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By F. S. Boericke

"INTRODUCTION The mineral found in natural-chromite deposits is never pure Fe0.Cr203, but rather one in which the Fe0 and Cr203 are in part replaced by Mg0 and A1203, respectively. The purest gravity concentrates from many domestic de¬posits consist of a mineral referred to as ""picotite,"" in which this isomorphous replacement is such that the ratio of chromium to iron is low. The Bureau of Nines has investigated methods of chemically beneficiating ores that contain too much iron to be classed as ""high-grade"" chromite 3/ Early investigations 4/ demonstrated that high-iron chromite or picotite ores can be roasted with carbon to obtain selective reduction of the contained iron, and that most of this reduced iron can be removed by acid-leaching the roast products to produce residues of higher chromium-to-iron ratios. tests 5/ indicated that commercially acceptable reaction rates cannot be obtained at roasting temperatures below 1,3000 C., using solid carbon as reducing agent. By this high-temperature reduction and subse¬quent acid-leaching, however, all ores investigated, regardless of the original composition, readily yielded residues considerably better than the minimum specifications for high-grade chromite.In an effort to obtain satisfactory reduction of chromite at lower temperatures, liquid and gaseous seducing agents were tested with varying success. Of the several reducing agents used, methane appeared to be the most promising and was shown to be highly effective at temperatures between 1,000º and 1,100º C., roughly 300º below the roasting temperatures necessary in solid carbon reduction. Further experiments indicated that mixtures of methate with some diluent (hydrogen or other nonoxidizing gas) gave better reduction than did methane alone."

Feb 1, 1946

By R. B. Porter

Bench-scale tests were performed by the Federal Bureau of Mines on lignite and subbituminous coal at pressures to 1,000 p.s.i.g. (pounds per square inch gage) in atmospheres of hydrogen or nitrogen to obtain information concerning the influence of pressure on carbonization of normally noncaking coals. The distribution of gaseous, liquid, and solid products as a function of processing pressure was determined. Except for special experiments, the carbonization was at 940° F. In a hydrogen atmosphere above 400 p.s.i.g., agglomeration of the solid residue (especially with lignite) became noticeable and increased directly with the processing pressure. Although in some instances the solid particles fused together, the mechanical strength of the agglomerate was always low. On the basis of visual inspection, the coals agglomerated in the following order of decreasing intensity: (1) Steam-dried lignite; (2) lignite; and (3) subbituminous coal. Addition of lignite tar in quantities to 25 percent by weight of charge did not increase agglomeration or change the carbonization characteristics of the coal.

Jan 1, 1961

By J. B. Zink, M. J. Peterson

A semiquantitative spectrochemical method was developed and applied to the analysis of ash of U.S. coals . A low- temperature ashing procedure was used to minimize the loss of volatile elements . The analytical procedure provides for the estimation of 68 elements including major , minor , and trace constituents . Standards for the trace elements were prepared in a synthetic base mixture that approximates the average composition of U.S. coal ashes . Excitation was achieved with a d- c arc , spectra were recorded photographically , and interpretation was made by visual comparison of spectra of unknowns with spectra of graded standards series . Thirty- six trace elements were found in the analysis of 900 samples . Details of the procedure are presented , including sample and standards preparation , excitation and exposure conditions , spectral lines used , and approximate limits of detectability .

Jan 1, 1964

By H. Dale Nichols

[The growing importance of the Sundence (Jurassic) formation an a source of oil, in the Rocky Mountain area has prompted the making of a series of porosity determinations of core samples collected. from the reservoir sands of the Lance Creek oil field, Niobrara. County, Wyo. These analyses are preliminary to a stud of fluid and energy relations in the Basal Sundance reservoir of that field, and the determinations of porosity will be used in subsequent studies requiring, calculations of the volumetric capacity of the reservoir and estimation of the reserves of oil and gas. However, the porosity characteristics an of the Sundance sands in the Lance Creek field are factory that affect the solution of many current practical problems of development and operation. Primarily for that reason but also because it is recognized that porosity values of different oil-production sands are of widespread interest throughout the industry, the results of the initial work have been presented in tabular and graphic form with no attempt to evaluate their significance as they relate to the production history of the field.]

Jan 1, 1938

By E. L. Garton

The Bureau of Mines for a number of years bas been conducting an investigation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from many oil fields of Oklahoma are given in Bulletin 2915. Analyses of 21 representative crude oils from various producing zones of the Oklahoma City field are given in this report. A close study of the analyses reveals very few differences in the general characteristics and chemical properties of these oils.

Jan 1, 1932

By M. M. Wong, J. E. Klosterman

Scrap beryllium chips ( nominally 96 to 97 percent Be ) were electrore fined in a prototype cell with 408 lb of electrolyte composed of 52.4 mole - percent LiCl , 36.3 mole - percent KC1 , and 11.3 mole - percent BeCl2 . The cell temperature was 500 ° C. In a typical 10-3 /4 - hour deposition cycle , 0.415 pound of metal was produced ; the metal contained impurities in parts per million as follows : C , 700 ; 0 , 610 ; Al , 34 ; Ca , 32 ; Cu , 20 ; Fe , 25 ; Mg , 9 ; and Mn , 23 . Operation of the prototype cell for 2 years demonstrated that adapting the electrorefining process to an enlarged scale of operation presented few difficulties in mechanical functions , maintenance of optimum operating conditions , and control of product purity . After the spent anode feed was leached in a 5 - percent nitric acid solution and the fine - sized particles were removed , it was recycled in some tests . The metal produced was somewhat higher in impurities than metal from the fresh scrap chips .

Jan 1, 1964

By Cheryl Hill, Michael Keane, Pamela Mike, Raghoottma Pandurangi, William Wallace, Mohindar Seebra, Val Vallyathan

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte bemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz and kaolin dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect of lecithin adsorption. Dust hemolytic potential versus medium pH is presented. Fourier transform infrared spectroscopy and photo-acoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis. INTRODUCTIONQuartz dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction.In the alveolar ·spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, among other functions, mechanically stabilizes the lung from collapse by reducing the surface tension of water in the alveolar sacs.1 This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11 % in dog lavage fluid), and phospholipids (about 88%).2 Pbosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalmitoyl lecithin (DPL).2 Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occurring upon deposition of a particle in a pulmonary alveolus. As may be seen from Figure 1, the DPL molecule has several fixed charges at neutral pH; a positive charge on the trimethylamine (choline) moiety, and a negative charge on the phosphate group. Also evident are the two fatty acid residues of palmitic acid, which are bonded through ester likages to the glycerol segment of the molecule. The fatty acid moieties of phosphatidyl choline make the molecule inso1uble in aqueous solutions under normal conditions, but a colloidal unit of aggregated molecules called a micelle is usually formed spontaneously above a certain minimum concentration. Small micellar vesicles are generally formed in the laboratory by using ultrasonic agitation or by solvent evaporation methods."

Jan 1, 1990

By Charles W. Huggins

To determine the nahcolite and dawsonite content in oil shales, the Bureau of Mines compared X-ray diffraction, infrared spectroscopy, thermal methods, and a previously published method by Smith and Young based on the selective solubility of sodium compounds. The Smith and Young method and a new method based on the weight of carbon dioxide produced by thermal decomposition are recommended for determining nahcolite. X-ray diffraction and the Smith and Young method are recommended for determining dawsonite. X-ray diffraction, infrared spectroscopy, and differential thermal analysis were useful for identifying other minerals in the samples.

Jan 1, 1973

By W. A. Stickney, J. W. Town

Studies on continuous - circuit leach - aluminum precipitation and leachelectrodeposition of mercury were made by the Bureau of Mines to determine optimum conditions and cost estimates for recovering mercury from mercury sulfide flotation concentrates . With 150 grams of sodium sulfide and 50 grams of sodium hydroxide per liter , from 98 to 99.8 percent of the mercury was extracted from flotation concentrates , with about 0.5 pound of sodium hydroxide used per pound of mercury produced . Precipitation of mercury from the caustic - sulfide solution with minus 8 - mesh aluminum shot required about 0.2 pound of aluminum per pound of mercury produced at a cost of $ 0.05 per pound of mercury . Electrodeposition cost with 7 mill power , based on 50 percent current efficiency , was below 2 mills per pound of metal deposited . Feed solutions ranged from 10 to 130 grams of mercury per liter , and current densities , from 2 to 70 amperes per square foot . The cost of open- pit mining 250 tons per day was estimated at $ 1.75 per ton , and flotation - leachingelectrodeposition of the ore , at $ 3.54 , resulting in a cutoff grade of about 0.1 percent mercury . The cost of underground mining 50 tons per day was estimated at $ 20.00 per ton , and the cost of milling the ore was estimated at $ 13.33 , which resulted in a cutoff grade of 0.6 percent mercury .

Jan 1, 1964

By H. H. Fields

The Bureau of Mines conducted research to determine the effectiveness of long holes drilled in solid virgin coal in degasifying an area of the Pittsburgh coalbed showing that horizontal holes drilled into a virgin coalbed from the bottom of any shaft will effectively remove methane gas in commercial quantities from the Pittsburgh coalbed. The in situ pressure at a depth of 214 feet into the coalbed and the average gas and water flows from the five degasification holes were 3 lb/in2 gage and 860,000 ft3/d and 1.7 gal/min, respectively. On June 19, 1975, after 593 days of degasification, a compressor was installed and pipeline quality gas was introduced into a commercial pipeline. As of June 1, 1976, after 1,022 days of degasification, over 753 million cubic feet of gas had been drained and 117 million cubic feet of gas had been purchased by the gas company for use in the local community of Wadestown, W. Va. The gas drained to date is six times the gas estimated to be in the area subtended by the holes. Methane emissions at the working face of 1 West mains, Federal No.2 mine has been reduced by 50 pct, proving the value of methane drainage by horizontal degasification holes drilled from shaft bottoms ahead of mining.

Jan 1, 1976

By R. S. Dean, John Gross

"In a preliminary report made a year ago it was shown that certain minerals when subjected to heating with water under high pressure and temperature were shattered upon the sudden release of that pressure. The main feature in which the results of this method differ from those of conventional grinding is in the differential effect obtained. The more metallic minerals, and hence the valuable minerals, are shattered more readily than are the gangue minerals. In other words, explosive shattering is unique among possible methods for comminuting an ore in that it wastes the least energy on the useless part of the ore. Explosive shattering, therefore, offers possibilities as a means for reducing grinding costs, arid it is this potential advantage of the process that makes it worthy of further experimental study. The first part of this paper is devoted to a study of the mechanism of the process; the, second part reports results obtained in toots on a selected list of ores to exhibit some of the advantages of explosive shattering."

Feb 1, 1933

By F. H. Gunnell, W. C. Dunham

"INTRODUCTION The Treasure Hill mines, situated in Dry Canyon, Ophir mining district, Tooele County, Utah, together with several other properties in the district, examined were examined by Frank L. Wideman, an engineer, the Bureau of Mines, in September 1942.In April 1945, development drilling was started on the Treasure Hill mines, which are operated under lease from the Madison Mines Co. The project was continued in 1946 and terminated in 1947.While the Bureau of Mines project was in progress, the Morgan and Fullion tunnel workings were surveyed by Bureau engineers.ACKNOWKEDGEMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy, It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative perk, and prepares the final report. The Branch, O. C. Ralston, chief, analyzes samples and performs beneficiation tests. The work here described was under the direct supervision of Paul T. Allsman, chief, Salt Lake City Division, Mining Branch."

Jan 1, 1948

By Alden H. Emery, J. J. Forbes

"IntroductionThe data contained in this paper were collected during the course of an investigation which covered 15 representative coal mines in 6 coal-mining States. The purpose of the investigation was to determine by atmospheric sampling how much dust was raised into the air during the various operations of coal mining, such as undercutting with machines, loading coal by hand, and transporting it from the working face to the surface. The data thus obtained were considered from two angles - namely, the possible physiological effect of inhalation and the explosion hazard of the dust. No attempt will be mode to discuss the former factor in this paper.CONDITIONS OF MININGThe mines in which this investigation was conducted were considered representative, and it is believed that the results obtained will suffice for the average dustiness encountered in most coal mines. .All of the coal mined was bituminous, from beds 30 to 120 inches thick. Only the ordinary room-and-pillar system of mining was employed. Daily production ranged from approximately 700 to 1500 tons and the men employed from 150 to 450. Coal was undercut by short-wall mining machines in all mines, with the exception of one in which pick mining was employed. Loading at the face was done by miners; none of the mines used mechanical loaders. Electric drills, both for brushing roof and for shooting coal, were commonly used although some roof work was done with jack-hammers and a. little of both with augers. Coal was hauled by motor, mule, or rope power in end-gate cars with capacities ranging from 1600 to 3600 pounds. With few exceptions, coal was won at the face by dry methods - that is to say, no water was employed fox wetting down the dust either during undercutting, loading, or transportation."

Feb 1, 1927

By W. M. Traver

During World War II, the Bureau of Mines investigated a large number of ore deposits in the United States and Alaska in a search for domestic sources of strategic minerals. Deposits chosen for exploration included those expected to contain metals of importance in the successful prosecution of the war. This report describes exploration of a district of known antimony occurrence on Coyote or Antimony Creek near Antimony, Garfield County, Utah. A preliminary report by Paul T. Allsman, Chief of the Bureau's Salt Lake City branch made in August 1941, recommended further investigation, and proposed methods for performing the work. The project, begun in November 1941 and completed in January 1942, included trenching and sampling in four of the most promising parts of the area The Federal Geological Survey cooperated in the work by detailed mapping and assisted in the interpretation of geologic data.

Jan 1, 1949

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1954 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 101 samples of aviation gasoline. Data also are given for 30 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers I 1954 production in their laboratories and the results submitted to the Bureau of Mines for compilation. The products of 19 manufacturers of aviation gasolines and of 15 producers of aviation jet fuels are represented.

Jan 1, 1955

By J. M. Mutmansky, C. Lee

"Measurement of the size and elemental characteristics was performed on airborne coal mine dust samples collected by multi-stage cascade impactors as well as channel samples of the geologic materials. Size distributions were obtained using precise weighing techniques on the impactor substrates. Elemental analysis on the samples was performed by the proton-induced x-ray emission (PIXE) method, a rapid and non-destructive method of multi-element analysis.The various analyses were performed on 9 major and 21 trace elements. The results indicate the importance of intake air and shuttle car movements as sources of dust. The association of coal dust characteristics with channel samples was investigated using the coefficient of proportional similarity as a statistical measure. Results show a strong relationship between major elements and the geologic material being cut but a similar relationship between trace elements and geologic materials is not consistent.1. INTRODUCTIONThe most significant occupational disease in the coal industry is known ·as coal workers' pneumoconiosis (CW'P). While CW'P has existed for centuries, its mechanism of occurrence and association with coal dust has been well understood for only a few decades. In the 1930s, the significance of this disease led state and government officials in the USA to perform extensive epidemiological and environmental studies in the major coalfields. Study of these results plus later studies in the coal producing countries of Europe eventually led to the dust regulations that appear in the Federal Coal Mine Health and Safety Act of 1969.The impacts of the 1969 act were a productivity decline and increased production cost. Many analysts attributed this in large part to difficulties in complying with the new dust standards (Brezovic 1981). However, compliance was met in most continuous miner sections rather quickly. The remaining problem area is that of longwall mining where the procedures and layout of the minin~ system make it difficult to meet the standards."

Jan 1, 1989

By Harold L. Rhodes

The Bureau of Mines has developed a quantitative method to determine water vapor in helium in the range of 0.1 to 15 ppm by volume. This method uses the quantitative chemical reaction of H20 with CaH2, which produces 1 mole of hydrogen for each mole of H20 in the sample. A gas chromatograph is then used to determine the concentration of hydrogen in the product. The precision of the H20 analysis is ±0.05 ppm at a concentration of 1 ppm. This method is used to calibrate a commercial platinum-phosphorus pentoxide (Pt-P205) electrolytic water vapor analyzer that has an improved inlet system and digital voltmeter readout.

Jan 1, 1981

By Robert J. Hundhausen, GEORGE M. GRISMER

This circular describes the methods and costs of deepening the Silver Summit three-compartment shaft in the Coeur d'Alene mining region of Idaho. A noteworthy rate of advance was achieved at this operation by the successful use of a mechanical shaft-mucking machine. The Silver Summit mine is 1 mile west from the town of Osburn, Idaho, via U. S. Highway 10. The adit-level portal of the mine is on the south slope of the Coeur d'Alene River Valley at an altitude of 2,700 feet. The Silver Summit shaft is 6,000 feet from the portal. In past years this shaft had been sunk from the adit level to a depth of 1,500 feet. During 1946 the Polaris Mining Co, deepened it to 3,095 feet. The work was done under a co- operative development agreement between the Silver Summit Mining Co. and the Polaris Mining Co.

Jan 1, 1948

By T. J. Ballard, Austin B. Clayton

"The Union Copper mine is in the Gold Hill district, Rowan and Cabarrus Counties, N. C.The mine was discovered in 1799 and first worked as a gold mine; but copper was encountered at depth, and the property became an important producer of copper. It is estimated that the mine produced 5,000,000 pounds of copper before operations were discontinued in 1907.As part of the strategic minerals program, the Bureau of Mines conducted a development project on the property from July 1943 to November 1943. Eight diamond-drill holes, totaling 2,500 linear feet, were drilled to delineate the ore body. Analyses of 205 core samples were made.Tabulations of sample analyses and drill-hole logs are presented in this report.The project work embodied in this report was under the immediate supervision of Austin B. Clayton, project engineer, and the general supervision of H. B. Ewoldt, district engineer for North Carolina and Tennessee. The preliminary report, written by Austin B. Clayton, was revised and the various figures redrawn for publication by T. J. Ballard under the general supervision of M. H. Kline, chief, Raleigh Branch, Mining Division.Acknowledgment is due the Metallurgical Branch for analytical determinations of the samples.The mine property is 1.5 miles southwest of the village of Gold. Hill, N. C. (fig. 1). Gold Hill is on U. S. Highway 52 between Salisbury and Albemarle and on a branch line of the Southern Railway. The latitude is 350 30' and longitude 80° 21 The tract consists of 553-1/2 acres in Cabarrus and Rowan Counties.A tentative list of the surface-rights ownership is as follows: William Hoy Barringer - 16 acres, A. W. Tucker - 1 acre, Frank Wagoner - 4 acres, and George Barringer - 3-1/2 acres, in Cabarrus County; A. W. Tucker - 2 acres, H. N. Hedrick - 54 acres, and William Atkins - 473 acres, in, Rowan County, N. C.The mineral rights are owned by Alfred Rossiter, Alice R. Hesslein? and the estate of the late Bella Rosenblatt. The attorneys for the owners are Neidle & Taylor, 6 East 45th Street, New York City.The Union Copper mine is in the Cold Hill mining district of North Carolina where gold was first discovered in 1799. The upper parts of the veins in the district were first worked for gold; however, the increase in the sulfide content of the veins with depth rendered the amalgamation process for gold recovery ineffective, and the mines were closed.The period of greatest activity at the Union Copper mine was from 1899 to 1906. At an earlier period the oxidized and leached part of the lode near the surface was mined from a working known as the ""big cut,"" the reported yield of which was $300,000 in gold.3/ The mine has not been operated since 1907.J. T. Pardee3/ lists the probable value of the production of the Union Copper mine as $1,050,000, of which about $675,000 was the value of some 5,000,000 pounds of copper produced."

Oct 1, 1948

By H. S. Auvil

[Coals of low-volatile rank cannot be coked without admixing large proportions of high-volatile cod in the used type of byproduct-coke oven, because they expend excessively and. exert side thrust, which ruins the oven wells. Some medium-volatile coals also give trouble. Since high-rank coals produce a strong, blocky coke, it is desirable to have the rank as high as practicable, particularly in the manufacture of foundry coke. Accordingly, it has become the practice to mix or blend high-volatile shrinking coals with as much low-volatile coal as possible and still have a mixture that mill not deform the walls or cause difficulty in pushing the coke. Occasionally, the safe limit of low-volatile cool has been exceeded and ovens have been damaged. It is desirable, therefore, to have a reliable method of determining the expending tendencies of mixtures before they are charged into the ovens. Furthermore, coal changes somewhat in its properties as mining progresses, end therefore, mixtures found to be safe at one time may cease to be so subsequently, particularly if nearly the maximum allowable percentage of low-volatile coal is being used. ]

Jan 1, 1938