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By Meifeng Zhi, Yuqing Niu, Xixin Chang, Fengqi Zhao, Weimin Qiu, Hao Wang, Zhenqian Wen, Zujun Shu

An applicable Eluex process was developed for acid in-situ leaching (ISL) uranium mine in Bayanwula. In this process, uranium was adsorbed with strong base anion resin from the pregnant solution, then the loaded resin was eluted by sulfuric acid. After D2EHPA extraction, the concentrated eluate was enriched, and the loaded organic phase was stripped by sodium carbonate. The yellow cake was obtained by sodium hydroxide precipitation at last. The uranium concentration in the loaded strip solution was 52.8 g/L. Parameters of the process were determined, and the impact of the Eluex process in underground leaching was also investigated. In industrial design, 95% of raffinate went back to elution and 5% back to in-situ leaching. No significant effect on uranium leaching or resin adsorption was found.

Jan 1, 2020

By P. H. Shipway, D. G. McCartney, H. Saghafifar

The microstructural changes during thermal ageing at 650ºC in the interfacial region of Alloy 625 weld overlay on a 2.25Cr-1Mo steel was evaluated. Optical microscopy, scanning electron microscopy in SE and BSE modes, electron probe microanalysis and hardness mapping were used to characterize as-welded microstructure and its changes during thermal ageing and precipitates of interfacial region. Carbon migration across the interface was recognised as a major issue. A region of 300 µm wide adjacent to the fusion line, which was found harder in the as-welded condition decarburized during thermal exposure. Studies revealed that this region transformed to a soft region containing large ferrite grains and micron-sized carbides. In the weld overlay, a 50 µm wide hard band (over 650 Kgf mm-2) adjacent to the fusion line formed and carbide precipitates were observed along grain boundaries. Carbide precipitation mostly occured in the 150 µm wide region close to fusion line.

Jan 1, 2017

By J. E. Hawley, R. C. Hart

"The Preston East Dome gold mine is in the southeastern part of Porcupine district, Ontario, 5 miles southeast of Timmins, and immediately south of the property of Dome Mines, Limited.The claims now owned by this Company were originally staked in 1909. After the property had remained dormant for many years, the present Company was organized in 1936 to resume development operations. Two shafts had been sunk: at the time of the early work on the claims, but lateral work from these failed to reach the ore deposits. A successful diamond drilling campaign undertaken under the direction of D. G. H. Wright, however, was followed by the sinking of a five-compartment shaft arid the erection of a mill. From the start of operations to the end of 1944, 1,292,000 tons of ore averaging $11.60 in gold a ton have been mined.An outstanding feature in this mine is the occurrence of the major gold deposits in quartz porphyry intrusives, though minor deposits are also found in the adjacent Keewatin volcanics. Most of the ore occurs in fractures, but the filling was accompanied by varying degrees of replacement of schistose wall-rocks. The ore deposits may be classified as:"

Jan 1, 1954

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter in blowing the copper stage has been developed to predict the molten temperature. The key assumption of the model was that white metal and gas phases in the converter were in thermal and chemical equilibrium. In this model, the chemical reaction of white metal and oxygen was accomplished completely. So long as sulfur existed in the bath, the generation of Cu2O was frozen. The reaction rate was considered to be constant and controlled by the reacted sulfur. The converter temperature was calculated by heat balances over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depended on process parameters such as oxygen efficiency, molten emissivity and oxygen enrichment.

Jan 1, 2007

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

By X. -P. Zhang, L. N. Y. Wong

Shale gas exploitation initiated in North America has rapidly extended worldwide. Hydraulic fracturing is an emerging field technique for stimulating the gas reservoir. The study of cracking processes, particularly crack coalescence, is vital for a successful hydraulic fracturing to enhance the gas exploitation. Experimental studies have observed that the size effects of the constituent particles are significant on the cracking behavior of the rock specimens. To further investigate the size effects, the bonded-particle model (BPM), which is based on the discrete element method (DEM), is adopted in the present research. In flaw-containing specimens, by varying the crack resolution (?= a/2R), which is the ratio of half flaw length (a) to particle size (2R), the size effects on cracking behavior under compressive loading are studied. By keeping the flaw length constant, the particle size is varied independently in the BPM analysis. Decreasing the crack resolution increases the first crack initiation stress, but it has no obvious effects on the uniaxial compressive strength. The trajectories of the first cracks and secondary cracks hence generated have a higher resolution and are well-defined in those specimens possessing a higher crack resolution. On the contrary, in lower crack resolution specimens, the macroscopic first cracks appear to be wider and less continuous. These findings from numerical simulation clearly demonstrate particle size effects on cracking behavior. Special attention should be paid to these effects in future numerical study using the bonded particle model.

Jan 1, 2015

By V. P. Mehrotra, D. W. Fuerstenau, A. -Z. M. Abouzeid

The use of pulverized coal for electric power generation results in the production of vast amounts of fly ash. One potential use for waste fly ash is the production of pellets for lightweight aggregates. This paper is concerned with the role of the physical and chemical characteristics of two different fly ashes in governing their agglomeration or pelletization behavior and their strength characteristics. In batch balling experiments, fly ash pellet growth was found to be extremely sensitive to the amount of moisture added. One ash (Mohave) exhibits marked pozzolanic activity whereas the other (Jim Bridger) does not. The pozzolanic activity has a very pronounced effect on pellet growth kinetics, moisture requirements, and the effect of various additives on growth kinetics. Slow drying under ambient conditions produces strong pellets from Mohave ash whereas Jim Bridger ash pellets lacking in pozzolanic activity are weak. Rapid drying at high temperatures results in weak pellets because water necessary for hardening is driven out of the pellet. Steam curing enhances pellet strength. Locked-cycle pelletizing experiments exhibit expected oscillation in pellet production rates and attendant fluctuations in pellet green strength.

Jan 1, 2004

By J. H. Walsh

IN THE DEVELOPMENT of procedures for the separation of minerals, the choice of reagents for flotation is frequently determined by the extent to which a given mineral is wettable by water. Measurements of the contact angle of an air bubble on wet mineral surfaces are often used in the laboratory to estimate the wettability of the surface. For the results of these measurements to be reproducible, the surface of the mineral must be polished to a mirror-like smoothness and must be free from oily contamination. Elaborate procedures for preparing mineral surfaces have been developed by Wark ( 1) and Taggart (2), and these procedures have been generally accepted as adequate for their purpose. The polishing techniques, how-ever, have certain inherent disadvantages which make it impossible to assess the effects of polishing, entrained abrasive, and adsorbed gases on the wettability of the mineral surface.

Jan 1, 1957

By J. H. Schloen

"One of the most important phases in Canada's relatively rapid development of its metal mining and refining industries was launched in 1928 when the directors of Noranda Mines Limited decided to establish an electrolytic copper refinery ""somewhere in Eastern Canada”. Noranda's president, J.Y. Murdoch, had already evolved the company's ""mine to market"" policy and was determined to prove the economic feasibility of refining Noranda copper in Canada. The time appeared to be ripe as buoyant business conditions continued into 1929. In addition, proven ore reserves at the Horne Mine in northwest Quebec had virtually tripled and the price of copper had reached a healthy 15 cents per pound. Letters Patent incorporating the company bearing the date February 6, 1929 had been granted by the Secretary of State in accordance with an application that specified a capital structure of $2 million divided into 20 000 shares with a value of $100 each. Noranda assumed 70% of the original investment in the proposed refinery, while the Nicholas Copper Company of New York (which later became Phelps Dodge Corporation) and British Metal Corporation Ltd. of London, England, each were responsible for 15%. Nicholas Copper Company agreed to supply the design and to supervise the construction of the refinery and British Metal Corporation would act as sales agent and market the refinery's products."

Jan 1, 1999

By L. Hacini

The start-up is the most critical phase of the cell life, as an uncontrolled start-up could lead to early infiltrations, instabilities, and in some cases to the cell death. Lots of efforts are put to increase the lifespan of cells, as it has a major impact on both the operating costs and the environmental footprint of the aluminum industry. Obviously, a true size test on a cell is a resources- and time-consuming approach that could be used only to validate mature concepts. Moreover, numerical modelling is a low-cost and versatile tool capable to test a wide range of potential ideas and concepts. In the present article, a thermal electrical mechanical slice model is presented. This model describes the preheating and bath periods of a P155 aluminum cell start-up, as used at the Grande Baie smelter. The impact of sodium diffusion and expansion is also included in the model. This model will be useful to study different problematical issues such as the global behaviour of lining materials, shell and cradle deformations during start-up and several start-up scenarios. Such a model will also be able to answer some interrogations regarding early infiltrations and their impact on the lifespan of the electrolysis cell.

Jan 1, 2011

By Carmen M. Neculita

Optimizing the long-term efficiency of passive systems for the treatment of highly contaminated acid mine drainage (AMD) is still a challenging issue. The optimization lies, among others, on improving the understanding and quantification of metal removal mechanisms in order to predict and enhance the stability of neo-formed minerals in secondary phases. Sorption, and precipitation as oxides-hydroxides, carbonates and bio-sulfides are likely the most important metal removal mechanisms involved in passive biotreatment of both slightly and highly contaminated AMD. In the same time, the preferred mechanism is precipitation of metal sulfides that are more stable and less pH dependent than carbonates and oxides-hydroxides. However, results of relatively recent research studies performed at laboratory scale showed that sulfides accounted only for up to 15% of total metals removed in passive bioreactors treating highly contaminated AMD dominated by iron (around 500 mg/L). Several approaches were used in the aforementioned studies to understand and quantify metal removal mechanisms in spent reactive mixtures collected from long-term (12-15 months) operating column bioreactors. These included: thermodynamic equilibrium modeling and various chemical extractions and mineralogical analyses (such as single and sequential extractions, acid volatile sulfides-simultaneously extracted metals determination, scanning electron microscopy, X-ray diffraction, and thermo-gravimetric analysis). The large proportion of metals (85%) removed by sorption and precipitation as oxides-hydroxides and carbonates suggests a relatively high mobility of the neoformed minerals, especially in low pH conditions. However, no data is available on the long-term stability of spent reactive mixtures and, on the implications for the sustainable management of this type of solid waste. Lately there is almost a consensus that the efficiency of highly contaminated AMD treatment is warranted by the use of multi-step passive systems, including both chemical and biological units, installed sequentially. However, very few well-documented studies are available on the design, construction, operation and long-term efficiency of these multi-step systems. A leading example is the tri-unit passive system installed on the abandoned Lorraine mine site (Québec) to treat a highly contaminated AMD dominated by iron (about 2,500 mg/L). This tri-step system (160 m3), consisting in two bioreactors separated by a unit filled with wood ashes, achieves to date a satisfactory removal of iron (up to 99%). Moreover, based on the data collected during laboratory testing, iron was mainly removed in the wood ashes unit (from around 3,200 mg/L to 10 mg/L) by precipitation of oxides-hydroxides as predominant mechanism and only partially by sorption. However, no data is available on the actual metal removal mechanisms in the field. Overall, theses multi-step systems are more complex and their long-term performance is even less predictable than the single unit systems. This paper presents the current knowledge and the research needs on metal removal mechanisms in passive bioreactors and multi-step systems for the long-term treatment of highly contaminated AMD. KEYWORDS

Aug 1, 2013

By C. Feng, D. W. M. Arrigan

Arsenic is often associated with gold mining operations and poses a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under alkaline conditions. In this study, the removal of As (III) and As (V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe3O4) or maghemite (?-Fe2O3) cores covered by various metal oxides with Langmuir adsorption capacities of As (III) and As (V) ranging from 31.4 to 79.1 mg/g and 10.2 to 25.5 mg/g, respectively, in arsenic-only solutions at pH 9. Their adsorption capacities were further recognised by the adsorption tests conducted in simulated process waters. The ability to remove As (III) is of particular importance as it is harder to remove it from alkaline solutions. The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles.

Jan 1, 2017

By K. Svens, M. Lahtinen, L. Lehtinen

"Outotec's direct leaching process is an atmospheric leaching process for sulphidiczinc concentrates. The direct leaching process, based on special leaching reactors developed by Outokumpu and leaching know-how, is the most economical way to produce electrolytic zinc. The newest industrial-scale application of Outotec's direct leaching process will be started up in 2008 in China at Zhuzhou smelter. The process isintegrated to the existing production plant, replacing part of the old production facilities by modern technology and increasing the production capacity significantly. The process equipment supplied by Outotec includes also tailor-made reactors designed on the basisof the work and experience of Outotec Research Centre."

Jan 1, 2008

By \/eena Sahajwalla, Alexander Blagus

This paper reports the effect of using High Density Poly-Ethylene (HDPE)/coke blends on the reduction behaviour of Mn3O4 to MnO at 1000°C. The results suggest that CH4 release increases with increasing HDPE addition. The results show that the rapid release of methane, over only the initial five minutes, limited the interaction of Mn3O4/MnO with CH4. With the devolatilisation of HDPE there was increased porosity in samples containing HDPE, assumed to be the major factor in differences of reduction rates.

Jan 1, 2011

By Derrick Hunter, Pat Feighan, Keith Chrystall, David Wells

"Equipment which may be remotely operated, has some degree of on-board intelligence, and which for periods of time may operate autonomously, is referred to as telerobotic. Recent advances in electronics, computers and hydraulic equipment have dramatically reduced the cost and simplified the process of converting standard industrial equipment to telerobotic control. The benefits of telerobotic equipment include improved safety by removing the operator from dangerous situations, reduced maintenance costs and increased productivity. This technology has been proven in various military, nuclear, and police applications.The surface mining industry has expressed an interest in automation and is characterized by a willingness to use remotely operated equipment, however, the majority of telerobotic equipment currently in use is experimental or prototypical. Potential applications of telerobotic equipment for surface mining include remote operation of equipment near dangerous high walls and other unsafe areas, utilization of robotic trucks for routine hauling operations, and control of jointed equipment. In addition, component technologies of telerobotic systems are relevant to various forms of condition monitoring, operator feedback systems, and vehicle positioning.Attention must now be directed toward resolving more complex problems associated with enhancing feedback to the operator, improving the man/machine interface, and ultimately, improving efficiency. Removal of the human operator from the work site introduces significant complications in replacing the sensory inputs that an operator normally uses to efficiently run his machinery. These can be difficult to define and even more difficult to replicate remotely and may include restrictions pertaining to vision, hearing, and touch.In cooperation with Defence Research Establishment Suffield and the Alberta Research Council, Robotech Industries Ltd. is pursuing the development of additional technologies to further enhance an operator’s ability to control remote telerobotic equipment. These developments include a head-mounted display, additional control station displays and improvements to coordinated motion control software. Prototypes of these developments are expected to be completed and tested by the fourth quarter of 1997."

Jan 1, 1996

By C. J. Edmonds, R. Bland, W. C. Ferguson, R. Whitehead

"In 1969, the Environmental Science Division of James F. MacLaren Limited received authorization from The International Nickel Company of Canada, Limited to carry out a water quality monitoring program in the Lake Shebandowan region of Ontario, where a new base metal mining and milling complex was expected to go into operation in 1972. The objective of the program is to establish base-line water quality characteristics. Fully realizing their corporate responsibility to minimize the effects of the proposed activities on the environment, Inco decided that it would be desirable to establish a program by which any change in the quality of environmental waters will be detected before detrimental conditions ensue, permitting prompt corrective measures to be taken. The program has been in progress for over two years. The waters are sampled and analyzed four to six times per year. Sampling stations are located in Lake Shebandowan and on the adjacent Gold Creek - Matawin River system. On-site analyses and measurements are made of flow, dissolved oxygen, temperature and pH. Samples also are collected for later analysis in the laboratory. These samples are analyzed for a wide range of chemical and biological characteristics. The paper discusses the extent of the sampling program, the techniques utilized and the value of such programs in maintaining the quality of the environment."

Jan 1, 1973

By Parissa Mirjafari, Ron Martel, Susan A. Baldwin, Luke Moger

Mine drainage contains metals and sulfate, which may be toxic to aquatic life at certain concentrations and should be removed to acceptable levels before release of any drainage to the environment. One method for treating mine drainage is passive treatment, which is increasing in popularity due to lower construction and operating costs. This method is based on the activity of sulfate reducing bacteria (SRB) respiring on sulfate while using fermentation products from decomposing complex organic materials. The product of this biological process is hydrogen sulfide, which reacts with metals in mine drainage and precipitates them as metal sulfides. However, in practice passive treatment systems are not always effective, reducing the reliability of this approach. In this study, a mixture of hay, cow manure and wood chips was tested in continuous flow experiments for efficacy at sustainable treatment of sulfate and selenium containing water from a mine tailings pond. Factors that contributed to a decline in performance included lowering of the pH due to acids leaching out of the organics, re-oxidation of sulfide back to sulfate and a reduction in dissolved organic compounds over time. In this paper methods are described to overcome these problems so that treatment is made more reliable.

Jan 1, 2011

By The Staff

IT is a high compliment to be invited to present a pap::r on the subject of "Mining in the National Economy". To cover it adequately would need the knowledge of the economic geologist and of the technical mining engineer, together with the arts of the statistician and of the economist in general, allied with generous psychic powers. Further, one should embellish the tale with a touch of drama. It is comforting that the subject is so broad that whatever may be said within the compass of a paper like the present, can hardly be criticized as going beyond the terms of reference. A conventional approach would be to begin with the noteworthy statistics of the mining industry of yesterday and today. But in the present company this would be "carrying coals to Newcastle"-or to give the venerable metaphor local colour, "nickel to Sudbury". Such statistics are available in all their stimulating detail in our official publications. Let us tackle at once, therefore, as a less hackneyed theme, the relationship of mining to other phases of the Canadian economy. RELATION TO TOTAL PRODUCTION While mining occupies a position of less importance than manufacturing or agriculture in Canada, its relative contribution has greatly increased during the post-war period. Due to the fall in wholesale prices, the net value of production in Canada has shown a decrease averaging about 1.5 per cent per year during the post-war period, though its volume of course has gone up. Mineral production on a value basis, on the other hand, showed a gain of 2.8 per cent per year. Mineral production was only 5.14 per cent of the net value of production of all kinds of commodities in 1919, bur from 1929 to 1936 the proportion rose steadily rill it reached no less than 12. 76 per cent in the latter year.

Jan 1, 1937

By J. Ander

About fifteen years age some mines in western Canada commenced using Diesel engines, partly for development work but also for operations on quite a large scale. In the Eastern mining field, the Diesel engine made its appearance some eight years ago and has since, at quite a number of mining plants, proved to be a reliable and economical prime mover. As a result, it is today used more extensively than could have been foreseen only a few years ago, and it is reasonably safe to predict that the next few years will see the Diesel engine utilized to a still greater extent in the Canadian mining industry. It is not much more than thirty years since the first Diesel engine was put in operation. During the early years of this century, the Diesel engine took, so to say, its first faltering steps in public service. Since then it has reached a high state of perfection, and its importance has grown in a most remarkable way, until today it is used in practically every field where power is required. It is slowly but surely superceding steam for a great many purposes, as, for instance, for ship propulsion. While in 1921 only about 8 per cent of all tonnage launched was motor-driven, the proportion had grown to 38 per cent in 1927, and for 1929 it was slightly over 45 per cent. Some of the finest passenger liners afloat are Diesel-driven. In the early days, Diesel engines were built only in comparatively small units. Today engines with a capacity per unit of up to 10,000 horsepower, or even more, are being built for marine and stationary purposes.

Jan 1, 1930

By Eduardo A. Pérez, Alejandro R. Alonso, Rosa María Luna-Sánchez, Gretchen T. Lapidus

Rare earth elements have been widely used in various sectors, from the aerospace and steel industries, to electronic applications, particularly in displays and batteries for portable devices. The high demand for newer and better equipment, such as cell phones, tablets and lap tops, has increased the consumption of the rare earth elements and at the same time the need for its recovery from electronic wastes. For that reason, the recycling of batteries is important, principally the Ni-HM batteries, due to their elevated content of rare earths elements, in addition to the high concentrations of cobalt and nickel. The current processes are based on dissolution in strong acid solutions (sulfuric acid concentrations from 2 to 4 mol/L), and temperatures from 30 to 90°C. In the present work, electrodes from spent Ni-HM batteries were leached using 1 mol/L H2SO4, in the presence of ozone as the oxidant, where recoveries of 96% for La, Ce and Nd were obtained at room temperature. The separation of Ni and Co from the leach solutions was performed using an electrochemical reactor, after which rare earth elements were precipitated, obtaining a mixture of its hydroxides with impurities below 1%, according to EDS analysis.

Jan 1, 2014