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By Lawrence Devon Smith

What is a Failed Project? For mining projects, some key indicators of a ?failed? project are: ? Cost is more than it should be (particularly capital) ? Schedule ? It takes longer to build than expected ? It takes longer to ramp-up than expected ? It does not do what it is supposed to do ? Poor performance; output, product specifications; ? Low revenue ? High costs ? No one is happy about it: Management, Shareholders, Bankers ? Does a project fail if it does not meet expectations that were unrealistic and unattainable? ? Caution: Failure may not become evident until years later

May 1, 2010

By Xu Feng, Han Shufeng, Zhu Bin, Wang Mingming

Due to urban subway tunnels mostly built in the cities with highly density buildings, the geological and construction conditions is complex, especially certain sections of the subway tunnel will pass through from the foundation of the overpass, therefore the stability and surface deformation control of that section’s tunnel excavation is particularly important. Taking Xi'an Metro Line Three interval tunnel as a research object, we have used FLAC3D simulation to analyze the tunnel’s surrounding soil deformation and tunnel lining stress distribution under bridge foundation with shallow buried covered excavation method. Analysis results show: (1) After the excavation of the tunnel right line, due to the bias of the upper bridge foundation the right of the tunnel showed relatively large deformation. In order to ensure the construction safety, we recommended using the grouting anchor reinforcement on the right side wall to further control the deformation zone. (2) The maximum vertical displacement of the ground occurred in the right wall of the tunnel portion which was due to the intensity of soil outside the grouting range of the arch is low, as a result the deformation is larger; this position requires special attention, strengthening the monitoring measurements of this part is necessary to avoid the large deformation and other adverse effects of the upper portion of bridge foundation. (3) The maximum vertical force area of the initial lining of the tunnel is in the middle of the side wall, while the second lining in this part of forces is smaller, thus at the beginning of the construction of the liner, attention should be paid to this area. On-site grouting or steel bracing reinforce support may be used if necessary.

Jan 1, 2015

By W. Yang, R. Rajasingam, K. Mohanarangam

"Copper Electrowinning (EW) is a complex electrochemical process that involves the production of LME grade copper from copper rich electrolyte. The process involves the deposition of the copper ions onto the cathode from copper rich electrolyte with the production of oxygen bubbles at the anode. The process setups up a complex flow pattern within the cell as it is subjected to varying density gradients due to the deposition process along with oxygen bubble driven flow. It is a necessity to understand and quantify the flow behaviour within these cells in order to maintain the production of highest grade copper. In fact, the oxygen bubbles originating from the process is responsible for the generation of acid mist which is a designated as a carcinogen a major health hazard around EW tank houses. Hydrodynamic assessment of the process has so far been restricted to simple mass balances and some limited numerical modelling. All the models are based on assumed boundary conditions which has not so far been verified by any real-time physical measurement. This apparent gap has led to models which could not be directly used to track process changes or troubleshoot problems in EW tank houses. In order to address this gap, CSIRO has established a full size (width and height) transparent cell capable of simulating plant operating conditions (across the range currently used). With the use of sophisticated diagnostic analytical tools and measurement techniques it was possible to study all the operating variables (current density, flow rate, temperature, etc.) independently and their effect of bubble size, bubble velocity, gas hold-up as well as acid mist generation and its size. In order to address safety concerns in tank houses around acid mist early results outlining the factors contributing to its generation as well as the effect of various barriers to mitigate acid mist is outlined below.INTRODUCTIONA significant part of today’s copper production is through hydrometallurgical route which predominantly involves leaching, Solvent eXtraction (SX) followed by ElectroWinning (EW). Producing copper using this approach have shown to be environmentally friendly (Dresher, 2001) compared to the traditional smelting process. EW is the final step in the production of LME grade copper using the hydrometallurgy route. The electro-chemical process involves the use of a lead anode (Pb-Sn-Ca) and a stainless steel cathode to produce copper sheets using the copper rich electrolyte from the SX process and with the applications of direct current to the electrodes. This electro-chemical reaction results in the deposition of copper ions on the cathode with oxygen released from the anode as a by-product. Hydrodynamically, the oxygen bubbles create a bubble driven flow within the EW tanks with the surrounding electrolyte. A direct result of this could be seen from the quality of the copper deposited on the cathode. Most of the copper plates produced from the traditional tank houses have a rough texture at its bottom one-third while the top two-thirds have a smooth finish with a finer grain structure."

Jan 1, 2016

By A. Warczok

The mechanisms and kinetics of copper oxidation and reduction have been investigated in small scale thermal gravimetric experiments as well as in laboratory pilot scale, packed bed reactors. With blister copper flowing gravitationally down through a packed bed of ceramic particles, counter-current to low oxygen containing combustion gases, the rate of oxidation was found to be very high due to the large surface area created. Similarly, reduction by flowing copper through a packed bed of charcoal lead to rapid de-oxidation. Based on these laboratory measurements, fundamental rate data have been obtained. Modeling of industrial sized packed bed reactors using the laboratory results, opened up the possibilities of developing a new, very intensive, continuous process for copper fire refining. The developed mathematical model together with a computer process simulator, allowed for the design of the industrial-pilot installation to be built and tested at the ENAMI Paipote smelter in Chile.

Jan 1, 2007

By W. F. Harkness, D. Hodgkinson

"A non-destructive testing program was established at Crows Nest Resources (C.N.R.), Line Creek mining operation following an in-service fatigue failure of a front wheel spindle on a large haulage truck.This failure identified a definite need for improvements in the ultrasonic techniques used during the mandatory spindle integrity examinations. Initial investigations using common mining industry ultrasonic examination techniques showed that the smallest detectable cracks were 75 mm in length for the spindle types in service at the C.N.R. site. The Initial findings indicated that inadequate inspection technique design was the cause of the poor performance. To improve inspection reliability it was identified that improved ultrasonic techniques were required. Results using designed ultrasonic techniques were encouraging, with the detection of simulated and natural cracks 12 mm long achieved. The cost benefits associated with the extended spindle life, following the removal of these small fatigue cracks, far exceeded those of the expertise and effort necessary to implement and conduct the N.D.T. program.Introduction During 50 years of evolution, non-destructive testing (N.D. T.) has progressed from a laboratory curiosity to a well accepted and invaluable tool used in the assessment of material integrity. Unlike destructive testing, N.D.T. does not deform or render the material useless. Non-destructive tests may involve many applications, from the determination of a corrosion prevention coating thickness to the examination of a raw material for internal and external deformities.Within the mining sector, highly-stressed components will normally have been subjected to some form of non-destructive test during their manufacturing cycle. These tests are used to ensure the component does not contain material flaws whichmay be detrimental to its service performance.While the component may have assured quality when produced, deterioration by fatigue may occur during an aggressive service life. Large dynamically-loaded components such as haulage truck front wheel spindles are , in particular, prone to this service related problem."

Jan 1, 1987

By G. Landry

"IntroductionThe Cape Breton Development Corporation (CBDC) is constantly searching for new technologies that will enhance the marketability of its coal. One technology which shows promise in utilizing Cape Breton coal while at the same time addressing the traditional problem of high sulphur inherent in the Sydney coalfield, is coal-water fuel (CWF).The CWF process incorporates a physical change of coal by grinding it to a flour-like consistency and then mixing additives with it to make a fine coal slurry. The result is a liquid dispersion of fine coal particles that looks like oil, stores and flows like oil but burns like coal. The equipment used in the CWF process is standard mineral processing equipment but application of the equipment to manufacture a specific coal particle size and the specified additives used in the mixing make it a unique technology.The product, which CBDC calls Carbofuel, consists of 70% coal, 29.5% water and 0.5% chemical additives. The key properties of the product are: (I) high solids loading, (2) medium viscosity levels, (3) stability against sedimentation, and (4) good atomization behaviour. Carbofuel specifications are presented in Table I. Carbofuel ProductionThe production of Carbofuel is based on the controlled processing of coal. This involves wet grinding of the coal to a specified fine size (-250 um), cleaning this fine product to remove mineral impurities and formulating (with chemical additives) a finalproduct from the cleaned coal. The flow diagram in Figure 1 indicates the processing circuit for Carbofuel production.CBDC operates a 7-tonne-per-hour continuous production plant complete with state-of-the-art control, full laboratory services, product storage and loadout facilities. The plant has operated since 1983 and has produced over 12000 tonnes for several major demonstrations. The plant is shown in Figure 2."

Jan 1, 1987

By Werner W. Scholz

A corrosion-resistant lining is, quite often, selected on the merits of its corrosion resistance only. This paper demonstrates the effects of temperature, pressure, weather, design aspects and variances of physical properties within the scope of the generic designation of a corrosion-resistant material or materials. The base for the study is a rubber- and brick-lined steel vessel, with unchanged chemical conditions. Graphs and sketches illustrate the various effects of physical influences on the selected lining specifications.

Jan 1, 1979

By R. D. Brown

This article summarizes some of the principal features of the taxation of industrial mineral mining in Canada. Where the rules applicable to such operations differ from those pertaining to the production and processing of precious and base meta s (non-industrial minerals), the two sets of rules are compared. If a conclusion could be drawn from such an over-all comparison, it may be that the total tax burden on an industrial mineral mine can be considerably more onerous than on both base meta mining operations and manufacturing profits.

Jan 1, 1979

By Dale A. Walters

The thermal recovery of bitumen reservoirs by steam assisted gravity drainage (SAGD) is often designed to maximize the operating pressure. In general, the benefits of higher operating pressures are higher steam temperatures that maximize the reduction of oil viscosity, potential permeability enhancement associated with lower effective stress and shear dilation, and a larger pressure window to allow flexible control of the producer. This is especially important for shallow reservoirs where the pressure window for injection and production is smaller. Higher operating pressure can reduce thermal efficiency (due to heat losses), but the other benefits usually compensate. The limitation of the maximum operating pressure is then based on maintaining caprock integrity. Thus, shear and tensile failure mechanisms must be quantified and managed. This paper presents a geomechanical analysis of caprock integrity for SAGD operation. Both analytical and numerical approaches are used to investigate the modes of caprock failure. Main factors in the analysis are the knowledge of the initial stress state and proper representation of the complexity of the geomaterials. Typical initial stress states for northern Alberta are presented showing the potential for low initial minimum total stress and elevated initial shear stress levels. The stress-strain behavior for the sand and caprock materials is discussed focusing on the potential for shear dilation in the sand and shear strength behavior in the caprock. Elasto-plastic constitutive models used to represent the sand and caprock are presented and compared using numerical analysis. The increase in pressure and temperature alter the stress state and disturb the soil matrix. This disturbance results in shear dilation of the sand matrix creating regions of enhanced permeability and porosity. Also, the transfer of stress and strain to the caprock causes dynamic stress changes and, therefore, dynamic behavior of shear and tensile failure conditions. Calculations are presented showing the stress paths associated with SAGD operations, suggesting better design of lab testing programs and the implications for shear dilation in the sand and shear failure in the caprock.

Jun 1, 2012

By Liu Liching, Yan Hongjiu

"In China, the electromagnetic induction initiating system f or blasting engineering has been greatly developed in recent years. With this system, the total number of detonators that may be blasted in each round has been increased from 420 to 940 as a result of the invention of a powerful exploder, and the length of leg wires of a detonator has reached 12 metres. These developments make the new system suitable for blasting engineering of medium scale. Another attractive feature of this system is a set of testing instruments which have been invented that enable a final check of the system to be made before firing as in normal electric blasting. This paper reports on these developments.IntroductionThe initiating system for blasting explosives is one of the key factors to the success of blasting engineering, along with the progress of explosives and blasting technology. Today, we have initiating systems which may be divided into two groups: electric and non-electric. The earliest initiating system was non-electric. Many mines, as well as many projects where rock excavation was involved, were blasting non-electrically before the new nonelectric initiating system came into use in the 1970s. Electric and non-electric initiating systems are the two main initiating systems which are now being widely used, each having its advantages and disadvantages. In electric blasting, the blasting supplies and the blasting circuit can be checked before it is used or fired and, therefore, is regarded to be more reliable. In many large-scale blasting engineering where reliability of the initiation is of great concern, a checkable initiating system is preferable. The electric initiating system is not considered to be as safe as the non-electric initiating system due to its inability to choose proper ignition energy. Therefore, a non-electrical initiating system would be preferable where a hazard of stray currents or static electric energy exists. At this stage of development, one would say it would be advantageous to develop a new initiating system."

Jan 1, 1988

By V. G. Minenko, A. L. Samusev

For efficient leaching of gold from sulfide ores and the oxidation of sulfides into sulfates, it is necessary to introduce a substantial amount of oxidant - atomic oxygen, hydrogen peroxide, ozone, potassium or sodium hypochlorite. In this paper, hypochlorite electrochemical treatment is proposed as an effective method of intensification of refractory ore leaching. The objective of the study is to increase the gold recovery from refractory ores with the application of chlorinated solutions that are modified by chemical or electrochemical treatment. The advantages of the use of the modified chlorinated solutions instead of cyanide for gold-sulfide leaching are considered to be the following: a high concentration of the oxidizing agent (hypochlorite ions) in solution helps to achieve a high speed of gold dissolution in the form of chloride complexes; the possibility to produce hydrochloric acid solutions that may be used for the recovering gold by electrolysis; the possibility of the processing of carbonaceous, arsenic-bearing and others kinds of refractory gold ores. The mechanism of the interaction of the modified chlorine solutions with gold-bearing sulfides (pyrite and arsenopyrite) was investigated. The efficiency of the application of chemical and electrochemical leaching method was proved. The main factor that limits the rate of gold dissolution is a high concentration of sulfate ions (SO4 2-) formed in the solution by the oxidation of sulfide minerals. The optimal parameters of chemical and electrochemical leaching method and effective ways to remove sulfate ions were determined. The method helps to increase the level of the gold recovery up to 87% from refractory ores. The intensification of leaching by chemical and electrochemical treatment opens up opportunities for the creation of modern efficient and environmentally-friendly technologies that may be applied for gold extraction from refractory gold ores.

Jan 1, 2016

By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

By Robert B. Parsons

"One of the disadvantages of the federal government's idea of ""taxation by consultation"" is that it seems to take longer to enact new legislation. The proposed new rules for taxing automobile benefits is one example. Here is a ball which has been batted around between government and the public several times and still has not come down to earth. Fasten your seatbelts, there may be more to come. IntroductionThe draft legislation released on April 13 contains the details of the government's current proposals on car expenses and benefits. They differ significantly from the last announced position. Finance Minister Wilson has indicated that the release in draft form will provide an opportunity for the Commons Standing Committee on Finance and Economic Affairs (the Blenkarn committee) and other interested persons to comment before the legislation is introduced in Parliament. Accordingly, there may yet be revisions.Notwithstanding the prospect of further changes, the proposed rules generally come into force in 1988. While taxpayers may welcome some of these changes, particularly the increase in the tax-exempt allowance, many must be frustrated that, at this late date, the rules for the current taxation year are not yet finalized."

Jan 1, 1988

By K. D. Card, K. Howard Poulsen

Abstract - The Archean Superior Province craton and the Paleoproterozoic Penokean Orogen are major geological sub-divisions of the southern Canadian Shield and account for much of the metallic mineral production of North America. The Superior Province experienced a mainly Archean history involving several cycles of volcanism, plutonism, and tectonism, primarily in the Neo-archean but also including Meso-archean and Paleo-archean cycles as well. Superior Province consists of northern and southern high-grade gneiss sub-provinces and a broad central region of alternating greenstone-granite and metasedimentary belts. The sub-provinces may represent tectonic terranes assembled in the Archean by accretion processes similar to those of some Phanerozoic orogens. Most of the mineral deposits, including VMS, intrusion-related, and lode gold deposits occur in the greenstone- granite sub-provinces where they were formed in an interval of 100 million years or less around 2.7 Ga. The Paleoproterozoic Penokean Orogen comprises supracrustal sequences deposited in fault-controlled epicratonic and rifted margin settings developed on and about the Superior craton. Deposition of the ~2.4 Ga Huronian Supergroup and its paleoplacer uranium deposits in the eastern Penokean Orogen, and their pre-2.2 Ga deformation, were probably unrelated to the deposition of the ~2.1 Ga Marquette Range and Animikie groups and their major taconite iron formations in the west. However, these sequences were deformed together during the ~1.85 Ga Penokean Orogeny which resulted when an assembly of island arcs containing VMS deposits, the Wisconsin magmatic terrane, collided with the Superior block and its Paleoproterozoic cover. The Sudbury structure with its world class Ni-Cu-PGE ores was also formed at this time, possibly triggered by meteorite impact. Metallogenic patterns in the Paleoproterozoic rocks were controlled by a complex interplay of factors including tectonically controlled variations in deposition and deformation, distribution of mineralization in the Archean basement, and oxyatmoversion, the transition from anoxic to oxygenic atmospheric conditions that occurred during the deposition of these sequences.

Jan 1, 1998

By C. G. Anderson

Alkaline sulfide leaching technology (i.e. ASL) has been studied, presented and published throughout the literature and utilized in some current engineering studies. Yet, the actual industrial applications are very few and the knowledge about these is very limited. Hence, a large gap between the laboratory, publications, engineering studies, and the actual industrial plant exists. Recent studies of ASL applied to copper enargite concentrates definitively bear out this dichotomy. Hence, this paper will seek to dispel the common misperceptions that continue to surround the selective industrial ASL hydrometallurgical technology. For edification of the reader, a listing of ten common misconceptions and myths is listed. As well, ASL history, fundamental aspects and a new flowsheet application for simultaneous gold and high purity antimony oxide production from low grade materials is included. The associated estimated economic considerations are also included to heighten enlightenment about the application of this industrially proven technology.

Jan 1, 2014

By F. Parada

During copper smelting and converting processes, slag generated is pyrometallurgically cleaned and then disposed, containing around 1 % of this metal. However, important amount of molybdenum initially contained in concentrates also goes to the slag phase. Research on molybdenum recovery from water granulated slags using acid leaching at low temperatures was conducted to find an efficient way for molybdenum extraction with lower magnetite in the slag. However because of the high fayalite content high acid consumption was found. Molybdenum can be recovered from solution using ionic exchange resins, but high silica content interferes with extraction. Some studies addressed to minimize silica extraction as well as alternatives of selective silica precipitation in order to develop a technically feasible process.

Jan 1, 2007

By S. H. Seyedein

A mathematical model was developed to study fluid flow and solidification in a single-roll casting system. Fluid flow coupled with energy equations were solved numerically using a finite volume method. A body-fitted coordinate transformation technique was adopted to handle the irregularly shaped domain. In order to couple the continuity and momentum equations, a SIMPLEC algorithm was used. A fixed-grid enthalpy method was considered to model the solidification in the system. The turbulence effect on flow field was modeled using a low-Re k-e model The model developed in this work was further run under various conditions to optimize the operating parameters of the process.

Jan 1, 2004

By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By D. R. Boyle

"Abstract - The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite > arsenopyrite > galena > Bi-Sb sulfosalts > chalcopyrite > tetrahedrite group > sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was trans- ported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995