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By M. A. Stogran-Baker, S. Cole

"Fluorspar mining occurred in the St. Lawrence area from the 1930s until the mid 1980s. In 2013, CFI discovered a new ore body, the AGS vein, which proved amenable to more economic open pit mining methods. A new mill was designed to produce 200,000 tonnes per year of high quality, acid-grade fluorspar concentrate. The simple mill flowsheet includes crushing, dense medium separation (DMS), grinding, sulphide flotation, pulp thickening, fluorite flotation, thickening, and concentrate filtration. The type of flotation cell used is being installed for the first time in North America. Site clearing commenced in the spring of 2016, followed by mill building erection completed by the fall of the same year. Civil and mechanical installation as well as site-wide construction was completed by the end of September 2017. Commissioning commenced, and at the time of paper submission mill production is on track to ramp up to full capacity by the beginning of 2018. This paper will focus on the use of fluorine NMR analysis applied to fluorite and the development of on-stream analysis, flotation cell selection and the decision to install the new cells, and the water control program designed to maintain process control with the least possible environmental impact.HISTORY St. Lawrence is located on the south-eastern coast of the Burin Peninsula in Newfoundland and Labrador. The first occurrence of fluorspar in the St. Lawrence area was recorded in 1843 by British geologist J.B. Jukes (DNR 2010). Fluorspar was likely extracted in small quantities prior, however commercial fluorspar mining did not commence until 1933 at the Black Duck Mine. The Black Duck Mine operation processed ore by washing and screening – acid-grade was hand-picked from the oversize, the undersize was sold as a lower grade product. The Black Duck Mine was closed in 1941 (Wilson 2010). The American Fluorspar Limited (New Fluor) commenced operations on the Director vein in 1936, and was bought by Alcan in 1942 (Cooper 2012). Alcan also developed the Iron Springs as well as the Tarefare deposits. The Black Duck Mine mill had closed, and a new mill was built. This new mill crushed the ore prior to dense medium separation, the sinks of which were sent to Quebec for use in Alcan’s aluminum smelter (CFI 2016). Alcan shut down it’s mining operations in 1977 due to the dropping price of fluorspar as well as labour disputes. In 1986, the British-based Minworth Limited began producing ore from underground at Blue Beach North and Blue Beach South, as well as from open pits at Tarefare and Director veins (Cooper 2012). A new mill was built by Minworth in order to process the ore using flotation to produce an acid-grade concentrate. The low price of fluorspar caused Minworth to shut down operations in 1990. Whilst exploration has been ongoing, no mining had occurred in the area since 1990."

Jan 1, 2018

By L. Veleva, Garcia. A., G. Perez

Aluminum is a metal used for the transmission of electricity of high voltage, in the construction industry and other areas. In atmospheric conditions aluminum forms an oxide layer (Alz03'H20) as a result of its corrosion, entering the passive state. The oxide layer can be destroyed by the presence of ions (Cr, SOx-n) developing localized (non uniform) corrosion attack by pitting, difficult for evaluation. The concepts of fractals and self-similarity were used in this study for the characterization of the development of localized corrosion. Images obtained with a scanning electron microscope (SEM) of samples of electrolytic aluminum wire that have been exposed during one year in ruralurban and marine-coastal environments of the humid tropical climate of Mexico, have been processed. The development of pitting has been studied as a function of time, making a statistics of the frequency of appearance of pits versus the area occupied by them. The data show that the distribution of the pits follows a power law. Therefore, the concept of self-similarity can be applied for the study of the phenomenon of localized corrosion, describing their development with time.

Jan 1, 2006

By F. Mackay, S. A. B. da Fontoura

"The theoretical solution for a viscoelastic well was presented by Gnirk and Johnson in 1964. From this an exercise was executed to validate the numerical simulation of a cemented salt well. The exercise comprised the geomechanical behavior through time of a cemented salt well, this was achieved using a finite element commercial software. This simulation showed the accuracy of the theoretical solution for viscoelastic materials such as salt rock. The theoretical solution presented elastic and viscoelastic analytic equations for the tangential and radial stresses. The equations for the elastic material (casing and cement) and for the viscoelastic material (salt rock) are presented here: Where equations 1a & 1b are the radial and tangential stresses of the elastic material; equations 2a & 2b are the radial and tangential stresses of the viscoelastic material; and a, r and b are the geometrical parameters explained in Figure 1. These equations are function of Pb, a stress time dependent factor that comes from the Burgers model of viscoelasticity. This is well explained in Gnirk and Johnson (1964) and for the sake of simplicity is not disclosed here. Po is the stress at section A-A’ dependent of the depth h."

Jan 1, 2015

By S. Markstrom

The Boliden AITIK copper mine is located 100 kilometres north of the Arctic Circle in northern Sweden. A pre-feasibility study was conducted in 2005 with the aim of increasing the capacity of the existing processing plant. After analysis, options to upgrade the existing plant were abandoned in favour of building a new processing plant, with higher capacity and therefore greater profitability. A new plant could be designed with greater flexibility to make potential future expansions easier. A feasibility study for a new 36 Mt/y processing plant including fully AG grinding circuits and flotation was completed in 2006. The project was approved by the Boliden board shortly thereafter. Construction started in the beginning of 2007 and was completed during 2009. Commissioning of the new plant was undertaken in the first half of 2010. The grinding circuit consists of two lines with each line consisting of a 22.5 MW AG mill and a 10 MW Pebble mill in closed circuit with a spiral classifier. The nominal production level is 2 200 t/h for each grinding line. This paper presents the start-up and operation of the grinding circuit.

Jan 1, 2012

By M. I. Kalashnikova, Y. M. Shneerson, M. V. Keskinova

Interaction between mattes having various compositions and solutions with a wide range of free acid and non-ferrous metals concentration have been studied in terms of chemistry, mechanism and kinetics. The solution acidity and oxidizers to reducers ratio in the matte-solution-gas phase system have been demonstrated to be the major factors determining the process behaviour. It was found that the types of copper and nickel secondary sulphides resulted from nonferrous metals precipitation from solution, depend on of the solution and initial matte composition. Based on these studies, technologies of matte leaching and nonferrous metal precipitation in the form of rich sulphide concentrates are developed.

Jan 1, 2004

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By Peter Broad

"Extracting any metal, especially specialty metals and rare earth elements, requires an in-depth analysis of the costs and potential revenue as well as a due diligence study of other stakeholder interests. Rare earth projects are generally in the billion dollar US range or above, and thus failure to accurately predict any loss of revenue caused by impurities within the product or additional effluent treatment costs can destroy an otherwise viable study. Two prime sources of input impurity are considered: impurities in the material feed and from reagents. The effect of these impurities factor on both the product (in reduced revenue) and on residual “tailings” that may incur additional unforeseen costs.INTRODUCTION“Truth passes through three stages. First, it is ridiculed. Second, it is violently opposed. Third, it is accepted as being self-evident” – Arthur SchopenhauerThe era of unscoped, unbudgeted construction ended about 150 years ago. Today’s engineer must design with confidence; but do so amidst proprietary secrets and unfamiliar pollutants, which present a myriad of interesting challenges. Is it possible to build a viable rare earth plant to a realistic budget, without destroying that which we cherish? Some see this as contradictory but in reality it is the only viable option.WHEN GOOD PROJECTS FAILWithout rare earths the Copenhagen agreement might be null and void. Running a wind turbine with a 30 tonne conventional magnet requires some hefty engineering and prohibitive investment. Despite their ‘Green metal’ applications, production of rare earths have created environmental nightmares, as Folger stated in 2011 when visiting Baotou, or has Jaing Mainheng who has been quoted by Ambrose Evans-Pritchard 6 Jan 2013. This comment is not a criticism of China; the details are from a 2012 white paper published by the Chinese Government that initiated a $6 billion environmental clean-up. Nor is China unique; other plants have had problems as well. There were toxic leaks in the 1990s from Mountain Pass, and the Mitsubishi Bukit Merah Plant (built in Malaysia in 1958) required a $100 million clean-up."

Jan 1, 2016

By J. E. Rehder

IN A DISCUSSION of use of any material of ?construction in the mining industry, two points of view must 'be kept in mind - that of the producer or manufacturer of mining and metallurgical equipment, and that of the maintenance and operating staff of the mining plant. In the first case, the choice of material of construction is up to the manufacturer and the user of the equipment has little direct say in the matter. However, if materials are badly chosen and the equipment does not function properly, wears out rapidly, or costs too much, repeat orders ?will likely go to a different manufacturer, so that, in the end, the consumer or mine operator does have the final voice. In the case of materials for maintenance work and plant operations, however, .the mill personnel have direct control over purchases and it is then that a well-balanced knowledge of materials, their properties, and their costs, can be directly useful. With all materials of construction, the final criterion is unit cost versus service performance, so that the lowest possible total operational cost will be obtained. Sometimes this means using the cheapest material available, sometimes the most expensive, but in any case careful analysis of service performance, replacement cost, and material cost is essential to determining the material that produces lowest total cost.

Jan 1, 1956

By W. Holdsworth

The flotation mill of Dentonia Mines, Limited, at Greenwood, B.C., went into operation on April 20th, 1934, and by October 11th a total of 15,000 tons of ore had been treated. It is intended in this paper to describe briefly the operation and to give some of the operating data which have been gathered. The metallic minerals in the Dentonia ore are pyrite, chalcopyrite, galena, and, occasionally, native gold, and the gangue includes chloritic material, vein quartz, and calcite. Pyrite makes up about 90 per cent of the metallic content of the ore, in which it is disseminated as irregular grains and well-formed cubes. An average analysis of the ore is: gold, 0.27 oz. per ton; silver, 1.73 oz. per ton; copper, 0.12 per cent; lead, 0.31 per cent; and zinc, trace. From the mine ore-bin, situated near the portal of the tunnel at the mine, the ore is hauled by motor truck to the mill, a distance of three-quarters of a mile, and there dumped into the receiving bin, which has a capacity of fifty tons. The hauling is done during one eight-hour shift, commencing at 7 a.m. The maximum size of the ore fed to the mill-bin is ten inches. Lumps larger than this are broken by sledge hammer to pass through grizzly bars, spaced ten inches apart, installed above the bin. The ore is drawn from the bin by a 30-inch, 6-ply conveyor belt, 18 feet 6 inches long. In the near future, when the cross-cut tunnel is completed, the ore will be trammed to the receiving bin. This will effect a considerable saving in cost. At the same time, the bin will be set back several feet, so that the length of the conveyor belt may be doubled. This will make efficient ore-sorting possible, and so ensure a minimum of waste rock in the mill feed.

Jan 1, 1935

By R. M. Oliver

THE Falconbridge property is almost completely covered with over-burden to a depth varying from 60 to over 200 feet. This overburden consists of grave], sand, and boulder, with bands of very fine silt, and there is usually a layer of water-bearing quicksand adjoining the r:ock surface. In previous shafts sunk at Falconbridge, this water-bearing quicksand had given considerable trouble, and further difficulties were expected in sinking No. 5 shaft, due to its greater size. The method described in this paper is the one adopted in sinking this shaft, after the matter had been carefully considered. No. 5 shaft is located 2,400 feet east of the old main No. l shaft, and is sunk in norite in the hanging-wall of the ore-body, which is, however, ? practically vertical to the deepest known intersection. The greatest depths of overburden prevail on the south side, or footwall, of the ore-body, and this, together.. with the fact that the footwall is wet and more badly fractured, swayed the final decision to sink in the hanging-wall. After the shaft site had been chosen and cleared, a diamond drill was set up a few feet away and a hole bored to a depth of 405 feet to test the over-burden and character of the norite bedrock. The depth of overbudren indicated by the hole was Ill feet, with the last 10 feet water-bearing. The norite was rusted and broken up for only a few feet below bedrock. A steel sinking shield (Figure l) was assembled at the shaft location, and consisted of 5/8-inch plate, 5 feet deep, built around a frame of 6 inch by 6 inch angle-iron, and braced at the corners with the same material. Twelve-inch I-beams held the shield as rigid as possible. In order to reduce binding against pebbles to a minimum, the shield was constructed with a 1-inch batter on all sides.

Jan 1, 1938

By Floyd Smith

Based on underground observations made in .the coal mines of the Dominion Coal Company Ltd., this paper deals with the stress phenomena in the approach roads and headways and in the gob areas associated with the longwall method of total extraction. The deformation of roadways during development and the deformation of roadways during the total extraction period is delineated and presented in graphical form .. Conclusions are made as to the feasibility of the introduction of the retreat method of longwall extraction in one of the colhenes. The importance of future studies are enumerated, especially. those pertaining to the determination .of the opti.m.um sizes of protective pillars and to increasing the efficiency of the current methods of artificial roadway support.

Jan 1, 1967

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016

By Raj Rajamani

In general, many past works examine mill load, mill power, shell lifter design etc with a view to improving the mill capacity. On the contrary, only a handful of papers have addressed the transport of fine slurry through the pulp lifters. We present the flow dynamics of pulp lifters via laboratory scale experiments, high speed photography and modeling with computational fluid dynamics. Next, the flow behaviour in ArcelorMittal?s Mont-Wright autogenous mill discharge flow is examined. In an effort to improve mill throughput, a comprehensive simulation and plant scale study of the mill was taken up with a focus on the shell and pulp lifter design. The shell lifter was found to be at its optimum limit for breakage of ore particles given the constraints of wear life and occupied volume. Next, the pulp lifter study was taken up with computational fluid flow code and discrete element code. The simulations directly showed that there was considerable carry-over of slurry. This effect was traced to the area restriction in the pulp lifter channels. Further, crash-stop studies confirmed slurry pooling within the mill. Thus it was readily apparent that mill throughput can be increased if the pulp-lifter could be redesigned. Consequently, the discharger section of the pulp-lifter was redesigned. First, this paper outlines the modeling in laboratory scale studies and plant scale studies leading up to the discharger design. Next, the discharge flow in seven different published mill surveys is predicted with computational fluid dynamics (CFD) methodology shown here. Finally, Mont-Wright mill circuit performance before and after the discharger redesign is described. The usefulness of fluid flow simulations in the design of pulp-lifters is emphasized.

Jan 1, 2012

By William D. Gallant, Thomas M. Barczak, Carol Tasillo

"This paper describes the results of full-scale testing of several multi-layered wood crib configurations that were tested in the Bureau of Mines mine roof simulator in cooperation with the Cape Breton Coal Research Laboratory and Cape Breton Development Corporation of Sydney, Nova Scotia. Nine different crib configurations currently being used as wood packwall supports for advancing longwall applications in Canada were evaluated. Configuration parameters understudy included the aspect ratio (height-to-width relationship) and percentage of solid material used in the crib construction. Test results and generalized wood crib behaviour are discussed in detail. Recommendations are made concerning crib constructions to maximize strength and stability. A cost benefit analysis of multi-layered wood crib configurations is made. A comparison of laboratory results and underground observations of several wood packwall supports in the Sydney coalfield suggest in situ load capacity is less than that measured in laboratory testing. Reasons for the apparent decrease of in situ load bearing capability are described.IntroductionA cooperative effort was undertaken by the U.S. Bureau of Mines with the Cape Breton Development Corporation (CBDC) and the Cape Breton Coal Research Laboratory (CBCRL) to evaluate the behaviour of gateside packing materials used in advancing longwall mining applications in the Sydney coalfield. As part of this effort, full-scale tests were conducted on wood packwall supports in the Bureau's 3-million pound (13.3 MN) active load frame.Nine different pack configurations were evaluated as part of this study. The wood packwall supports were multi-layered crib constructions from 6 in. (0.15 m) by 6 in. (0.15 m) cross section timbers using timber s 30 in. (0.75 m) and 60 in. (1.5 m) in length . The percentage of solid material in the crib constructions varied as illustrated in Figures 1 and 2. A summary of crib constructions is provided in Table 1."

Jan 1, 1991

By G. K. Livingstone

"This paper describes mining conditions in the Kaiser surface and underground coal mines in the Sparwood area of southeastern British Columbia. Mining methods are explained, major mining equipment is listed and production rates are given. Reclamation methods and results are described. Data are given on safety organization, safety practices, accident statistics, safety inspections and absenteeism. IntroductionThe coal mines of Kaiser Resources Ltd. are located in the southeast corner of British Columbia. All present mining is in the Sparwood area, where operations began in 1900 with the opening of the Michel underground mines. Production increased rapidly at first, then went through successive periods of depression and prosperity. Following are the highlights. Quantities are in clean, short tons. 1900 1910-Rapid rise in production to a peak of 512,000 tons in 1910.1911-1924-Reduced rate of production, averaging 238,000 tons per year, due to strikes, manpower shortage during World War 1 and post-war depression.1925-1929-Second prosperous era, with production climbing to 383,000 in 1929.1930-1933-Second depression-production falling to 231,000 in 1933.1934-1942-Third era of prosperity-production recovered and new production peak of 908,000 tons reached in 1942 during World War II.1943-1956-Corttinued prosperity, with production averaging 720,000 tons per year.1957-1959-Loss of markets to oil and gas; production dropping to 517,000 tons in 1959.1959-1969-Recovery due to new coal market in Japan; production climbing back to the 900,000-ton level.197D-Present-Jump in production reaching 6.6 million tons in 1975. This was the result of the purchase of the property by Kaiser Steel, who negotiated a large-volume, long-term contract with Japan, built the coal port of Westshore, reduced shipping costs by instituting unit trains, and reduced production costs by investing in large-scale mining machinery and a new preparation plant."

Jan 1, 1980

By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006

By R. Erpelding

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By J. D. Allan

"IntroductionThe purpose of this paper is to present a general picture of the Lynn Lake nickel area of northern Manitoba. The geology of the area will not be discussed in great detail, nor will the mining op; rations presently being conducted. Both subjects will be treated briefly and, in addition, mention will be made of some of the problems encountered in mapping in the area. some of the questions which still remain unanswered, methods of prospecting that have been applied and the future possibilities of the area.For present purposes, the Lynn Lake area will be considered as extending from west of Lynn lake to east of Barrington lake. Thus, more correctly, it should be termed the Lynn Lake-Barrington Lake area. It comprises five 15-minute map-areas, or a total of 800 square miles, in a block 47 miles east-west and 17 miles north-south.Lynn lake itself is about 120 miles north of Sherridon, Manitoba, the closes t rail terminal. The area is part of the Granville Lake sheet which was mapped by the Geological Survey of Canada in 1932, 1933, and 1935, the results being published in Summary Report 1933. Part C, and as Maps 343A and 344A on a scale of four miles to o.ne inch. In 1940, the McVeigh Lake area was mapped by the Geological Survey of Canada on a scale of 1,500 feet to 1 inch and a map was issued in 1945."

Jan 1, 1950

By Jiahao Xu, Namsoo P. Kim, Guikuan Yue

Iron (ferrous ions and ferric ions) plays an important role in the heap leaching of copper sulfide minerals and copper electrowinning. In our previous study, a novel oxidation-reduction potential (ORP) equation only based on the variables of temperature and nominal ferric/ferrous ratio was developed to predict the redox potential of the quaternary H2SO4-Fe2(SO4)3-FeSO4-H2O system, and its applicability was also extended to more complex acidic iron sulfate solutions, especially those generated during the acidic leaching and bioleaching of Printed Circuit Boards (PCBs) to recover copper. In this work, the broader range of applicability of this equation to other complicated acidic iron solutions containing copper ions has been extended and determined. Specifically, synthetic iron-containing solutions with copper ions according to the conditions of industrial electrolyte during copper electrowinning and heap leaching have been used to measure the ORP and test the developed equation. It seems that this equation can still be employed to predict the redox potential of the Fe3+/Fe2+ couple for the simulated solutions under conditions related to copper electrowinning and pregnant leaching solution generated during heap leaching over a wide range of solution concentration, nominal Fe3+/Fe2+ ratio and temperature. It has shown that the prediction and measurement of redox potential is highly useful to estimate and understand the iron chemistry of industrial leaching and electrowinning processes. INTRODUCTION It is well-known that iron (ferric or ferrous) ions are widely involved in the hydrometallurgical production of non-ferrous metals such as Cu, Au and Zn, mainly in the form of acidic iron sulfate solutions. As far as Cu is concerned, in a typical leaching-solvent extraction-electrowinning process, ferric ion plays a central role in the heap leaching process and is reduced to ferrous ions in the pregnant leaching solution. Ferric ion is the most important surrogate oxidant and the dissolved ferric/ferrous couple plays an important catalytic role in accelerating the leaching rate with oxygen as an oxidant (Peters et al., 1986; Schlesinger, King, Sole, & Davenport, 2011). In addition, during the traditional electro-winning process, oxygen is evolved at the anode, and copper is reduced at the cathode. A common idea is that iron in the electrolyte in copper electrowinning cell (with total iron of 1–4.4 g/L) plays an important role in reducing the current efficiency. According to the published results (Winand et al., 1975; Dew et al., 1985; Moats et al., 2009; Khouraibchia et al., 2010), thecurrent efficiency decreases linearly with increasing ferric ion concentration and the energy consumption increase was mainly caused by the decrease in current efficiency.

Jan 1, 2019

By Robert Yobou, Jacques Naho, Benjamin A. Allou, Jacques Carignan, Huan-Zhang Lu, Jayanta Guha, Koffi Pothin

"Résumé - Les seules productions de columbo-tantalite en Côte d'Ivoire sont effectuées dans les éluvions, colluvions et alluvions d'Issia, au Centre-Ouest de la Côte d'Ivoire. Même si un lien direct avec les roches granitiques est suspecté, aucune attention particulière n'a été accordée à l'étude de la minéralisation primaire en relation avec l'évolution de ces granites et des pegmatites associées. Ces granites, qui sont en intrusion dans les roches sédimentaires du Protérozoïque inférieur, comprennent: le granite orienté à deux micas (type Lobo), le granite orienté à muscovite dominante (type Bitapia) et le granite porphyroïde non orienté à muscovite dominante (type Issia). Les résultats de cette étude indiquent que les pegmatites à Nb-Ta-Be-Li sont liées au granite de type Issia. Les observations de terrain et les analyses sur roche totale montrent que: (1) les trois principaux granites de la région sont de type-S et peralumineux dans leur composition, (2) ils ont été formés pendant la période tardi- à post-Éburnéenne, (3) le granite de type Issia fut le dernier à se former.Les pegmatites liées au granite de type Issia ont été classées en quatre types : A- pegmatites stériles; B- pegmatites à Be; C- pegmatites zonées à Nb-Ta-Be; et D- pegmatites zonées à Be-Nb-Ta-Li. Les pegmatites zonées comprennent les zones suivantes: I- zone à aplite; II- zone graphique; III- zone à albite, microcline, béryl et columbo-tantalite; IV- zone à microcline massive; V- zone à quartztourmaline. Ces pegmatites présentent une zone d'altération métasomatique externe.La minéralisation de Ta, Nb, et Be est liée à la zone III des pegmatites de types C et D, la minéralisation de Li est associée aux greisens qui peuvent être observés n'importe où dans les pegmatites de type D. Les données de terrain et de laboratoire indiquent que le granite de type Issia est la roche parentale des pegmatites à éléments rares de la région. Les pegmatites minéralisées sont distribuées seulement autour du granite de type Issia et les patrons des terres rares des granites et ceux des pegmatites à éléments rares sont très similaires. Les analyses de la composition totale montrent un lien génétique entre le granite de type Issia et les pegmatites à éléments rares. Il est suggéré que les pegmatites ont été formées durant le transport et la cristallisation fractionnée du magma. Les éléments rares sont restés dans le liquide résiduel jusqu'à ce que les conditions favorables à leur précipitation soient atteintes.L'établissement de ce lien génétique ouvre des voies pour des nouvelles stratégies d'exploration."

Jan 1, 2005