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By William J. Campbell

This study was a part of two programs: The first, to develop and evaluate high-temperature refractories; the second, to investigate reaction-rate kinetics and phase equilibria in the sinter step of the lime-soda process for the recovery of alumina. High-temperature X-ray diffractometer techniques are to be used extensively in both programs. This paper summarizes developments in the field of high-temperature X-ray diffractometers through 1959, evaluates various furnace designs, and describes briefly the X-ray diffraction facilities of the Federal Bureau of Mines. A more detailed description of the equipment and its calibration is planned in a future paper on thermal expansion and phase inversion of rare-earth oxides.

Jan 1, 1961

By Laurence G. Trudell

Geology and oil-yield data are presented for a 58-square-mile area encompassing the U.S. Department of the Interior oil-shale leasing program tracts in the western Washakie Basin, Sweetwater County, Wyo. Lithology and oil yields of samples from three Bureau of Mines coreholes are evaluated and correlated with Kinney Rim surface sections measured and sampled by the U.S. Geological Survey. Minable sections of oil shale averaging up to 25 gallons of oil per ton crop out on Kinney Rim in the Laney Member of the Green River Formation. Thick oil-shale sections in the Laney Member that average 15 gallons per ton represent 155 million barrels of oil in place per square mile. In the lower part of the Green River Formation the Tipton Shale Member contains a 20-to 40-foot section averaging 15 gallons per ton. Beds of high-volatile C bituminous coal up to 6 feet thick are present in intertongued parts of the lower Green River Formation and upper Wasatch Formation.

Jan 1, 1973

By D. W. Bridges

Solvent extraction has become important in recent years as a unit process in extractive metallurgy. The flexibility and simplicity of the technique have attracted widespread attention, and numerous papers describing actual and projected metallurgical applications have been published. However, differences in terminology, procedure, objectives, and standards, as reflected in reports by different operators and investigators, have sometimes made appraisals and comparisons difficult. Consequently, a need appeared for n series of basic reports on the subject. This Bureau of Mines Information Circular is the first of such a series. It deals with the status of solvent extraction in metallurgy, as well as with the rudiments and terminology of the unit operation. In analytical chemistry, extraction of molecular species from aqueous media by immiscible organic solvents has been used for many years to separate and determine chemical elements (61).4 Complex chlorides of iron and other metals are readily soluble in ethers and ketones, as are the nitrates of uranium and thorium. Most metals are extractable as complex salts of some organic reagent, such as dithizone, 8-hydroxyquinoline, or cupferron.

Jan 1, 1962

By J. M. Singer

The Bureau of Mines investigated the threshold of dispersal of monolayers and piles of rock dust, anthracite, and Pittsburgh seam coal dust in a small wind tunnel that simulated a coal mine gallery, with the objective of preventing or limiting the formation of flammable dust clouds. The effect of selected variables on entrainment velocity was examined. Mode of entrainment and flow processes in the wake region of dust configurations were investigated by means of high-speed motion pictures. Significant results were as follows: 1. Local minimum air velocities required for dispersal were only slightly higher for shallow dust ridges than for dust particles. 2. Minimum velocities for entrainment of dust particles from smooth glass and coal surfaces increased in the order rock dust, anthracite, Pittsburgh seam coal. 3. The mechanism for dispersal of dust poles depended significantly on dust pile geometry, cohesiveness of dust, bulk density and compaction of dust, adhesive surface, and vibrations perturbing the supporting surface.

Jan 1, 1969

By IRVINGC. ALLEN, W. A. Jacobs

Realizing the great importance and wide application of petroleum and its products for fuel,lighting and lubrication, and the absence of authentic and comprehensive information in the literature on the commercial value of American petroleums, the United States Geological Survey has for a number of years' been making analyses and other examinations of these oils and their products. In 1907 the technologic branch of the Survey began a study of certain economic problems having to do with the natural mineral oils. The prime object of the investigations was to determine the economic value of the petroleums and natural gases in the United States with special reference to the supplies in the public lands, and to ascertain how these resources could be utilized in the industries withleast waste and greatest efficiency. This work, which is now being conducted by the petroleum section of the Bureau of Mines under authority of the act of May 16, 1910, will include the collection at the wells and refineries of information as to the following details: Facilities for handling and storage at the wells. Facilities for transportation, whether by pipe line, rail, or water. Distance to the nearest port or center of industry and time necessary for delivery. Facilities for storage at such point of delivery. Suitability of the crude oil for fuel, or the treatment necessary to convert itmost economically into the best fuel. Best processes of refining or of converting the crude oil into its many products. The examination of these products. The utilization of the by-products and residues of the refineries. The collection of adequate and reliable samples, and the complete chemical and physical examination ofthese samples in the laboratory.

Jan 1, 1911

By Paul M. Tyler

One by one new metals come to share the burden of modern industry. Long before the Christian era potters and glass workers employed fine and costly blue pigments that contained cobalt. Cobalt blue class has been found in the tombs of the Egyptians and in the ruins of Troy, and many of the colors used by the ancient Greeks and Romans contained cobalt. The ancients, however, were apparently unaware that the colors they used were caused by cobalt, and it was not until late in the 17th century that the existence of the element was recognized, Writers in the Middle Ages referred to "cobalos" as an evil spirit that haunted mines and caused trouble to the miners. Subsequently the German worms "Kobold," meaning goblin, came to be applied to any baffling mineral and particularly to minerals that resembled ores but failed to yield metal when smelted. Even to-day there is something of an air of mystery about cobalt, and a medieval cloak of secrecy still surrounds many of the metallurgical processes employed in its production. "Zaffre" was mentioned about the middle of the sixteenth century by Biringuccio, and in 1735 the metal war, first prepared by G. Brandt. To preparation of cobalt compounds, however, must have been carried on in at least a small way ever since the opening of the silver-cobalt deposits of Schneeberg in 1470. By 1790 there were 25 works engaged in the industry, rust of them located in Saxony, but the total output of these works probably did not exceed 300 tone of cobalt annually, mostly in the fore of smalt. The smalt which contained approximately 6 per cent cobalt was sold in Venice in 1520 at about 16 cents a pound. A few refineries in Holland supplied the Irish linen trade, contributed a farce amount to the Dutch linen industries, and alto provided smaller quantities for the manufactuer of litmus in Holland. A complete description of the early [histor,] of the cobalt industry in Saxony, is given by Mickle in the Deport of the Bureau of Mines of Ontario, vol. 19, 1913, pt. 2, pp. 234-251.

Jan 1, 1930

By J. R. Thoenen

During the past 6 years the Mining Division of the U.S. Bureau of Mines has prepared many information circulars containing valuable technical data covering the operating details of mining and ore-dressing plants throughout the United States, Canada, Mexico, and other countries. These papers, written for the most part by operating officials in the field, have been designed to comprise a reference library for the operating engineer. In order to make the information contained in these publications more readily available to the busy engineer the enclosed series of reference tables has been compiled. The tabular arrangement is by subject rather than alphabetical order, thus avoiding the bulk of an alphabetical index.

Jan 1, 1935

By D. N. Tallman

The electrokinetic properties of MgO have been utilized to simultaneously filter suspended solids and remove trace amounts of dissolved heavy metals from synthetic mine water. Greater than 95 pct removal of metals from influent at neutral pH containing 1 to 6 mg/L of dissolved Cd, Cu, Mn, Ni, and Zn can be routinely achieved by filtering through a granular bed of MgO at flow rates typical of rapid sand filtration (0.3 cm/s). Filtrate concentrations of most metals can be maintained below 0.1 mg/L for 160 bed volumes or more loading. The more mobile metals (those with larger solubility products) are more difficult to remove, and are strongly bonded to the MgO granules so that chemical stripping with chelating agent is required to clean the bed. Less mobile ions are easily removed by the filter and are effectively stripped by conventional filter backwashing. The fraction of metals recovered by chemically stripping the loaded MgO filters correlates to the zero points of charge of the metals. This process may be applicable to removal and recovery of trace amounts of heavy metals in mine drainage that is partly neutralized by liming. Also, since many of these metals are critical and strategic, the technique can be adapted not only to recycle process water from mineral and milling waste streams, but also to reclaim their metal values.

Jan 1, 1986

By W. M. Bangert, F. S. Boericke

"INTRODUCTION Determination of the thermodynamic properties of metallurgically important compounds of chromium has been one of the activities of the Pacific Experiment Station of the Bureau of Mines. Earlier reports have dealt with the entropies 4/ 5/ of chromium, chromic oxide, and chromous and chromic chlorides, with the thermodynamic properties of the chlorides of chromium, 6/ and wits the thermodynamic properties of the carbides and oxide of chromium. 7/ Evaluation of the thermodynamic properties of chromite, FeO.Cr2O3, is desirable, as this material in impure form constitutes the only natural source of chromium of any consequence.Two general methods are available for directly determining heats of formation - (1) measurement of heats of combustion and (2) measurement of heats of solution. Neither of these methods is directly applicable at present to ferrous chromite, which accounts for the lack of previous data. Combustion of a stoichiometrical mixture of iron and chromium under conditions prevailing in a calorimetric bomb yields a mixture of iron and chromium oxides rather than chromite. None of the usual calorimetric solution media dissolve chromite at temperatures low enough for solution calorimetry. Sulfuric acid and an oxidizing agent, such as MnO2 or CrO3, are known to dissolve chromite, but the possible calorimetric use of t is medium would require long preliminary investigation. Consequently, recourse must be taken to some indirect method. At the start of the present work, the most promising method appeared to be the determination of equilibria in the selective, reduction of the iron in chromite by hydrogen;"

Jun 1, 1945

By John E. Husted

Quantities of kaolin in Georgia in-contiguous or single bodies had been established by previous work to be sufficient for an alumina industry. The need for characterization of this kaolin to determine its suitability as an ore of aluminum resulted in the studies described herein. It was determined in an area roughly 7 x 27 miles, known as the Wrens district that approximately 5.9 billion short tons of kaolin averaging 35.55 percent A1203 exist in an essentially continuous clay body. The Macon-Sandersville district consists of discontinuous kaolin bodies averaging 35.28 percent A1203 with an average thickness of 28 feet. Tonnages for this district are not available. One hundred and twenty core samples of kaolin were analyzed for K20, CaO, MgO, Al203, T102, Cr203, Fe203, Si02, P205, and F. The P205 and F were analyzed by wet chemistry methods and the others by electron microprobe. Seventy-nine of the samples were from the Wrens district forty from the Sandersville-Macon district and one from the Andersonville district. Emission spectroscopic analyses were also made to qualitatively determine all elements present for each core. X-ray diffraction studies were made of each core to determine mineral species present. Scanning and transmission electron microscope pictures also are given for each I' core sample. Elevations, overburden thickness, and kaolin thickness are given for each core site as well as map locations. Isopachs for over-burden and kaolin thickness are given for the Wrens district.

Jan 1, 1983

By L. B. Berger, W. P. Yant, J. B. Littlefield

"INTRODUCTION Hydrogen sulphide (H2S) is one of the most toxic industrial gases and of relatively wide occurrence in industry. Among its common industrial occurrences are, in the production and refining of high-sulphur petroleum, in natural gases, in gypsum and sulphur mining, in rock strata and underground waters (where it is encountered in tunneling and caisson work) in blasting with black powder and in blasting high-sulphide ores with other explosives, in gas manufacture, in the carbonization of coal, and in the manufacture of chemicals.The usual methods of detection, other than by the sense of smell, which is lost in 2 to 15 minutes' exposure to 0.010. to 0.015 percent of this gas, 5/ either are too cumbersome for frequent and rapid analyses or, like the wet lead acetate paper test, afford only qualitative results. A qaantitative determination usually involves the use of solutions, bubblers, flowmeters, standard solutions, burettes, and indicators manipulated by trained technical men. All apparatus and methods in common laboratory use are, in general, unsuitable for the field.The physiological response attending exposure to various Concentrations of hydrogen sulphide in air, is as follows, in percent by volume 6/:0.005 to 0.010: Subacute poisoning - slight symptoms, such as mild conjunctivitis and respiratory-tract irritation after 1-hour exposure."

Jun 1, 1935

By Renpei Yoda

An investigation was conducted to develop columbium alloys with e1evated-temperature strengths higher than those exhibited by more common commercial columbium alloys, and attention was given to improving the oxidation resistance and ease of fabrication. Additions of carbon, aluminum, and chromium were made to some columbium-base alloys, and their effects on workability, recrystallization, oxidation resistance, and mechanical properties at elevated temperatures were explored. The additions were made to take advantage of (1) solid solution strengthening, and (2) precipitation hardening. Three alloys displayed good high-temperature properties with relatively good oxidation resistance at 1,000° C, and tensile strengths from 26,000 to 32,200 psi at 1,400° C. When the properties of these alloys were compared with those of commercial alloys, B-66 and FS-85 (1),4 the outcome was favor-able for the alloys studied in this investigation.

Jan 1, 1967

This report covers the work performed by the Advanced Products Division of FMC Corporation under Bureau of Hines Contract J0155166, Design Evaluation for Development of an Advanced Bolter Module. FMC has evaluated the existing ISMS bolter designs, and the corrections and improvements in progress, including the effect of the three-chain magazine presently being fabricated, and recommends that a complete bolter module featuring a new magazine, safety post and lower stabilizer or similar device be designed, fabricated, and tested, A 29 week program is proposed which includes a four week demonstration. This module would eliminate those reliability problems not presently being solved and would provide a reliable bolter module for a production oriented miner/ bolter.

Jan 1, 1975

By A. Renton Amell

The rate of dissolution of U02 was measured in acid solutions similar to those used for in situ leaching, with S04 of 10-1.82 to 10-4 M, Fe(III) of 10-2 to 10-4 M and pH's of 1.1 to 2.3. The dependence of dissolution rate on pH was small and inconsistent, probably reflecting the combined effects of a very weakly polar oxidizing complex, probably FeSO4+, and a nearly neutral U02 surface. Differences in the state of the U02 surface may explain this variability as well as contrasts between these results and results reported in other work. Changing either S04 or Fe(III) concentrations significantly affects dissolution rates. Increasing low sulfate concentrations in solutions containing 10 2 M Fe(III) at pH 2 results in formation of FeSO4+. In such solutions, rates increased with (S04)/(Fe(III)) up to 1:30, thereby indicating that the oxidation of U02 by FeSO4 is more rapid than by Fe3+. However, the dissolution rate decreased at higher (SO4)/ (Fe(III)), due either to sorption of SO42- on the UO2 surface or to formation of other less reactive sulfate complexes such as Fe(S04)2 or FeHSO4+ However, Fe(III) concentration is the dominant factor in determining solution rates. The rate was directly proportional to ferric iron concentration, indicating that the rate-determining step of the dissolution reaction is a single-electron oxidation by a ferric complex. Dissolution rates were lower in solutions of 0.1 and 1.0% H202 (0.029 and 0.29 M) than at similar concentrations of ferric iron because of formation of an insoluble surface coating of uranium peroxide, UO4?4H20. This phase may limit the value of hydrogen peroxide as an oxidant in lixiviants, not only by its very low solubility, but perhaps also by filling pores and reducing permeability in the ore body.

Jan 1, 1978

By John J. Ginty

The objective of the work reported herein was to evaluate state-of-the-art repeaters used in wireless communications to determine their suitability for use in extending the range of portable and mobile communications in underground mine applications. The scope of the work included wireless repeaters in the frequency range from LF (500 kilohertz) up to the one giga-hertz range. These repeaters included not only single-channel repeaters, that is F1/F1 repeaters for short range simplex party line communications, but in addition, F1/F2 type repeaters currently commercially available in the HF, VHF and UHF bands.

Jan 1, 1975

By M. R. Peterson

The U.S. Bureau of Mines investigated column flotation for recovery of a high-grade fluorite (CaF2) concentrate and byproduct concentrates from the Fish Creek fluorite deposit in Eureka County, NY. The recovery scheme consisted of (1) grinding the ore to minus 48 mesh, (2) fluorite rougher and cleaner flotation, (3) desliming the rougher fluorite flotation tailings at 20 Jjm, (4) mica flotation, and (5) silicate rougher flotation. Acid-grade fluorspar, mica, free silica (Si02) sand, and low-grade beryl (Be3Al2S~018) concentrate were produced in a 100 lb/h continuous column flotation unit (CCFU). The highest results achieved were %.6-pct CaF2 recovery in a fIrst cleaner concentrate containing 99.7 pct CaF2. Beryl recovery was as high as 92 pct at a grade of 5.3 pct BeO. The silica sand, which assayed 98 pct Si02, was recovered as the rougher beryl flotation tailings. Collector reagent consumption was reduced 45 pct for fluorite and 58 pet for silicate flotation in comparison with bench-scale conventional flotation. All products were signillcantly improved in both grade and recovery over conventional flotation results, and the recovery scheme was simplifIed by removal of several stages of flotation in the fluorite and silicate flotation steps.

Jan 1, 1990

By C. F. Jackson

This paper has been prepared as a progress report in connection with the series of articles on mining methods and costs which are being published by the U. S. Bureau of Mines in the form of information circulars. Then enough circulars have been completed it is planned to publish a more complete and comprehensive paper in bulletin form dealing with the subject of underground transportation. Progress reports, followed by bulletins, will be prepared from time to time dealing with other subjects included in the general study of mining methods at individual mines, such as mine development, drilling, and blasting; stoping methods (each principal stoping method to be summarized in a separate paper); ventilation; wage, contract end bonus systems, etc.

Jan 1, 1930

By B. K. Shibler, A. O. Ipsen, W. W. Agey

"INTRODUCTION As a part of the program of investigation of domestic sources of manganese ore, mining engineers of the Bureau of Mines obtained and examined samples of ore from six properties in the vicinity of Pioche, Lincoln County, Nev., and from one property near Caliente, Lincoln County, Nev. As the ores were too low-grade to be acceptable for the direct production of ferromanganese, their amenability to concentration by ore-dressing methods was investigated.In general, the Pioche ores had a low manganese content and, owing to extremely intimate association of manganese minerals with iron oxide and nonmetallic gangue, were refractory to concentration by ore-dressing methods. Only two samples (Zero Gap and Wheeler ores) were amenable to the production of concentrates that would sinter to a marketable plus 35-percent manganese grade. The Prince Consolidated and Ely Valley No. 1.ores were roasted and sintered to produce lead-silver-zinc fumes. The residues were of possible value as manganiferous iron ore. No marketable manganese products were made from Calton semi-oxidized ore, but over 80 percent recoveries of lead, silver, and zinc were made by bulk sulfide flotation followed by Diming of the sulfide concentrate. No satisfactory results were obtained by treatment of Golden Eagle and Ely Valley No. 2 ores.The Cudverwell ore was amenable to the production of high-grade manganese concentrates by ore-drssing methods. However, fine grinding was required to effect mineral liberation, and loss of manganese as slime limited the mangenese recoveries obtainable.In the coarse of the investigations, many data were obtained and compiled, but for the sake of brevity, several data, of secondary importance have been omitted or condensed, and only the tests giving the more promising results are discussed in detail. For convenience, the report has been divided into two parts, one opertaining to the Pioche ores and the other summarzing results obtained by testing Culverwell ore."

Aug 1, 1947

Auger operations produced 14 million tons of coal in 1974, or approximately 5% of all surface mined coal. It was the most efficient of all coal mining methods, producing 40.0 tons per man-day. Exhibit 1.1 gives a breakdown of productivity of all coal mining methods. Exhibit 161 PRODUCTIVITY OF COAL MINING METHODS (Short tons per man-day) [Method - 1971 1972 1973 1974 Conventional 11.00 10.00 9.75 9.30 Continuous 13.00 12.50 12.25 11.90 Strip Mines 35.69 35.95 36.00 36.00 Auger Mines 39.00 43.00 45.33 40.00 ] Unlike other surface mining methods, augering produces clean coal, largely uncontaminated by foreign materials, other than those existing in the coal seam itself. However, compared to other methods, the coal recovery rate is relatively low. For example, a triple-headed auger in a 35-inch seam would recover approximately 50% of the coal in the seam as compared to a 90 to 95% recovery rate for strip mining and a 55 to 65% recovery rate for deep-mining. The low auger recovery rate is due to the circular cuts and pillars left in the seam.

Jan 1, 1975

By R. S. Fowkes

A study was made by the Bureau of Mines of the penetration of selected granular materials in an unconfined state by wedge-shaped tools having dimensions comparable with the dimensions of the particles composing the materials. The output force for larger particles fluctuated radically. A custom-designed integrator was used to obtain work as a function of depth of penetration in the form of smooth curves. The influence of wedge angle, depth of penetration, penetration rate, entry angle, compaction state, and particle size on the force required and the work performed was ascertained. Empirical equations describing force and work as a function of penetration were obtained for each set of experiments.

Jan 1, 1973