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By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By U. Dillon, G. Blackwell

"Geographic information systems (GIS) provide an efficient means for the recording, manipulation, revision, display and analysis of spatially referenced data. GIS are widely used at the exploration stage of mine development, and are increasingly used for reclamation planning. The ability of a GIS to perform spatial searches and query spatially referenced data make it a powerful tool for use at all stages of mine development. As the amount of data available for analysis increases, so does the power and flexibility of GIS as a planning tool.Starting from the exploration database, this paper describes how a GIS can be used for the development of mining plans based on topography, geology and mineralization information stored in a relational database. Planning decisions approaching the optimal can then be made for a wide range of parameters, including stockpile and waste dump locations, the location of potentially acid generating and neutralizing material for dump design, profitable and risk-controlled mine extraction sequencing, and haul road locations. This is made possible by the overlay and buffer analysis capabilities of a GIS which are explored and exploited to produce a continuous mine production planning program, as well as site remediation and reclamation using a successful case study. The Ore and ProductsThe mines in the Saskatoon area — Agrium, PCS-Cory, PCS-Allan, PCS-Patience Lake, PCS-Lanigan and IMC-Colonsay — extract the ore from the Patience Lake member. The mines in the southeast corner of Saskatchewan — IMC-K1 and K2, PCSRocanville — extract from the Esterhazy member, while IMC-Belle Plaine, near Regina, solution mines potassium chloride from both potash-bearing members.Ore from the Patience Lake member is a medium-grained mixture of sylvite and halite, with a KCl content of 36%, insolubles averaging up to 5.5%, and little or no carnallite.The ore from the Esterhazy member is a coarse-grained mixture of sylvite (KCl) and halite (NaCl) with a small amount of water insolubles, and some carnallite (a K-Mg chloride). Average run-of-mine grades are about 30% KCl."

Jan 1, 2003

By R. A. D. Pattrick, D. A. Polya, D. J. Marsh, J. -J. Bao

"Abstract-The utility of high-density stream sediment and stream water sampling to the exploration for silver deposits was investigated by the study of the epithermal Ag-Au base-metal prospect at Lagalochan in western Scotland. The geology of Lagalochan is dominated by a calc-alkaline Caledonian intrusive complex emplaced into Dalradian Supergroup rocks (Harris et al., 1988a). The complex consists of subvolcanic porphyrytic rocks associated with intense hydrothermal alteration and brecciation. Early Cu-Ag-Mo-rich mineralization is found in the core of the complex with later Pb-Zn-Ag-Au-As-Sb-rich mineralization toward the margins (op. cit.).Stream sediment sample analysis spatially resolved the Cu-rich and Ag-rich mineralization. Ag and Cu anomalies relative to local background values were found in all size fractions analyzed (-125 µm, +125 µm, +180 µm, +250 µm) but the more pronounced anomalies were found in the -125 µm fraction. The coarser fractions generally revealed more erratic but longer dispersion trails. The separation of Cu-rich and Ag-rich mineralization is also apparent in the distribution of relatively high dissolved Cu and Ag in stream waters, particular when expressed relative to the solute load as Cu/TDS and Ag/TDS.The mineralization at Lagalochan is indicated by Ag, Cu and Pb stream sediment and water concentrations that are anomalous with respect to local backgrounds, but are difficult to distinguish from regional backgrounds. This emphasizes the further potential of high-density stream water sampling, in particular, as a viable geochemical exploration tool on a sub-regional scale for epithermal deposits in relatively unpolluted upland terranes."

Jan 1, 1995

By Peter Heine

Diavik Diamond Mines Inc. (DDMI) has treated systems development as an integral part of the construction project when it built Canada?s second diamond mine. Fully aware that the proper collection and processing of operational data is needed to drive business decisions during production and planning, key Performance Indicators (KPIs) were defined to effectively manage operations when the mine went into production. The Production Information Management System (PIMS) allows KPIs to be measured, reported, and transferred to other systems in a reliable and convenient manner. PIMS provides a mechanism to collect real time production data from the various control systems around the site and acts as a tool to ?drill-down? and establish the important cause-effect relationships that impact the value of a KPI. Thus PIMS provides a data collection, storage, management, and an environment in which cause-effect relationships can be analysed and statistically verified. This understanding of the real cause-effect relationships, close to the source of the data and in the context of the operation, can be used to improve both operations and maintenance performance. The PIMS includes the PI Database implementation, its associated external interfaces with the various Control Systems, Cleaning Packaging Weighing System, Environmental System, Enterprise Asset Management (EAM) System, and Diamond Tracking System (DTS), as well as laboratory data collection, custom applications (downtime tracking, data reconciliation) and user clients. The interface with the EAM system provides material flow quantities and equipment availability on which the plant performance reports are based. The transfer of equipment usage to the EAM system is fed into the maintenance notifications and work orders functionality in the EAM. The environmental system interface provides the mechanism for capturing water consumption data required to generate the various regulatory reports. The interface to the cleaning-packaging-weighing system provides the mechanism for capturing batch data for transfer to the DTS for diamond product tracking at the production splitting facility in Yellowknife. The PIMS lab application provides a means of getting sample data into the system for critical metallurgical metrics, and the data reconciliation application provides a means of manually verifying the data before it is published or passed onto other systems.

May 1, 2003

By John Starkey

This paper examines 5 years of SAGDesign testing data with particular emphasis on the grinding test results from two recent projects, the Fortune Minerals Limited NICO project, and the Aurora Energy Resources Inc., Michelin deposits, located in the Northwest Territories and in Labrador respectively. The context is to compare these results with the SAGDesign database. The required SAG mill pinion energy for these two ores showed vast differences, even though both ores had similar average Bond Ball Mill Work Index values - about 13 kWh/t each for the two deposits respectively. Bond Rod Mill Work Index values for NICO ranged up to 19.7 kWh/t for the hardest ore, confirming the harder nature of the coarse material. SAG mill pinion energy to grind the NICO cobalt-gold-bismuth-copper ore from F80 152 mm to T80 1.7mm varied from 16 to 35 kWh/t, while for Michelin uranium ore, it varied from 2 to 9 kWh/t. NICO ore is harder than any other material encountered to date using SAGDesign testing. SAG pinion energy is more than double the ball mill pinion energy using a transfer size T80 of 1.7mm and a final grind P80 of 74 microns. For NICO, the ore is ?off the charts? for simulation design techniques because there is no comparable operating SAG mill treating ore that is this macro-competent. For Aurora, the relationship between SAG and ball mill pinion energy is reversed in that the SAG mill requires less than half of the ball mill pinion energy using a transfer size T80 of 1.7mm and a final grind P80 of 90?. Because these discoveries are so important for grinding mill design, their impact will be dealt with in future papers, at the August METSOC Conference in Sudbury, and at the September SME Workshop in Tucson. It has now been concluded that the ratio of SAG pinion energy to Bond Ball Mill Work Index, is valuable data to use in designing a SAG/ball mill grinding circuit, to help choose the power split needed.

May 1, 2009

By D. J. Bowen

"The Great Dyke extends for 540 krn along strike, to unknown depth, and varies in width from 3 krn to 11 krn. Rb/Sr age determinations gives values of approximately 2470 Ma.The Dyke consists of a variety of mafic and ultramafic rocks, many altered to serpentinites. These include, from top to bottom, successions of gabbro/norites, pyroxenites, peridotiteslharzburgites, and dunites/picrites.The layers dip in from either margin, steepest at the edges (20°) and flattening toward the central sections. Four separate complexes are present. From north to south these are termed the Musengezi, Hartley, Selukwe and Wedza Complexes, and are described as 'boat-shaped' or 'pig-troughed'. All are similar in petrological sequences. Physiographically, the Dyke is spectacular in the north, where as a mountain range it meets the Zarnbezi Escarpment. Elsewhere in the central parts there is little surface expression and wide open treeless vleis. Dyke rocks cut through granite and schist belt terrain and are termed 'The Magnesia Belt'.Vast mineral resources exist. These include chrome, asbestos, platinoids, nickel, copper and gold. Up to eleven chrome seams numbered from top to bottom occur in the lower ultramafic sequences. Seams are narrow at 10 em to 30 em but of high grade. The platinum occurs 10 m to 40 m below the norite/pyroxenite contact.A 60 m wide zone of Light Sulfide Mineralization (LSM) of less than 1070 sulfides extends from the lower gabbronorites into the upper pyroxenites. In this LSM, four enriched zones carry up to 5% sulfides. The most widespread is termed the Main Sulfide Zone (MSZ), below which is No. 2, No.3 and No.4 Sulfide Zones. The MSZ carrying pyrite, pyrrhotite and chalcopyrite is a multielement ore with components of PGE (pt-Pd-Rh), nickel, copper and cobalt, and gold and silver.Extensive exploration programs have been carried out and the intention is to begin large-scale mining. However, with Russia supplying metals to the western markets, South Africa's cutback on production, and an end to the Cold War, delays have arisen."

Jan 1, 1994

By H. Henao, F. Canales

The present work evaluated the use of copper ore flotation tails as flux in the process of smelting copper concentrates. For this purpose, experimental and simulated liquidus lines were obtained at different ratios of tail/flux. Experimental variables included temperature, partial pressure of oxygen and sulfur dioxide and the conditions of tridymite or spinel saturation. The results indicate the feasibility of replacing the flux by increasing the temperature of the smelting process by 20°C. Results of simulation using FactSage and HSC confirm that the required increase in temperature can be achieved by increasing the flow of concentrate, enrichment of oxygen or increasing the matte grade. INTRODUCTION In the pyro-metallurgical process of copper production, the smelting stage produces two liquid phases, a sulphide phase rich in copper and another composed mainly of oxides called slag. The slag phase is the product of oxidation of the iron contained in the flotation concentrate. The smelting process which is carried out at temperatures of 1250°C, require the addition of silica as a flux and the injection of air enriched in oxygen (Schlesinger 2011). Currently, one of the most important aspects of the mining industry is the minimization of costs, the optimization of the use of available resources and the reduction of environmental impact. Under this context, the use of flotation tails from as a flux in the copper smelting process has the potential of reduced production costs and generate an environmental benefit by reduce the disposal amount of this waste material Regarding the use of copper tails as flux in the copper smelting process, a thermodynamic simulation study using the FactSage software had been reported in the literature (Parra et al., 2011). The results indicated an increase of 35°C in the temperature the liquidus for the equilibrium matte/spinel and a subsequent requirement of energy in the process of approximately 350 [MJ/ton slag]. Given that the calculated viscosity remains in the same order of magnitude, the melting temperature is a more relevant parameter for the evaluation of the use of tailings as flux.

Jan 1, 2019

By Bernard Vigneault

Les critères de qualité de l?eau pour les métaux visant à protéger la vie aquatique sont présentement basés sur les concentrations totales. Cependant, la complexation (association de ces métaux avec des ligands en solution) peut diminuer de façon importante la toxicité des métaux sur les organismes aquatiques. Pour évaluer l?importance de la complexation pour diminuer la toxicité des métaux dans les effluents miniers et métallurgiques, nous avons étudié la spéciation des métaux et la toxicité chronique de différents effluents miniers et métallurgiques. La phase dissoute des effluents a été échantillonnée à l?aide de la dialyse in situ et la spéciation du cuivre, du zinc et du cadmium a été calculée à l?aide du modèle d?équilibre chimique WHAM. Les concentrations de métaux libres ont également été mesurées à l?aide d?une technique d?échange ionique. Les concentrations de métaux libres calculés et mesurés indiquent que la complexation est importante dans les effluents miniers, particulièrement pour le Cu. Pour relier la spéciation des métaux et la toxicité chronique, nous avons mesuré en parallèle l?inhibition de croissance de l?algue Selenastrum capricornutum et des larves du poisson Pimephales promelas de même que l?inhibition de la reproduction du cladocère Ceriodaphnia dubia. (tests de toxicité chronique inclus dans le programme de suivi des effets environnementaux du règlement fédéral sur les effluents de mines de métaux). En absence de thiosels, aucune mortalité a été observée pour l?ensemble de ces tests et il n?y a pas eu également d?inhibition la croissance de la larve de poisson P. promelas. L?inhibition de la croissance de l?algue S. capricornutum, n?est pas reliée aux concentrations de métaux traces mais plutôt par aux concentrations de calcium. Les inhibitions de la reproduction du cladocère C. dubia sont reliées aux concentrations de métaux dissoutes et libres et non pas aux concentrations totales de métaux, démontrant l?importance des effets de la spéciation chimique sur la toxicité des métaux. Nos résultats indiquent que l?inhibition de la croissance de l?algue l?algue S. capricornutum est due aux concentrations élevées de calcium retrouvées dans les effluents miniers et que les concentrations totales de métaux ne peuvent être utilisées pour prédire la toxicité chronique vis à vis le cladocère C. dubia.

Nov 1, 2002

By L. C. Hsu, H. F. Jr. Bonham, M. O. Desilets, P. J. Lechler, J. G. Price, L. J. Garside

Abstract-Geochemical background levels have been established for unmineralized sedimentary rocks that are elsewhere the hosts of Carlin-type gold deposits in the Getchell Trend. The Paleozoic rocks in the Winnemucca Quadrangle consist predominantly of the lower Paleozoic siliceous and clastic sequences that were carried eastward along the Roberts Mountains thrust during the Late Devonian and Early Mississippian Antler Orogeny and the late Paleozoic Havallah and Pumpernickel sequences brought along the Golconda thrust eastward during early Mesozoic Sonoma Orogeny. Over 260 rock samples were collected from the Paleozoic sequences. Major and trace elements were determined by instrumental methods best suited for the specific elements. The general geochemical features of the Paleozoic sedimentary rocks are discussed in detail with reference to the data of average abundances of elements in sedimentary rocks. The background and threshold values of certain trace elements in sandstone, shale, and carbonate rock of one formation, as well as back- ground levels for the entire sequence were obtained. The characteristic geochemical features of the Paleozoic rocks in this area include: consistently high Ba and low Au contents (1.1 ppb, 1.5 ppb, 1.1 ppb Au for average sandstone, shale and carbonate, respectively); generally low contents of those elements which may be of environmental concern such as As, Cd, Hg and Pb. Plots of major and trace elements suggest that the majority of the Paleozoic clastic rocks are related to a passive- margin tectonic setting. Samples with gold values higher than threshold are considered to have been affected by hydrothermal alteration related to gold mineralization. Most of these samples generally also have higher values of Sb, Hg, V and/or As. These observations support the use of such elements as pathfinders for gold, although V has not been identified as such before. Ba is not effective for gold exploration in this area due to the generally high background value of Ba, even though it may be an important pathfinder elsewhere.

Jan 1, 1995

By Anne-Laure Bonnet

Les connaissances acquises au cours des dernières décennies sur les gîtes de métaux de base et précieux intensément métamorphisés (p. ex. Vokes, 1991; Cornell et al., 1992; Zaleski et Peterson, 1995) ont permis d?élaborer des guides d?exploration pour de tels gisements dans les terrains de haut-grade métamorphique (Spry et Scott, 1986; Rubin et al., 1993; Hand et al., 1994; Spry, 2000; Spry et al., 2000). Un transfert de ces connaissances à la cartographie des vastes terrains gneissiques non différentiés de la province de Grenville permet d?affiner l?approche cartographique nécessaire pour reconnaître les systèmes hydrothermaux métamorphisés en terrains vierges et peu diagnostiques puis d?en discriminer les divers halos d?altération (Corriveau et al.,1996, 1997, 1998, 2003; Williamson et al., ce volume). Cette approche prend en compte les « empreintes métamorphiques » observées sur le terrain, telles que les variations des assemblages minéralogiques, du mode et de la composition des minéraux métamorphiques, pour reconnaître des roches présentant une composition inhabituelle caractéristiques de protolites altérés par hydrothermalisme. Ces empreintes citées cidessus sont facilement reconnaissables dans les terrains de haut-grade où la recristallisation induit un grossissement des grains qui permet de déterminer la nature et le mode des minéraux dès les levés de terrain. Cette approche raffine la compréhension des terrains de haut-grade métamorphique et illustre que leur complexité (i.e. polyphasage de la déformation et du métamorphisme) n?est pas forcément une limite à leur exploration. Elle a donc été utilisée systématiquement lors des levés de terrain réalisés dans le cadre d?un projet de l?Initiative géoscientifique ciblée de RNCan. La zone cartographiée se situe le long de la marge sudest du Groupe de Wakeham dans le secteur est de la Province de Grenville. Deux régions ont été plus particulièrement étudiées, celle du lac Musquaro (SNRC 12K10, 11 et 14) et la région côtière comprise entre Kégashka, La Romaine et Baie des Loups (SNRC 12K1, 2, 3 et 7) (fig. 1).

May 1, 2003

By Michel Noël

Cet article présente une compilation partielle des mesures adoptées pour la fermeture des haldes de stériles pour des mines situées au Canada et en Alaska, et dont le climat comporte des hivers froids. L?article présente également le processus de sélection qui a été suivi pour certaines de ces mines. Les exploitations minières produisent habituellement des quantités de stériles qui peuvent être importantes. De plus, la nature du dépôt minier ainsi que la roche mère vont souvent entraîner des impacts sur l'environnement. Ces impacts doivent être gérés non seulement durant les opérations minières, mais souvent à très long terme après la cessation de l?exploitation minière. Les plans de fermeture de mine doivent par conséquent procurer des solutions à très long terme, voire même à perpétuité dans bien des cas. Le processus de sélection implique souvent l'évaluation des risques liés aux responsabilités environnementales et financières. Il doit considérer l?aspect scientifique, comporter une définition des objectifs, tout en incorporant une gestion des ressources et des plans de travail. La planification de fermeture est essentiellement un exercice de prise de décisions comportant des contraintes. Une matrice de classement basée sur la performance et le risque est souvent développée durant ce procédé pour identifier les options préférées. Les études de cas présentées dans cet article présentent quelques exemples. L?état des connaissances sur le drainage acide minier provenant des haldes de stériles a augmenté considérablement au cours des dernières décennies. Ceci n?a pas nécessairement augmenté le niveau de complexité des méthodes adoptées pour la fermeture. Une approche qui est fréquemment utilisée consiste à stabiliser les pentes des haldes de stériles en abaissant la pente des talus pour ensuite recouvrir les stériles d?une couche de sol pour soutenir la végétation. De telles couvertures empêchent les animaux d?avoir un contact direct avec les stériles, minimisent l'érosion et réduisent l'infiltration à divers degrés. L'inclusion d?un traitement des eaux dépend évidemment de la qualité de l'eau au point de déchargement.

Nov 1, 2008

By Richard Morland

The Ekati Safety Guarantee is a conversation that has been taking place at Ekati for the last two years. It is a challenging, confronting, inspiring conversation which encourages people to see and pursue the possibility of guaranteeing that nobody who works at Ekati will be seriously injured or killed at work. The conversation takes us out of the normal, incremental approach to safety improvement; it takes us out of the world of striving, of seeking, of trying, and allows us to stand in, and be a stand for the future possibility of Zero Harm. It requires an unreasonable stand for, and commitment to, our own safety and the safety of our colleagues. A Powerful Conversation The safety guarantee began with conversations between executive team members and has been propagated regularly through the line through management meetings, pre-shift meetings, during workplace inspections, job safety observations, job and project planning, orientation and induction sessions, and when opportunities present themselves. This is a conversation that continues outside of Ekati with family, with government, with community members. It is a stand for safety as a value. The conversation about the safety guarantee is now pervasive at Ekati and forms part of a framework of initiatives that have led to sustained improvement in safety performance. During the last two years, the recordable injury frequency at Ekati has dropped to its lowest level in Ekati?s history. At the same time, job safety observations have increased from 500 per month to 4000 per month, whilst the overall number of people at Ekati has reduced by 30%. It has led to new ways of thinking about the conduct of operations. It influenced the 2008 upgrade of the Ekati process plant, resulting in the development and implementation of a crane lift protocol that eliminated injuries during over 100 lifts in two weeks, in an area of difficult geometry and with multiple entrances. It created space to successfully conduct a challenging commissioning period for the process plant crusher, during which time the machine was disassembled and reassembled several times, without incident or injury. No production pressure was permitted to interfere with this work, in line with our stated aim that we wanted everyone involved to guarantee that they would not be seriously injured or killed?our people had the space to do the work at a pace, and in a way, that guaranteed this outcome.

May 1, 2010

By A. J. Basu

Air quality in underground mining operations can fluctuate significantly during the working day, but until recently the only way to ensure a mine had sufficient air quality was to over-ventilate and, with significant delay in adjusting the volume or direction of the airflow, working conditions were tolerable but rarely ideal. Underground ventilation management systems have been considered to achieve improved energy efficiency since at least 1995 in Canada. However, Mine Ventilation Optimization, (MVO) and integrating it with Ventilation on Demand (VOD) is only becoming more of a reality in the last seven (7) years. A systems approach to MVO takes into account all the elements from the point the power is distributed into the ventilation fans through to the actual quality and quantity of fresh air to the working face. Opportunities exist throughout the system for energy savings but not all of them are cost-effective. Depending on the application, these opportunities can be easily realized by properly sizing, streamlining, maintaining and operating the ventilation system using premium mine proven energy efficient components throughout. Implementation of VOD is a key step in achieving the MVO objective. However, VOD is a concept, and it requires various tools, procedures, and strategies for cost-effective and operationally viable implementations. This paper provides a historical background in the development of VOD and provides a framework for proper and cost effective implementation. In addition, an optimized ventilation system will also allow increased airflow by reducing resistances and shock losses. This turn in would allow production target improvement, which could be an attractive objective compared to energy savings. Mine ventilation is the life support system of an underground mine, and contributes to sustainable development and corporate social responsibility goals assuring health and safety aspects of strategic planning. The proposed framework addresses implementing mine ventilation optimization integrating ventilation on demand as a vehicle for energy, health and safety improvement and overall productivity gains in the mining cycle efficiency while significantly reducing carbon footprint of a mine.

Aug 1, 2013

By R. A. D. Pattrick, D. A. Polya, D. J. Marsh, J. -J. Bao

"The utility of high-density stream sediment and stream water sampling to the exploration for silver deposits was investigated by the study of the epithermal Ag-Au base-metal prospect at Lagalochan in western Scotland. The geology of Lagalochan is dominated by a calc-alkaline Caledonian intrusive complex emplaced into Dalradian Supergroup rocks (Harris et al., 1988a). The complex consists of subvolcanic porphyrytic rocks associated with intense hydrothermal alteration and brecciation. Early Cu-Ag-Mo-rich mineralization is found in the core of the complex with later Pb-Zn-Ag-Au-As-Sb-rich mineralization toward the margins (op. cit.).Stream sediment sample analysis spatially resolved the Cu-rich and Ag-rich mineralization. Ag and Cu anomalies relative to local background values were found in all size fractions analyzed (-125µm, +125 µm, +180 µm, +250 µm) but the more pronounced anomalies were found in the -125 µm fraction. The coarser fractions generally revealed more erratic but longer dispersion trails. The separation of Cu-rich and Ag-rich mineralization is also apparent in the distribution of relatively high dissolved Cu and Ag in stream waters, particular when expressed relative to the solute load as Cu/TDS and Ag/TDS.The mineralization at Lagalochan is indicated by Ag, Cu and Pb stream sediment and water concentrations that are anomalous with respect to local backgrounds, but are difficult to distinguish from regional backgrounds. This emphasizes the further potential of high-density stream water sampling,in particular, as a viable geochemical exploration tool on a sub-regional scale for epithermal depositsin relatively unpolluted upland terranes."

Jan 1, 1995

By Ana Adé

The use of gold compounds in homogeneous catalysed organic reactions has been undervalued for many years due to the preconceived opinion that gold is an expensive and extremely chemically inert metal. However, recent reports have changed this assessment and gold salts in small amounts are known to display high catalytic activity.[1] Thus, it has been reported recently that anhydrous AuCl3 catalyses the formation of C-C and C-O bonds (usually mediated by hydrochloric and other protonic and Lewis acids).[2] Some examples include Michael type additions, selective cross cycloisomerisation/dimerisation of propargyl or allenyl ketones, benzannulation between o-alkynylbenzaldehides and alkynes or cyclisation of alkenyl furans. It is noteworthy that some of these reactions[2a] can be also catalysed by silver salts but with much lower yields. The 1,3-dipolar cycloaddition of nitrones to alkenes is a powerful synthetic method that has found numerous applications in the synthesis of a variety of carbon frameworks.[3] Several laboratories have focused on the development of Lewis acidic reagents to modulate the selectivity of the reaction.[4] Despite the extensive study performed, there are not many examples in which a metallic complex catalyses the dipolar cycloaddition. Most of these reactions require the presence of a metallic complex and nitrone in a 1:1 molar ratio. Recently, we have carried out stoichiometric reactions of the N-benzil-C(2-pyridil)nitrone, 1, with different dipolarophiles in the presence of zinc and silver compounds.[5] Apart from an increase of the reaction rate and the selective formation of one of the possible isomers, we have shown the formation of zinc and silver-nitrone complexes during the reaction, which behave as the intermediates in the cycloaddition process. As suggested by the results obtained with silver complexes, we decided to test gold derivatives (in the oxidation states of I and III). Interestingly, we have found that they can be used not only as stoichiometric reagents but they can also mediate these cycloadditions in catalytic amounts (5 to 10 mol % respect to the nitrone). Here we present the results on the 1,3-dipolar cycloaddition reaction of the N-benzil-C(2-pyridil)nitrone (2-PyBN), 1, and methylacrilate, 2, (Eq. 1) catalysed by gold(III) derivatives.

Oct 1, 2003

By Jessica Hurst, Mark Holdsworth, Jeff McKay

"In 2002, Kennecott Utah Copper Copperton Concentrator installed an Expert Control system for optimization of their SAG and Ball milling circuits. The advanced process control has been well received and is utilized well over 95% of the time. In the years since, many lessons have been learned and many advances have been made. Improvements have produced millions of dollars of benefits and have included directly controlling feedrate with complex logic as opposed to using a bearing pressure controller, modifications to how sound is used for control, modifying logic for maximizing asset utilization and using advanced control for automating equipment restart. INTRODUCTIONRio Tinto’s Kennecott Copperton Concentrator produces copper, molybdenum, gold and silver. The mill has 4 SAG mills (SAG 1-3, 34 foot diameter and SAG 4 36 foot diameter), 8 ball mills and copper and molybdenum flotation plants, as seen in Figure 1. The 2010 average data is shown in Table 1.In 2002, a Metso Cisa OCS Expert Control system was installed at Copperton for SAG and Ball mill advanced control. The expert control was first placed on SAG 2; data from the first few weeks compared with operator performance indicated approximately an 11 percent increase in throughput. After full commissioning, the system was gradually refined further by plant personnel to develop key performance indices based on SAG feed size, refinement of the sound setpoint for control of mill speed and throughput, specific rules to help the adjustment of speed based on loss of a feeder, etc. With the addition of the pebble crushing circuit, the expert control began utilizing a model estimation of crushed pebble bin level to help stabilize the impact of returned crushed and uncrushed pebbles on the SAG mills. As the ore and limitations change, it is necessary to evolve the SAG logic to better handle any constraints."

Jan 1, 2012

By J. Koponen, K. S. Stadler, A. Fuerst, S. Gaulocher, Th. von Hoff, R. Veldsman

"Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO).A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components:1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user.2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer.3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD.In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples."

Jan 1, 2012

By Z. D. Hora

Several deposits of crystalline magnesite are known in southeast British Columbia. Deposits at Cross River and Marysville have been thoroughly explored, but as yet there has been no commercial production.

Jan 1, 1984

By T. Donkin, B. Patterson, M. I. Guthrie, J. T. Ross

"Interest in the use of particle-based ore sorting has increased significantly with recent advances in sorting technologies and higher capacities per unit. Particle-based ore sorting has the potential to provide great value in processing lower grade ores from mines while delivering higher grades to the mill, as well as in upgrading waste rock into ore. Typically the focus is on the amenability of the ore to ore sorting and associated reductions in energy, water, and consumables utilization. However, layout significantly affects the installed cost of a processing plant, and the impacts on layout from fitting an ore sorting circuit into the plant plan need to be carefully considered. This paper examines processing plant layout considerations that play an important role in ore sorting projects, including additional crushing and screening requirements, transport of rejected material back to the waste stockpile (mine fleet requirements), and effects on the processing plant footprint. ¦ KEYWORDS Cold climates, Ore sorting, Plant layout RÉSUMÉ L’intérêt porté à l’utilisation du tri granulométrique du minerai a considérablement augmenté au vu des récents progrès réalisés en matière de technologies de triage et des capacités supérieures par unité. Le tri granulométrique du minerai offre une plus-value intéressante en termes de traitement du minerai à plus faible teneur extrait des mines ; il permet par ailleurs l’acheminement vers le concentrateur de minerai à plus haute teneur et la revalorisation des stériles dans le minerai. On met généralement l’accent sur la susceptibilité du minerai au triage et sur les réductions connexes en termes d’utilisation de l’énergie, de l’eau et de biens consommables. Cependant, l’aménagement physique de l’équipement a une incidence non négligeable sur le coût installé d’une usine de concentration, et les répercussions sur l’aménagement de l’installation d’un circuit de triage du minerai dans l’usine doivent être soigneusement examinées. Cet article étudie les considérations relatives à l’aménagement de l’usine de traitement qui jouent un rôle important dans les projets de triage du minerai, et notamment les exigences supplémentaires en matière de concassage et de criblage, le transport de matériau résiduel jusqu’à la pile de stockage des déchets miniers (nombre de camions requis dans le parc minier) et les effets sur l’empreinte de l’usine de traitement. ¦ MOTS CLÉS aménagement de l’usine, climats froids, triage du mineraiINTRODUCTION Ore sorting has been practised throughout history. An early report by Agricola in 1556 documents how metallic and non-metallic minerals were extracted from rocks by laboriously breaking them with hammers and picks and hand-picking selected material with higher grade (Hoover & Hoover, 1950). The concept has not changed, but sorting technology has evolved significantly over the last 20 years"

Jan 1, 2019

By Lee Nichols

The Oil Sand Industry in northern Alberta, Canada, disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called Consolidated Tailings or Composite Tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities. Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are long-term stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface. The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process.

May 1, 2004