, Chow, Baumann, & Tafazoli, 2012), are used to determine the proper scaling factor. In recent years, 3D imaging and sensing have also been incorporated to improve rock delineation. Specific methods include using camera-laser combinations and stereo imaging to measure rock fragmentation on conveyor belts (Noy, 2013; Thurley, 2013; Dislaire, Illing, Laurent, & Pirard, 2013) as well as portable fragmentation analysis devices with 3D imaging sensors (Sameti, et al., 2014)."

Jan 1, 2018

By William F. Abercrombie

The role of the laboratory is described in relation to the prospecting and exploration of kaolin clays. Test methods used to evaluate crude ore samples of kaolin clay for commercial consideration are reviewed. A background of the kaolin mineral and known means of prospecting this mineral are presented. Common analytical methods are discussed with special emphasis on those in use today.

Jan 1, 1982

By S. S. Peng

A well designed mining plan is one which minimizes the cost and the mining induced problems and maximizes the recovery of the coal reserve. In order to minimize the negative effects on surface structures caused by ground subsidence process due to underground mining activities, two kinds of practices are commonly employed by the mine operators. One is the support techniques which leaves an area of coal un-mined or partially mined beneath the structure to be supported. The other is the protection techniques which protect the structure when it is subsiding with ground taking advantage of the ground subsidence process (Luo et al., 1992). In designing the supporting techniques, the only currently available method in the U.S. is the one stated in the Pennsylvania Underground Coal Mining Rules (1985). However; The size of the support area designed by this method will be excessively large resulting in wasteful use of coal reserve when the overburden depth is more than 350 ft. A more scientific method is proposed in this paper for de-signing the support area. This method is based on a large amount of subsidence data collected throughout a number of major U.S. coal fields and the authors' experience with monitoring and protecting surface structures undermined by longwall panels. It considers the critical deformation in-dices that a structure can tolerate, and depth and height of underground extraction. The support area designed by this new method will not only assure the safety of the structure to be supported but also maximize the extraction of the coal reserve.

Jan 1, 1993

By Thomas H. Ferrigno

Modern Plastics (July, 1983) reported that about 2.2 million tons of mineral fillers were expected to be consumed by the plastics industry that year, of which 7096 was limestone derived. The combination of fillers and polymers is called a composite and, in the more general sense includes continuous and discontinuous components in a matrix. The only significant technical advance in the fillers industry has been the greater general availability of surfied (Ferrigno 1959), an acronym for surface modified, fillers. The many reasons for this occurrence will be given in detail later, but the primary reason lie with differences between inorganic filler surfaces and the polymers which bind them together to form the composite. Minerals and glasses (fiberglass, fly-ash and beads) have surface tensions in excess of 200 dynes/cm, whereas organic materials have surface tensions less than 75 dynes cm. Water has a surface tension of 72 dynes/cm and is always present as an absorbed layer on high surface tension materials to reduce the surface tension. Although almost any organic liquid or polymer has a surface tension low enough to displace the water layer, the highly polar nature of filler surfaces requires highly polar agents to produce a permanent effect, and frequently the water is so tightly bonded or so much more active that the displacement is temporary. Furthermore; the water layer causes tiny particles to adhere to each other (agglomerate) to make sepaartion or dispersion of the individual particles very difficult. The solution to these problems is then to form a chemically bonded layer on the filler surface similar to that of the polymer so that immediate wetting, dispersion and uniform distribution of the filler particles is obtained.

Jan 1, 1985

By G. S. Dobby

High-intensity wet magnetic separators have been successfully introduced into the mineral processing field over the past ten to fifteen years, due largely to rapid advancements in magnet design. Wet magnetic separation, until recent years, was applied solely to the concentration of minerals of high magnetic susceptibility, such as magnetite, at relatively coarse sizes. Now, however, high-intensity separators are capable of treating weakly paramagnetic minerals and have extended the range of treatable particle size down to about one micrometre(1,2). . One of the more recent-high-intensity separators developed is the Kolm¬Marston Marston type high-gradient magnetic separator (HGMS) (3,4) It consists basically of an iron-clad solenoid surrounding a matrix material - a fine, ferromagnetic steel wool or expanded metal lath. A schematic diagram of the device is shown in Figure 1. Large, highly localized, pertebations of the magnetic field are created by the ferromagnetic matrix. It is these field gradients that are instrumental in developing large magnetic forces which act on the mineral particles. Operation of the separator is simple. Slurried sample is fed through the matrix and, depending upon the mineral parameters of particle size and magnetic susceptibility and. the operating parameters of flow rate, field strength and feed weight, some particles will be attracted to and adhere to the magnetized matrix, while the others will flow through the matrix. The separation is completed by later removing the background magnetic field and flushing the captured mineral particles into a separate container. The process can also be applied on a continuous basis (S).

Jan 1, 1977