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By G. G. Barbante

An understanding of the thermodynamics of smelting copper anode slimes is a prerequisite for improvements to the process. During slimes smelting, a silver-copper selenide matte is formed and subsequently oxidised to silver metal. As part of a series of investigations, molten silver selenide matte was oxidised at 1 100 degrees C with pure oxygen. The chemical potential diagram for the system was developed and used for qualitative prediction of the results of the experiments. A simple, computational thermodynamic model of converting is presented, the adjustable parameters of which were determined by matching the model with the experimental results. The practical usefulness of the model was demonstrated by predicting the effect on silver recovery of smelting temperature and of using either oxygen or air as the smelting gas

Jun 21, 1905

By R. Poulin, C. F. Gleeson

The Birimian rocks of the region are gold-bearing and show many similarities to those of Burkina Faso. All three greenstone belts (Goroual, Tera and Sirba) host gold-bearing quartz veins. It appears that, contrary to previous misconceptions, lateritic terrain is not an unfavourable environment for exploration geochemistry. This is demonstrated by the results for the Koma Bangou area, where soil and termite-mound geochemistry have been successfully used in the search for gold. Soil provides an effective sampling medium where it is shallower than about 2 m; there is evidence that some soil anomalies are enhanced by the presence of secondary (botryoidal) gold. In areas of thicker, allochthonous soil cover, termite-mound sampling is more effective. At Koma Bangou an identified resource of some 11 100 000 tonnes with an average gold grade of 2.44 g/t has been reported. The gold mineralisation occurs in quartz veins and stockworks aand in the wallrocks of shear and fault zones that trend N, NW and NE. The host rocks are a granodiorite-syenite porphyry and intermediate metavolcanic rocks and tuffs

Apr 1, 1996

By J. E. Misiewicz, A Rozendaal

Paper presented at Geofluids '93, held in Torquay, UK, 4-7 May 1993. The tin field consists of a fragment of Lower Proterozoic volcanosedimentary rocks surrounded by granitoids. Almost all the significant deposits are hosted by arkoses and are classified as replacement and space-filling types, with particular styles of mineralisation dominating at different mines. Petrological and geochemical investigation of borehole cores from four centres indicated the presence of a stratified zone 500-600 m thick and continuous over at least 20 km along strike, consisting of pervasively altered clastic arenitic sediments. The alteration is zoned into a grey-green sodic albitised footwall, an 80 m thick sericitised-tourmalinised sulphidic tin zone and a red haematitic potassic hanging-wall. The zoning and the localisation of three cassiterite phases are consistent with the tectonic history and with multiple pulses of stanniferous hydrothermal fluids derived from late differentiates of the granites over a prolonged period. Areas of high fracture density acted as conduits for the fluids, whose initially rapid ascent was retarded by decreasing pressure contrast, limited development of fracturing and/or impermeable shaly arkose to cause lateral spreading and pervasive alteration over a broad, stratified front. Lateral overlapping of local fronts at the various centres suggests a continuous zone, while the many petrological and geochemical similarities point to a shared fluid composition

Aug 1, 1995

By L. E. Mordberg, E. N. Nesterova

Geochemical studies of the bauxite deposits show that the primary composition is gibbsitic. Some trace elements were relatively mobile during bauxite formation with the content of Th, U and Zr increasing and that of Rb, Ni and Co decreasing. Y and Pb were relatively immobile during lateritisation; their contents and ratios were inherited from different types of underlying rocks. The supply of Ni and Co took place at the diagenetic or epigenetic stages; their ultimate source was the crystalline basement in the region. The studies support the view that the bauxite was likely to have originated as a result of in-situ lateritisation and not through sedimentary transport and redeposition

Jun 18, 1905

The reduction of zinc from slags by a molten, carbon-saturated bath was examined in a laboratory study under conditions of continuous slag feeding. The results show that it is possible to reduce the bulk of the zinc from the slag before there is a net reduction of iron. However, the recovery of zinc was not as high as in batch tests performed in an earlier study. Lead in the slag was reduced simultaneously with the zinc to very low levels and was volatilised. Copper in the slag was reduced and dissolved in the alloy. An attempt was made to identify potentially commercial ways of treating zinc slags using an iron bath. The approaches that appear to have the greatest potential are reduction in a batch process using electrical heating and reduction in a continuous process with co- or countercurrent flow of the slag and alloy. In the latter the alloy would be prepared in a separate furnace before being contacted with the slag. The purpose of this would be to superheat and carburise the alloy so that no additional heat or reductant would have to be supplied in the slag-alloy reactor

Jul 1, 1991

By D. K. Bose, R. H. Rakhasia, V. D. Shah, J. C. Sehra

A series of experiments was conducted to determine the effects of roasting temperature, soaking period and quantity of soda ash added. At a laboratory scale, under optimum conditions of roasting at 873 K for 2 700 s with soda ash 10 wt% in excess of stoichiometric, molybdenum recovery was 99%. The investigations indicate the technical feasibility of producing high-purity MoO3 by combining the roasting process with carbon adsorption/desorption. The process uses low-cost chemicals, can be scaled up readily and is free of the SO2 pollution generated by conventional roasting, as the sulphur content of the concentrate is converted to sodium sulphate

Jun 18, 1905

By S. P. Ball, A. J. Monhemius

In a laboratory study under acidic oxidising conditions, the thiocyanate system gave results at least as good as cyanide and considerably better than thiourea, with modest consumption of SCN (less than 1 kg/t ore). For both cyanide and thiocyanate lixiviants a residence time of about 24 h was required for maximum gold extraction, which was generally in the range of 92-96%. The adsorption of gold from thiocyanate leach liquors was found to be rapid, but activated carbon catalyses the autoreduction of ferric iron to ferrous iron in thiocyanate solutions, suggesting that ion exchange may be a better recovery route

Dec 1, 1995

By M. W. Robotham, H Wang

removal efficiency is analysed from a stochastic

Apr 1, 1995

By W. R. Paterson, W. Morton, D. B. Cameron

The Massbal II computer simulation program has been used to develop a general framework for the building of thermochemical models of metallurgical processes. The framework allows the rapid, simple construction of complex models of process equipment for use in flowsheet design, planning and plant operation. Application of the program to model the iron-making blast furnace and a flash smelting process is described

Apr 1, 1991

By Dean S.

Further discussion at the The Midland Counties Institution of Engineers' general meeting held in Nottingham on 6th May 1916, of the paper published in Trans. I.Min.E., vol.L, 1915, p.179, included brief oral contributions by Bragge G.S., Lewis W.H. and Hepplewhite W.H.

Dec 1, 1916

By S. J. Parry, D. M. Evans, D. L. Buchanan

The reef is a PGE-enriched sulphidic zone, stratigraphically associated with and overlapping the C1d chromitite layer, that was formed by magmatic processes at the 1e-1d subunit boundary. Two distinct patterns of PGE enrichment are related to the presence or absence of Cr2O3 oversaturation during sulphide liquation that occurred during a complex sequence of changes at this boundary

Apr 1, 1996

By F. Tailoka, G. Zhao

Pb is an unwanted impurity in Al for which there is no established method of removal. As it interacts strongly with alkali metals, separation was achieved by adding Na or K to molten Al at 953-1 003 K. Direct Na addition led to considerable evaporative loss but in-situ addition by electrochemical titration from a eutectic NaCl-KCl or KCl-BaCl2 mixture was found far more effective, in some cases reducing Pb content below detection levels within 2 h of titration. K appeared more effective than Na at low Pb concentrations but the use of Na was preferred as it is less toxic and explosive. Na removal from Al-Na and Na-Pb alloys was also carried out electrochemically, the use of these two alloys rather than the eutectic salt as a source of Na avoiding liberation of Cl2 at the anode

Apr 1, 1995

By D G. Oldfield

Pall has developed and supplied to several airlines cabin air libers to provide clean air for passengers and crew in flight, while reducing airline operating costs. Most of today's modern commercial passenger aircrafts employ cabin air recirculation as a means of reducing operating costs. With large numbers of passengers being subject to an increasing proportion of recirculated air for hours at a time, the matter of cabin air quality, with particular respect to the health effects on passengers and crew, has to be addressed. Commercial pressure will ensure that the airlines and aircraft manufacturers will not revert back to the total fresh air systems of the 1960s and 1970s. In fact, feasibility studies are already being undertaken to look at increasing the proportion of recirculated air to 80% and above. With the application of specialist nitration technologies. Pall is able to ensure that the requirements for economy are met whilst ensuring that the air is effectively rendered as 'fresh air’ each time it is recirculated.

Jan 9, 1996

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

Two concentrates from Palabora, in South Africa, containing 0.056-0.068% undesirable Cu and 0.8 or 2.2% Ti, were chlorinated with air:chlorine ratios of 10:1, 15:1 and 20:1 at temperatures between 1 200 and 1 329 K. The resulting volatile chlorides were condensed and the solutions analysed for Cu, Fe and Ti. Recovery of Cu was less than 25% at low temperatures and short reaction times, but at 1 258 K almost all Cu was removed from the magnetite at all ratios of chlorine to air. At higher temperatures, the increased carrying over of iron as FeCl3 could be minimised by decreasing the partial pressure of chlorine. No titanium was detected in the volatile products and the percentage of Cu recovered was independent of Ti concentration in the concentrates, though as a function of Cl2 vol%, more Cu was recovered at 1 200 K from the low-Ti than from the high-Ti concentrate. In a fluidised-bed reactor, Cu recovery was 58-90% and iron carry-over less than 10 ppm

Jun 21, 1905

By H. S. Sichel, W. J. Kleingeld, C. E. Dohm

A model of ore value distributions is presented that is the culmination of a statistical approach rather than simply a model that has been successfully applied to the evaluation of ore reserves. Detailed geological and physical observations based on large sampling data sets have been used to support the statistical modelling. Fundamental to the modelling process is the concept that the occurrence of a given grade value in space is a function not only of the presence of the mineral but also of the fact that it is associated with a specific trapping mechanism. The concepts have been specifically applied to gold mineralisation

Aug 1, 1995

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By J R. Leeming

The paper describes a technique that has been developed by the Health and Safety Executive (USE) to make an assessment of the effectiveness of Health and Safety (H and S) management at complex sites. The paper then describes how the technique was adapted and used for the first time at a large coal mine. The results highlighted certain deficiencies in the safety management system, allowing directed advice to he given to management.

Jan 4, 1997

By G Fakes

This paper describes the history of civil engineering tunnelling and developments in soft ground techniques during the 19th and 20th centuries, culminating in the design and use of high speed tunnelling machines for all types of ground conditions. Some of the problems encountered are outlined, and descriptions are given of some contemporary developments in rock tunnelling techniques, with comparisons of methods used in the mining industry.

Jan 5, 1996

By L. J. Cabri, J. M. D. Wilson, R Lastra

An image analysis program can search for gold minerals in polished sections by scanning about 100 x 100 back-scattered electron images at a magnification of x400, allowing gold grains as small as 1 micrometre in diameter to be detected. Typically, a c.15 h overnight search of a product smaller than 45 micrometres will scan c.1 500 000 particles, providing data that are not easily obtained through manual operation of an optical microscope. The program locates grains of the correct brightness, acquires gold X-rays from them by wavelength-dispersive spectrometry, filters the data to remove artefacts and record the images and stage locations for subsequent retrieval. At the end of the run, the program allows the operator to verify and identify the grains found. Industrial studies at Canmet have included determining the nature of gold in cyanidation tailings, checking the mineralogy and size of gold grains in samples from an Indonesian Cu-Au concentrator and locating and measuring gold liberation and grain sizes in an ore

Jun 21, 1905