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By W. P. Yant, C. E. Traubert

"INTRODUCTION Canister-type gas masks have become an essential part of the equipment of many industries, not only for use in emergencies, but also in performing normal operations of industrial processes and procedures, particularly where ventilation is not practically or economically feasible. They are also used widely for enhancing safety of operations which previous to the development of gas masks had been performed in harmful atmospheres.Since the inception of industrial gas masks the Bureau of Mines has been actively engaged in endeavoring to increase the efficiency and safety of these devices, and this bureau has become a source of advice to manufacturers in producing devices of good quality and to industry in the proper selection and use of these devices. In order to give first-hand information and keep current with the demands and needs of industry it is necessary to perform investi-gations from time to time. This report deals with tests of certain types of commercial gas-mask canisters for protection against mercury vapor.TYPES OF CANISTERS EXAMINEDThis investigation included tests of the following types of canisters:(a) Gas-mask canister filled with 725 c.c. of granular activated charcoal, 8 to 14 mesh, and of a quality used in gas masks which meet the Bureau of Mines approval requirements 4 for protection against organic vapors."

Oct 1, 1932

By H. C. Ko

As part of the Bureau of Mines effort to provide thermodynamic data for the advancement of mineral technology, the standard enthalpies of formation for ZnO?2ZnSO4 and COS04-6H20 were determined by HC1 acid solution calorimetry. The values are -550.31 ±0.28 and -641.33 ±0.15 kcal/mot, respectively.

Jan 1, 1982

By W. K. Overbey

Surface fracture trace density, changes in roof rock type, and topographic unloading due to drainage were mapped for the mining areas located in the Blacksville-Osage, W. Va., quadrangles to investigate their influence on mine roof falls. Using these factors, a technique was developed to predict probable roof fall areas ahead of projected mining operations. As a feasibility test of this proposed technique, areas were delineated where one, two, and all three of these factors were operating to formulate a "potential hazard map" for comparison with roof fall observations that were made. The limited evidence suggests that in combination these factors are reliable predictors of where roof falls are likely to occur. This technique promises to be a useful tool in planning mining operations.

Jan 1, 1973

By P. D. Tracy, M. W. Von Bernewitz

"IntroductionA study of 256 coal-mine explosions, which occurred during the period 1909-1924 killed 4113 men and injured 570 others, reveals the fact that there are the critical times of day when explosions are most likely to occur, and when corresponding care should be exercised to guard against disaster. Of these 256 explosions, 83 straight as explosions, 89 were straight coal-dust explosions, and 81 were mixed gas and dust explosions, while three were undetermined.It has been determined from the times given in these reports (in several cases no times were given,that the critical period in the morning ranges between 6 and 9 o'clock when 83 explosions took place with a peal. at 7;30 o'clock. Of these 55 were straight gas explosions, the remainder being either coal dust or mixed gas and coal dust explosions. The critical period in the afternoon or early ranges between 3 and 7 o'clock, when 113 explosions took place, with a peak at 6 o'clock. Of these, 87 wore straight coal-dust explosions the remainder being neither gas or mixed gas and coal-dust explosions. Between these morning and evening periods is one which might be called the noon period - that is, from 11m to 7. p. m. - when 26 explosions occurred while some of these were normal type of explosions - that is, as to causes - others were of unusual cause and character, and. are discussed later. A number of explosions (29 in all) took place during mid-afternoon, late at night, and early in the morning - that is, after midnight."

Sep 1, 1924

Reduce well construction and operation costs associated with in situ leach mining while increasing mineral recovery. Approach To accommodate the size of centrifugal pumps presently in use, in situ leaching production wells are typically drilled to 6 inches in diameter, while monitor wells are drilled to measure 4 inches in diameter. However, in order to reduce the cost of drilling these larger diameter wells and to increase recovery, the Bureau has developed jet pumps which have smaller diameters than centrifugal pumps of the same capacity. This allows both production and monitor wells to be drilled smaller. Bureau estimates indicate that the cost of drilling a 3-inch-diameter production well at in situ leaching operations would be about 35 percent less than the cost of a 6-inch well. Similarly, the cost of drilling a 2-inch-diameter monitor well would be about 26 percent less than the cost of a 4-inch well. Such significant savings in the cost of drilling these wells would effect a substantial reduction in total capital cost. Use of the new jet pumps can also increase the percentage of recovery because less costly wells allow closer well spacings, improving the distribution of the leach solution. How the System Works After the borehole is cased, the new small-diameter jet pump, along with piping and accessories, is installed and connected to a centrifugal pumping unit on the surface. High-pressure water from the surface pump is forced through a nozzle into the venturi of the jet type pump injector. This jet action lifts the leach and mineral-bearing solution to the surface.

Jan 1, 1984

By D. D. Harbuck

To decrease reliance on foreign sources for the strategic and critical metals gallium and germanium, the U.S. Bureau of Mines identified and developed processing technology for two domestic sources of these metals: a Tennessee zinc residue and a Utah ore. Sulfuric acid (H2S04) solutions were used to solubilize gallium and germanium in both sources. Statistically designed experiments showed that the most important parameter for high metal extraction from zinc residue was the H2S04 concentration. At a concentration of 2.9M H2S04, 95 pct of the gallium was extracted, and at a concentration of 0.6M H2S04, 73 pct of the germanium was extracted. Controlled H2S04 concentration was also the key for high metal extractions (97 pct Ga, 87 pct Ge) from the Utah ore. Such control was achieved using a two-stage countercurrent leach circuit. Testing showed that the insoluble germanium in both the residue and ore was tied up with silica. Several methods for overcoming this problem are given. To recover gallium and germanium from the leach solutions, the solvent extractants octylphenyl acid phosphate (OPAP) (for gallium) and LIX 63-OPAP (for germanium) were identified. These extractants were tested in separate, continuous, solvent-extraction circuits yielding a gallium recovery of 94 pct and a germanium recovery of more than 90 pct.

Jan 1, 2010

By D. W. Bridges, L. Crocker, R. O. Dannenberg

About 95 pct of the beryllium was dissolved from most ore samples by agitation leaching with 600 lb of H2SO4 per ton of ore for 24 hours at 65 ° C and 35 pct solids . Leach slurries generally were viscous , and the limiting pulp density for thorough mixing was about 35 pct solids . Settling of the leached pulp required 0.6 to 0.8 lb of a polyacrylic flocculant per ton of ore leached with 600 lb of H2SO4 per ton , whereas ore leached with 800 lb of H2SO4 per ton required only 0.2 to 0.3 lb of flocculant per ton . Terminal densities of the settled pulps were about 28 and 35 pct solids , respectively , from leaches using 600 and 800 lb of H2SO4 per ton . Vacuum filtration of settled pulps at 15 in . Hg resulted in a filter cake containing 50 to 59 pct solids . Roasting the ore at 500 ° C before leaching increased the limiting pulp density for effective mixing to 50 pct solids . Acid requirements , however , were not diminished , although leaching roasted ore with 600 lb of H2SO4 per ton resulted in densification of settled pulps to about 40 pct solids . Filter cake from leaching preroasted ore contained about 20 pct less water than that from unroasted ore .

Jan 1, 1963

A Helix Pressure Gauge to Indicate roof bolt loads was designed, fabricated and field tested. The gauge indicated loads between 3,000 and 15,000 pounds with a ± ten per cent error. The coat of fabrication of the gauge was estimated to be $3.39 including an assumed overhead and profit per indicator for a series production of 5,000 unite. The unit can be read on a bolt to within ± 1,000 pounds load from a distance of twenty feet.

Jan 1, 1974

This study assesses whether Narragansett Basin coal deposits could be developed commercially in the near future. To do this, we identify the potential market for the coal, assess the price these users would be willing to pay for Narragansett coal, and this price to the expected costs of producing Narragansett coal. The study concludes that the major market, New England utilities, could burn bituminous coal from Pennsylvania or West Virginia at a lower total cost than Narragansett Basin coal, assuming expected mining conditions and emission policies. Therefore, the study concludes that Narragansett Basin coal resources could not be developed economically in the next ten years.

Jan 1, 1979

By G. L. Oldright

In an earlier series of 15 Reports of Investigations on Smelting in the Lead Blast Furnace, experimental data were given on the operations of a custom smelter, a smelter treating rich lead products, and a smelter treating highly zinciferous charges. Five "reports" were written on each of the three types of operation, which were later compared in a summary written for the Institute. Developments in each of these types of operation in lead smelting since the last of the above reports was written have continued and have followed modifications necessitated by changes in the nature of the products received for smelting. The sintering-blast furnace-smelting plants have improved their sintering operation .and have made "2-pass" sintering a more standard operation; the richer lead feeds are diluted when marginal precious metal ores are not available to prevent fusion of the sinter cakes and to permit air to contact the sulfides. Means have been devised to make it easier to remove metallic lead from the wind boxes, but no attempts have been observed to use the D & L somewhat as an ore hearth to make more metallic lead. Except in those cases where zinc-rich lead blast-furnace slags were to be retreated in a "slag-fuming furnace," the sintering and the blast-furnace operations were so carried out that a relatively "clean," lead-poor, final slag was discarded.

Jan 1, 1949

By A. F. Baker

Laboratory flotation of synthetic coal-pyrite mixtures and high-pyritic-sulfur coal indicated that ferric chloride (FeCl3), aluminum chloride (AIC13), chromium chloride (CrCl3), and cupric sulfate (CuSO4) are potential pyrite depressants. For each metal salt there appeared to be a range of pH values and optimum concentration for selectively depressing pyrite in coal flotation. Pyrite was depressed in the pH range from 4.5 to 7.0 with ferric chloride, from 5.8 to 7.0 with aluminum chloride, from 6.4 to 7.1 with chromium chloride, and from 6.4 to 7.4 with cupric sulfate. Best separation of pyrite from coal was achieved in flotation solutions containing from 2 X 10-5 to 5 x 10-5 mole/ liter of each salt. In solutions containing excess salt concentrations, coal was also depressed. These Bureau of Mines tests demonstrated on a laboratory scale that, in solutions containing 4 X 10-5 mole/liter ferric chloride and from 1 x 10-4 to 2 x 10-4 mole/liter sodium hydroxide, the pyritic sulfur content of a Lower Freeport bed coal sample could be reduced from about 2.51 percent to less than 0.60 percent with recoveries of over 83 percent. The depression of pyrite appears to be due to the adsorption of positively charged colloidal metal hydroxide at the pyrite-solution interface. This hypothesis is supported by zeta potential determinations which showed that suspended coal and pyrite particles in solutions containing metal salts are positively charged in the pH range where depression occurs.

Jan 1, 1971

By David K. Denton

Results of the mineral resource study of the Upper Priest Lake RARE II study area indicate a low potential for the discovery and economic recovery of silver and lead in the Prichard Formation near contacts with the Kaniksu Batholith in the vicinity of the Mountain Chief Mine (fig. 1). Silver and lead minerals locally occur disseminated and in irregular quartz fissure-fillings in the Prichard Formation. Between 18^6 and 1967, 105 lode raining claims were located in the study area. The area was designated for "further planning" in the Final Environmental statement but was later changed to "nonwilderness" by President Carter after work was scheduled for the area.

Jan 1, 1981

By S. M. Molloy

The postwar demand for insulating material such as mineral wool, in-creased in proportion to the rapid construction of new buildings, placing an enormous burden on the existing mineral-wool industry both in known sources of raw materials and in available plant facilities. In view of the increased demand on the industry, the Bureau of Mines in its Mississippi Valley Experiment Station" Rolla, Mo., undertook an investigation to aid the industry by establishing resources of raw materials through actual laboratory wool-blowing tests and by developing certain methods for evaluating the physical proper-ties of a mineral wool. As material was received from the public, laboratory-evaluation technique had to be developed, the results of which would reflect in the mineral-wool-industry standards. The methods of testing used by the mineral-wool industry, not only would have required a pilot-plant installation capable of producing a large tonnage of mineral wool, but each wool-blowing campaign would have been very expensive and necessitated considerable personnel and equipment. The present laboratory wool-blowing equipment can produce as high as eight wool-blowing campaigns a day. The nature, simplicity, and size of the physical testing equipment permit testing as small a sample of wool as 25 grams and give information as reasonably accurate as in a 40-pound bag of wool. The purpose of this report is to describe the laboratory method of production and the evaluation of the physical properties of small quantities of mineral wool. Considerable work has already been done, and the interest of the public and industry is measured in the number of samples being submitted for testing.

Jan 1, 1948

By John C. Machisak

The National Safety Competition is sponsored and conducted annually by the Bureau of Mines, U. S. Department of the Interior, to stimulate greater interest in safety in the mineral-extractive industries and to encourage the development of more effective accident-prevention programs. Since its beginning in 1925, thirty-four safety contests have been conducted. This publication reports results of the 11 annual contests for the period 1948-1958, inclusive. Mineral operations awarded the "Sentinels of Safety" trophy for the best safety record in their competitive group as well as those ranking second, third, fourth, and fifth are listed along with a summary of their achievements in preventing disabling injuries. In addition, this publication contains statistical information reflecting the disabling work-injury experience of all other mines and quarries enrolled in the annual contests. The injury statistics of these operations are arranged in the six groups of the competition and through 1955 are the only data on injury-severity at noncoal mineral operations published by the Bureau of Hines. Recognition of the National Safety Competition in promoting safety has increased steadily during its 34 years. The number of plants participating in these annual competitions increased from 210 in 1925, its first year, to a record of 675 in 1958. The expanding scope of the National Safety Competition indicates that more mines and quarries in the United States are enrolling 90 all available means to promote safety on the job will be used. Safety contests like this are generally recognized, in the field of safety promotion, as an effective way to arouse and hold the interest of employees and officials in accident-prevention programs. They tend to forge individual precautionary acts into group action centered on a common objective, such as winning the ?Sentinels of Safety? trophy.

Jan 1, 1960

By Forrest T. Moyer

Quarry accidents in 1963 caused 61 fatal and 3,468 nonfatal injuries which occurred at respective frequency rates of 0.31 and 17.91 per million man-hours of worktime. The fatality record in 1963 was better than in 1962 but was appreciably worse than in 1.961. For nonfatal injuries, the 1963 record was slightly worse than in 1962 but was better than in 1961. The injury--severity rate of 2,913 days lost or charged per million man-hours in 1963 was better than that of 3,046 in 1962, the first year for which such data became available. The average severity of all injuries in 1963 was 160 days lost or charged per injury, 15 less than in 1962. An average of 91,960 men were at work on active days in 1963 and these men had an aggregate worktime of 193.7 million man-hours during the year.

Jan 1, 1972

By R. R. Sayers

Carbon monoxide poisoning, as usually encountered, is an acute condition resulting from breathing atmospheres containing that gas. It is characterized clinically by headache, dizziness, weakness in the legs, increased respiration at first which later becomes irregular and depressed, collapse, unconciousness, and death; anatomically it is characterized by temporary changes in the red blood cells due to the combination of carbon monoxide with hemoglobin, and, in prolonged severe exposures, degenerative changes in various tissues of the body, especially those of the central nervous system. No race or nationality is immune or has a, special tolerance for carbon monoxide. From data at hand, it is known that both sexes are about equally susceptible. All ages are affected, but small percentages seem to have a more deleterious effect upon young animals and this is possibly true of children. Exercise, high temperature and humidity, and low oxygen content of en atmosphere increase the degree of poisoning for a certain concentration of carbon monoxide. Anything that lowers the physical fitness of a man, such as illness, overwork, or excesses of any kind, exaggerates the effects. More cases of poisoning from carbon monoxide occur in coal mines in the cold months of the year, because explosions take place more frequently during that period, also in homes where gas is used for beating purposes, and in garages from accumulation of automobile exhaust gases due to poor ventilation.

Jan 1, 1923

By E. A. Loria

High-quality sheet of electrowon molybdenum was attained by a sequence of procedure on pressed and arc-melted crystalline powders. The procedures included high-temperature, high-vacuum sintering treatments and the use of metal deoxidizers instead of carbon to improve the mechanical properties of the molybdenum sheet. Rolled sheet 60 mils thick was evaluated by tensile and bend tests, hardness measurements, microstructures, and recrystallization treatments. After stress relieving, yield strength ranged from 85,000 to 110,500 psi (0.2- percent offset) and ultimate strength ranged from 87,200 to 117,250 psi with 4.5- to 25-percent elongation observed for arc-melted sheet, and 5.0- to 23- percent elongation observed for powder metallurgy sheet. In room temperature bend tests the sheet yielded plastically, indicating that the ductile-brittle transition point was below room temperature. The diamond pyramid hardness (DPH) of the molybdenum sheet changed from 214 to 293 DPH for the stress-relieved condition to 177 to 185 DPH for the fully recrystallized condition. The brittleness of recrystallized molybdenum, reported by other investigators as characteristic of sheet prepared from commercial-grade hydrogen-reduced powders, was not in evidence. Recrystallized tensile specimens pulled at room temperature had an average elongation of 31 percent.

Jan 1, 1966

By M. M. Myers

"Importance pf the small stone problem.Profitable disposal of limestone too small for making lime in the shaft kiln, is one of the most urgent problems in the lime industry. Reports received by the Bureau of Mines from 31 quarries show that the proportion of small stone varies from 2 to 40 per cent, averaging 18 per cent of gross pro¬duction, Modern methods of heavy blasting, and the use of crushers in large quarries tend to increase the proportion of small stone above that produced in early days when light blasting and hand sledging were almost universally used. There is also a growing movement toward underground operation of lime deposits, a method which in general produces a greater proportion of fines than is encountered in open-pit work. Thus the small stone problem is of growing importance, and demands the attention of every progressive lime producer. As the problem is of almost universal interest, it is urgently desired that every operator who reads this report will contribute from his knowledge or experience, answers to the questions on the final sheet.There are several markets in which small stone may be sold but in these markets the competition is generally keen and the prices low. The lime producer's chief product is lime, he understands its manufacture and marketing, and brings him a greater return than can be obtained from most limestone by-products. For these reasons it is evident that the conversion of small into lime is the nest desirable means of disposal."

Apr 1, 1924

By R. R. Sayars

"Carbon monoxide is a gas slightly lighter than air, with which it diffuses readily to make a homogeneous mixture. It will burn and has a wide explosive range, that is, an explosion is possible when the air contains from 15 to 73 per cent of the gas3. This explosive range is about the same as that for hydrogen and over nine times As Tide as that for marsh gas (methane). Like air, it has neither color nor taste and has no odor in concentrations usually encountered, therefore it cannot be detected by the ordinary senses with which men are endowed. It is produced by burning carbon containing fuels, no coal, wood, gasoline, etc., whenever not enough air or oxygen is supplied to burn and oxidize the fuel completely.The human race has probably been exposed to this gas since men first began using fires in confined or sheltered places. The poisoning as usually encountered is an acute condition resulting from breathing atmospheres con¬taining this gas. A number of eases described in the ancient literature Indicate that carbon monoxide was a frequent cause of death by accident, suicide and is a means of punishment or torture. A quotation by Lewin from Aristotle who lived in 384-322 B.C., states that ""animals collapse from harmful odors as men gets a severe headache and often dies through charcoal vapors"". The Roman knew that smoke was poisonous, and used the greenest most smoke-producing wood to put persons to death. The occurrence of carbon monoxide increased in frequency through the years until at the present time it is found in the home as well as in many industries. The following table gives the approximate percentage of carbon monoxide found in gases from various sources of poisoning.4"

Apr 1, 1924

By Mark S. Sanders

Based on laboratory tests and preliminary field tests of off-the-shelf steel toed rubber boots, a molded sole design was developed to provide increased traction over conventional calendared sole miners' boots. The pattern provided sharp edges perpendicular to both lateral and fore-aft slip vectors. The sole was designed to reduce mud caking. An instep lace-up capability was added to better secure the foot inside the boot. A five month field evaluation compared the prototype boots to the boots the participants usually wear. Although objective slip and fall data showed no significant advantage for the prototype, subjective evaluations made by the participants indicated increased traction for the prototype boots. Approximately 75 percent preferred the prototype to their own boot. Approximately one-third used the lace-up capability. It was concluded that molded soles provide better traction than calendared soles for the underground mining environment.

Jan 1, 1982