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By E. K. Kleespies

The Bureau of Mines determined the kinetics of the reaction of titanium-iron alloys with titanium trichloride dissolved in sodium chloride to provide a basis for understanding the reactions occurring in metallurgical processes involving reduction of the metal halides or alloy refining in fused salts. The rate of the heterogeneous reaction was determined between titanium-iron alloys and titanium trichloride to elucidate the effects of alloy composition on the rate. Measurements were made in an inert atmosphere with a high-temperature thermobalance using high-purity reactants. The rates of the reactions were about 1 x 10-5 g Ti/cm2-sec, and the reaction was phase-boundary controlled. Titanium alloys of the body-centered cubic beta structure reacted faster than those with the hexagonal close-packed alpha structure. The inter-metallic compound, TiFe, reacted very slowly, whereas TiFe2 was inert. Alloys containing above 89 atomic percent iron gained weight by reacting with titanium species in the salt solution and depositing titanium in the alloy. The effect of TiCl3 concentration on the reaction rate was determined from 2 to 12 weight-percent TiC13 and at various alloy compositions. At high iron contents, above 50 atomic percent, the TiC13 concentration effect was small. At lower iron contents, the TiC13 concentration effect was greater for beta-crystalline alloys than for alpha-crystalline alloys. The temperature dependence of the reaction between titanium alloy containing 8.7 atomic percent iron and titanium trichloride was measured over the temperature range 1,062° to 1,220° K, and the energy of activation was 7.7 kilocalories for the reaction.

Jan 1, 1967

By T. Christos

The explosive oils, nitroglycerin (NG) and ethylene glycol dinitrate (EGDN), were extracted from dynamites by a halocarbon solvent and were then determined by high-pressure liquid chromatography. Separation was achieved by liquid-liquid chromatography on a column packed with Durapak-Carbowax 400/Corasil II and the eluted NG and EGDN were detected with a double-beam ultraviolet detector.

Jan 1, 1973

By Martin Harper

This paper concludes a five year program on research into the use of a portable X ray fluorescence (XRF) analyzer for analyzing lead in air sampling filters from different industrial environments, including mining, manufacturing and recycling. The results from four of these environments have already been reported. The results from two additional metal processes are presented here. At both of these sites, lead was a minor component of the total airborne metals and interferences from other elements were minimal. Nevertheless, only results from the three sites where lead was the most abundant metal were used in the overall calculation of method accuracy. The XRF analyzer was used to interrogate the filters, which were then subjected to acid digestion and analysis by inductively coupled plasma optical emission spectroscopy (ICP OES). The filter samples were collected using different filter holders or "samplers" where the size (diameter), depth and homogeneity of aerosol deposit varied from sampler to sampler. The aerosol collection efficiencies of the samplers were expected to differ, especially for larger particles. The distribution of particles once having entered the sampler was also expected to differ between samplers. Samplers were paired to allow the between sampler variability to be addressed, and, in some cases, internal sampler wall deposits were evaluated and compared to the filter catch. It was found, rather surprisingly, that analysis of the filter deposits (by ICP OES) of all the samplers gave equivalent results. It was also found that deposits on some of the sampler walls, which in some protocols are considered part of the sample, could be significant in comparison to the filter deposit. If it is concluded that wall deposits should be analyzed, then XRF analysis of the filter can only give a minimum estimate of the concentration. Techniques for the statistical analysis of field data were also developed as part of this program and have been reported elsewhere. The results, based on data from the three workplaces where lead was the major element present in the samples, are summarized here. A limit of detection and a limit of quantitation are provided. Analysis of some samples using a second analyzer with a different X ray source technology indicated reasonable agreement for some metals (but this was not evaluated for lead). Provided it is only necessary to analyze the filters, most personal samplers will provide acceptable results when used with portable XRF analysis for lead around applicable limit values.

Jan 1, 2007

By John R. Benham

The Blue Joint Mtn. RARE II area may contain barite resources. One claim, the Woods Creek Barite No. 1, contains two veins of barite of drilling mud quality. The quantity of barite present could not be determined due to limited surface exposures. Sections 1, 2, 11 and 12 of T. 2 S., R. 23 W. in the study area are classified by the U.S. Geological Survey as prospectively valuable for geothermal energy resources. These sections border Blue Joint Creek Hot Springs, which are outside the study area.

Jan 1, 1981

By Martyn F. Roetter

The work of the operational communication systems' group dealt with a range of communication needs and functions within mines, primarily along haulageways, to and within sections up to the working face itself, and in mine shafts. A mixture of communication techniques and hardware is needed to satisfy this variety of communication needs within the differing environments encountered in U.S. mines. Substantial progress, both experimental and theoretical, has been made in recent years towards developing alternative communication systems suitable for use in mines which are based on "guided" waves, including wire-less (waveguide-like propagation in mine tunnels) and wire-based systems (leaky coaxial cables or wires) . Major priorities identified for further work needed to confirm (or deny) the applicability, and refine the operational specifications of promising communication systems for mine use include: Short-Term Projects o Cost/performance analyses of promising leaky coaxial cable and UHF radio communication systems which require further data from: - Experimental investigation under U.S. mine conditions of the performance of potentially applicable leaky coaxial cable communication systems developed in Europe (France, Belgium, and the U.K). - Cost estimates on these coaxial cable communication systems. - Measurements of UHF radio propagation in low-coal mines. - Investigation of the influence of obstacles (e.g. shuttle cars and section machinery) in the entries on UHF radio propagation in mines. o Investigation of the problems of transmitter and receiver coupling and termination matching associated with the two-way propagation of low frequency radio waves in hoist shafts.

Jan 1, 1973

Objective To characterize the roof fall risk associated with underground limestone mining. Background During the first 5 years of this decade, more than one-fourth of the underground mining fatalities occurred as the result of fall of ground. The large openings in underground stone mines present limitations in observing ground conditions because of floor-to-roof heights ranging from 20 to 60 ft or more. Generally, the status of ground conditions in under-ground stone mines is based on observation and experience obtained during mining development. Some mines use monitoring instruments to gain information on roof conditions, but this practice is typically focused and localized to address issues in a particular area or section of the mine. The Roof Fall Risk Index (RFRI) described here provides a method of systematically characterizing the risk of roof falls to enhance the safety of mine workers. Approach As in many industries, a defective product signals the potential for failure. Similarly, defective rock or strata in an underground stone mine presents a potential risk. Assessing ground conditions relative to the concentration of defects observed provides a way to index or rate these conditions and the subsequent risk. Through observations at approximately 50 underground limestone mines in the United States, strata defects were categorized to develop a quantitative method for determining the RFRI. This method is specifically geared to underground lime-stone mines because strata defects are difficult to see and limited by the experience and knowledge of the observer. Overall, 10 defect categories were deter-mined: 3 that relate to geology, 4 that result from mine development, 2 that are indicative of the roof profile, and 1 that addresses moisture or water flow (see RFRI Chart 1). The defect categories are also weighted to reflect the conditions indicative of roof or strata movement or separation (categories 4 through 8). These weights are multiplied by the assessment value to determine the total category value. The benefit of using monitoring techniques to gain information on roof conditions is also factored into the RFRI for overall assessment of an area in the mine. Each defect category is assessed with a value of 1 to 5 based on parameters as defined in each defect category, with 5 indicating the highest degree or level of defect. The assessment value of 3 is also used when information on a parameter is unknown. The parameters for the defect categories are illustrated in RFRI Chart 2 for use in determining the assessed value. How It Works The RFRI provides a means to categorize the risk for roof falls in underground stone mines. The concept of this calculation is aimed at providing an indication of the level or degree of defect relative to the area of the mine examined. The RFRI for the calculation produces a distribution where RFRI values approaching 0 represent a stable condition and those ap-proaching 100 represent an unstable condition.

Oct 1, 2006

By Roy C. Bartholomae

This U.S. Bureau of Mines study found that the performance of the active noise cancellation hearing protector in a reverberant field was mixed. The performance varied when the conditions changed from ideal to nonideal. The active noise cancellation (ANC) component provided substantial additional noise reduction from 125 to 500 Hz for all testing conditions (broadband noise or pure tones both with and without safety glasses). While the ANC under ideal conditions provided additional attenuation from 500 Hz and below, under nonideal pink noise conditions the ANC amplified noise below the 125-Hz third octave band. There was a middle band of frequencies at which the ANC amplified noise levels ranging from 630 to 4,000 Hz. The results for pure tones showed that attenuations were higher but that they followed the same general trend.

Jan 1, 2010

To provide accurate navigation and control of continuous mining systems.

Jan 1, 1996

By E. J. Kloos

The Bureau of Mines developed a test for evaluating gas masks designed to protect against phosphine gas; phosphonium iodide is used as a source of phosphine. Gas masks approved by the Bureau for respiratory protection against phosphine include the GMC-SS-1, Mine Safety Appliances Co.; the LG-10 and LG-10G, Willson Products Division, The Electric Storage Battery Co.; and the 084-PHOV-R, Acme Protection Equipment Co.

Jan 1, 1966

By E. J. Kloos

The Bureau of Mines developed a test for evaluating gas masks designed to protect against phosphine gas; phosphonium iodide is used as a source of phosphine. Gas masks approved by the Bureau for respiratory protection against phosphine include the GMC-SS-1, Mine Safety Appliances Co.; the LG-10 and LG-10G, Willson Products Division, The Electric Storage Battery Co.; and the 084-PHOV-R, Acme Protection Equipment Co.

Jan 1, 1966

The Bureau of Mines Minerals Information organization collects worldwide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. This data collection activity was instituted by the 47th Congress in an appropriations act of August 7. 1882 (22 Stat. 329), to place the collection of mineral statistics on an annual basis. The most recent authority for the Bureau of Mines Minerals Information activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress), which strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1985

By R. W. Nash

This report describes the design and operation of a digital instrumentation package for the Bureau of Mines improved torsion pendulum, a scientific instrument that measures the vibration damping of metallic materials. The new design eliminates manual analog-to-digital conversion, reduces the data acquisition time, and increases the precision of the measurements. The digital output can be coupled directly to a micro-processor or computer to produce the final data in real time.

Jan 1, 1983

By Gordon L. Kinney

Following a year of great uncertainty, the political situation in Bangladesh improved during 1976. The major problem for Bangladesh remained the high birth rate and crowded conditions. Bangladesh had the highest population density of any agrarian country--over 80 million people in a land area of 144,000 square kilometers, 65% of which is considered arable. The Government, with considerable foreign assistance, was actively encouraging voluntary family planning, and set a growth rate target of 2% per year or less. However, even if the growth rate was reduced to the target level immediately, the population of Bangladesh would nevertheless nearly double within 20 years.

Jan 1, 1980

Develop a cost-effective, flexible method for extinguishing underground coal mine Fires that can be readily used in fire conditions encountered in both abandoned mines and coal outcrops. In addition to the abatement of an underground coal fire, a secondary objective was to prevent subsidence by filling the voids with a material having sufficient compressive strength to minimize subsidence. Approach The Colorado School of Mines Research Institute was awarded a research contract to determine the viability of using Foaming Mud Cement for abating underground coal mine fires and preventing subsidence. The program consisted of a laboratory and pilot scale investigation and process development. An extensive, controlled test program was conducted simulating floor, rib, roof and rubble fire conditions. Field demonstrations were conducted after the pilot scale research was completed. How It Works Traditional techniques have targeted the control of burning by eliminating the air, fuel source or heat. This has been accomplished by trenching, quenching, mothering or combinations of these three methods. These techniques were not always successful, particularly in the case of fires in abandoned mines.

Jan 1, 1991

By John R. Benham

In 1987, at the request of the Bureau of Land Management~ the U.S. Bureau of Mines studied 7,600 and 3,000 acres, respectively, of the Slocum Creek (OR-003-075) and Upper Leslie Gulch (OR-003-074) Wilderness Study Areas in order to evaluate their mineral resources. They are located in Malheur County, OR, about 25 mi northwest of Jordan Valley. Both areas have an occurrence of stone (welded tuff) covering about 3,000 acres which is suitable for construction purposes including road metal, ballast, and road fill. However, similiar deposits are more accessible and closer to markets.

Jan 1, 1988

By Robert W. Freedman

This report describes sampling and analytical procedures used for measurement of sulfates in diesel tailpipes and in the diluted exhaust within dilution tunnels. A variety of methods exist for sulfate analysis for such systems, including ion exchange. Two chemical methods used by the Bureau of Mines are described in detail. These are based upon spectrophotometric measurement of chloranilic acid using barium chloranilate. The procedures are rapid and relatively inexpensive. In general, ion exchange is preferred by many analysts for sulfate analysis. However, it is more complex and expensive than chloranilic acid procedures, which are adequate for exhaust analysis.

Jan 1, 1982

By Pablo Velasco

Ecuador had limited mineral output, al-though the Government attempted to stimulate metallic mineral exploration and also evaluated a gypsum and a phosphate deposit. A pilot plant to exploit gold deposits was established, and there was extensive gold exploration activity in southern Ecuador. Domestic output of iron and steel declined sharply. Among all minerals, petroleum output was the dominant factor with both exports and production increasing significantly over that of 1988. Crude oil exports contributed 63% of total export earnings and about 70% of the central Government's revenue.

Jan 1, 1986

By E. G. Valdez

The Federal Bureau of Mines, in cooperation with Ford Motor Co., investigated the recovery of polyurethane foam and other assorted plastics from the nonmagnetic reject of automobile shredders. Preliminary studies were con-ducted on a 1957 hulk augmented with additional foam and assorted plastics. The proposed flowsheet developed by the Bureau from the preliminary studies consists of a combination of screening, water classification, and gravity separation. The process was then tested on reject from two shredded 1972 cars. All of the foam and between 52 and 70 pct of the assorted plastics were recovered. The composition of the reclaimed foam concentrates ranged from 46 to 66 pct foam; the concentrates were hydrolyzed in laboratory tests by Ford Motor Co. to produce a reusable liquid mixture of polyether glycol monomers and toluene diamine.

Jan 1, 1975

By Forrest T. Moyer

THE SAFETY record of the mineral and mineral-fuel-mining-and-processing industries retrogressed slightly in 1964, as indicated by the 3-percent increase in the frequency rate of all injuries. A slight improvement in the fatality rate was more than offset by the less-favorable rate of occurrence of nonfatal injuries. The overall-operating activity of these industries was lower in 1964 as measured by slight declines in employment and total man-hours of worktime. Injury Experience.-The rate of occurrence of all disabling work injuries in the mineral industries was 18.00 per million man-hours. This overall rate in 1964 comprised frequencies of 0.29 for fatal injuries and 17.71 for nonfatal work disabilities, which compared with respective rates of 0.30 and 17.20 in 1963. Fatalities totaled 538 or 30 less than in 1963. However, the total nonfatal disabilities of 33,151 in 1964 was 492 higher than in the preceding year.

Jan 1, 1965

By P. W. Jeran, M. C. Irani, D. H. Lawhead

The Beckley mine is one of five new mines in a heretofore unmined portion of the Beckley coalbed. The remoteness of these new mines from prior mining and their greater overburden preclude applying methane emission experience obtained in the old mines. Four sections of the Beckley mine were monitored. The data gathered show that variations in methane emission cannot be explained by variations in coal production. Although overburdens varied by as much as 30 pct, no correlation with methane emissions could be determined. The rib emissions increase with increased length of rib from a section advancing into virgin coal and do not decline over a prolonged idle period (32 days) whereas some decline has been measured for a section not mining into virgin coal. The indication is that degasification prior to mining will reduce the hazard of methane emissions in this area of the Beckley coalbed.

Jan 1, 1977