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By W. D. Ludemann, E. A. Loria, E. A. Rowe

The isothermal recrystallization of electrorefined vanadium has been studied as a function of annealing time , temperature , and prior deformation . Specimens were cold- rolled from 30- to 75 - percent reduction in thickness , then annealed from 700 ° to 1,200 ° C at time periods ranging from 1 minute to 96 hours . The course of recrystallization was followed by means of hardness , metallographic , and X- ray techniques , and a recrystallization diagram was constructed . Interpretation of the data indicated that there was around 50- percent softening due to recovery ( first stage of softening) before recrystallization began . The defining of recrystallization limits with respect to the amount of deformation was precisely established for electrorefined vanadium . More than 30- percent reduction was necessary for recrystallization to occur at 850 ° C. With 60- percent reduction , it was initiated at 750 ° C and completed at 950° C. The activation energy for recrystallization , as derived from the data , was 95,300 cal per mole for 60 - percent reduction and annealing at 750 ° to 900 ° C. Recrystallization by the mechanism of nucleation and growth was the principal process during the second stage of softening . minor part of the second stage of softening took place as strain- induced boundary migration , which was observed in specimens reduced 30 percent , bent in L- shape , and annealed at 950 ° C. Grain size decreased significantly only with the largest reductions and annealing between 750 ° and 950 ° C. Grain growth was expressed by the empirical relation D = KKtt"" ,, the exponent being the same at 60- percent reduction and annealing from 750 ° to 900 ° C. Accordingly , the activation energy for grain growth was 75,000 cal per mole .

Jan 1, 1964

By M. A. Mahtab

This report describes the procedures used by the Bureau of Mines for obtaining attitudes of joints surveyed with a borescope in inclined boreholes. An algorithm for computing the dips and azimuths of the observed joints is presented. The algorithm is used to solve an example problem. A computer program based on the algorithm is listed. It is hoped that the procedures described here will be useful in treating large quantities of data obtained from comprehensive borehole surveys.

Jan 1, 1973

By H. R. O'Brien

"During the past year, the Pittsburgh experiment station of the Bureau of Mines has been investigating methods for the quantitative estimation of carbon monoxide in blood. This work was necessary because reliable methods of analysis are of the greatest importance in the bureau's research work on prevention and treatment of carbon monoxide poisoning among workers in mines and metallurgical plants. Two of the methods considered involve color comparisons. In one of these methods, differences in tint can be noted fairly readily, while in the other, they are much more difficult to detect. The latter, however, is otherwise considerably simpler. It was decided, therefore, in studying the possibilities of this second method, to use the most sensitive eyes in the laboratory force.Preliminary trials.The method under investigation was the Haldane carmine determination of carbon monoxide in blood. The plain oxyhamoglobin of the blood in dilute solution is a pale straw color, when exposed to carbon monoxide it becomes a cherry pink. In the analysis dilute indigo carmine is added to oxyhsmoglobin until the solution matches in tint the carbon monoxide hemoglobin. The eye wanted, then, was the one most sensitive to faint pinks. But just how to select the analyst was not clear At first the Williams test scale, used in the Navy, was considered, but on con¬sultation with Dr. L. L. Thurston, bead of the Department of Psychology at Carnegie Institute of Technology, the following procedure was adopted.Instead of standard tests made up of all colors, only those occurring in the analysis were used. Solutions were prepared of the two hemoglobins, from which twenty-four different pairs were made up and placed in test tubes like those expected to be used in the analysis. One of each pair differed from the other in percentage of carbon monoxide hemoglobin by amounts varying from 2-1/2 per cent to 20 per cent. Each pair was compared in a box built in our own shop. This was 20 inches long and 5 inches square in cross section. One end was covered with ground glass. Just inside this glass cover were provided two slots, each the width of the test tubes used. The tubes to be compared were dropped into these slots through two holes in the top of the box. The device was placed before a window away from the sun, and so arranged that the light conditions were the same on each slit or opening. The person to be tested was seated before the box, and as the two tubes were placed before him side by side, he marked whether A (left) or B (right) contained the more cherry pink. This procedure was continued till he had compared all the pairs."

Jul 1, 1921

By E. D. Gardner

This paper is one of a series on milling methods being published by the United States Bureau of Mines. Atlanta is in Elmore County, Idaho, about 80 miles from the railroad at Mountain Home, Idaho. The concentrator is at an elevation of, 6,000 feet and located in a timbered, well-watered region of relatively heavy snowfall. The snow, however, does not seriously affect local operations. The track road to Mountain Home, which passes over a mountain range, is closed each winter from about November 1 to June 15. During this period concentrates are stored and bullion is shipped by airplane. Power is generated by a Diesel engine and by an auxiliary hydroelectric plant. Gold is the principal metal produced; the or also contains an able quantity of silver.

Jan 1, 1935

By C. Stephan, E. Weiss, J. Trackemas, M. Sapko

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory (PRL), in collaboration with the Mine Safety and Health Administration (MSHA), the mining industry, and seal manufacturers recently conducted a series of full-scale experiments within the underground experimental mine at PRL’s Lake Lynn Laboratory. The purpose of the experiments was toe valuate the explosion-resistant characteristics of several new seal designs for rapid deployment during mine emergencies. These seals can be deployed in 6 to 10 hr and are capable of with standing explosion overpressures in excess of 140 kPa (20 psi). These novel seal designs use available mine materials, do not require conventional rib hitching, and, most importantly, can substantially reduce exposure time for coal miners during sealing and mine recovery operations.

By Ivan L. Nichols

Tailings dumps at Mercur, Utah, contain about $7 million worth of gold in 3.5 million tons of mill tailings assaying about 0.07 ounce of gold per ton. Commercial mining and milling at Mercur ceased in 1942. To determine whether improved technology was now available that might permit economic reprocessing of the Mercur dumps, the Bureau of Mines probed for a low-cost method that would be applicable to these tailings. A composite sample prepared for laboratory studies assayed 0.062 ounce gold per ton. About 10 percent of the gold occurred as a water-soluble cyanide. Conventional cyanide leaching dissolved 32 percent of the gold, and hot, strong cyanide solution dissolved 42 percent. Results were not improved by pretreatment with acids, bases, or oxidants. After expensive preroasting, gold recovery by cyanidation was increased to 65 percent. The simple procedures were ineffective, and more effective procedures were too costly for economical processing of Mercur tailings.

Jan 1, 1970

By Joseph Cervik, Gerald L. Finfinger

The Bureau of Mines conducted an experimental degasification project in Island Creek Coal Co.'s Virginia Pocahontas No. 5 mine. Methane from the over- lying Pocahontas No. 4 coalbed was entering mine workings in the Pocahontas No. 3 coalbed through fractures in the roof rock. Small-diameter (1-5/8-inch) holes were drilled into the overlying coalbed to reduce the gas pressure and intercept methane flows, which were piped to the surface through an under- ground 6-inch-diam steel pipeline. The total methane flow rate from the vertical holes averaged 150,000 ft3/day for the first month. Methane flows into the mine were reduced by 47 pct, thereby demonstrating the effectiveness of this form of degasification in reducing ventilation requirements and providing a safer working environment.

Jan 1, 1979

By Bernard Porter

The rate of the heterogeneous reaction between reactor-grade yttrium and lithium fluoride in lithium fluoride-yttrium fluoride mixtures was measured using a quartz spring balance. At 950° C the magnitude of the rate of reaction is 10-5 grams of yttrium/cm2-sec. The heat of activation for the reaction is 38.3 kilocalories per mole of LiF. A surface-controlled mechanism is proposed in which LiF is adsorbed on the yttrium metal surface. An activated complex is formed when additional LiF reacts with the adsorbed LiF-metal site. The activated complex then decomposes to the products) which are lithium metal and YF3. The importance of the reaction in the electrowinning of yttrium metal from fluoride electrolytes is discussed.

Jan 1, 1967

By C. E. Hennig

On January 1, 1959, the United States had 313 petroleum refineries with a total installed crude-oil throughput capacity of 9,819,846 barrels per day, according to the Bureau of Mines annual survey. Compared with a year ago, this represents a net decreased of five in the number of slants mild a net increase in capacity of 412,139 barrels per day. The continued increase in total capacity and decrease in number of plants raised the average capacity of a refinery to a new high of 31,373 barrels per day. During 1958 total capacity increased in every refining district except the Louisiana Gulf district, which showed a 2-percent decrease due mainly to the retirement of the American Oil Company's plant at Destrehan, La. The largest increase, 14 percent, occurred in the Texas Inland district followed by a 12-percent increase in the Arkansas-Louisiana Inland district. At the beginning of 1959 the industry was building facilities that would add 108,400 barrels per day to crude-oil capacity. It also had under construction a capacity of 226,100 barrels per day as replacement. On January 1, 1959, no new refineries were under construction.

Jan 1, 1959

By Bruce I. Thomas

In 1943, the Bureau of Mines investigated the occurrence of cassiterite in the gravels of Morelock Creek which flows into the Yukon River 32 miles east of the confluence of the Yukon and Tanana Rivers in central Alaska. Samples of the gravels were obtained by churn drilling test pitting, shaft sinking, and open-cut mining. The gravels along Morelock Creek are about 6 feet in depth and covered with about 2-1/2 feet of overburden. The overburden is frozen, but the underlying gravels are not. Cassiterite, with gold and other heavy minerals, is usually concentrated in the first 2 feet of' gravel above bedrock and in some places penetrates into joint planes in the bedrock. The various methods of obtaining samples are discussed, and drill logs and analyses are tabulated in this report.

Jan 1, 1948

By Raymond W. Hiteshue, Henry H. Ginsberg, Paul S. Lewis

Coal was gasified in the presence of up to 3.57 million roentgens of gamma rays by the Bureau of Mines to determine whether the irradiation increased the gasification rate or yields of methane and hydrogen . High volatile A bituminous coal was gasified with steam at 500 and 1,500 psig and temperatures of 1,400 ° and 1,800 ° F ; five other coals ranging in rank from lignite to anthracite were gasified at 500 psig and 1,800 ° F. The average results of replicate experiments with and without radiation were compared for possible effects of radiation from 40,000 curies of radioactive cobalt . The irradiation had no gross effect on the gasification rate or on the yield and distribution of methane and hydrogen . It was concluded that gammaray irradiation produced no improvement in the technology or economics of coal gasification .

Jan 1, 1964

By Peter F. Steidl

Seven degasification wells have been completed in the Pittsburgh coalbed at the new Emerald mine near Waynesburg, Pa. Funding was provided by the Bureau of Mines to perform stimulation treatments on five of the wells, to show that this is a feasible and economical means of degasifying part of a coalbed. The seven wells ranged in depth from 590 to 910 feet. Stimulation treatments used 25,260 to 42,660 gallons of foam and 7,400 to 12,800 pounds of 20/40-mesh prop sand. Pumping rates were 10.8 to 11.6 bbl/min and treating pressures were from 1,050 to 1,600 psig. On the day following stimulation, gas production ranged from a few hundred cubic feet per day to more than 100,000 cu ft/day.

Jan 1, 1978

By R. V. Ramani

This volume is the third of a four-volume final report on research carried out under a contract from the U.S. Bureau of Mines on the development of a computer simulation model for surface mine reclamation planning. The other volumes are titled as follows: Volume I: Ore Reserve Estimation, Volume II: Dragline Model, and Volume IV: User's Manual for OPMHS/2. The Mine Coordinate Generator System serves as an interface between the Geology and Reserves System (Volume I, final report) and OPMHS/2 (Volume IV, final report) to provide local mine grid information which is used as input to the decision making process and dynamic simulation routines of OPMHS/2. After the Geology and Reserves System has been successfully run for a property, a data base containing values for each grid cell covering the property is created at the end of execution, if chosen as an option by the user. The Mine Coordinate Generator reads this information and creates a special direct access data set from the sequential data input. When information defining the mine grid is read, the values present in the property grid are for the interpolation of values for each mine block.

Jan 1, 1985

By H. P. Holmes

Tonnage quantities of hafnium metal have been prepared in Kroll-process equipment designed for producing zirconium. Some slight process modifications have been necessary, but overall operation is the same as for zirconium. Hafnium oxide is chlorinated in the presence of carbon and the resultant hafnium tetrachloride reduced by magnesium metal. Byproduct magnesium chloride is removed in a high-vacuum distillation step and the hafnium sponge metal crushed for further use. Arc-melted metal can be forged and rolled to sheet, but the best material produced to date would not be considered cold ductile. INTRODUCTION This investigation is part of the program for the production of pure metals from domestic and foreign ores that has been underway at the Bureau of Mines for several years. It was done in cooperation with the Atomic Energy Commission and the Bureau of Ships.

Jan 1, 1955

By G. M. Potter

During the investigation of the occurrence of manganese deposits in the western United States, examining engineers of the Bureau of Mines collected samples from four properties in Siskiyou and Mendocino Counties northern California. As the ores were too low-grade to be acceptable to manufacturers of ferromanganese, beneficiation studies were made between 1941 and 1945 to determine the amenability of the ores to concentration. The Johnson and Reynolds properties are near Fort Jones Siskiyou County. The ore occurs in a number of small lenses in that area. Samples were taken for testing for amenability to treatment in a small custom-gravity plant, tentatively planned. by the Waiter Johnson interests of San Francisco. A 2-ton representative sample was obtained from numerous exposed portions of an outcrop on the property of the Mayland Mining Co. The Mayland mine is about 8 miles from Sawyers Bar in Siskiyou County. The ore body consists of stringers and irregular masses of oxide, and. silicate ore scattered through quartz, which these minerals have replaced.

Jan 1, 1952

By Albert E. Long

This paper presents a description of the operational mechanics involved in block-caving a granodiorite-capped, limestone deposit. This method was used for 24 years at the Crestmore mine, near Riverside, Calif., which was operated by the Riverside Cement Co. as a source of raw material used to manufacture a portland cement. The Crestmore mine is the only place where a block-cave method has been used to mine a limestone deposit. Structurally, limestone is relatively strong, and it is not usually considered to be a substance amenable to mining by block caving. It is therefore a credit to the engineering department of the Crestmore mine that it developed a satisfactory, relatively efficient method of block-caving a structurally stable rock. In the discussion, covering the methods applied to produce about 7.9 million tons of limestone and granitic rock materials by block caving, particular emphasis has been placed on an assessment of (1) physical properties of the deposit, (2) ground pressure and support, (3) methods used to induce fragmentation and maintain cave action, (4) surface and subsurface subsidence, (5) secondary blasting of oversize, (6) production rate, (7) safety, and (8) the advantages and disadvantages of the cave method as applied to this specific limestone deposit.

Jan 1, 1958

By Lambert Dolphin, George Oetzel, Robert Bollen

An electromagnetic sounder developed for an archaeological application in Egypt has been successfully tested in a California dolomite mine. Chambers in the mine 100 to 130 feet from the surface gave intense, well-defined echoes consistent with an average attenuation coefficient of 0.6dB/m and a relative dielectric constant of 11. By moving the transmitter and receiver units on the hillside above the underground chambers, various characteristics of the propagation could be observed such as dispersion, chamber aspect sensitivity and cross section. The transmitted pulse was one to one-and-a-half radio-frequency cycles long at a peak power of 0.2 MW. Frequencies employed were 16 to 50 MHz. The light weight, highly portable, battery-powered equipment is potentially suited to other underground sounding applications.

Jan 1, 1973

By R. J. Heemstra

A continuous flowing paper electrophoresis cell was used to separate petroleum and petroleum extracts into characteristic patterns. The electrophoresis of Bachaquero, Lagunillas, Boscan, and Gibson petroleums in nitro-benzene and acetic acid-based electrolytes was investigated. The extent of separation in the patterns was studied by measuring the metal and porphyrin contents of the effluents. Qualitative separations were achieved in some systems, whereas either system demonstrated only a high degree of electrophoretic migration.

Jan 1, 1967

By D. J. MacDonald

The Bureau of Mines investigated two alternative methods for treating a zirconium-bearing chloride-sulfate strip liquor to obtain reactor-grade Zr02. One method involves neutralization with NH3 and the other hydrothermal precipitation. The strip liquor was derived from zircon sand by a Bureau of Mines method for separating zirconium and hafnium via solvent extraction with a tertiary amine. Neutralization with NH3 to precipitate hydrous zirconium oxide required 0.9 to 1.1 g NH3 per gram of zirconium. The NH3 can be recovered for recycle. Zr02 that met reactor-grade specifications was produced by precipitation with NH3? Hydrothermal precipitation of Zr02 from strip liquor required that the solution be maintained at 2600 C and 680 psi for 10 min and in a non-corrodible pressure vessel. In bench-scale experiments both methods gave-zirconium recoveries greater than 99 pct.

Jan 1, 1984

By A. J. Barry

An apparatus and procedure have been developed for testing the anchorage effectiveness of slotted-type bolts. The apparatus consists of: (1) A hydrualic Jack assembly for loading the bolt and (2) a device (extensometer or cathetometer) for measuring displacement of the bolt as it is loaded. This apparatus and procedure permit measurment of anchor slip for loads up to the yield load of the bolt. Two representative makes of slotted-type bolts (a total of 94 bolts) were tested in typical sandstone and shale mine roof. Analysis of the test results showed that (1) anchorage capacities up to the yield load of the bolts can be developed in either rock type; (2) the shape of the slotted end of the bolt affects the ease with which the bolt can be driven; (3) all bolts for which the driving distance was more than 1.25 inches produced satisfactory anchorage in both rock types (thus, driving distance can be used as a criterion for satisfactory anchorage); (4) for the group of bolts that was satisfactorily anchored the anchor slip was unaffected by the type of bolt but was considerably larger in shale than in sandstone; and (5) the bolt expansion, that is, the amount the wedge expands the prongs in excess of the diameter of the hole, can also be employed as a criterion for satisfactory anchorage. Although the bolt-expansion and driving-distance results do not differ appreciably, the latter is recommended because it is easier to determine.

Jan 1, 1954