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By B. Pesic

Northwest Alloys, a wholly owned subsidiary of Alcoa, produces magnesium from dolomite by reduction with ferro silicon and aluminum. This process produces alkaline by-products in quantities that allow their consideration for use as commercial by-products. Two such products are dicalcium silicate slag, Di-Cal, and magnesium oxide condensate, MgO. The alkaline properties of these materials offer acid neutralizing capability comparable to the traditionally used lime, therefore, warranting a study for their use in applications where the neutralization of acidic waters or process solutions is required, such as treatment of mine waters. In this ongoing study, three mine waters (Bunker Hill Mine, Berkeley Pit, and Blackbird Mine) were selected for treatment with Di-Cal and MgO. Lime was used as the background control. The solid precipitates were subsequently contacted with pure water at four different pH conditions for stability testing of prepared metal precipitates (expanded TCLP). It was found that neutralization with Di-Cal results in precipitates which are of equivalent to superior stability than those from lime treatment.

Jan 1, 1999

By John A. Rajala

The water chemistry of the froth flotation pulp is one of many parameters which can affect the flotation process. The fluid may contain certain inorganic salts which, along with increased ionic strength, can produce undesirable flotation depression or activation. A source of a salt could be the use of calcium chloride to prevent freezing in ore cars, chutes, and bins (Anon., 1980). Alternately, the salt or salts could be initially contained in the water as in the case of sea water and some brackish waters. These salts may become more concentrated because of the need for recycling of plant water due to environmental regulations and/or economic considerations (Davis, F.T., et. al., 1976). The presence of inorganic salts in flotation pulps and their effects upon the recoveries and surface chemistries of different oxide minerals have been the object of various studies. Some researchers (Fuerstenau, D. W. and Raghavan, 1976; Fuerstenau, D. W. and Modi, H. J. 1960; Kulkarni, R. D. and Somasundaran, P., 1977) have reported that addition of a salt can increase or decrease flotation recovery depending upon the particular system.

Jan 1, 1982

By Bryson D. Trexler

Man's activity in developing, operating, and abandoning a mine often affects the quality of the ground water and surface water. Acid water drainage from mines is an example of an impact from mining that results in degradation of ground and surface water. New flow systems are created by the mining activity. The mining made possible complex chemical reactions that, with water movement, create a discharge of low pH, poor quality water. Remedies for these problems fall into two general solutions: 1) treatment of the end product and 2) reversal of some aspect of man's disturbance of the natural system. The relative reversibility of various aspects of man's impact from mining activities ranges from relatively easy to very difficult, from economically feasible to economically infeasible, and from technically possible to essentially impossible with present knowledge. The relative reversibility of a mine-related problem cannot be assessed without first understanding the detailed physical interactions that combine to form the problem. Acid water drainage is a combination of the availability of several chemical factors with the availability of water for a transport mechanism.

Jan 1, 1982

By Curtis A. Pledger, H. Lee Wimmer, I. Michael Gowring

The Upper Diamond Fork Project, as part of the Central Utah Project Completion Act, conveys water six miles from the existing Sixth Water Aqueduct to the Diamond Fork Pipeline. During design, a Value Engineering team proposed a single-tunnel alignment that would be less destructive on the environment and might have a lower life cycle cost than the proposed design of two tunnels connected by two pipelines on steep hillsides. A decision was made to include this option in the bid process as a design-build alternative. The bid for this option was the lowest and a contract was awarded. During the TBM excavation a segment of tunnel wall caved in containing large quantities of water saturated with extremely high levels of hydrogen sul?de (H2S)gas (measured at 380 to 520 ppm in the air). The Central Utah Water Conservancy District (District) in consultation with Obayashi/Clyde (Contractor) quickly developed anew plan to finish the system by incorporating parts of the original tunnel/pipeline concept and re-bid the remainder of the project as a Phase 2 Design-Build contract.

Jan 1, 2003

By H. F. Haller

Large volume sand plugs are placed in tunnels to stem underground explosions at the Atomic Energy Commision's Nevada Test Site. Placement through long, narrow accessways is like stemming coyote holes and blast chambers in mining and construction. Experience with several other methods showed that pipeline conveying could be preferable. Small scale tests justified predicting a placement rate of 20 y. p. h. at 1000 feet, with a modified gunite placer. The initial production trial placed over 2000 c. y. and was estimated to effect a small cost saving after paying for new equipment. Initial problems included duct replacement and supply delays, dust, and other personnel hazards. Operations analysis and SOP'S reduced delays during the second field trial, minimized hazards, doubled production. Re cent re search and operations analyses produced data on abrasion resistant ducts, identified minor equipment modifications which can improve production, developed techniques for impact compaction to 90% ?maximum? and for extension of the practical range to 2000 feet. Twenty-two illustrations include an air consumption-distance chart.

Jan 1, 1967

By Roberto Zaragoza

Historically, the control of flotation operations has been viewed by many as an art. Only recently has process measurement and control come to be viewed not as an ?art? but as a very complex and productive science. In recent years, process control applications to flotation plants have been established and already some gains have been reported for several industrial operations using individual stabilizing control loops including level, pulp flow, pulp density, reagent addition rate and pH (Paakinen, 1979; Hales, 1985). The use of process control computers combined with on-line x-ray florescence (XRF) in industrial flotation circuits has made the application of more sophisticated control techniques feasible in the mineral recovery process. In spite of the availability of reliable instrumentation in modern flotation plants, satisfactory control strategies are difficult to develop and implement. Extremely important factors such as changes in ore type, liberation characteristics, flotability, degree of oxidation on particle surfaces, and specific gravity constitute unmeasured disturbances to the process. Most current control systems cannot adapt specifically to such disturbances.

Jan 1, 1987

By S. Triantafyllidis

The tailings produced from the Kirki (Agios Filippos) high sulfidation epithermal deposit processing plant are laminated, weakly cemented and their particle size ranges from fine sand to fine silt. They are mainly composed of milling residues of gangue (quartz, dickite/kaolinite, pyrophyllite, illite); sulfides and secondary minerals (jarosite group minerals, butlerite, anglesite, beudantite and gypsum) are present to a lesser extent. They have high Pb and Zn (average 0.75 % and 0.57 % respectively) and low S (1.04 to 2.92 %), Cu, As, Cd, Ni and Sb content (average 248, 163, 59, 27, 20 g/t respectively). Stagnant waters forming small ponds on the surface of the impoundments exhibit low pH and high heavy metal and sulfate concentrations. Negative Net Neutralization Potential (NNP) characterizes the tailings, indicating moderate to high potential for acid generation. Application of the TCLP test revealed that the tailings are characterized as toxic because of the increased solubility of Pb and Cd. On the other hand, As TCLP solubility is very low.

Jan 1, 2006

By Carl E. Schubert

The application of geophysical technology relative to the exploration, planning, and operation of coal mines is expanding. This is due to the trend of the industry to increase the size of operations, use of mechanized equipment and mining of more difficult coals, where unforeseen conditions can affect mine profitability. Coal is a good geophysical target because of its lower density, higher electrical resistivity, lower seismic wave velocity, and lower magnetic susceptibility in comparison to typical country rock. The more important techniques are well logging, high resolution seismic reflection, seam wave velocity, and radar. These methods can be used to map coal horizons, determine the physical properties of the coal, and identify mining hazards. The methods are not a pancrea however. Their use should be based on a careful assessment of their expected success and cost benefit analysis in comparison with conventional technology, primarily drilling, which none of the techniques presented should entirely replace. In general, the level of technology developed for geophysics surpasses their current level of application to coal problems. In some cases, identifying hazards in advance of mining using seam wave seismic in particular, the state of the art has been developed in Europe and is awaiting fruitful application in the United States.

Jan 1, 1982

By James A. L. White

Although the quantity of native sulphur associated with volcanism is large, production from such deposits represents only a very small percentage of total world production, This paper describes the location of the known deposits, the typical geology of these deposits and the nature of the sulphur mineralization. Methods of treatment are discussed and some comments are offered on the economic position of these occurences in world sulphur markets.

Jan 1, 1967

By J. E. Gebhardt, D. W. Fuerstenau

The use of small quantities of polyacrylic acid (PAA) was found to significantly improve the flotation of fine-sized hematite particles at pH 4.1 and 0.001 M NaCl with sodium dodecykulfonate (SDS). Low polymer dosages before collector addition aid flotation by forming flocs of primary particles, but excess polymer results in low flotation yields due to surface saturation by the hydrophilic polymer. Contact angles, measured on a hematite disk, substantiate the hydrophilic nature of an adsorbed polymer film. Pre-adsorbed PAA reduces the amount of SDS adsorbed on the hematite particles, but the flotation of hematite flocs occurs, even at reduced amounts of adsorbed SDS, and is not depressed until PAA dosages in excess of the saturation value are used. Separation of a hematite-quartz mixture can be achieved by SDS flotation of PAA,-flocculated hematite. Maximum selectivity results with the addition of small quantities of PAA, while excess polymer is detrimental to the recovery of hematite. Consecutive flotation states on a single feed yield a higher grade hematite product at some expense to the overall recovery.

Jan 1, 1987

By J. P. Barbosa, R. V. V. Araújo, R. B. E. Trindade

Bromide stabilizes the auric or aurous ion by forming a stable complex in acidic aqueous solution. The oxidizing agent normally used for the process is bromine, which is a corrosive liquid with high vapour pressure. This is, in fact, the main reason why it has not found acceptance yet as an industrial oxidant for gold. Ferric ion with hydrogen peroxide and/or sodium hypochlorite have already proved to be effective oxidants for the dissolution of gold from a rotating disc in a bromide-containing aqueous solution. In the present work, preliminary tests with four selected ore samples were tested to evaluate the dissolution of gold with the same system already tested with the rotating disc (Br-/Fe3+/H2o2/NaCIO). Compared to the conventional cyanidation, results were superior in one instance only. The major obstacle seems to be the maintenance of a suitable potential to allow the complex formation. However, the studied system may be interesting, is in some situations it may yield better results than conventional cyanidation; therefore, further investigation seems to be worth doing.

Jan 1, 1995

By K. N. Han, P. B. Queneau, A. Stojsic, M. J. Collins, V. J. Ketcham, R. M. G. S. Berezowsky, W. D. Vardill

The bulk of the ore found in the Lihir Island deposit is refractory in nature, with the gold contained in auriferous pyrite. In support of an evaluation of the development of this deposit by Kennecott (a wholly owned subsidiary of RTZ) and Niugini Mining Ltd., testwork has been carried out at the Sherritt Research Centre to demonstrate the amenability of the Lihir ore to pressure oxidation pretreatment to liberate the refractory gold. The results of pilot plant treatment of the Lihir ore in a continuous circuit with a feed rate of between 10 and 30 kg/h ore are described. The integrated circuit comprised pressure oxidation, residue washing, and gold recovery from the washed residue by carbon in leach or carbon in pulp cyanide leaching. Significant factors affecting gold recovery included temperature and retention time in the pressure oxidation step, and the concentration of soluble chloride in the feed. Gold extraction from well washed ore, after oxidation at 210°C for 66 minutes in the autoclave, was typically between 94 and 96%, compared with less than 30% by direct cyanidation.

Jan 1, 1993

By E. Suoninen, K. Laajalehto, L. Kartio

Efficient separation of pyrite from other sulfides is of great importance for the metallurgical performance of flotation processes. In this work Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS) were used to study the surface chemistry of pyrite in depression, activation and xanthate adsorption under conditions of controlled potential. Modifications of pyrite surfaces after treatment with depressants (lime, sulfur dioxide, sodium cyanide) and after activation with metal ions (Cu, Pb) were studied. The principal adsorption product identified on pyrite was dixanthogen whose formation started at about +0.15 V and +0.25 V (vs, SHE) in ethyl and amyl xanthate solutions, respectively. Copper xanthate was formed on copper(II) activated pyrite. Activation mechanism of pyrite by copper(II) salts is likely to be electrochemical where copper occurs as copper(I) on the surface of pyrite. Effective depression is achieved by sulfur dioxide and sodium cyanide. Depression at high pH is due to formation of iron(III) hydroxides. Calcium ions do not affect the electrochemistry but adsorb on pyrite and reduce the surface sites for dixanthogen adsorption.

Jan 1, 1995

By B. Bergmark, O. Guyot, A. Broussaud, C. Bouché

The Boliden Aitik concentrator in Sweden processes 2,000 t/h (2,200 stph) of low-grade copper ore. The plant consists of five grinding lines that feed four bulk-flotation banks with a scavenger-concentrate regrind mill und a column cleaner circuit with a regrind mill. The authors installed a model-based expert optimizing control system to maximize copper recovery in the bulk-flotation circuit while maintaining an appropriate copper grude in the cleaner feed. The optimizing control system uses on-line assays and calculates and implements set points for cell pulp levels, air rates and reagent- addition rates. It combines the power of a dynamic population-balance model that estimates mineral liberation in each stream, an optimizer that computes appropriate set points and a rule-based module that implements the strategy. The benefits have been evaluated over a period of three months. The model-based expert optimizing control system generates a measurable increase in copper recovery, around 0.5%, and an optimized bulk-concentrate grade. The need to maintain the optimizing control system and other practical aspects are discussed.

Jan 1, 2000

By Andrea Biagi, Elisa Comis, Gianluca Bella, Enrico De Panicis, Guido Barbieri, Matteo Giani

The Sotra Link Project is a major infrastructure project in Norway involving the design, construction, financing and maintenance of several underground and surface structures between Sotra island and the city of Bergen, among them 23 tunnel portals, 12.5 km of tunnels and a 900 m long suspension bridge. This paper describes the benefits in applying a Building Information Modelling (BIM) approach to tunnelling, from Early Design to the Detail Design Phase. The BIM application to the Sotra Link Project resulted in several improvements, such as efficient handling of clashes and inconsistencies, deeper understanding of effective design choices (reduction of errors), more efficient communication between designers, enhanced control of project quantities and costs. The advantages of the BIM approach during the ongoing Construction Phase are also explained.

Jun 23, 2024

By R. G. L. McCready, G. Dr. Heinrich, V. I. Lakshmanan

The objective of this study was to prove repeat loading capacities of physically stabilized fungal biomass from Penicillium sp. for the removal and recovery of uranium from mine water (Denison Mines). The testwork was carried out on a bench scale in small columns and proved that it is possible to stabilize the biomass in an inorganic compound. A lifetime of 10 loading-eluting cycles of the stabilizer biomass product was obtained by additional pretreatment. Sodium carbonate proved to be an effective elution medium. Loading and elution can be controlled by the pH values of the column. The effective loading capacity until the breakthrough point is approximately 70 % of the overall loading capacity. The loading capacities of the stabilizer biomass product are comparable to that of the original biomass. Uranium recoveries of 90 to 99 % were achieved during the loading and eluting under optimized conditions. Depending on the used biomass the described process might be applicable to remove uranium or other dissolved heavy or rare metals from effluents.

Jan 1, 1989

By Ronald B. Gabitzsch, Norbert P. Hanke

During 1982, record advances have been achieved in the excavation of vertical shafts with a V-Mole (a vertical shaft boring machine). The V-Mole, supplied by Wirth GmbH in Erkelenz, West Germany, has been used in West German coal mines since the early seventies, mainly for the construction of internal shafts. In 1981, it was brought into the United States for the construction of a series of ventilation shafts with depths varying between 512 m (1680 ft.) and 622 m (2040 ft.) excavated to 7.0 m (23 ft.) diameter. These shafts were needed for the development of coal mines for Jim Walter Resources, Inc. in Brookwood, Alabama. After a description of the mechanized shaft excavation system with the V-Mole, the conditions and parameters, such as ground, shaft dimensions, and linings are discussed. These factors are important considerations for a technically and economically feasible utilization of the V-Mole. In addition, the advantages and disadvantages of using the V-Mole technology in comparison to other shaft construction methods are evaluated.

Jan 1, 1983

By Arthur P. Chaves, Lauro S. Norbert Costa, Adão B. Da Luz

A series of bench-scale bleaching tests have been carried out on kaolin samples from the Rio Capim area( northern Brazil) at CETEM/CNPq. The whole sample has been homogenized and submitted to particle size separation, when the + 44 µm fraction has been discarded, prior to being bleached. The main objective of this series of tests has been to evaluate the possible effects of interactions among variables which are believed to play important roles in the bleaching operation on the efficiency of the process itself in terms of the brightness achieved in the final product The tests have been planned according to a classical four-variable, two-level factorial technique. The chosen variables have been the pH, sodium dithionite addition, aluminium sulphate addition and bleaching time. The study has shown that, apart of time, all other three variables are significant. None of the interactions among them have shown to be of significance. Brightness numbers close to 88 have been obtained in the products, which represents an improvement, since brightness for the non-bleached - 44 µm Rio Capim kaolin sample averages 83.

Jan 1, 1995

By K. I. Cunningham, C. S. Spirakis

Two types of native sulfur deposits have been found in Lechuguilla Cave: thin late-stage crusts and massive early- formed deposits. Most, if not all, of the crusts appear to have formed by remobilization of native sulfur contained within gypsum and sulfur masses. The process is occurring today and is slowly converting the sulfur to gypsum. The absence of primary gypsum or reductants in the cave indicates that the early-formed massive sulfur deposits did not form by in-place reduction of sulfate, which is the process that formed the commercial sulfur deposits in the Delaware basin. Instead, it appears that H2S dissolved in basinal brines was oxidized by oxygen in near-surface ground waters in the cave. Fluid- inclusion data, which suggest the presence of both fresh water and saline water as the sulfur formed, support this interpretation. Although individual sulfur deposits in Lechuguilla Cave are no more than several tens of metric tons, the abundance of secondary gypsum (as much as 10 meters thick) indicates that native sulfur may once have been much more extensive.

Jan 1, 1992

By Christopher D. Henry

Environmental geologic maps of the Wilcox and Jackson-Yegua lignite belts of the Texas Coastal Plain delineate land areas on the basis of their natural characteristics. Criteria used to define map units include substrate, soil, topography, geologic process, vegetation, and land use. The maps are useful in planning and reclamation of lignite mines and in meeting the requirements of State and Federal surface mining laws. Specific applications include identification of land capability, recharge areas and geometry of aquifers, flood-prone areas, areas that may qualify for prime farmland status, and other areas sensitive to lignite mining.

Jan 1, 1982