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By Milton E. Wadsworth, M. Ken Han

The kinetics of leaching of galena in hydrochloric acid solutions with sulfur dioxide gas have been investigated experimentally. The leaching method is then applied to complex sulfide concentrates to evaluate its selective leaching capability and to develop a new hydrometallurgical lead extraction process based upon the method. The leaching reaction follows a linear rate with an activation energy of 61.9,KJ/mole. The rate Is of first order with respect to the product [H+] [Cl-] . Excel lent selective leaching capability f s demonstrated and an attractive hydrometallurgical process flow sheet is proposed.

Jan 1, 1989

By Pradip

Chelatang agents, because of their metal specificity, can function as effective mineral processing reagents. A brief review of the work carried out in this area is presented. Some of the salient features of mineral flotation and flocculation with chehting-type reagents, such as bulk us. surface chelation, the role of pH, mineral solubility, solution chemistry of reagents, and temperature, are illustrated with appropriate examples. The problems associated with the commercialization of chelating reagents for ore beneficiation and the research efforts required in this area are also discussed.

Jan 1, 1987

By S. L. Zhu, Brij M. Moudgil, J. L. Pinault

Prompt neutron activation probe (PNAP) was evaluated to determine chemical composition of phosphate rock slurry in-situ. The technique was able to precisely analyze Ca, Si and H using a 252Cf source. Direct measurement of P and Mg was not accurate due to interference by the rare earth elements associated with the Florida Phosphate Rock. The solids loading, particle size distribution and flotation reagents present in the slurry had no significant effect on the accuracy of the measurements. The technique was found to be reliable also under industrial conditions.

Jan 1, 1993

By G. X. Wang, J. O. Marsden, M. C. Fuerstenau

Zinc cementation of high-temperature carbon eluates is now used extensively in gold processing to replace electrowinning. Under these conditions, zinc consumption is high. In this paper, zinc solubility is press rated us functions of temperature, cyanide concentration and pH in the presence of gold, silver and mercury cyanides (both individually and in combined solutions). Based on the experimental results, cementation of these metals is characterized and discussed. The importance of cyanide concentration in cementation efficiency and the effect of mercury and its co-precipitation onto zinc are also discussed.

Jan 1, 1997

By S. Behl, S. Mathur

The viability of physico-chemical purification methods such as selective, flocculation for the separation of two components having similar chemical compositions and the same crystal structure but different surface properties is demonstrated. A loss of selectivity was observed in a dolomite-dolomite mixture when polyethylene oxide (PEO) (five million molecular weight) was used us the flocculant. Heteroflocculation was minimized using a low molecular weight PEO (MW =105) as a site blocking agent (SBA). Near complete separation was achieved at pH 10.5 at the 100% recovery level

Jan 1, 1996

By K. N. Han

The adsorption of gold onto activated carbon in iodide solutions was studied. The adsorption rates were determined as a function of temperature, salt concentration and pH, as well as activated carbon concentration. A kinetic model was developed for the adsorption. The adsorption rate was believed to be controlled by a combined mechanism of film diffusion and pore diffusion with the film diffusion having the most significant effect. Experimental findings were in good agreement with the model developed. The apparent activation energy was found to be 14.9 kJ/mol.

Jan 1, 1995

By S. Chander

The effect of pretreatment potential on the response of a gold electrode for Eh measurements in sulfide solutions was examined in terms of measured Eh values and electrode response time. The electrode response time is defined as the time required for the electrode to reach a steady-state value. The relationship between measured Eh values and the hydrosulfide ion concentration is established. The effect of pH, the reversibility of the gold electrode in the sulfide solutions, and the reproducibility of measurements are also investigated. A mixed potential theory is proposed to explain the observations.

Jan 1, 1989

By R. Sharma, S. Svoronos, S. Gupta, N. A. Abdel-Khalek

This paper presents the results of a column flotation study on a fine feed sample of Florida phosphate. A central composite design was used to study the main and interaction effects of parameters affecting column efficiency. The statistical design is also used to determine the optimum conditions. The results indicate that, depending on the experimental conditions, it is possible to produce a high-grade concentrate with a high recovery. A 15ppm concentration of nonionic frother was found sufficient to maximize the recovery at pH of 9.5.

Jan 1, 2002

By James P. Sabogal

A control and monitoring system is being developed by Betz Laboratories for the heap leach process in gold recovery. Called Betz 14000GL, the system is designed to improve gold leaching and provide savings in chemical consumption by controlling and monitoring key parameters in the heap leach gold recovery circuit. The system uses information from on-line sensors to control antiscalant chemical addition, pH and cyanide levels. The proprietary graphics and report features of the computer system allows the user to monitor and critically evaluate the performance of the process.

Jan 1, 1998

By M. Misra

The interaction of xanthate with SO2 in the flotation of sphalerite and chalcopy.ite is discussed. 'The SO depression of sphaledte is due to the decomposition reaction of xanthate by SO2 The decomposition reaction is dependent on the cole ratios of xanthate/SO2, oxygen concentration and pH. Xanthate adsorbs at a faster rate by chalcopyrite than sphalerite. The faster rate of xanthate adsorption by chalcopyrite and the specific action of S02 on the surface of chalcopy.ite facilitate the selective separation of chalcopyrite from sphaledte.

Jan 1, 1989

By Jacques Monette

Gold and silver cyanide complexes are presently desorbed from activated carbon by means of hot caustic elutions. These solutions may or may not contain additional sodium cyanide. There are several parameters which affect the rate of stripping. Some of these include pH, ionic strength, and tempera­ture. Stripping is conducted in recirculating (ZADRA) or once through (AARL) circuits. This paper describes the development of a new chemical eluant which increases the rate of stripping of both gold and silver cyanide complexes from carbon. Two case history applications are described.

Jan 1, 1995

By Zhengbin Cheng, Wenguang Lu, Baoqi Sun, Jiaying Tang

This paper studied the flotation separation of feldspar, zircon and kyanite from quartz with a mixture of cationic and anionic collectors. Tests show that collector mixture has specially good effect, using it, the separation of these three silicate minerals from quartz can be successfully achieved at the natural pH value of tap water in the absence of any acid, fluoride and other inorganic reagents. The properties and characteristics of collector mixture were analysed. By means of IR-spectra, ESCA and AES, the action mechanism between collector mixture and minerals was throughoutly studied.

Jan 1, 1995

By Nikhil Dhawan, Shrey Agrawal, SHAILA MIR

The current study investigates the effect of microwave processing on low-grade banded iron ore using charcoal, coking coal, and non-coking coal. Charcoal showed better microwave heating response at low temperatures, and the coals exhibit better heating response at higher temperatures. Low carbon dosage ~ 12% is sufficient to generate concentrate with 61.8% iron grade and ~6% for 94.8% iron recovery comprising of magnetite phase suitable for iron-making applications. The process separation efficiency of ~ 95% is achieved at 6% carbon dosage and decreases with an increase in carbon due to formation of the fayalite phase. The metallization degree showed a strong dependency on reductant dosage and achieved amaximumvalue of 22.7%at 18%charcoal. The comparison of ore with pure iron oxide and the synthetic mixture of iron oxide indicated that the underlying bonding due to banded structure enhances the Joule heating during microwave irradiation and thereby aids in attaining higher temperature and better separation.

Sep 21, 2020

In early March 2011, a 6.2 m (20.3 ft) diameter Rob-bins Double Shield tunnel boring machine (TBM) crossed the finish line in Sochi, Russia. The machine completed a 4.5-km- (2.8-mile-) long section of tunnel that will ultimately become part of the transportation infrastructure for the 2014 Winter Olympic Games. The TBM advanced through difficult ground at aver-age rates of 100 to 120 m/week (330 to 390 ftpw) for contractor OJSC Bamtonnelstroy, a division of the SK Most Company. The section of tunnel will ultimately become a service tunnel for Complex #3 - a section of Sochi?s transportation infrastructure under construction, which includes road and rail tunnels. A second, 10 m (32.8 ft) diameter Robbins Double Shield TBM is currently excavating the parallel 4.6-km- (2.9-mile-) long main railway tunnel using a continuous conveyor system for efficient muck removal. A 13.2 m (43.3 ft) diameter highway tunnel is also under construction. The 6.2 m (20.3 ft) Robbins TBM achieved high rates despite difficult conditions. The tunnels run through mixed ground including massive to completely fractured limestone with clay seams. Some sedimentary rock including sandstone and siltstone is present, along with fault zones consisting of breccias and conglomerates. In May 2010, the machine was stopped after encountering a significant fault zone consisting of broken rock and running soft ground. Field service personnel and crew successfully freed the machine by excavating a bypass tunnel around the TBM, freeing the cutterhead. Following the restart, a combination of continuous probe drilling and ground treatment with cement silicate and foam kept the machine moving forward.

Jan 1, 2011

By Robert H. Scott

Developments during the past few years have brought coal-based composite fuels to commercial readiness. During the next few years, composite fuels will become available from a number of suppliers. Potential users must evaluate the combustion properties of these fuels to determine equipment and operating changes required for their use. Most work to date has been done with boiler applications. However, many potential non-boiler applications exist in the metals and minerals industry. These applications require specific evaluations appropriate for the processes involved.

Jan 1, 1982

By John Turney, John Gathje, Donald Gale

The Eskay Creek deposit, located in northern British Columbia, is a high-grade gold/silver ore associated with complex polymetallic sulfides. Process development began in 1989 and continued through 1993. Because of the refractory nature of the ore, options including roasting and smelting were investigated. The selected process of pressure oxidation was the basis for basic engineering design until a re-evaluation of economics and risk indicated a preference for toll smelting. Although well proven in many industrial applications, pressure oxidation of the Eskay Creek ore dictated several innovations to solve problems associated with silver jarosite formation, preg-robbing, and high soluble copper and zinc concentrations.

Jan 1, 1995

By Andrew Trusiak

Brunswick Mining, employing approximately 1600 employees, is located 40 km south of the city of Bathurst in north eastern New Brunswick. The mine has operated as two lead-zinc operations - the underground mine(No.12) and the open pit mine (No.6). The open pit orebody is presently being' mined by underground methods. It is expected that the No.12 mine will furnish the entire ore supply by the end of 1981. The flotation practice prior to 1971 has been described by Neumann and Schnarr(1) and by Erskine (2). More recently, the current flotation practice has been described by McTavish(3) and deals with some major circuit modifications between 1972 and 1978. The period 1978 to 1980 has seen the completion of. a major flotation cell replacement and expansion program for the No.6 concentrator, and the implementation of computer control in the No. 12 CuPb and Zn flotation circuits.

Jan 1, 1981

By R. V. Ramani, R. Bhaskar

While the National Academy of Sciences has stated that gravimetric sampling technology for compliance purposes is adequate, research into various aspects of respirable dust control require data on many other parameters of airborne dust. These, in turn, have created the need to use many instruments, other than personal gravimetric samplers, in mine environments for dust measurement. There is a need to evaluate the performance of these instruments under conditions of potential use. As part of research in the Generic Technology Center for Respirable Dust, cascade impactors, gravimetric personal samplers and gravimetric samplers collecting dust using isokinetic sampling principles were employed for dust measurements under identical conditions in a mine airway. During the course of the experiments, 8-stage cascade impactors and gravimetric samplers drawing air isokinetically were located in the center of a mine airway at various stations. Two types of data were examined - concentration of dust and size distribution of the dust collected in the samplers. The data show that the amount of dust collected by an impactor is less than half the amount collected isokinetically. The size distributions of the dusts collected from the two instruments, though comparable, show a consistent difference in median diameters. The cause for this bias is examined. The paper presents and discusses the results of the tests, including the concentrations and size distributions obtained from the two instruments for different experimental conditions. There is a need to document the performance of various dust measuring devices in mine airflow conditions.

Jan 1, 1987

By W. Jacobi, B. Haider, D. Regulla, J. Huber

[Introductory Remarks] Thermoluminescence (TL) detectors are widely used for the dosimetry of X- and[ y]-rays. Also filter devices for radon daughter monitoring have been developed in which the a activity on the filter was measured with TL-detectors (Breslin et al., 1977). For this purpose normal LiF-tablets with a thickness of 0.4 - 1 mm were used. However the lower detection limit of such TLmonitors for radon daughters is relative high, especially in areas with a high [y]-background, due to the low [a /-y]-sensitivity ratio of such thick LiF-detectors. This [a/y]-sensitivity ratio can be increased if TL-detectors are used whose thickness is comparable with the range of [a]-particles. On the basis of this consideration we have developed a simple light weighted and sensitive TL-monitor for the measurement of the cumulative radon daughter exposure in air. [Description of the "Monitor] The monitor consists of two parts: The sampling pump with the accumulator, and the sampling probe which contains the air filter and TL-detector system. Both parts are connected with a plastic tube. For operation in mines a light weight, portable air sampler with a built-in accumulator (DuPont model 125 and 200, 400 g) is used which enables an adjustable, constant flow rate in the range of 7.5 -12 1/h. These air samplers allow a sampling period of 10 hours before recharging is necessary. For radon daughter measurements in houses this pump is replaced by a larger, netoperated pump with a flow rate of 180 1/h. Figure 1 shows a schematic cross section through the sampling probe whose weight is 40 g. The radon daughters are collected on a hydrophob membrane filter (Sartorius) with an effective filter diameter of 11 mm and a pore diameter of 3 µm; its collection efficiency for radon daughters is [>] 95%. Above the filter the detector system is mounted. It consists of two thin Tm-activated CaSO4-TL films of 8 mm diameter on a Al-carrier foil manufactured by Matsushita Inc., Japan. The thickness of the TL-film is 6 mg/cm2, which is comparable with the range of a rays. The first detector is faced in 3.5 mm distance above the filter; in addition to the ambient y background this detector is exposed to the [a] and ß radiation from the radon daughters on the filter. Between the first and the second TL-detector is an Al-absorber of 0.5 mm thickness which shields this detector against the [a] radiation and partly also to the ß radiation from the filter. Both detectors have the same [y] shielding. After air sampling both TL-detectors are read-out with a commercial, hot-air reader (Matsushita Inc. / Japan, Model 505 A). The glow-curves are identical for [a and y] rays (Regulla et al., 1980). The integral TLsignal from both detectors is displayed in mR-units (or mR-equivalent). The difference between the response of the unshielded TL-detector above the filter and the shielded TL-detector is proportional to the time-integral of the filter activity, integrated over the sampling period. Calibration and Intercomparison Measurements] The linearity of the a response was checked with a 241Am-source for an [a] fluence on the detector surface of 5400 [a's/cm2•s] in the range of 102 -105 mR-equivalent. Within the experimental error of 15% the response function is linear. The TLD-monitor was calibrated for radon daughters in air by comparison with a calibrated integrating, monitor (WLM-meter) equipped with a Si-surface barrier detector and a direct electronic read-out; this instrument was developed by us for area monitoring some years ago (Haider et al., 1976). The results of simultaneous measurements with the TL-monitor and the electronic WLM-meter in mine areas and in indoor air of houses are shown in figure 2. On the abscissa the mean potential [a] energy concentration (in WL) during the sampling period is given which was derived from the measurements with the electronic WLM-meter. On the ordinate the corresponding response of the TLDmonitor to radon daughters (difference between both TL-detectors) is displayed, expressed in terms of mRequivalent per liter sampled air. It follows from this comparison a linear relationship over the whole range of 0.005 - 5 WL with a standard deviation of 10%. The resulting calibration factor for the TLD-monitor is 18± 2 mRequiv per WL • 1.

Jan 1, 1981

By Betty L. Gibbs

Before the first shovelful of dirt is removed from a developing mining property, a wide range of data must be collected, organized and analyzed. Among the key steps in this process are: • Visualization of the deposit from drill hole data and geologic interpretation, using all available information, including surface geology, geochemistry and geophysics. • Drawing of vertical and horizontal sections. • Construction of a 3D solid model of the deposit. • Contouring of deposit outlines and geological structure until the model represents best estimate of reality. • Estimation of grade and quality distribution. • Calculation of reserves. • Examination of possible mining methods. • Determination of economic feasibility. Many techniques are available to aid in this process of mine project feasibility analysis, from quick pencil calculations to sophisticated computer methods. However, time races faster in the complex modem business world than it did 50 years ago. Tried and true pencil methods take too much time. Opportunity may pass a mine developer by while a property is still in the first stages of analysis. In the days of hand techniques, initial analysis of the economic feasibility of a mining project usually stopped with reserve calculations and broad mine planning. Further planning was not done or was done only for the short term. Manual techniques require too much time and manpower to evaluate a longterm mining program. Mining-industry recognition of computer utility has increased. Most companies now use computers in technical applications and could not conceive of working without them. Building initial computer models of a deposit may take nearly as long as hand techniques. But the payback comes when changes are needed and a variety of mine plans are quickly tested.

Jan 1, 1990