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By Leland A. Yerkes

Refining aluminum from crude aluminum alloys by the subhalide reaction was investigated to develop a method of producing aluminum by means other than electrolysis of its oxide. The best materials and design for the apparatus and also optimum operating conditions, including temperature, pressure, vapor flow rate, and composition of alloy charge were studied. In the subhalide process, aluminum-trihalide vapor reacts with aluminum in the alloy under high temperature and low pressure, forming volatile aluminum monohalide which reverts to aluminum metal and aluminum trihalide on cooling. The only halide used in this investigation was aluminum trichloride. The crude aluminum-silicon alloys used as the principal raw material contained from 21.9 to 36 percent aluminum, and significant quantities of iron and titanium. These alloys were produced by direct electric smelting of clays. Graphite tubing that was heated by an induction coil proved to be satisfactory material for the laboratory reactor chamber, Enclosed in an insulated glass or quartz pipe, the reactor was used in both vertical and horizontal positions with various baffle and tray arrangements for directing the trihalide vapor both over and through the alloy. Aluminum trichloride vapor was generated in the sublimer at one end of the glass pipe, passed into the reactor where contact was made with the crude alloy, and aluminum monochloride gas was formed. When the gaseous mixture of aluminum monochloride and unreacted tri-chloride passed out of the reactor and entered the condenser, the gases were cooled to 900° C. or less, causing the monochloride to disproportionate into aluminum and aluminum trichloride vapor. The aluminum was deposited on the condenser walls while the aluminum trichloride vapor was carried out of the condenser and into the opposite end of the glass pipe where it solidified on the cooled copper coils.

Jan 1, 1961

By Martin H. Stanczyk

Acid leaching of selected copper sulfide minerals, impure copper sulfide flotation concentrates, and a cement copper precipitate at elevated temperatures and pressures was investigated. Copper extractions of 97 to 99 pct were obtained by leaching chalcopyrite and the flotation concentrates with water under oxidizing conditions at 200° C for 30 to 60 min. In tests with bornite, chalcocite,and cement copper, addition of sulfuric acid or pyrite to the autoclave was required to obtain similar copper extractions. The chemistry of leaching copper minerals was studied. It was determined that different copper sulfides altered to covellite as one step in their dissolution.

Jan 1, 1963

By John D. Sullivan

The recovery of copper by leaching from relatively low grade ores containing both oxidized and sulphide minerals is rapidly gaining in commercial importance. There is an economic limit below which certain ores can not be treated by concentration methods, and material with values below this limit must be discarded, possibly to be treated later, or the copper must be extracted by wet processes. Heap leaching has been carried out by the Phelps Dodge Corporation, Copper Queen Branch, for several years, and to-day its plant is a large producing unit. The Ohio Copper Coy at Bingham, Utah; has been leaching in place since 1919. Many other leaching operations are also being; carried out in various parts of the United States and in foreign countries. The plant at Rio Tinto, Spain, may be considered the father of heap leaching.

Jan 1, 1931

By George T. Motock

In Germany the extraction of lithium and its salts has been handled mainly by units of the two major concerns - Metallgesellschaft A, G. and Deutsche Gold und Silber Scheide Anstalt, both with headquarters in Frankfurt. Zinnwaldite, which belongs to the mica group, is the major source of the lithium-containing raw material in Germany. Lepidolite and amblygonite also are used when available, but they are imported, as there are no major deposits of these two minerals in Germany.

Jan 1, 1946

By A. A. Cochran

Methods of preparing small heats of steel containing radioisotopes were developed, and the techniques of stripping film autoradiography were used to detect and study the carbide and sulfide phases in titanium-bearing steels. Metallography had revealed areas of titanium sulfide and ferrite or pearlite adjacent to areas of titanium carbide and ferrite, and unidentified, irregular phases at the boundaries between these two areas. Sulfur 35 was used to deter-mine the extent of the titanium sulfide inclusions, and carbon 14 was used to delineate the titanium carbide phase. Individual radioactive areas were located with a resolution of approximately 10 microns. A general background exposure that was not correlated with microscopically visible phases was observed in the carbon 14 autoradiographs. The evidence from both sulfur 35 autoradiographs and carbon 14 autoradiographs indicated that the unidentified inclusions were sulfides rather than carbides. INTRODUCTION The use of radioisotopes to facilitate the work at the Rolla Metallurgy Research Center was expanded in fiscal year 1959 when the Bureau of Mines authorized the installation of an intermediate-level radioactivity laboratory. Before this time, sealed cobalt 60 sources had been employed for radiography, but no tracer work was done. The primary objective of the first experiments conducted in the new laboratory was to supplement physical metallurgy investigations of selected problems in steel research.

Jan 1, 1962

By L. P. Kleinmann

To control the formation of acid drainage at its source, the Bureau of Mines has investigated the role of iron-oxidizing bacteria in the oxidation of pyrite. In laboratory tests, it was determined that Thio-bacillus ferrooxidans could be controlled in coal refuse using anionic surfactants, with an associated decrease in acid production of about 75 pet. Based on these results, large-scale tests were conducted at an 8-acre active coal refuse area in northern West Virginia and an 11-acre inactive refuse pile in southern West Virginia. Acid production was decreased 60 to 95 pet for 4 to 5 months after application of 55 gal/ acre of 30-pct sodium lauryl sulfate solution. To date, effluent surfactant concentrations have been extremely low. Either a hydroseeder or a road-watering truck can be used to apply the surfactant. Since the surfactant solution must reach the pyritic material to be effective, sites that have been reclaimed are generally not amenable to these procedures. A simple laboratory test is described that provides an estimate of adsorption potential; this can be used to calculate a safe application rate.

Jan 1, 1983

By M. E. Volin

The Buckeye manganese deposits are in Stanislaus County, Calif., about 33 miles south of Tracy. From 1917 to 1919 the deposits produced 13,370 tons of ore reported to average 46 percent manganese and 14 percent silica. The deposits are confined to two areas of' development, known as the north mine workings and the south mine workings, about 700 feet apart horizontally. Mineralization occurs chiefly as rhodochrosite and psilomelane interbedded in cherts of the Franciscan formation. As a part of the Bureau of Mines program of investigation and development of domestic mineral deposits, a development project was started November 25, 1940, and completed June 27, 1941. The Federal Geological Survey cooperated by mapping the topography and geology and logging the drill cores. The program included road and. trail building, trenching, underground excavation, diamond drilling, and sampling. The following pages mention the location, brief the history, and note the physical .features of' the district. Mine workings are sketched, the deposit is described, and the plan of the project is noted. The work performed by the Bureau of Mines is explained in the concluding pages with a summary of the drill-hole logs.

Jan 1, 1949

By R. P. Jewett

The object of this investigation was to correlate the crushing strength of green pellets prepared from magnetite, specular and earthy hematite with the particle size of these respective raw materials. In this study no attempt was made to correlate the strength of fired pellets and particle size. The effect of particle size upon a number of fine ores and concentrates was studied. Much of the low-grade ore reserves in the Lake Superior Region must be finely ground before concentration and then agglomerated for iron and steelmaking processes. Fine natural ores also must be agglomerated. Pellets constitute an important type of agglomerate. Considerable handling occurs during screening to remove undersize and oversize pellets, and in transfering green unfired pellets from the balling machines to the heat-hardening equipment. As a result the strength of the green pellets is a factor of great importance.

Jan 1, 1961

By Charles R. Harrison

The purpose of this study and resulting development of the training program, "Safety--Let's Make It Happen" was to determine the relation of concepts to the development of desired Health and Safety behavior. After extensive pre-contract study, it was hypothesized that improved acceptance and understanding of the Federal Coal Mine Health and Safety Act of 1969 could possibly contribute to the reduction of accidents. Second, in order for an individual to accept and understand the Act, he or she must have a working knowledge of its purposes and application. Third, acceptance and understanding of the Act, necessary to protect the individual from negligence, was imperative. Fourth, an actual operating company could provide the base in which to test these hypotheses in a meaningful manner and develop this type of training program. Six assumptions were agreed upon before embarking on this study and training program development. (1) In the cognitive process, a concept introduction into an individual's personality may result in a behavior quite different than if he or she had been exposed to a different concept.

Jan 1, 1977

By D. J. MacDonald

This U.S. Bureau of Mines report reviews published information on synthetic berlinite (AlP04) and suggests experimental conditions requisite for its production. Berlinite is a piezoelectric material with potential use as a substitute for quartz in the crystal oscillators, which are components of electronic and electroacoustic equipment. Information gathered here (mostly from published sources) includes historical background, physical properties, end-use applications, criteria of quality, and physio-chemical factors involved in berlinite crystal growth. It is concluded that growing large high-quality berlinite crystal would require high-purity starting materials in an autoclave equipped with a noncorrodible liner and operated with temperature control of ±O.OO5 ac over a range of 250 to 350 ac.

Jan 1, 1995

By N. S. Dalal, X. Shi, V. Vallyathan

"Electron spin resonance (ESR) and cytotoxicity measurements were made on newly fractured silica to examine specifically the role of the fractured-induced, siliconbased radicals (Si· and SiO·), and silica-generated hydroxyl (·OH) radicals in the mechanism of the cell membrane damage by silica. The concentration of the Si· and SiO· radicals was controlled through decay processes, thermal annealing, and boiling, while that of the ·OH radicals was varied by using catalase, superoxide dismutase, KMnO4, Ha2seO3, ascorbic acid, and metal ions, and monitored via ESR spectroscopy. The dust's cytotozicity potential was evaluated by measuring the silica-induced hemolysis and also by determining lipid peroxidation (using linoleic acid). Prom the comparison of hemolysis and ESR results it is deduced that the radicals play little· or no role in the silica-induced hemolysis. However, the lipid peroxidation data indicate that the radicals might be involved in the initiation of an oxidative chain reaction leading to the macrophage membrane damage through lipid peroxidation. INTRODUCTIONThe biochemical mechanism of Quartz-related pneumoconiosis is still not fully understood. It is believed, nevertheless, that one event of primary importance is the perturbation of cell membranes by the dust particles (Allison et al., 1966; Allison and Harrow, 1971; Bateman et al., 1982; Parazzi, et al., 1968; Reiser and Last, 1979; Shi et al., 1989; Summerton et al., 1977). The ensuing cell-membrane damage unleashes certain lytic enzymes resulting in additional cell injury and eventual fibrosis (Nolan et al., 1981; Summerton et al., 1977). Thus considerable effort is currently being made towards the understanding of the processes by which quartz particles disrupt the membrane of a red blood cell (RBC) or a pulmonary alveolar macrophage (PAM). A simple but important method of evaluating the membrane damage potential of a dust is the hemolysis test (Harington et al., 1971). Even though this test is used routinely for screening dusts for their cytotoxicity potential, the biochemical mechanism underlying the cell lysis by many dusts, including quartz, is still controversial (Kilroe-Smith, 1974; Singh and Rahman, 1987), and this provided us the impetus for the present undertaking."

Jan 1, 1989

By R. V. Ramani, W. Miola, R. Srikanth, S. C. Soboleski

"Dust control in high-production longwalls requires attention to operating practices and ventilation schemes. Several studies have shown that the shearer is the major source of dust on a longwall face. Support movement has not been regarded as a major source of dust in US longwalls. Yet, under certain conditions, 31% of the shearer operator's dust exposure can be due to support movement.Several methods have been developed for the control of shield-generated dust. But the need for better methods is apparent. In this paper, the amount of airborne, respirable dust generated per shield move is estimated from specially designed experiments on longwall faces. Ten experiments were conducted on five longwall faces in four mines. Each experiment involved one face visit and lasted three to six hours. The contribution of shield movement to the airborne, respirable dust concentration immediately downwind of the shield move varied between 0.12 and 1.75 mg/m3 in the five longwall faces. The mass of airborne, respirable dust gener-ated by shield movement was found to vary between 39 and 386 mg per shield move. The results from this study reveal that control of dust from longwall shields requires a combi-nation of approaches involving alternative operating prac-tices, reducing shield dust generation rate, increasing face air flow and decreasing personnel exposure.IntroductionIn 1992, longwall mining accounted for about 36% of US underground coal production, a 240% increase from a decade ago. The absolute longwall tonnages were 46 and 133 Mt (51 and 146 million st), respectively. Compared with room-and¬pillar mining systems, the longwall mining system is charac¬terized by higher recovery, enhanced safety and higher pro¬ductivity.However, personnel dust exposure on a longwall face is higher than in other types of mining. According to Mine Safety and Health Administration (MSHA) data, fewer longwalls were in continuous compliance with the applicable dust standard in 1992 than in 1989.Controlling shearer-generated dust and reduction of per-sonnel exposure to airborne dust have commanded attention in the design of longwall faces, operational practices and ventilation schemes. Studies in the United States and abroad have revealed that support-generated dust can be a major obstacle to compliance under certain conditions (Becker et al., 1989; Bradley et al., 1983; Jankowski and Organiscak, 1983; Jankowski et al., 1990; Organiscak et al., 1985)."

Dec 1, 1996

By M. H. Rinkenbach, C. A. Taylor

The detonating compound cyanuric triazide was discovered*** and patented**** by Erwin Ott, and on account of his claims, the Bureau of Ordnance, U. S. Navy, desired more complete data, so an investigation was made. The results obtained were such that the Bureau of Crdnance recommended publication thereof for the benefit of the explosives industry. Some of the patent claims regarding cyanuric triazide are as follows: 1. It is not poisonous in contradistinction to fulminating mercury and lead azide. 2. In contradistinction to the hitherto employed priming agents it is fusible, and its fusion point (94°C) is so low that the product melted by a single heating in water or steam bath, can be poured without danger in the capsule shell. It solidifies therein after cooling, and shows the density of 1.5. 3. It has been determined that the cyanuric triazide, in spite of its very much higher priming actions, is much less brisent then ful- minating mercury and lead nitride. 4. The chemically pure cyanuric triazide (C3M2) constitutes colorless crystals melting at 94°0., and is not volatile. It is not affected by cold water, and only slowly saponified by hot water. It is relatively insensitive to friction and not too strong concussion, but explodes by impact or when hea ted to 170°C., or when heated suddenly. It is not more sensitive to friction and shocks then fulminating mercury. 5. The preparation of the triazide is preferably carried out by acting with an excess of sodium azide in an aqueous solution; in the cold, on cyamric chloride gradually suspended in the said solution.

Aug 1, 1923

By Stanley M. Walker

Safety consciousness is not a constant for which a specific value can be assigned, but is a variable, which is frequently intangible. Its evaluation is not simple. We all know that safety consciousness is the most potent factor in the prevention of accidents. Safety consciousness may be defined as awareness of hazard and alertness to danger, which controls every action of an individual through his desire to remain alive and uninjured.

Jan 1, 1951

By Clinton C. Knox

The Townsite mine, consisting of 40 acres in the town of Cardin, Okla., is in the center of a highly productive part of the Picher-Cardin district of the Tri-State zinc and lead field. Previous to the time of the work done by the Bureau of Mines, the property had been partly explored by churn drilling, and an area-of about 8 acres in the southwestern corner had been exploited by underground workings. The Bureau of Mines investigation had as its object the more intensive development of the northern part of the property where previous drilling had indicated a possible ore deposit of commercial grade. Churn drilling by the Bureau began in September 1942 and continued to February 1943. Twenty holes totaling 4,827 feet of bore were completed. Utilizing the information gained from these drill holes, the Weidman Mining Co., lessee of the tract, sank a shaft and proceeded to the exploitation of the indicated ore bodies.

Jan 1, 1949

By W. M. Merritts

The control of coal dust created and released during the operation of continuous mining machines in bituminous-coal mines of the United States is a problem. The interest manifested in this problem indicates the seriousness of the hazards involved, particularly when the dust has not been abated at its source and has become air-borne. Officials of the Sunnyside No. 1 mine, Kaiser Steel Corp., were confronted with the problem of abating the coal dust created by operation of a recently installed continuous-mining machine, and they requested the aid of representatives of the Coal-Mine Inspection Branch, Bureau of Mines, United States Department of the Interior, in developing an effective method of allaying the coal dust at its source.

Jan 1, 1951

By H. R. Shell, Robert C. Johnson, Wilbur H. Warwick

Alpha silicon nitride fibers , Si3N4 , were successfully grown in graphite crucibles by a new method utilizing silicates and silicon ( S in equations below) as sources of silicon and using carbon , aluminum , and silicon as reducing agents (R in equations below ) . The basic reaction mechanism is believed to be generally as follows : 1,300 - 1,500 ° C S + R + N₂ SiO + RO + N₂ › 3Si0 + R + 2N₂ _1,300 - 1,500° C 3RO + Si¸N • ( 1 ) ( 2 ) A build - up of coatings on the solid raw- material particles hindered the evolution of silicon or silicon monoxide vapor and thereby slowed down further formation of silicon nitride fibers . Free oxygen in the crucible caused the formation of amorphous silicon dioxide ( SiO2 ) fibers . This problem was solved by passing , entering , and exiting gases through layers of lump graphite inside the reaction vessel . The silicon nitride fibers grew best around 1,400 ° C. Nitrogen flow rates from 4 to 6 liters per minute were adequate . The fiber widths were generally only a few microns whereas their lengths sometimes reached one - quarter inch or more . Chemical and X- ray analyses indicated that bulk fiber samples were usually 80 to 90 percent Si3N4 . The fibers had good oxidation resistance to about 1,260 ° C. Thermal shock resistance was excellent . Electrical resistance was determined .

Jan 1, 1964

By A. E. Back

A method has been developed in the laboratory for successfully treating titaniferous magnetite ore from the deposit at Iron Mountain, Wyo. The ore is roasted with 15 percent sodium carbonate to convert the vanadium to a water-soluble form and fix the soda for the subsequent electric-smelting step. Approximately 90 percent of the vanadium is recoverable in a product assaying 80 percent V2O5. The leached calcine is briquetted and smelted in a graphite-lined electric-arc furnace. Substantially all of the titanium is recovered in a soda slag, assaying 60 percent TiO2 and 2 percent Fe, which can be upgraded to 75 to 80 percent TiO2 by leaching with dilute sulfuric acid. The upgraded slag could be utilized for the production of titanium dioxide pigments or titanium tetrachloride. About 90 percent of the iron is recovered as pig iron, containing only minor amounts of vanadium, titanium, and sulfur. The high TiO2 slag compares favorably with slag containing about 70 percent TiO2 being produced by the Quebec Iron & Titanium Corp. at Sorel, Quebec. The data obtained from this investigation indicate that a feasible process has been developed for treating Iron Mountain ore, and larger-scale testing is warranted to develop engineering data for the ultimate utilization of this deposit as a source of titanium, iron, and vanadium. There are adequate supplies of basic raw materials, electric power, water, sodium carbonate, coal, and petroleum products within fairly short distances of Cheyenne and Laramie, Wyo., the nearest cities and probable plant- and labor-supply points.

Jan 1, 1952

This report summarizes the results of several field tests conducted by Collins for the Bureau of Mines under contract SO122076 and contract H0232056. The field projects represent a part of Collins continuing effort on a broad study of coal mine communications. These experiments analyze the propagation characteristics of radio signals in a working coal mine environment. The intent of the program is to provide basic propagation loss characteristics by which we may evaluate various approaches to an integrated mine communications system. The goal of such a system is to satisfy both operational and emergency communications needs in the mine. Field testing was conducted during the last week of November 1972, at a coal mine operated by Inland Steel Company, near Sesser, Ill, and in the Robena No. 1 Mine, Waynesburg, Pa, on 12 March 1974. The tests included uhf propagation losses and noise (200 MHz to 1 GHz) in the Sesser, I11 mine location and vlf propagation loss and noise (1 to 200 kHz) in both of the above locations. The basic experimental parameters were frequency, polarization, antenna type/orientation, and distance. The following reports treat the various aspects of the test programs in detail. Since different antenna configurations were used in the two mines, each report contains its own experimental predictions drawn from its corresponding test activities. A test equipment list and block diagrams of typical experimental setups for the tests of section 2 are contained in appendix A.

Jan 1, 1974

By R. S. Conti

This U.S. Bureau of Mines (USBM) report discusses the results of research conducted in the USBM experimental mine at its Lake Lynn Laboratory to determine the alarm times of smoke and carbon monoxide (CO) sensors, and a point type heat sensor (PTIIS) to slowly developing coal-conveyor belt fires. The tests were conducted at air velocities of 0.44 and 0.97 m/s, The data clearly indicate that smoke sensors provide earlier warning of fire than 10 ppm CO sensors, and that 10 ppm CO sensors provide earlier warning than PTHS, A success rate of 1.0 (indicating detection of every test fire) was obtained for both smoke and C8 sensors. For the PTHS, the success rate was 0.57 at the lower air velocity, decreasing to 0 at the higher air velocity, Data are also presented showing the sequence of fire events and detection events at the two air velocities as a function of time. Results show that early detection and warning of underground mine fires will improve the probability of miners' escape.

Jan 1, 2010