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By Ginger Gibson

As an occupational culture, mining comes with its own set of rules, agendas and values. Yet mines often also operate in the traditional territories of indigenous communities, with whom specific agreements are negotiated that commit to respect culture, economy and environment. Mines in these locations employ extremely diverse workforces whose value systems often come into conflict in on-the-job relationships. Adaptation of individual worker attitudes and industrial operating culture thus both need to occur if there is to be the negotiation of a workable relationship. This paper will discuss ways that NWT diamond mines have adapted to their workforce, to ensure that rights and cultures of their diverse workforce can be respected. Historically, the concept of culture has been dealt with solely through the forum of ?cross-cultural? workshops. Gibson presents a model of a new type of ?cultural-engagement? workshop based on the top ten cross-cultural conflicts that actually arise at a remote mine-site. This model helps managers, team leaders, and workers to tackle in-mine conflicts that arise based on differing value systems of aboriginal and non-aboriginal workers and management. In addition, Gibson suggests that the concept of culture must be more rigorously applied throughout the mine structure and not discussed only in the forum of the cross-cultural workshop.

May 1, 2007

By Charles A. Taschereau

Burkina Faso ? Formerly known as Upper Volta; Country is landlocked and dry (Sahel sub-Sahara zone); ? Among poorest countries in the World, according to the United Nations Human Development Index (in 2005, 178 out of 179 countries; in 2009 173 out of 179); ? Population 13,9 Millions; Life expectancy is 51.4 years; Fertility rate 6.47 children/woman; Average age is16 years; literacy rate 23.6% and GDP per capita $1,213; ? French is official language; Politically stable country; very low criminality rate; corruption level low. Multiparty elections since early 90s; Legal and political systembased on French civil law system; ? Country just opened a few years ago to International mining companies, with a new mining code and investment code; ? No experienced labour; ? All new codes and laws; no established practices; Very limited economic development, mining is already main product of exportation and the country will become with Essakane a mineral economy (over 50% of total exports from mineral sources);

May 1, 2010

By T. M. Waterland

A GREAT deal of work has been done at Britannia during the past three years in improving and standardizing rounds for development headings, and the results obtained have been very gratifying. The round which has recently been adopted as a standard for all drifts and cross-cuts has, in some instances, doubled the average length of break formerly obtained. It has also increased the footage of advance per labour shift and reduced explosives' consumption. At the present time, with a shortage of skilled labour, more control is necessar7 in directing the drilling of rounds. The use of a standard round has been o great assistance to the foremen and shiftbosses. NATURE OF GROUND Most of the ground encountered consists of a moderately silicified chlorite schist, known locally as G.M.S (green-mottled schist). It cannot be termed hard ground, because a three and one-half inch Leyner will drill at an average rate of twelve inches per minute. Due to the abrasive nature of the ground, the gauge of the steel wears rapidly and in most cases one set of steel is needed for each hole. The ground is not 'free breaking and holes must be spaced correctly to obtain a maximum break. DEVELOPMENT OF STANDARD ROUND FOR THREE-SHIFT OPERATION Late in 1940, a development programme was started involving 7,000 feet of drifting, 6 ft. By 7 1/2 ft. In cross-section, in two headings. Plans were drawn up to advance the headings on three shifts. Equipment used in the headings was as follows: D.A.35 Leyner?machines, Eimco Model 12B mucking machines, nine one-ton end-dump cars, one Mancha Little Trammer on the longest heading, 20-pound rail, 4-in. 15 compressed-air line, 15-in. Fan pipe connected to 5 h. P. Coppus fan. Diamond-drill cross-cuts, 16 feet in length, were cut every 250 feet. Switches were installed at these cross-cuts and they served as passing points for the cars. One siding seventy feet in length was cut in each heading at approximately the half-way point. The cycle of operations planned was to muck out, drill, and blast each shift. Previous performance in this type of ground indicated that a daily advance of 12 feet to 14 feet might be made. However, if a better type of round could be developed, an increased daily advance would be possible. A study of the time available for each operation in a net working shift of six and one-half hours indicated that the maximum depth of round that could be mucked, drilled, and blasted each shift would be six and one-half feet. When this maximum depth was decided upon, the next problem was to develop a satisfactory round. Due to ventilation difficulties and to the short net working shift, the whole round had to be blasted at one time. In other words, no blasting of the cut-holes could be done.

Jan 1, 1942

Operating CIP/CIL gold recovery plants in the arid regions of Western Australia face unique challenges due to water and ore quality issues. The presence of cations of Mg, Fe and Cu metals in water supplies and leached sulphide ores can have considerable effect on plant consumption of lime and cyanide, due to pH buffering and complexation effects. Reagent costs are critical to many of these operations. In this paper, computational modelling is used to analyse a number of process options to mitigate such issues. This requires careful consideration of the chemistry of the process system, and the ability to predict accurately the response of speciation and precipitation reactions to changing process conditions. The Mg-Fe-Cu-CN-H20 system is specifically modelled in this application. The Gibbs Free Energy Minimisation thermodynamic framework has been selected to model equilibrium phenomena. Furthermore, this approach has been extended to the process flowsheet level, incorporating multiple unit operations and recycle streams in a steady-state mass balance model. The Gibbs equilibrium composition module of HSC Chemistry software has been successfully integrated into the commercial flowsheeting package SysCAD. Consideration of the Gibbs Energy Minimisation capabilities of other flowsheeting packages has also been given. This approach has been successful in simulating the aqueous process chemistry typical of such plants. It has resulted in a predictive capability where equilibrium states respond appropriately to process changes. Potential cost savings may be identified by examining alternative process conditions to minimise overall reagent consumption.This methodology may be extended to other hydrometallurgical plants where issues of solution ideality, temperature and other equilibrium processes are sufficiently understood.

Jan 1, 2005

By Edouard Asselin, Tasawar Javed

The precipitation of hematite from ferric sulphate - cupric sulphate - lithium chloride acidic solutions was studied in a batch reactor. The effect of several variables on the extent of hematite precipitation as well as on its crystallinity and purity was investigated. The variables studied include: initial ferric concentration (1.5 - 30 g/L), retention time (0 - 12 h), initial sulphuric acid concentration (0 - 30 g/L), temperature (150 - 220 °C) and chloride concentration (0 - 25 g/L). The results show that hematite is preferentially precipitated at lower initial iron concentrations. Longer retention times increased the fraction of hematite in the precipitates but did not affect its crystallinity to a significant extent. On the other hand, higher temperatures increased the purity and crystallinity of the hematite. At lower acid concentrations hematite and goethite were precipitated. However, only hematite was precipitated when the initial acid concentration was > 12.5 g/L. Better crystalline hematite was formed at lower acidities. Increasing chloride concentration increased the amount of hematite and decreased the amount of iron sulphate hydroxide phases, but did not affect the crystallinity of the hematite.

Jan 1, 2015

By Constantin Pitis, Paul Slatter, Behnam Pirouz, Laura Contasti, Markus Zeller, Sadegh Javadi

"The centrifugal slurry pumps feeding cyclones are critical components used in the grinding process. It is well known that for this type of pumps the performance degradation is very intense. To minimize downtime a complete stand-by slurry pump is always installed in a parallel circuit. The replacement decision of slurry pumps is sometimes set on specific periods of time that are empirically determined, based on previous experience; unless a pump failure triggers the second (standby) pump. Given the significant energy costs in the grinding process and a desire to increase competitiveness, engineers and scientists started research in this field while manufacturers also took actions in order to improve pumps reliability and performance. The lack of standardization regarding the methods used to benchmark and evaluate the energy performances of cyclone slurry pump systems in the mining industry makes it difficult for an enterprise to take informed decisions concerning the replacement or optimization of its process based on energy benchmarking of such slurry pump systems. This paper proposes a new methodology of benchmarking slurry pump performances using a new concept of Benchmark Energy factor (BEF) based on Mathematical Model Benchmarking. The concept of BEF has been proven successful in other industries. A new standard addressing the guidelines for benchmarking the energy performance of slurry pumps for cyclones was proposed within the Canadian Standards Association. This standard will provide a unified and consistent methodology for performing measurement activities with the ability to measure and verify the system energy performance in the field through the BEF approach. Practical examples based on the new concept are presented with comments."

Jan 1, 2017

By T L. Horsley

The change from a seasonal to a continuous mining operation at Cassiar has been accompanied by increased emphasis on the preventive maintenance of mining equipment. This paper describes how equipment maintenance is organized, and details some maintenance practices that have proved advantageous to the Cassier operation. Introduction Cassiar Asbestos Corporation Limited is currenly carrying out an open-pit mining operation at the 6,300-foot elevation on McDame mountain in northern B. C. A 6-mile road connects the mine to the mill and plantsite at the 3,500-foot elevation. Ore concentrate is delivered to the mill via a 3llz-mile tramline. Naturally level ground does not exist in the mine area. The weather is typical of mountainous regions, exhibiting wide and rapid variations in temperature. It is generally wet and windy at the mine elevation, and a heavy snowfall is common. The rock types vary from a soft, sheared serpentine to massive serpentine, to medium-hard, friable sediments to hard, blocky volcanic flows.

Jan 1, 1964

By L. W. F. Mackenzie

The influence of rolling temperature and annealing on the recrystallization and texture of magnesium AZ31 has been investigated. 100x125x6 mm AZ31 plate was cast in a permanent steel mould and then homogenized at 380°C. As-cast and homogenized microstructures were then characterized, and 35x30x6 mm specimens were machined from the homogenized material. Specimens were rolled up to 40% at temperatures between 25 and 350°C; selected specimens were subsequently annealed at 400°C. Following rolling, the microstructures were compared. The influence of rolling temperature on as-rolled texture has been demonstrated, and texture evolution has been evaluated following annealing. The recrystallization behavior has also been characterized. Optical microscopy, scanning electron microscopy and electron backscattered diffraction (EBSD) were used to characterize the microstructures of the alloys. X-ray texture analysis was used to investigate the texture in as-rolled and annealed specimens.

Jan 1, 2006

By Michael Jerome Wallace

"This paper refers to the wet open circuit ball mil ls in operation at Sidbec-Normines'5 pelletizing plant at Port-Cartier, Quebec, which commenced operations in late November· 1977. Prior to detailing our experiences in the grinding area at Port-Cartier, a general description of the total Sidbec-Normines project is outlined.HI STORYSidbec-Normines was incorporated in 1976 to develop the Fire-Lake - Port-Cartier iron ore mining, concentrating and pelletizing project. The primary objective of Sidbec-Normines is to produce 6mi11 ion tons per year of oxide pellets, of which 3 mi 11 ion tons per year are of a low silica grade suitable for direct reduction purposes. The participants in the project are Sidbec, the Quebec Government steel producer, British Steel Corporation (lnt'l) and the Quebec Cartier Mining Company. Equity interest is held in the company by the participants in the proportions of 50.1%, 41.6:7% and 8.23%, respectively."

Jan 1, 1979

By V. V. Severov, Z. Lafhaj

The flotation separation of salt type calcium minerals is problematic, due to the similarities in their formation properties and the same active Ca2+ related site for interaction with anionic collectors and similar physicochemical characteristics such as solubility, point of zero charge, surface speciation, Ca-site density. The work was performed to achieve effective and selective separation of the calcium-minerals using pure minerals samples: four calcite, two fluorite, and two apatite samples. The effect of pure and mixing anionic collectors such as oleic and linoleic acid to different ratio (2:1; 1:1; 1:2) as well as the role of nonionic collectors on the selective separation of Ca minerals were studied. All flotation tests were performed in self-aspirated flotation cell. The results obtained with the blend of anionic collectors with the molar ratio of 2:1 show a separation between apatite and calcite at pH 5 and a ratio 1:2 at pH 9. The enhancing of separation contrast using the sodium silicate as a depressant for calcite and apatite is also examined as a function of oleate/linoleate ratio. Additionally, this paper discusses the enhancing of the selective separation of Ca minerals when anionic collectors were blended with nonionic reagents. The surface reactions in aqueous mineral suspensions and the adsorption of anionic collectors blended with nonionic reagents were studied by FTIR spectroscopy. An unexpected synergistic effect was observed for some ratios between anionic and nonionic reagents. The mixture of fatty acids and nonionic reagent showed very high flotation efficiency in comparison with fatty acid alone for the flotation of an igneous low-grade phosphate ore.

Jan 1, 2016

By Yuki Soma, Tsutomu Ogawa, Jae Hyung Hong, Toshihiro Nagato

The Saganoseki flash furnace was built in 1973. The steel frames of the flash furnace were designed to absorb the expansion of refractories and contain expansion-absorbing materials between their frames and the skin plate. Expansion and deformation resulted in the furnace settler because of the repeated increase and decrease in temperature from more than 30 maintenance shutdowns. Preliminary investigations were conducted to confirm the condition of the settler, and it was found that partial cracks accompanied the expansion in the lower layer of the refractories. As a result, the risk of molten-matte leakage increased. Based on the above investigation, it was decided that the entire settler should be replaced by introducing a spring-displacement structure that was capable of maintaining the furnace integrity over an extended period. The difficult redesign and rebuilding of the Saganoseki flash furnace was accomplished successfully and safely in 76 days from September to December 2017, as planned. Because of various redesigns, the furnace was changed to a flash-smelting furnace that can withstand higher thermal loads based on recent trends of copper concentrate with increased sulfur and reduced copper. The new furnace is operating smoothly at present. INTRODUCTION The flash-smelting furnace of Pan Pacific Copper Co., Ltd. Saganoseki Smelting & Refinary commenced operation in 1973, with an original designed feeding rate of 71 t/h. As a result of facility remodeling and operational improvements, shown in Figure 1, the feeding rate was increased to 215 t/h in recent years. After more than 40 years of operation, the original settler in the melt holding section of the flash furnace underwent significant expansion and deformation.

Jan 1, 2019

By Rufus L. Chaney

A new technology is available to the Ni mining and remediation community to “phytomine” Ni from mineralized or contaminated soils using rare plants which hyperaccumulate Ni to over 1% of shoot dry matter. Research has identified useful plant species, and even bred improved cultivars of Alyssum murale and Alyssum corsicum for commercial phytomining in temperate regions. All agronomic practices (fertilization, soil amendments, planting and harvest methods) needed for economic phytomining were identified to attain high yields and high Ni concentration in the biomass. In tropical regions, other species are available such as Phyllanthus which accumulate over 1% Ni in dry shoots. These species are perennial so they regrow after annual cutting to harvest biomass. Expiration of our patents on the technology opens the opportunity for other organizations which control Ni rich natural soils or contaminated soils requiring remediation to commercialize the technologies. Inexpensive methods to remediate/revitalize Ni contaminated phytotoxic soils using agronomic approaches have also been developed and demonstrated at Port Colborne, Ontario, but adoption is delayed until formal agreements with government are completed. These new simple remediation and profitable phytomining technologies can obtain Ni from soils which contain Ni well below levels considered economic for current mining technologies, and the plants biopurify the Ni so it is easy to recover Ni metal from plant ash by pyrometallurgical or hydrometallurgical technologies. Although increasing pH decreases the solubility of Ni in all soils, raising pH increases Ni accumulation by Alyssum species. Hence usual chemical extraction methods for phytoavailable soil metals such as the DTPA- or NH4-OAc-extraction cannot predict Ni accumulation by Alyssum species.

Jan 1, 2016

By Jian Li, Robbie McDonald, David Robinson

"The pressure oxidation of sulfide minerals at temperatures above 200°C enables the extraction of base metals, improves the extractability of gold from refractory ores, enables solubilisation of PGEs and can be used to hydrothermally upgrade base metal-containing feeds. Fundamental studies reveal that the solution chemistry (and mineralogy of the solids) during pressure oxidation can be manipulated with outcomes that include (1) increased leaching rates, (2) lower oxygen requirements and (3) the formation of chemically more stable residues. This paper presents examples describing how these outcomes might be achieved based upon fundamental investigations.INTRODUCTION The application of pressure oxidation to the processing of gold ores and concentrates dates back several decades and continues to be the process of choice at operations such as Pueblo Viejo (pyritic gold) which host the largest autoclave of its kind in the world (Barrick Gold Corporation, 2016). Commercial application to the processing of base metals and PGMs resides with long established processes such as the Sherritt process, ore specific applications such as by Noril’sk, at Sepon etc. or has not proceeded to date beyond pilot scale testing (e.g. Phelps Dodge, CESL, Activox, Platsol). Recently there has been significant interest in hydrothermal upgrading options for concentrates including the NONOX and Toowong processes (Rohner et al., 2016; Weidenbach et al., 2016). The latter options suggest directions where sound knowledge of the underlying fundamentals enables novel outcomes and efficiencies to be obtained. It comes as no surprise that investigations similar to those underpinning these developing processes can be traced back several decades. It is not the subject of this paper to provide a historical perspective of the relevant autoclave chemistries but rather, to present some potential opportunities suggested by studies in our laboratories. Topics to be discussed in this paper include (1) control of metal extraction rates, (2) control of iron-residue composition and (3) control of sulfur oxidation and hence acid generation and oxygen requirements. The work described will focus upon the pressure oxidation of a nickel concentrate."

Jan 1, 2017

By Sandeep Singh Sandhu, Karanvir Singh Ghuman, Manjit Singh

"Cobalt based super alloy stellite 6 was weld cladded on AISI 304 L stainless steel using SMAW process in order to improve the wear resistance for tyre crusher blades. Microstructure characterization and micro hardness testing was performed on stellite 6 cladding. The suitable parameters viz. 80 Amp current with arc weaving technique was selected by performing bead on plate experiment were further used for depositing multipass multilayer cladding to achieve full filler chemistry at the top surface. Further GTAW process was used for re-melting the top surface of the cladding. Comparative evaluation of the claddings showed that TIG re-melting resulted in increased microhardness and wear resistance in comparison to as cladded specimens even with lesser deposition of material. It was observed that TIG re-melting improved the hardness from 603 HV0.5 kg to 712 HV0.5 kg. Micro structures of stellite 6 contained cobalt solid solution matrix along with inter dendrite chromium carbides which resulted in the increased micro hardness values. Pin on disc abrasion tests were carried out at room temperature and the worn out surfaces were characterized using SEM and EDS.INTRODUCTIONThe crusher blades are used in many industries for crushing various types of material and its wider applications in tyre rubber crushing mills, metal-powder crushers industries etc. Most of the crusher blades are damaged by the wear and impact loading conditions. It is because of metal to metal abrasion and the temperature also plays a vital role in blunting the cutting edges of these blades. The wear is the major cause which leads to loss of material and thus the productivity that can never be recovered (Kotechi et al., 1992). The wear can be reduced by coating of various super alloys which could reduce the behavior of metal degradation even in aggressive environments. Cladding of cheaper low alloyed material with expensive superalloys to enhance the performance of components at low cost has been investigated by many scholars (Deng et al., 2010, Kennametal, 2007, Lolla et al., 2014, Singhet al., 2014, J.N et al., 2003, Ramkumar et al., 2012). Many researchers have reported that cladding is an application of build-up deposits of specialized alloys to resist abrasion, high temperature corrosion and impact loadings. Cladding is used for providing required mechanical strength properties as well as inhibition of oxidation and other corrosive degradation. Coatings are used to protect the heat affected areas like tubes of fluidized bed combustor etc. (Kirchbner et al., 2008, Wang et al., 1994, Hocking et al., 1993, Ananthapadmanabhan et al., 1991, Staia et al., 2001). Coating techniques are widely used for the protection of turbine engine and boiler tubes against high temperature corrosion attack, power generation equipment, chemical process equipment, aircraft engines, pulp and paper processing equipment, bridges, rollers and concrete reinforcements, orthopedics and dental, land-based and marine turbines, ships. Coatings of stellite 6 are widely used in steam turbine blades and boiler tubes for power generation because of an excellent combination of impact, wear and other properties. It can maintain its properties even at high temperature and in harsh environments (Kobayashiet al., 1999, Alam et al., 2009, Munehru et al., 2009). The loading and unloading conditions experienced by the material may induce the surface cracks which lead to its breakage and leaving large pits in the surface (Meng et al., 1995). Many researchers have reported that the properties of cladded layers can be increased by various techniques such as controlling the current variations, dilution, heat input, laser and other re-melting processes, addition of special alloying elements, speed of weldingetc(C.M Anaet al., 2002, Kumaret al., 1999, Luo et al., 2012, et al., Madadi et al., 2011, Shin et al., 2003, Kuzucu et al., 1997, Sudha et al., 2008, Sawant et al., 2017, Houdkova et al., 2016, Ciubo"

Jan 1, 2017

By Alain Tshilombo, Vijay Reddy, Chowdary Meenavilli, Kelvin Buban, Cory Kosinski, Sriraj Meenavilli, Siddhartha Tirumalaraju

The use of artificial intelligence (AI) for process optimization is expected to play an increasingly important role in the future of the mining industry. The objective of AI is to develop a data driven soft (virtual) sensor using historical data that can estimate unmeasurable characteristics of the process and provide appropriate recommendations during operation to optimize the process through continuous learning. The application of AI to a hydrometallurgical process was evaluated by Sherritt Technologies in coordination with NTWIST. Historical operating data obtained from the Ambatovy facility’s High Pressure Acid Leach (HPAL) circuit was used to develop models to predict autoclave discharge parameters based on operating conditions and ore mineralogy. The prediction models were developed in such a way to also allow the user to simulate and test different operating conditions. A second set of models (AI model) were developed based on the prediction models, economic data and operating constraints for a given process unit to identify optimal reagent and steam dosages across the HPAL circuit. The development of these models was significantly complex due to the dynamic and interactive nature of the HPAL process. Despite the complexity of the models, the models were able to predict, with accuracy, the relationship between ore composition, leach autoclaves retention time, acid addition and steam addition with metal extractions as well as levels of impurities in the autoclave discharge slurry. The study showed that AI has the potential to improve the overall operation of a facility through providing tools to assist with training, troubleshooting and process optimization. INTRODUCTION The Ambatovy project, located in Madagascar, is one of the world’s largest nickel and cobalt mining and processing operation, with a design capacity of 60.000 tonnes of nickel and 5,600 tonnes of cobalt per year (Collins et al., 2016). Commissioning and start-up of the Ambatovy mine and plant facilities were completed in 2012, with acid first introduced to the ore leach in March 2012. Commercial production (defined as 70% of design capacity) was achieved in January 2014 and the production level required to achieve financial completion (90% of design capacity for 90 days) was achieved in March 2015 (Valle et al., 2016). Figure 1 shows a simplified flowsheet of the hydrometallurgical pressure acid leach (PAL) process employed by Ambatovy.

Jan 1, 2019

By Janice Zinck, Maziar E. Sauber

"To counter the recent uncertainty in the rare earths market, diversify the supply source, and help meet the future demand in this sector Canada initiated development of several new rare earth deposits. In the past few years, a number of various studies on rare earths plant design have taken place mainly covering process development, process selection, and flowsheet design. The purpose of this paper is to provide an overview of known domestic and potential resources and reserves of rare earths and their status quo with a focus on the metallurgical processes using the information available in the public domain. Plant designs currently under consideration in Canada are reviewed and evaluated. An outline of the areas of opportunity for selective innovation and technology development in the rare earths flowsheet development and the associated risks and rewards is provided.INTRODUCTIONThe rare earth elements (REE) have a very small annual market, but they are categorized as very strategic metals vital to global economic growth due to their indispensability to the development of modern defence system, green technologies and electronic applications. The International Union of Applied and Pure Chemistry (IUPAC) defines the REE as the 15 elements on the lanthanide series on periodic table of elements, plus yttrium and scandium. REE are classified as light rare earth elements (LREE; La to Gd), and heavy rare earth elements (HREE; Tb to Lu). Physical properties and chemical reactivity of yttrium is similar to those of HREE, thus it is categorized as such. Properties of scandium are not similar enough to classify it as either a LREE or HREE (Weng et al., 2015; Sappin & Beaudoin, 2015). However, the mining industry does not always abide to this definitive classification of the split between LREE and HREE. Therefore, in a comparative study of projects, there is a need to pay attention to how the elements are classified."

Jan 1, 2016

By N. E. Izatt

Molecular recognition technology (MRT) has a wide range of applications in the hydrometallurgical and chemical processing industries for the selective removal of iron as well as various other impurities from a variety of streams, including aqueous solutions through a wide pH range, as well as organic solutions. An example of a commercial application is provided for the removal of iron from an aluminum chlorohydrate stream. In this example, MRT has a selectivity for iron relative to aluminum which is significantly higher than that of ion exchange resins. A discussion of MRT capabilities for other impurities and streams is also provided.

Jan 1, 2006

The SART (sulfidisation, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide from each other in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation I reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulfide to copper molar ratio of around 0.56, a pH of 4, and a minimised cyanide to copper molar ratio. The experiments also showed that thickening time may have drastic impacts on SART performance.

Jan 1, 2011

By M. Takebayashi, K. Takenaka, S. Matsubara, T. Yoneyama

The cathode production of Toyo Smelter and Refinery, owned by Sumitomo Metal Mining Co., Ltd. reached 450,000 tons per year in 2016 with three tank houses. Niihama tank house commenced operations in 1919 with conventional sheet cathode technology. Approximately 100 years of operation experience and the technical development enabled that the current density of Niihama tank house and the Toyo tank house #1 increased to 320 A/m2. These operation techniques were utilized at the Toyo tank house #2 which started in 2005, and its current density reached up to 350 A/m2 with permanent cathode technology. In order to achieve high current efficiency under condition of 350 A/m2 operation at Toyo tank house #2, continued efforts had been made to verticality of anodes and permanent cathodes. To improve verticality of anodes and cathodes, reduction of short circuit ratio by changing the shape of the anode, optimizing the anode pressing machine and off-line process for rectifying the distortion of permanent cathodes was carried out. In addition, concentration control of electrolyte and expansion of Ni removing ability from the electrolyte prevented passivation. Finally, more than 96% of the current efficiency was stably confirmed. INTRODUCTION Today, Toyo Smelter and Refinery of Sumitomo Metal Mining operates three tank houses in Japan, namely, Toyo tank house #1, Toyo tank house #2, and Niihama tank house with a total capacity of 450,000 metric tons of copper cathodes. Figure 1 shows the trend of cathode copper production and the current density at three tank houses over the last 10 years. Cathode production by Toyo Smelter and Refinery reached 450,000 tons per year in 2016 with three tank houses.

Jan 1, 2019

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005