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By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By E. K. Stanek, P. Kantabutra, R. A. Wolf

This paper summarizes the cause and effect of induced voltages in multiple conductor cables supplying alternating current power to equipment in under- ground coal mines. The investigation of this phenomenon revealed that the electrical energy produced by the resultant electric arcing between the frames of mobile electric face equipment was of a sufficient magnitude to ignite explosive methane-air mixtures. The results of laboratory tests and field tests made between equipment frames during actual operation in numerous coal mines are discussed. Several methods of eliminating or suppressing the induced voltages to nonincendive levels are also described. It is the purpose of this paper to convey to the mining industry a knowledge of this problem and to recommend methods of eliminating or reducing these induced voltages or arcing currents to safe levels.

Jan 1, 1975

By C. L. Karr

U.S. Bureau of Mines (USBM) research has shown that fuzzy logic and genetic algorithms (GA's) have great potential for industrial process control. A technique has been developed by the USBM in which GA's are used to substantially reduce the time needed to design fuzzy logic controllers (FLC's).This technique shows promise as an efficient, robust approach to developing control systems. The research described in this report is twofold. First, the basic approach to developing an FLC using GA's is presented. The GA-designed FLC is developed for a specific physical system, a pH titration system. Second, empirical results are presented in which variations in the FLC implementation are compared. Specifically, the effects of altering five aspects of the pH FLC are considered: (1) membership function form, (2) number of fuzzy classes, (3) the center-of-area method, (4) implication operator, and (5) fuzzy rule form. Results indicate that (1) the technique in which GA's are used to design FLC's is effective, and (2) when this technique is used, variations in FLC implementation have little effect on FLC performance in a chosen control problem.

Jan 1, 2010

By D. S. Kimmel

The Bureau of Mines sponsored development of a system to remotely energize and de-energize the trolley wire in a section in response to demands from vehicles as they enter and leave the controlled section. The system developed utilizes a detector/actuator that controls a dc contactor at the outby end, and a 3 kHz oscillator at the inby end. A prototype system has been built and installed at the Bureau's trolley test site at Bruceton, Pennsylvania which has demonstrated the ability to also provide load discrimination for faults of 300 amperes or more. The system could readily be modified by locating the oscillator on the vehicle to provide automatic de-energizing of the trolley wire when the vehicle's pole is removed or the vehicle leaves the section.

Jan 1, 1978

By R. Ward Stahl

Fire has been one of man's most useful tools through the ages and certainly is a "must" for industrial progress but when uncontrolled is one of the most destructive agencies. This fact is even more important in a coal mine, where many persons and much expensive equipment are confined in a relatively small area. Means of escape from a burning area, as well as from the products of combustion, are often limited; and in many instances the entire surroundings are combustible. Numerous mine fires, which resulted in a high death toll and great financial loss through the years, have caused mine owners to search for the best fire-fighting equipment; much of this has been installed, the quantity depending largely upon the experience of the individual companies or neighboring mines in certain coalfields. A mine owner or operator has meager published information on the actual fire protection afforded and systems of fire-fighting inaugurated in the coalfields, by which he could compare his efforts and get some idea of the adequacy of his own protection. To further general knowledge of the subject, it was decided to survey a representative number of mines in the field and show what has been accomplished. Representative mines were selected in various coal beds; some had similar tonnage, so comparison could be made if desired.

Jan 1, 1957

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX A - PNEUMATIC TRANSPORT OF FLY ASH 1. Introduction Two types of pneumatic transport of fly ash are critical to the success of (1) Transport of fly ash from the fly ash truck to the entrance to the borehole. Depending on the surface topography, this may be horizontal, decential and ascential. (2) Vertical downflow of fly ash through the borehole. All fly ash trucks have limited pressure with which they can pump the fly ash. Thus, the pressure drop in the fly ash hose will define the maximum length for pumping and consequently the maximum distance that the fly ash truck can be parked from the auxiliary blower. The same relationships describe the flow of the dilute fly ash-air mixture produced by mixing with the auxiliary air from the blower and thus define the selection of the pipe diameter. These are im¬portant considerations in the proper selection of the location of the passages to be sealed and the type of surface preparation required. The flow characteristics of fly ash down the borehole determine the selection of the minimum borehole diameter and the blower pressure. This appendix presents theoretical analyses of these flow regimes and summarizes the limited experimental data obtained during the field tests at Grant Town, described in Section 8.4. The analysis for the borehole flow is presented first as it is of greater interest to the program. This is followed by a discussion of the horizontal flow.

Jan 1, 1973

By Forest J. Sur

"INTRODUCTION This report describes an exploratory project conducted by the Bureaus of Mines on a fluorite deposit, near Glenwood, N. Mex. Results of wagon drilling, crosscutting, and test pitting are given, together with results of metallurgical tests made upon samples of the ore. Mining and treatment methods are suggested.C. H. Johnson, Bureau of Mines engineer, examined the deposit in August 1942. H. E. Rothrock, of the Federal Geological Survey, completed a preliminary geologic study and mapped the deposit during the fall of 1942. As a result of these brief investigations, it was concluded that the deposit contained substantial inferred ore reserves, and exploratory work was recommended. G. A. ApelI, also of the Bureau of Mines, made a topographic and underground survey and report on the mine in March and April 1944. A wagon drill, air compressor, and other equipment and supplies were delivered to the property on May 19 to 23, 1944. Drilling began under the direction of the author on May 25, 1944, and was completed in October 1944. The results of drilling and. sampling form the basis of this report."

Apr 1, 1947

By Jeran Paul W., Michael A. Trevits

Subsidence data gathered by the U.S. Bureau of Mines over a series of longwall panels in the Pittsburgh Coalbed were studied to obtain insight as to the role of time in the subsidence process. It was found that subsidence began essentially with undermining and was completed within 1 year. The progress of the subsidence was dependent upon location above the panel. Subsidence in the central area of the subsidence trough, where subsidence is the greatest, was about 90 pct complete by the time the face had progressed a distance equal to one overburden thickness beyond a particular surface point. For a point over the rib of the longwall panel, the subsidence was only about 60 pct complete at this time. Data from three other sites in the northern Appalachian Coal Basin were analyzed to determine if an anomaly or the true characteristics of the subsidence process had been observed. All sites behaved similarly in the central portion of the subsidence trough. However, the subsidence of points over and adjacent to the ribs of the longwall panels was site specific. The fact that movement across the width of the panel was not uniform should be taken into account in assessing damages or the potential for damages resulting from mining-induced subsidence.

Jan 1, 1995

Tax for Toxic Waste Cleanup. - The Superfund Act of 1980 became effective April 1, and provides that producers of certain metals and chemical substances are to be taxed in order to fund toxic waste cleanup. Industry will provide 88% of the 5-year, $1.6 billion fund. The Environmental Protection Agency will administer the Act, but the Internal Revenue Service will be responsible for collection of the industry tax. Under the Act, nickel companies, for example, will be required to pay a tax of 0.225 cents per pound on pure nickel products produced or imported into the United States. Standard for Exposure to Lead. - The Occupational Safety and Health Administration (OSPA) has announced a stricter standard on the test of a worker's exposure to lead. Effective May 15, in all lead intensive occupations with the exception of those at primary and secondary lead smelters, a worker would have to be removed from his work station if the level of lead in his blood tests out at 60 micrograms of lead per 100 grams of blood, instead of the previous standard of 70 micrograms. In the case of primary and secondary lead smelters, the ruling has been stayed until June 1, 1981, to allow time for further study.

Jan 1, 1981

By Ivan F. Avery

DOMEST1C production of carbon black in 1963, remained at about the same level as in 1962. Carbon black produced by the furnace process increased 2 percent to 1,880 million pounds in 1963 and accounted for 91 percent of the total output. Channel black production continued to decline and was 14 percent less than a year ago. Shipments during 1963 totaled 2,098 million pounds, a 1 percent increase for the year. An increase of 88 million pounds in domestic sales was partially offset by a decrease of 72 million pounds in carbon black exports. Total value of carbon black production in 1963 was $148 million. The average value per pound was 7.18 cents or 0.12 cent per pound more than in 1962.

Jan 1, 1964

By L. B. Pankratz

The Bureau of Mines conducted heat-content measurements above 298.15° K for dehydrated analcite (NaAISi2O6) to 1,000°K, kaliophilite (KA1Si04) to 1,800° K, and leucite (KAlSi206) to 1,800° K. Heat content and entropy increments were tabulated, and the heat content data, were given in equation form. A first order transition was noted for kaliophilite near 810° K with a heat absorption of 160 cal/mole. Leucite had a second order transition which became complete near 955° K. In this transition a crystal change occurred from tetragonal (low-temperature form) to cubic (high-temperature form).

Jan 1, 1968

By B. M. Bench

This Bureau of Mines report describes photo lineaments obtained from stereoscopic examination of vertical aerial photographs and by the Ronchi grating study of aerial photoindex sheets. The photolineaments are compared with the trends of oriented fracture systems procured by measuring the compass direction of joints in bedrock. The relative reliability of the methods is shown, and the results are presented in graphical, tabular, and written form. Analyses of field measurements of strikes of bedrock joints in the project area indicate for the most part two intersecting sets of major joints oriented N 76° W -N 15° E, and N 57° W -N 27° E. The analyses of lineaments determined by stereoscopic examination of aerial photographs show dominant trends of lineament zones of weakness to be an average of N 65° W -N 20° E. Analysis of lineaments found by Ronchi grid viewing of aerial photoindex sheets indicate dominant trends of N 70° W -N 27° E. The three methods give similar findings and verify the work of previous authors. The Ronchi grid method is a useful guide, but it cannot be substituted for the two more painstaking methods.

Jan 1, 1977

By P. G. Pigott

This investigation by the Bureau of Mines demonstrated that building bricks can be produced by the steam-curing process from various types of industrial mineral wastes. Wastes, utilized to produce bricks, consisted of copper mill tailings, roofing granule fines, asbestos fines, and zinc mill tailings. Bonding of the wastes with either Ca(OH)2 or portland cement resulted in building bricks that met ASTM specification C73-67 for grade SW and MW bricks when evaluated in accordance with ASTM designation C67-66 on sampling and testing of brick. An economic evaluation of the process indicates the total operating cost per 1,000 bricks is about $36.

Jan 1, 1974

By A. May

Florida has accumulated about 400 million tons of phosphogypsum, a mineral process waste generated in the production of fertilizer, and is adding 30 million tons to this annually. To minimize storage of this waste and reduce potential environmental effects, the Bureau of Mines conducted research into utilizing the phosphogypsum, by identifying and developing high-volume uses for this material. Admixtures of phosphogypsum, fly ash, and lime that could produce a coarse aggregate suitable for road construction were investigated. Using phosphogypsum with asphalt, cement, cement-kiln dust, silica, clays, and oxychlorides to pro-duce aggregate was also examined.

Jan 1, 1985

Great strides have been made in recent years to reduce the disaster potential of underground mine fires. However, mines can still be caught unprepared for a fire emergency. Fires can grow too large before they are detected, warning systems can be too slow and uncertain to reliably signal the danger, and suppression systems can be inadequate to extinguish the flames. New mining systems and equipment may create unanticipated fire hazards, and new materials may generate highly toxic combustion products. This report contains papers that summarize recent significant developments from the Bureau of Mines mine fire protection research program relating to these problems. Certain of these findings are also applicable to surface mining operations. The papers fall into the general categories of fire detection and instrumentation, fire warning, fire suppression, diesel equipment, spontaneous combustion, and toxicity analysis of combustion products.

Jan 1, 1988

By C. H. Elder, Fred N. Kissell, S. D. Maksimovic

The Bureau of Mines evaluated the hydraulic stimulation of a gob-degasification borehole to determine if this procedure would aid in degasifying a longwall panel. The stimulated borehole did not degasify the longwall panel as expected either before or after mining of the panel started. It reduced the underground methane emission only 11 pct, considerably less than the reductions effected by two unstimulated boreholes in the same panel. Some probable reasons for the reduced methane flow from the hydraulically stimulated borehole are very low reservoir gas pressure, location of hydraulically stimulated zones within the grouted casing, a casing break caused by lateral shifting, possible vertical movement of rock strata during caving, grouting of a 4-inch pipe blocking three stimulated zones, plasticity of shales, and possible hole damage by swelling of water-sensitive minerals. The borehole was also located between two second-mined areas, which may have allowed partial degasification of the overburden and the coalbed in advance of mining. Finally, a period of 3 months is probably not long enough for the borehole to degasify the overburden before mining.

Jan 1, 1977

By C. R. Stephan, N. B. Greninger, S. J. Luzik

The U.S. Bureau of Mines conducted explosion tests on various full-scale cementitious bulkheads used in abandoned mine areas to evaluate the ability of the bulkheads to withstand gas explosion over-pressures of 20 psig. Tests were performed on 120-ft2 solid-concrete-block seals of varying thicknesses and designs. Of the seven solid-concrete-block seals tested, only the standard-type seal, having a 16-in thickness, keyed at the floor and ribs, all joints mortared, wedged at the roof, and a center pilaster, maintained its integrity when subjected to a 20-psig pressure wave. After being subjected to repeated explosions, the standard seal only showed a small hairline crack and had an air leakage of 87 ft3/min at a pressure differential of 1 in H2O. Tests were performed on cementitious foam seals of varying thicknesses and compressive strengths. Explosion tests have shown that 200-psi strength, 4- and 8-ft-thick seals can withstand a 20-psig pressure wave. At a pressure differential of 1 in H20, no air leakage was detected through the 200-psi, 8-ft-thick foam seal.

Jan 1, 1991

By J. S. Tosh

The Federal Bureau of Mines has investigated the equilibrium of the system potassium carbonate (K2C03) potassium bicarbonate (KHCO3) potassium bisulfide (KHS) carbon dioxide (C02) hydrogen sulfide (H2S) water (H20). Partial pressures of hydrogen sulfide, carbon dioxide, and water vapor were measured at 70° to 130° C. over solutions of 20-, 30-, and 40-percent-equivalent potassium carbonate containing from 20 to 3,000 grains of equivalent hydrogen sulfide per gallon of solution. This study was made to obtain equilibrium data for evaluating the feasibility of using solutions of hot potassium carbonate for removing, hydrogen sulfide from gas mixtures. The equilibrium partial pressure of hydrogen sulfide may be correlated with the ratio of the molal concentrations of the solutes (KHC03) (KHS)/ (K2CO3). The relationship is shown graphically for the 30- and 40-percent solutions. Once this ratio is determined, the partial pressure of hydrogen sulfide can be obtained from the curves. The equilibrium data show that effective removal of both carbon dioxide and hydrogen sulfide can be achieved simultaneously with hot solutions of potassium carbonate.

Jan 1, 1960

Introduction The NIOSH Office of Mining and Construction Safety and Health Research has redesigned its Mining Safety and Health Web topic page. The updated page incorporates a significant amount of new safety and health information, plus an improved layout to better serve stakeholder needs. It also provides back-ground information about the NIOSH Mining Research Program, including research awards, core competencies, unique labs, community and educational outreach, and a brief discussion of how the research program is structured. The new Web topic page can be found at www.cdc.gov/niosh/mining. "Search" Feature The redesigned Web topic page features improved search capabilities. The "Search Mining" feature on each page lets you search only the NIOSH Mining Safety and Health Web topic page. The user can still search the entire NIOSH Web page by using the "Search NIOSH" option. New Safety and Health Topics Developers expanded the "Safety and Health Topics" and reorganized the site to make it easier to find information. Each topic link now has a significant amount of new and updated information, as well as links to related topics of interest. Safety and health topics include dusts, diesel exhaust, hearing loss, contact with electric current, fires, explosives, ventilation, emergency management, new and older workers, and education and training. All topics can be accessed from the home page (Figure 1). Publications Although the Web topic page highlights many of the most requested publications on the safety and health topic links, you can find a complete list of downloadable publications as well. More than 600 mine safety and health publications are now downloadable from the page. Short summaries let the user quickly identify publications of interest. Products The updated Web topic page offers more than 120 NIOSH mine safety and health products, including training exercises, toolbox talks, videos, computer software, guides, and checklists, many of which are downloadable. If not, instructions are given on how to obtain copies. Some of our products include: • Software to analyze horizontal stress, design pillars for longwall mines, and select roof bolts for ground control. • Educational software including the Hearing Loss Simulator, which simulates the effects of noise and aging; and Coal Country, which teaches children about coal formation, mining techniques, and everyday uses of coal. • Utility software including the HazCom Helper software to assist individuals in writing a HazCOM plan, as required by the Mine Safety and Health Administration (MSHA), to track hazardous chemicals at their mine sites. • Guides for troubleshooting roof support systems, under-ground workstation design, and seating design. • Training exercises and videos that can be used for safety training. Data and Statistics General mining statistics are used by a wide variety of stakeholders. The NIOSH Mining Web topic page offers statistical graphs, tables, maps, fact sheets, and other publications that document the mining population, injuries, fatalities, diseases, and occupational exposures for all mining commodities. If users prefer to analyze data themselves, downloadable files of MSHA data are available. These cover employment, production, injuries, fatalities, and accident data from 1983 to the present and are available in both SPSS® and dBASE® formats.

Jan 11, 2005

By J. P. Powell

Systematic waterflooding was first tried in Washington County, Okla., in 1937, when a 40-acre project was begun in secs. 24, 29, 32, and 33, T. 27 N., R. 13 E., jointly by the Keener Oil Co. and the Phillips Petroleum Co. The property later was sold to Lee Morrison. A second project was begun in 1941 in sec. 14, T. 6 N., R. 12 E., by the Oklahoma Oil Corp. Both projects were abandoned by the end of 1942. A third project was begun in 1945 and the fourth in 1948, but 1949 actually was the beginning of intensive waterflooding development in Washington County. The results of previous waterflooding projects are described in Bureau of Mines Reports of Investigations.2 3 4/ Oil production in the county followed a similar trend, dropping to a low of 990,000 barrels in 1945, then steadily increasing until 1956, when more than 4 mil-lion barrels of oil was produced. Most of the increase in oil production is directly attributable to water injection.

Jan 1, 1957