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By A. Roca, V. A. Quezada, O. A. Benavente, M. Cruells

The leaching pretreatment of copper ores is widely used in the Chilean mining industry. Agglomeration and acid curing have been identified as the most useful pretreatments. Of these, acid curing was recognized as beneficial in the dissolution of copper minerals, even in sulphides such as chalcopyrite. Extensive acid curing times have an impact on copper extraction, generate a homogeneous acid distribution in the mineral bed and benefit the inhibition of aluminum-silicate minerals (acid consumers). This document describes some of the theoretical background and results regarding the effect of acid curing in a chalcopyrite sample with 74% purity according to Qemscan analysis and a 28.5% of total copper. Leaching tests are carried out at 25, 50 and 70°C, evaluating the effect of a pretreatment on the chalcopyrite dissolution. The original sample and products generated were characterized by X-ray diffraction analysis and Scanning Electron Microscopy (SEM). The performed experiments indicate a direct relation between the effect of curing time and temperature in copper extraction. 92% of copper can be extracted in a leaching at 70°C and with 15 days of curing. Elemental sulfur, jarosite and copper polysulfide (CuS2) have been detected in leaching products. INTRODUCTION The copper extraction from minerals is a technique that has been developed for hundreds of years in the world. In 2017, the largest copper producer was Chile, exported 5.5 million tons (COCHILCO, 2018). However, in order to preserve this production level means overcoming multiple challenges. In the case of the Chilean copper deposits, the average copper grade in 2016 was 0.65%, lower than the 1% declared in 2004 (Consejo Minero, 2018). This is mainly due to the deeper of the deposits reaching sulfide mineral zones, mainly chalcopyrite. Traditionally, these sulfurized zones ore are treated through concentration by flotation and subsequent pyrometallurgical treatments. However, for some copper companies it is complex to process by this alternative, due to the high costs and high rates of water consumption. The mineral resources of these companies are known as "low-grade sulfides" and do not allow, economically, the treatment of these minerals through concentration by flotation. This is how hydrometallurgy becomes an alternative for the treatment of this type of deposits. In addition, several companies have hydrometallurgical plants, which would allow the operational continuity of these plants.

Jan 1, 2019

By James Ransford Dankwah

High sulphur carbonaceous materials like petroleum coke and rubber tyre are unsuitable as reductants in ironmaking because part of the sulphur is transferred to the reduced metal. Globally, while large amounts of petroleum coke are produced annually from the industrial processing of crude oil, billions of end-of-life rubber tyres are held in landfills and stockpiles. This work therefore investigates the potential feasibility of utilising these high sulphur carbonaceous materials as reductants in ironmaking without transferring the sulphur into the reduced metal. Composite pellets of iron oxide containing end-of-life rubber tyre (RT), petroleum coke and blends of RT/petroleum coke and petroleum coke/high density polyethylene (HDPE) were heated under argon atmosphere in a horizontal tube furnace. Reduced pellets were analysed after 10 minutes of reduction for their sulphur content. The results showed that sulphur-free metallic iron can be successfully synthesized using RT and petroleum coke as reductants. The level of desulphurisation depends on the nature of blending of the carbonaceous materials.

Jan 1, 2014

By Charles Tkaczuk

Key issues ? No business tool has greater potential to effect change and enhance profitability than process control. ? Successful businesses see process control as an integrated engineered system, designed and built into their business models from day one. ? The integration and use of process control sets the stage for years of compounded returns. ? Has been used for years to optimizing recoveries and minimizing waste. ? However, the mining/ore extraction sector has been slow to adopt integrated process control. What is the problem? ? Most executives and engineers do not clearly understand process control when applied to mining/extraction activities. ? Common approach has been to apply generic process control strategies as a blanket cure all and wait for it to pay off. ? No central focus which results in multiple group involvement, overlap and inconsistent application of questionable technology. ? Considered a low priority until production activities commence. ? Comfort in using brute force mining methods. ? An off-the-shelf integrated under ground mining process control architecture has not until recently been available.

May 1, 2004

By K. Thuro, H. Käsling, C. Wieser, G. Nuijten

"The time-dependent behavior of brittle rocks during stress relaxation is of great interest for mining industry, nuclear waste disposal as well as tunneling and underground construction. Several studies have shown that both elastic as well as inelastic deformation occur during stress relaxation (Emery, 1964; Zang & Berckhemer, 1989). While elastic strain occurs already during the drilling process, inelastic deformation is time-dependent and can endure for hours, days or weeks. To investigate the evolution of microcracks during core relaxation, two crystalline core samples were recovered from high in situ stress conditions in Europe’s deepest mine in Pyhäsalmi (Finland). Samples were prepared for testing within one hour after coring such that a large portion of the time-dependent component of relaxation could be recorded over several days using ultrasonic velocity as well as acoustic emission (AE) measurements.Results from AE analysis show an exponential decrease in the number of events over a period of several hours. Repeated sudden increases of acoustic events can be related to the propagation or the interaction of cracks. In the first hours of recording also the signal energies reached the highest values and the increases in signal energy correlate well with increased event rates. On additional drill cores, P-wave velocities were measured parallel and in 45° distances perpendicular to the core axis. After core recovery, stress-induced microcracking caused an exponential decrease in wave velocities similar to AE rates. Lowest compressional wave velocities were measured parallel to the core axis and thus normal to the foliation and in the direction of the maximum in situ stress component. The highest measured velocities occurred parallel to the foliation plane. Within the samples, the anisotropy ratios were up to 1.37 at the beginning of the measurements and increased to values of up to 1.8 after 45 days. The wave velocity anisotropy is in agreement with the in situ stress orientations."

Jan 1, 2015

By J. Smit, F. Parada, R. Parra, E. Balladares, M. P. Merino

"In this study, a two-step process was developed for recovering copper, molybdenum, zinc and iron (hematite). In the first step, grinded slags (-65 mesh) were sulphated with SO3 at 350-500ºC to form iron, copper and zinc sulphates. In the next step, the formed sulphates were decomposed to hematite, copper and zinc sulphates and oxysulphates at 700-750ºC. The generated SO3 was recirculated back to the sulphation step. The generated calcine in the decomposition step is leached with 25 gpl acid at 50ºC to dissolve the copper, zinc and molybdenum for further conventional separation and recovery. The hematite residue, of intense red color, can be used as pigment, in the ceramic industry or as pellet feed. The fine crystalline silica remains in the hematite residue."

Jan 1, 2014

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014

By D. Shishin

Continuous integrated experimental and thermodynamic modelling work is conducted in Pyrometallurgy Innovation Center (PYROSEARCH). The target is to develop a tool, which is capable to predict the compositions of phases, phase equilibria and enthalpy balance for pyrometallugical processes with higher accuracy. All these can be achieved by thermodynamic calculations based on Gibbs energy minimization algorithm. Recent developments made it possible to predict important factors, such as the chemical solubility of Cu in slag as a function of matte grade, temperature, P(SO2), Fe/SiO2 ratio in slag, wt% Al2O3, CaO and MgO in slag. In industrial practice, it is not only chemical solubility, but the overall amount of slag, which affects the recovery of copper and other valuable metals. It will also impact the energy balance. The presence of solids in the slag matrix influences the physical entrainment of matte in slag. Oxygen enrichment which is sometimes used to control the temperature of the furnace, may also affect the volatilization of minor elements into the gas phase. Same is true if additional fuel is used to compensate for heat balance. In other words, all key process parameters mentioned above are interrelated. Present study demonstrates the ways thermodynamic modelling can be used to link those process parameters on the example of copper smelting. INTRODUCTION Research methodology involving integrated thermodynamic modelling and experimental approach has been recently reported by the authors (Shishin, Hayes, & Jak, 2018 Shishin, Hidayat, Jak, Decterov, & Belov, 2016). Present paper reviews the updates and discusses challenges in the development of a large self- consistent thermodynamic database. The database covers the Al-Ca-Cu-Fe-Mg-O-Pb-S-Si-Zn-(Ag, As, Au, Bi, Ni, Sb, Sn) chemical system. The database works in the environment of FactSage software Bale et al., 2016 and related family of products: ChemApp (Petersen & Hack, 2007), ChemSheet and SimuSage. A list of phases, and thermodynamic models is shown in Table 1. For the copper industry, most important phases are Gas, Slag, Spinel and Liquid matte/metal/speiss. Black-colored elements represent the base system, elements in green can be considered as slag modifiers (slagging elements), and elements in red are minor. Ni is highlighted because it was included recently, in 2019, and currently under development. In addition to copper, the database covers the conditions typical for lead and zinc pyrometallurgical extraction. It is developed in consistency with the experimental results for high concentrations of Pb and Zn. Examples of applications in the present study include the thermodynamic analysis of fluxing for an agitated copper reactor to show the effect of Fe/SiO2, and calculations of copper slag cleaning using reductant.

Jan 1, 2019

By S. Kaushik

The control room in a mineral processing plant has become increasingly complicated with complex unit operations coupled with rapidly evolving systems of sensors and control. Even with significant automation, human intervention is required to counter various scenarios that play out every day. A typical control room operator must monitor over 300 individual points of data in order to ensure the safe and efficient operation of the plant. At the same time, the experience of the workforce is decreasing as operators retire and the new generation enters the concentrators. Global competition for skilled operators continues to be strong and the opportunity to apprentice has diminished. The challenge is to provide a skill foundation for the operators so that they can be effective in the concentrator in a timely and safe manner. Progressively, the industry is turning to dynamic simulation tied into the control system. The simulator environment operates behind the control system to emulate the plant operation, reacting as the plant would when a change is made. The operator drives the process, with realistic feedback, which enables learning in a safe environment. This paper will take the reader through a green-field case study and discuss the effectiveness of integrating an operator training simulator (OTS) on the operator’s learning curve.

Jan 1, 2014

By E. R. Rivenbark

"The coal handling plant represents an investment of about $100 million in coal handling and storage equipment. The coal receiving is done by a continuous ship unloader that can handle ships in the 60 000 T range at Q rate of 1750 /ph. A unique feature in the system is a stacker/reclaimer unit which will work inside a dome storage structure. The coal for the unit will include any low sulphur coal that can be delivered by sea at an economical price blended with New Brunswick high sulphur coal.ThE flue gas scrubber is a wet limestone system capable of 95% SO2 removal. The scrubber will utilize about 150 000 tonnes of limestone per year and will produce commercial grade gypsum by the forced oxidization method.IntroductionWith the need for new generating capacity being required, New Brunswick Power reviewed, in 1985, its options for the next unit. The study indicated that the most attractive option for New Brunswick Power would be a coal-fired unit capable of receiving imported coal at a sea port. The site selection process resulted in three site options being considered.The existing Coleson Cove and Dalhousie sites, and the Belledune site were considered. To meet load distribution needs, it was then decided that the unit had to be located in the northern section of the province, thus eliminating the Coleson Cove site. The Belledune site was selected because it had the capacity to have additional units added where as the Dalhousie site would have only been able to accommodate one unit"

Jan 1, 1994

By John Campbell, William Trahant

"Total Quality Management (TQM) is becoming a reality in the mining industry. Widely adopted in the manufacturing and services industries, TQM has become the operating style of choice in numerous mining companies across the Americas and Australia. Iron Ore Company of Canada, Inco, MSA, Graniterock, Magma Copper, and CRA's Hamersly Iron - all are pioneers of TQM. These companies and others are confronting the challenges of implementing TQM and are managing the changes required of their people and cultures. What these companies are doing, why they are doing it, and how they are successfully managing the changes are the subjects of this paper.Driving the need for change in these organizations are a host of issues, some of which all mining companies are facing. Requirements from customers for ISO 9000 certification is becoming one of the initial motivators for Total Quality Management. These standards, commonly used in manufacturing throughout the European Community (EC), emphasize quality in the processes that create outputs, instead of just the outputs themselves. Iron Ore Company of Canada, for instance, responding to the requirement of one of its customers, British Steel, has become one of the first mining companies to meet the quality standard. Suppliers who meet the standards are highly desirable to customers who are themselves operating under the ISO or their national quality guidelines."

Jan 1, 1995

"High Pressure Grinding Roll (“HPGR”) technology is applied in a broadening range of minerals processing applications for relatively wet or moist materials. HPGR grinding of dry material or involving drying and air classification is more common, for example in cement manufacturing. A number of minerals processing plants are also operating with dry material, either due to process reasons, such as considerations of preceding or subsequent process stages, or as dictated by local conditions of arid areas and scarcity of water. The present world-wide expectation of decreasing availability of water supply urges us to look for alternatives that minimize water consumption.Recently established and envisaged future HPGR applications with dry ores have indicated that the technology of dry crushing and classification as practiced in cement and limestone grinding can be applied in minerals processing. Moreover, dry technology could very well be applied for generating a final fine product at sizes near or below 100 microns, as may be required for beneficiation by, for instance, flotation, magnetic separation or tank leaching.Dry HPGR grinding requires special attention in maintaining suitable process economics, when considering power input in grinding, drying and classification. In some cases, HPGR capacity and roll surface wear life may be negatively affected by a lack of moisture in the feed.This publication summarizes some of the features of, and experiences in dry HPGR applications. This includes design aspects of the classification system and discussion of the wear protection of the roll surfaces. The paper also includes examples of operational experiences of dry practices in minerals processing and cement plants."

Jan 1, 2012

By M. Leroux, S. R. Rao, J. Kim, J. A. Finch

"Continuous in-plant testing of collectorless Cu/Pb bulk flotation on Lyon Lake ore at Matlabi Mines Ltd. Was conducted using a portable circuit based on 5 L mini flotation cells. It is concluded that collectorless Cu/Pb flotation is a reliable phenomenon for this ore over the usual range of plant operating conditions.IntroductionFlotation of some sulphide minerals without the use of conventional collectors (e.g. xanthates) is now widely recognized. The requirement appears to be some degree of oxidation, although the nature of the surface product formed is still uncertain (Luttrell and Yoon, 1984; Buckley and Walker, 1988). The phenomenon has been termed ""collectorless"" or ""self-induced"" flotation. One of the minerals most responsive to coUectorless flotation is chalcopyrite; in contrast pyrite and sphalerite show little response and galena usually shows intermediate response (Hayes et al., 1987; Shannon and Trahar, 1986).Most of the work on collector1ess l1otation has involved single mineral or batch flotation on ore samples. There are only occasional references to collector1ess l1otation under plant conditions (Sandstrom and Jonsson, 1988; Vargas, 1990; Boyce et al., 1970). Creating and maintaining the appropriate oxidation conditions and differences in water quality are among the reasons why the phenomenon may not transfer readily to the plant (Grano et al., 1990). Periodically from the spring of 1989, Mattabi Mines Ltd. ran full-scale tests of collector1ess bulk CulPb flotation while treating Lyon Lake ore*: the observations confirmed the laboratory finding that chalcopyrite and galena floated without collector (Leroux et al., 1989).To explore this finding continuous in-plant testing using mini flotation cells was conducted which is the subject of this paper. The main objective was to determine if collectorless flotation was a reliable phenomenon over the expected range of redox conditions in the feed pulp to bulk CulPb roughing. As background, the previous work (Leroux et al., 1989; Martin, 1988) is briefly reviewed."

Jan 1, 1994

By C. D. Smith

Numerous studies have shown the potential of air rate profiling to significantly improve the flotation performance of a bank of cells. To date many profiles have been implemented; balanced, increasing, decreasing and combinations of these. Previous work has typically shown using an increasing air rate profile, where the air rates are increased proportionally to each cell down the bank, yields a higher grade for a given recovery compared to other profiles. Air rate profiling can then be thought of as having two distinct components; determining the correct distribution of a given volume of air and, perhaps more importantly determining the correct total volume of air to add to the bank. To date no method for this second component has been established. In an alternative technique the air rate to each cell is adjusted in order to optimise the air recovery from that cell. Air recovery is the fraction of the inlet air which overflows the weir of a cell as unburst bubbles. The peak in air recovery (PAR) is a robust measurement that indicates optimal performance for the operating conditions in the cell, and sets the PAR air rate. By doing this for each cell in the bank, the optimal total air rate to the bank and the optimal distribution of that air can be simultaneously determined. In this study plant trials evaluated different air rate profiles, and profiling based on PAR. The total air rates to the bank for all profiles tested were approximately equal, allowing direct comparison. The results showed that the highest cumulative mineral recovery was achieved by operating at air rates which gave the PAR for each cell down the bank. Different distributions of the same total air rate to the bank gave the same cumulative upgrade ratio, but lower cumulative recoveries. In this study, the increase in cumulative mineral recovery, at the same upgrade ratio, was more than 33%. Peak in air recovery (PAR) based optimisation of air rates to banks of cells and to the individual cells has been shown to significantly improve flotation performance as it simultaneously determines the optimal air rate to the bank, and the optimal distribution of that air.

Jan 1, 2009

By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By M. S. Moats, F. Elnathan

"The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.INTRODUCTIONCatalytic titanium anodes (CTAs) were developed in the 1960’s to replace graphite anodes in chlor-alkali cells. CTAs exhibited much better dimensional stability than graphite leading to lower operating potentials by promoting smaller electrode gaps and better operational efficiencies as they had to be replaced less often. CTAs are simply Ti substrates coated with precious metal oxides (such as IrO2 and RuO2) mixed with other components (such as TiO2 and TasO5) (Trasatti, 2000).CTAs are used in many other electrochemical industries, including water disinfection, wastewater treatment, cathodic protection and metal plating. RuO2 based coatings are typically used for chlorine evolution. IrO2 based coatings are for the most part utilized for oxygen evolution (Comninellis & Nerini, 1991; Forti, Olive, & De Andrade, 2001; Kotz, Stucki & Carcer, 1991; Trasatti & Lodi, 1981)"

Jan 1, 2016

By J. I. Jr. Moore

Many articles have been written about the various operations of Britannia mines and mill, as well as treatises on the geology and ore deposits. A partial list of these papers is given below. Most of these papers have covered well the history of Britannia, and have included a thorough discussion of the geology and ore deposits; therefore, in this paper, no account of these subjects. is necessary. However, a short description of the ore deposits will be given as an aid to a clear understanding of the descriptions of the various mining methods. The Ore Deposits The ore deposits at Britannia occur along a shear zone and are five in number, named for the claims in which they lie, as follows: Jane, Bluff, Fairview, Empress, and Victoria. Each of these deposits is called a mine, as they are separated by 500 to 1,000 feet of barren ground. The Jane mine, although the first producer of the Britannia group, has not been in operation for a number of years. The deposit is a silicified replacement in sediments; with very little evidence of shearing. The Bluff deposit is a highly silicified replacement in porphyry, massive and irregular, very hard in the upper 600 feet with practically no shearing, and softer within chlorite schist in its lower 1,000 feet . The Fairview deposit consists of a series of twelve distinct veins or lodes, rather lenticular in shape, and occasionally merging.

Jan 1, 1928

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By Patrick Andrieux

Cet article décrit une nouvelle méthodologie qui quantifie les chances de succès d’un sautage confiné à grande échelle de relaxation des contraintes dans un pilier de mine souterraine, pour un massif rocheux et un régime de contraintes donnés. La méthode est basée sur un nouveau paramètre nommé « Indice de relâchement », qui considère huit paramètres géomécaniques et de forage-sautage qui contrôlent ultimement le procédé. La rétro-analyse d’études de cas bien documentées a démontré que l’approche peut indiquer de manière fiable si une situation donnée de hautes contraintes de terrain est susceptible d’être améliorée par un tir de relâchement confiné à grande échelle et si le design proposé est adéquat pour atteindre ce but.

Jan 1, 2009

By Jürgen Antrekowitsch, Gerardo R. F. Alvear Flores, Mehmet Ayhan, Christoph Zschiesche

Synergies between copper and lead extractive metallurgical processes enable the processing of a broad range of polymetallic materials. However, this complexity also brings some challenges expressed in terms of complex intermediates and final products. For instance, based on the limited solubility of Cu and Ni in crude lead bullion additional phases will appear during the crystallization of the melt. Beyond the need for continuous optimization of metallurgy the control of phase solidification is a further important pillar to achieve a more efficient process by minimizing the amount and cycles of reverts. This paper describes the microscopy study of one of the most relevant intermediate in the Cu and Pb metallurgy, the Cu based alloy and highlights the importance of applying a well-controlled cooling sequence to improve the overall process efficiency. INTRODUCTION One of the key aspects in Aurubis’s 2025 vision is to move towards the implementation of a multi metal recovery strategy. The implementation of this new multi metal vision is supported by the long tradition of the company, founded in 1866 as Norddeutsche Affinerie, and further developed by adopting modern copper smelting and lead smelting technologies for the processing of primary and secondary materials. The combination of these assets have already build the basis for processing of complex materials in the copper and lead circuits implemented in Aurubis’s facilities. The addition of a new smelting facility, will enhance these capabilities. Aurubis current flowsheet combines Cu, Pb and Zn metallurgy. This includes primary smelting of copper concentrate, processing of secondaries (residues, slimes, slags) and recycling materials (scrap, shredder material, e-scrap). These broad range of materials contain not only the mentioned base metals but also a number of minor metals that requires to be properly managed to ensure efficient recoveries and quality of the targeted metals.

Jan 1, 2019

By Tong Qin, Jinxia Zhang, Fusheng Niu, Limei Bai

"The interaction between a deformable bubble and a rigid particle in viscous liquids under microgravity conditions is studied by direct numerical simulation via an Arbitrary-Lagrangian-Eulerian (ALE) method. Due to the microgravity, the bubble will stay as a sphere in the fluid without external forces and its deformation is caused by the moving particle. In this study we assume the flow field is axisymmetric and the motion of the gas inside the bubble is neglected. The particle equations and the Navier-Stokes equations for the fluid are solved in a unified finite element framework. The particle obtains an impact velocity by an external force and the impact velocity is varied over a wide range. A ‘critical time scale’ T0 was identified for the interaction process. For successful contacts between particle and bubble, the time scale of their relative motion must be less than T0.INTRODUCTIONThe particle-bubble interaction is an important process in many applied industrial domains such as water treatment, froth flotation and liquid steel purification. It is a complex three phase process in that it embraces many research areas: fluid hydrodynamics, interfacial forces, particle and bubble behaviour and solution chemistry.Derjaguin and Dukhin(1961) clarified the particle-bubble interaction by introducing three-zone model for small and medium size particles. When the particle is far away from the bubble surface, the hydrodynamic forces are dominant. The particle is driven toward the bubble surface by the particle inertial and gravity. This region is regarded as Zone 1 and the interaction in this zone is a collision subprocess. As the particle gets close to the bubble, it exits a zone where the liquid flow around the bubble surface creates a tangential stream from the upper surface of the bubble toward the rear of the bubble. This is Zone 2 which is called the diffusiophoretic zone. In Zone 3, the particle is very closed to the bubble, surface forces like van der Waals, electrostatic and structural forces are considered. Contrast to Zone 1, Zone3 can be regarded as an attachment subprocess."

Jan 1, 2016