Search Documents

"As part of a series describing the nickel operations of Vale Canada (formerly known as Inco), this paper focuses on the 1973 to current operations of the Copper Cliff nickel refinery in Ontario, Canada. The process used there employs the formation of Ni tetracarbonyl at high CO (gas) pressure and its subsequent decomposition at somewhat elevated temperatures to produce highly pure Ni pellets and powders. Personal sampling of workplace aerosol dusts is reported, with information on specific Ni compounds in the aerosols.RÉSUMÉ Dans le cadre de la série d’articles décrivant les opérations de nickel chez Vale Canada (anciennement Inco), le présent article cible les opérations de 1973 à ce jour à l’affinerie de nickel de Copper Cliff en Ontario, Canada. Le procédé utilisé à cette usine est la formation de tétracarbonylnickel sous une pression élevée de CO (gaz) et sa décomposition subséquente à des températures plutôt élevées pour produire des granules et des poudres de Ni pur. Un échantillonnage par l’auteur des poussières en aérosol est présenté ainsi que de l’information sur les composés spécifiques de Ni dans les aérosols."

Jan 1, 2015

By A. Desbiens, M. Maldonado, R. del Villar, Aguilera. R.

This work details the application of a multiple model approach to estimate frother concentration in flotation processes. The methodology consists of identifying a set of linear dynamic models representing the effect of gas rate on the collection-zone gas holdup at different known frother concentrations (calibration step). An adaptive law is then obtained using Bayes' rule to evaluate the conditional probability that each model represents the observed system behavior. In this way, a frother concentration estimate is calculated as a weighted sum of model probabilities and their associated (known) frother concentrations. Experimental results conducted in a two-phase system using Dowfroth250C are promising. Modeling and analysis for MIBC frother are also provided.

Jan 1, 2009

By H De Beer

The 14MW SAG mill at Tarkwa, Ghana, experienced a frozen drop charge incident on 10 February 2010. This caused downtime of 112 hours, a repair cost of $200k and production loss of 162,000 tons, corresponding to a loss of $8.9M. A new locked charge protection system was installed on the two Tarkwa mills on 30 July 2010, mitigating this risk. This system calculates the ore angle in real time while the mill is starting up and trips the mill if the ore angle exceeds a trip angle setting. The calculation of the ore angle is derived from the mill motor rotor currents only - no mechanical transducers are required. The head of Gold Fields West Africa, Peter Turner, says of the new system: "This is excellent work and the type of technology that has had and will continue to have, major opportunity cost impacts on our business."

Nov 1, 2011

By I. P. Swainson, A. Ilbagi, H. Henein

Powders of Al-50wt%Ni, Al-40wt%Ni and Al-36wt%Ni were produced using the Impulse Atomization technique, a rapid solidification technique. The molten droplets were cooled in-flight by the stagnant helium or nitrogen in the atomizing chamber. The resulting powders were sieved into different size ranges. X-Ray diffraction and neutron diffraction were used in order to quantify the phase fractions in the samples. The computer software GSAS was used to calculate the weight fraction of the existing phases, namely Al3Ni2, Al3Ni and Al, by profile refinement method. The effect of processing parameters, alloy composition and particle size will be discussed in this paper. In brief, no AlNi was found in any of the samples analyzed. Higher cooling rates resulted in the reduction of the ratio of Al3Ni/Al3Ni2. Also, at high cooling rates, Scheil closely predicted the ratio of Al3Ni/Al3Ni2. Some metastable phases were found in Al- 36wt%Ni.

Jan 1, 2010

Particles for heap leaching in conventional circuits are prepared using Cone crushers. Cone crushers are used to crush the ore to the size range between 12-25 mm for heap leaching operations. Leaching from these relatively coarse particles occurs only at the surface and in subsurface regions, which are accessible from the surface by cracks and pores. Since leaching is active in accessible areas, the method of comminution that forms multiple cracks and pores would offer an advantage for heap leach. An investigation was performed in this study to assess if the HPGR forms more cracks and pores than a Cone crusher. X-ray computed tomography (CT) was used to characterize the degree of cracks and pores formed by these two comminution devices that can be used for heap leaching feed preparation. In order to compare the effect of the comminution method on crack network generation, a bulk sample of the zinc ore was crushed by the HPGR at three different pressure settings (45, 95 and 120 bar), the sample ore was also crushed with a Cone crusher for comparison purposes. Products from the Cone crusher and HPGR experiment were then screened into five size fractions ((-25 +19), (-19+16), (-16+9.5), (-9.5+5), (-5+4.75) mm), Subsamples from the ((-25 +19), (-16+9.5), (-5+4.75) mm) size fractions were analysed. The spatial distribution of the crack network of sphalerite particles was characterized using a highresolution industrial X-ray CT system. This paper describes the use of image analysis techniques including image segmentation, which uses a combination of thresholding and other methods to characterize and quantify crack and mineral dissemination in the sphalerite particles after comminution with the HPGR and Cone crusher. The results are validated with those obtained using traditional techniques such as physical gas (with N2) adsorption, mercury intrusion porosimetry, SEM and QEMSCAN.

Jan 1, 2012

The following briefing is intended to provide an overview of the present and future challenges associated with our access to a secure and adequate supply of electrical energy necessary to support safe, productive and sustainable mining initiatives at Musselwhite. Contents ??Site power demand vs. current available supply ??Supply technical deficiencies ?adequacy and security of present supply ??Present internal generation ??Anticipated future internal generation requirements ??Increased requirements necessary for planned expansion ?demand/security ??Goldcorp?s strategy to achieve required supply ?transmission line initiative ??Subsequent benefits to others from the Goldcorp initiative. ??Economic impact of MusselwhiteMine on the northwest region ??Anticipated economic impact of planned expansion ??Expected life cycle of MusselwhiteMine ??Comparative energy costs for similar operations in other jurisdictions ??Conclusions ??Anticipated action plan ??Energy Management Initiatives ??Site Orientation

May 1, 2009

By P. van Zyl, M. Lombaard

The 14MW SAG mill at Tarkwa, Ghana, experienced a frozen drop charge incident on 10 February 2010. This caused downtime of 112 hours, a repair cost of $200k and production loss of 162,000 tons, corresponding to a loss of $8.9M. A new locked charge protection system was installed on the two Tarkwa mills on 30 July 2010, mitigating this risk. This system calculates the ore angle in real time while the mill is starting up and trips the mill if the ore angle exceeds a trip angle setting. The calculation of the ore angle is derived from the mill motor rotor currents only - no mechanical transducers are required. The head of Gold Fields West Africa, Peter Turner, says of the new system: "This is excellent work and the type of technology that has had and will continue to have, major opportunity cost impacts on our business."

Jan 1, 2012

By Guillermo Diaz, Roberto Pérez, René del Villar

"Pulp-froth interface position is a key variable in column operation. In plant practice, it is commonly estimated through a system of three pressure-transducers which allows the calculation of the pulp height. An alternate method based on the measurement of the conductivity profile across the interface has been proposed and successfully tested. Both methods however, present some practical problems related to the assumptions made in the calculation of the pulp height in the former case, and to the response time and the precision of the reading in the latter case.In this paper, the use of the neural network technique for improving the estimation of the pulp-froth interface in flotation columns is discussed. The technique is used with both conductivity-based and three pressure-transducer methods. Results obtained in a 2"" laboratory column and a 12"" pilot scale column are presented. A major obstacle in applying this approach in practise is the training of the artificial neural network. This problem is analyzed here for the conductivity-based method and some solutions are proposed."

Jan 1, 1995

By I. I. Bethcherman

Introduction 1.-lmportance of Physical Nature of Condensates The metals of commercial interest which have reasonably high vapour pressures below 1,200° C. are mercury, cadmium, sodium, zinc, magnesium, lithium, and calcium. With the exception of mercury, these metals occupy high positions on the electrochemical series and form compounds with very high negative free-energies of formation. It is highly desirable that such metals should not be produced in a form which is finely divided, on account of their reactivity with atmospheric gases. Powders of magnesium, calcium, and even zinc (blue powder) are dangerous to handle and cannot be coalesced by simple melting techniques. Vaporization in vacuo forms a convenient method of handling and purifying the alkaline earth metals in particular and a previous paper by the authors dealt with some of the factors controlling the separation of metals by this technique (12). An essential part of the operation is the condensation of the vapour to produce a massive deposit which may be conveniently melted and handled by established metallurgical techniques. This investigation sought to determine the conditions affecting the nature of solid condensates.

Jan 1, 1951

By Jianhong Xu, Hailong Hou, Yu Jing, Yundong Wang

Microcapsules containing extractants have been applied to the extraction of metal ions, organic acid, pesticide, and herbicide. The difficulties of conventional liquid-liquid extraction in phase mixing and phase separation (e.g. high energy consumption, emulsification phenomenon, and large equipment requiring housing) could be overcome in a liquid-solid system by using microcapsules. Even some extractants with high viscosity and poison can be encapsulated conveniently into microcapsules. In the work described in this paper, polysulfone microcapsules containing 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (P507) were successfully prepared. Then, the extraction rate of lanthanum, samarium, and erbium in dilute solution into the microcapsules containing P507 was studied. An extraction kinetic model is proposed based on the interfacial reaction model accompanied by intraparticle diffusion expressed by Fick’s law. The extraction efficiency was obtained by using the kinetic model with the separately determined complex formation rate constant and the intraparticle diffusion coefficient. From the results, it was confirmed that the kinetic model could predict the experiment in a microcapsule system over a wide concentration range of lanthanide solution. In the future, the model could provide good guidance for the design and application in extraction of lanthanides.

Jan 1, 2014

By Nigel Saunders, Zhanli Guo

"Quench sensitivity of heat-treatable aluminium alloys is closely related to the precipitation process taking place during quenching. Faster cooling results in less precipitation of coarse phases during cooling, leaving more solutes in the solution before ageing. An alloy in such state would be of greater hardening potential as larger amounts of hardening phases may precipitate out during ageing. Hence, to understand the quench sensitivity of an alloy, it is essential to understand its precipitation process. Precipitation is a diffusion-controlled process and the diffusion is made complicated by the so-called quenched-in vacancies. These vacancies form during solution treatment, become “excess” when temperature goes down, and annihilate during the following cooling and ageing treatments, making diffusion now a function of both temperature and time. This paper first investigates the formation and annihilation of quenched-in vacancies and their effect on diffusion. The diffusion affected by quenched-in vacancies is considered in the kinetic models to realise the calculation of TTT/CCT diagrams for aluminium alloys. The calculated CCT diagrams have been used to explain the observed quench sensitivity and age hardening behaviour of various commercial alloys. The transformation from GP zones to other hardening phases during ageing is also discussed.INTRODUCTION The heat treatment of aluminium alloys mainly consists of three stages: a solution treatment at an elevated temperature, quenching from this solution treatment temperature to room temperature, followed by an ageing treatment to allow the precipitation of strengthening phases(Davis, 1993).The following statements generally describes how quench sensitivity is observed in heat-treatable Al-alloys: faster cooling results in,(i) less precipitation of coarse phases formed at high temperature during cooling, (ii) more solutes kept in solution before ageing, and (iii) larger amounts of hardening phases being formed, i.e. a greater hardening potential. Thus, the quench sensitivity of an alloy is closely related to its precipitation kinetics."

Jan 1, 2018

By Dirk Claessens

The term ?cost? is too small when describing the destructive power of safety incidents for mining companies. Breaches in employee or environmental safety are felt way beyond the bottom-line: human life can be taken; ecosystems tarnished; the ire of peoples, media and government inflamed; significant halting of production; and high levels of legal and financial challenges. According to a recent survey of Mining executivesi, ?ensuring workforce safety? was the most important issues identified above any other, with a plurality of 31 percent, reigning above capital projects, product efficiency, and equipment reliability. We accept that safety is a most paramount issue, yet for many reasons we keep approaching the problem the same way we have in the past. We need to stop doing the same things decade over decade and try something new. New innovations are significantly changing the fundamentals of how mining companies explore, excavate, produce, refine and distribute their valuable commodities. Technologies such as visualization, analytics, location awareness, and gaming simulation are making these enterprises smarter. Now, attention turns to an area we?ve long held as integral to our business: safety. By using the same breakthrough technologies that are changing our business, we can now boldly imagine ? and credibly strive for ? a world of zero incidents.

Aug 1, 2013

By M. Leijd, K. S. Forrester, M. Saxon, M. Oczlon

This paper provides an introduction to wet high intensity magnetic separation (WHIMS) and its successful application to the beneficiation of rare earth element (REE) enriched eudialyte. The analysis includes an in-depth reporting of the deportment of key elements as well as a statistical interpretation of the relative importance of operational parameters including magnetic field intensity, flow velocity, and matrix loading density. Conclusions are drawn on the relative success of the technology, potential areas for process improvement, and the research direction that continues to be investigated. Three original equipment manufacturer (OEM) technologies were subjected to a series of screening and characterization tests to identify the optimal operating parameter set to magnetically beneficiate eudialyte from Norra Kärr, Sweden. Upon the completion of the characterization test it was apparent that the Metso HGMS technology was superior with respect to REE recovery and gangue rejection for the Norra Kärr composite. The Metso HGMS was then subjected to a series of verification tests to confirm the repeatability and reproducibility of the system.

Jan 1, 2014

By Chris J. Pritchard

Pumpable, two-component resins for anchoring rock bolts provides significant advantages over traditional cartridge resin and cement grout systems where fast and easily adaptable support is required for difficult ground conditions. Cartridge resin anchoring with rock bolts is often ineffective in oversized, fractured and washed-out holes. Cement grouting of cable bolts is frequently plagued with QA and QC issues related to the grouting process. Installation of cable bolts with resin injection techniques is routinely completed in cycle allowing blasting immediately after cable bolting. Xstrata Nickel has evaluated the Minova Resin Injection System since 2007. The Nickel Rim Mine and partner Minova have tested and validated the Resin Injection process for bolting procedures including Hollow Fiberglass Bolts, Rebar, Modified Cone Bolts and Cable Bolts. The resin injection process is adaptable to most bolting processes and equipment. Currently, Nickel Rim Mine use 2 resin injection products with different set times to grout deep cable bolts and development support in highly variable ground conditions. The product predictability and adaptability in application along with a high crew acceptance continues to make this support process part of an adaptable ground support system. Product consistency and quality significantly reduce the quality control concerns for ground support in highly variable ground conditions.

May 1, 2011

By Jaroslaw W. Drelich

Despite the success of DLVO and extended-DLVO models that have been developed for homogeneous and smooth surfaces, a vast majority of practical surfaces encountered in mineral ore beneficiation are typically rough at various scales; they are also typically heterogeneous. The interactions of gas bubbles with particles having rough and heterogeneous surfaces are much more complex than the commonly used DLVO or extended-DLVO models predict. The effects of surface roughness on flotation and colloidal interactions have been reported many times in the past, although a clear understanding of their origins has been lacking. To explain differences in colloidal interactions for spherical hydrophobic particles, a theoretical analysis of the interaction potential was carried out for a model rough particle interacting with a bubble surface in an electrolyte solution in this study. The attractive hydrophobic interaction potential was added to repulsive retarded van der Waals and repulsive electrical double layer interaction potentials. The rough microscopic particles were modeled as spheres decorated with nano-sized asperities. Parameters that reflect common flotation separation systems were selected for testing this theoretical model and computation of the energy barrier applicable to particle – flat bubble surface interactions. It was found that hydrophobic asperities with the height of only several nanometers can reduce the repulsive interaction energy by an order of magnitude. Theoretical analysis also reveals that surface coverage of microscopic particles by nano-sized asperities is important as well. The findings of this research suggest that manipulating and engineering the particle surface topography could lead to better control over flotation separation.

Jan 1, 2016

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

By B. D. Thompson

Many mines adopt necessarily conservative backfilling strategies due to a lack of understanding of their backfill behaviour. In the past five years, extensive instrumentation campaigns have focused on measuring in-situ cemented paste backfill behaviour. These tests have resulted in optimised backfilling efficiency through elimination or reduction of cure periods where; i) controls on backfill behaviour are understood, and ii) barricade pressures are demonstrated to be within a safe range using routine monitoring as a required QA/QC procedure. Recently, this work has been extended to consider hydraulic backfill operations. Two stopes have been instrumented at Vale?s Coleman and Garson Ramp mines. The instrumentation and deployment methods are discussed, and representative total earth pressure, pore pressure, and temperature data are presented. In one case, pressures in the stope are relatively low as drainage causes strength gain in the fill and so pressures are arched. In a second example, again, drainage causes strength gain in the fill, but increasing temperatures correlate with pressure increases even during downtimes in filling. These pressure increases are thought to be caused by thermal expansion of the backfill in confined locations. Generally, the instrumentation approach has proven successful in measuring hydraulic backfill behaviour and offers good potential for incorporation into a procedure to safely maximise backfilling efficiency through routine barricade pressure monitoring, when combined with safeguards to ensure adequate fill drainage.

Aug 1, 2013

By V. K. Srivastava1

Coal mine fires burn about 20?21 million tons of coal per year throughout the world, which not only results in loss of valuable coal reserves, but also cause serious environmental hazards over large areas. The famous Jharia Coalfield of Dhanbad, India is no exception; here a coal mine fire originally reported nearly a century ago is still continuing unabated in vast areas of the coalfield. In this paper, an attempt has been made to analyse high resolution multispectral thermal images of ASTER for mapping and delineating surface and subsurface coal mine fire areas of this coalfield. From the generated temperature gradient map, as well as from the surface temperature anomaly map, it has been possible to differentiate shallow and deep coal mine fire regions and other erroneous cultural features. It is observed that the coal fires are distributed mostly in the eastern part of the area, which has branched into two major coal fire zones: one along Lodna- Tisra-Bhulanbarari-Kujama-Jealgora Jharia and the other along the Kusunda-Kendudih area. The western fire zone is restricted in Dumra-Nadkhurkee-Jayramdih area. From ASTER thermal infrared data from 2006, the total affected area is estimated to be about 7 km2, of which the deep subsurface coal mine fire area is around 3 km2 and the shallow surface coal mine fire area is around 4 km2, as compared to 18 km2 coal mine fire area estimated in 1987 using Landsat TM thermal band data. In other words, the fireaffected region has decreased by about 50 % during the last 18 years. However, such decrease in coal fire area is seen in the central portion only, and has in fact increased in the south eastern parts of the Jharia coalfield. Study of Differential Interferometery images, generated from Earth Resources Satellite (ERS) synthetic aperture radar (SAR) tandem data has shown that the active coal mine fires are in general associated with low topography/subsidence areas.

Aug 1, 2013

By F. Logsch, H. Pempel, J. Markowski, P. Ay

"Due to the European Directive 2000/53/EC on end-of-life-vehicles, from 2015 on more than 95% of car materials have to be recycled. In order to recycle the materials back into the economic cycle, it is necessary to produce products with high quality and purity.Plastic components in cars, which are coated with metals by vapour deposition or electroplating, have a wide circulation (e.g., as cladding panel or trim strip for interiors and exteriors). In the end-of-lifevehicle recycling process, these plastic-metal composites are not considered in usual technologies (car shredder) and are not separated from Automotive Shredder Residue. These parts can be separated by optical or HF-detection sorting and then introduced to a specific treatment.Experiments with a specially developed bioleaching configuration showed that the thin coatings, which consist mainly of copper, nickel and chromium, can be removed efficiently from the polymer base materials by a bioleaching solution with Acidothiobacillus ferrooxidans as a leaching agent. The solution used was produced in special fermenters with a 9K-nutrient salt media. During the bioleaching process at 35°C maximum temperature, most of the copper is dissolved and the other metals accumulate as metal sludge. The bacterial cultures based on A. ferrooxidans are robust and resilient.After a 48-hour bioleaching period while the composites were stirred regularly with ventilation, the plastic particles were completely free from metallic coatings. The metal components are separated for further use: undissolved components (mainly Ni and Cr) are separated by decantation of the solution; dissolved copper recovey is carried out by cementation of copper. The cementated solid contains ~98% Cu, along with small amounts of other metals.With the bioleaching process, good separation and re-utilization of the metallic coatings is possible. The cleaned plastic parts were prepared by compounding for new applications with injectionmoulding."

Jan 1, 2016

By F. H. Samuel, P. Burke, F. Mucciardi, J. Gruzleski, S. A. Musmar

A new thermal analysis technique has been developed and tested. It utilizes the enhancement in heat transfer characteristics associated with a recent advancement in heat pipe technology. Heat is extracted from a liquid sample of a melt taken in-situ within a vessel or furnace. The rate of heat extraction is such as to cause the sample to solidify. The technique was tested in both laboratory scale and industrial scale (Grenville Castings, Perth, Ontario). A 356 Al Alloy, subjected to various melt treatments was used to perform the tests. Classical thermal analysis was also performed simultaneously using a preheated graphite cup and at the same melt conditions. The comparison showed the potential of the new technique over classical thermal analysis. The major advantages of the new method are that it conducts the analysis inside the melt (i.e. a physical sample is not removed from the melt), it consumes less time and the cooling rate can be precisely controlled during the solidification process. Moreover, the resolution of the results is better than that of conventional techniques. Aluminium

Jan 1, 2006