Search Documents

By A. F. Banfield

"IntroductionELEMENTAL sulphur occurs in three types of deposits: in salt domes in the Gulf Coast region of the United States and Mexico, from which over 90 per cent of world native-sulphur production is obtained; in sedimentary deposits such as those in Sicily, which are thought by some authorities to contain the largest world reserves of elemental sulphur; and as surface deposits, associated now or in the past with some phase of vulcanism, the type which bas the greatest world-wide distribution.Deposits of the volcanic type are the subject of this paper.From antiquity until the successful development of the sulphur-bearing salt domes at the beginning of this century, important sulphur production for local needs was obtained from volcanic deposits in many parts of the world. Due to technical and economic factors, however, producers could not compete in price with sulphur from salt domes. •The result has been that, except in Japan and Chile, little sulphur was produced from volcanic deposits from about 1910 until the start of the Korean war in 1950. Shortly after the outbreak of the Korean war, an acute world sulphur shortage developed and prices skyrocketed in many countries up to several hundred dollars a ton. Interest in volcanic deposits was renewed and exploitation of many was undertaken. Few of these operations have been successful, mostly due to inability of management to solve technical problems.While important volcanic deposits of elemental sulphur have not been reported ( 1) in Canada, and it is doubtful that any will be found, data presented in this paper may be of interest to students of ore genesis.This paper is based on field examination of numerous deposits of the volcanic type in North and South America."

Jan 1, 1954

By C. F. Chung, F. P. Agterberg

"Prediction of a variable sulphur content in Cape Breton seams is important for planning the production of a highgrade metallurgical coal. Two extrapolation methods (Kriging and a version of Universal Kriging) to predict sulphur content in blocks of coal before mining are presented and applied to the New Lingan Mine reserves in the Harbour seam. The uncertainty of the predicted values is expressed by using standard deviations. Some statistical results for the Phalen seam, which occurs about 400 ft below the Harbour seam, are presented for comparison. The two mathematical models consist of two sets of equations which have been used in computer algorithms. Some limitations of the present approach and possibilities for further statistical work are indicated."

Jan 1, 1973

By R. Barbaroux, J. -M. Lalancette, D. Lemieux, K. Nasrallah, G. Garcia Curiel

"Arsenic released from the lithosphere by mining and metallurgical activities is a growing global environmental concern. Dundee sustainable technologies (“DST”) has developed a processing technology to sequester arsenic by means of vitrification. This method can effectively sequester arsenic trioxide without the need to oxidize from As (III) to As (V). Arsenic oxide is incorporated within a silica glass matrix that is stable as per the Toxicity Leaching Characteristic Procedure (“TCLP”) or EPA Method 1311. In this paper, the conventional treatment of arsenopyrite, commonly referred to as “two-stage roasting”, is discussed along with the options traditionally available for the remediation of the arsenic trioxide by-product. The drawbacks limiting the adoption of this processing flowsheet are discussed and a new processing route is presented for the treatment of arsenopyrite. This new flowsheet outputs an auriferous aluminosilicate highly amenable to gold extraction (> 96%) while eliminating the sulfur dioxide production associated with the second-stage roasting of pyrrhotite and ultimately uses vitrification as a definitive sequestration solution to arsenic trioxide.INTRODUCTION Faced with the depletion of conventional gold ores, the gold industry has witnessed a trend towards the exploitation of arsenical deposits. Arsenic is a naturally occurring metalloid often found in mineralogical association with gold. Many northern Canadian regions, from the Northwest Territories to Northern Manitoba, Northern Ontario and the Abitibi region are facing significant arsenic challenges. Projects are deemed uneconomic or prevented from going into operations due to the costs associated with handling arsenic material and there are penalties imposed to complex concentrates by smelters. In addition, Canadian mining operations have left an environmental legacy of gold tailings with grades typically of up to 9 grams per tonne with no processing solution as they also contain significant arsenic contamination at grades of up to 20%. Table 1 presents a list of Canadian deposits known to contain arsenic."

Jan 1, 2017

By D. Hodouin

Jan 1, 1978

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013

By P. Nos, L. Kolbeinsen, M. W. Kennedy, A. Filzwieser, R. T. Jones, A. MacRae

Modern furnace designs often incorporate extensive use of cooled elements to achieve long campaign lives at high operating intensities. However, contact between water and high temperature fluids can result in powerful Boiling Liquid Expanding Vapour Explosions (BLEVEs). Therefore cooling such elements with water carries inherent risks when used under slag and particularly below molten metal or matte. Alternative cooling media exist that can reduce or eliminate the risk of BLEVEs. These media are analysed and discussed in the context of deeply cooled furnace elements. Important factors in selecting alternative coolants are explored including: critical heat flux, thermal limits, toxicity, flammability, unit cost, etc. Key cooling system design criteria are reviewed in the context of both traditional and alternative coolants. Results of Computational Fluid Dynamics are presented for an example tap-block cooler design using a number of selected coolants. Research needs to advance the safe use of alternative coolants are presented.

Jan 1, 2015

By O. G. Olvera

"Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Typical cyanide operations show poor performance and require oxidative pretreatments to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. This work focuses on evaluating the effect of the addition of a carbon resin as a sulfur collector on the oxidation of different arsenopyrite concentrates under atmospheric tank leaching (ATL) conditions. The addition of the resin improved the oxidation of sulfides and favored the formation of elemental sulfur over the generation of sulfate. The use of AF5 in ATL resulted in higher gold recoveries under standard cyanide carbon-in-leach and thiosulfate leaching.INTRODUCTION Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Gold is not readily accessible to solutions in these types of ores and typical cyanide operations show poor performance, thus making the use of oxidative pretreatments a requirement to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. The use of carbonaceous materials to enhance the dissolution of sulfides is not novel, and leaching additives such as coal, activated carbon and carbon powder have been considered for the improvement of bioleaching, atmospheric leaching, and pressure oxidation leaching processes. However, this type of technology has been focused mainly on the recovery of copper from copper concentrates containing chalcopyrite with less attention paid to other sulfides."

Jan 1, 2017

By A. F. Sirianni

The Peace River iron ore deposit represents the sole source of raw material for an integrated steel industry in Alberta. The ore has proved refractory to beneficiation by a number of techniques. A selective oil-phase agglomeration technique is described. Medium-grade concentrates, analyzing 48-53% Fe and 10-14% SiO2 were obtained with recoveries of about 75% of the total iron. These results appear to represent the optimum possible for this ore body.

Jan 1, 1977

By Hyung Sup Choi

The preparation of high-purity zirconyl compounds was studied in order to develop an economical process for obtaining pure zirconium via the caustic fritting of zircon sand. The direct dissolution of caustic frits with concentrated hydrochloric or nitric acid at 80c. followed by the addition of a small amount of acidified gelatin, gave high-purity zirconyl chloride or nitrate. The addition of a small amount of gelatin caused a mutual flocculation between colloidal silica and gelatin. The precipitation of this silica floc markedly lowered the content of silica in the product. The silica content of the compounds (or solution) so produced, generally less than 100 ppm., was sufficiently low for tributyl phosphate extraction for nitrate solutions. It was found that the degree of purification de-pends not only on the procedures employed but also on the nature of the frit itself. Silica was more effectively eliminated from the fritted product produced at higher temperatures, and less silica was present in the com-pound prepared from the frit produced in a shorter heating time. In order to ascertain the nature of the

Jan 1, 1965

"The success or failure of coal mining operations in Western Canada may hinge on the ability to extract thick coal under a variety of geological and mining circumstances and conditions. The paper presents, in who-where, what- how pattern, the current status of undergrounud mining of thick coal seams based on a review of foreign technical literature. The underground production of coal from what are considered to be thick seams is over 300 million tons per year. Methods of mining have evolved, through years of trials and tribulations, capable of meeting the requirements of a modern mine: high bulk outputs from a limited number of mining faces by concentrating in the horizontal (mechanization) and in the vertical (increased working lift)."

Jan 1, 1972

By S. W. Marcuson, P. J. Mackey

The Canadian non-ferrous mining and metallurgical industry has made great strides in environmental protection during the past half century. The path taken by the copper-nickel smelting industry in reaching today’s level is traced in this paper. Following the practice at early copper smelters in Wales and in the US, Canadian smelters originally used tall stacks to disperse furnace of-gases. This was the normal mode of operation and was accepted by society and by Government. Gradually, Government regulations required fixation of sulphur dioxide emissions and Canadian companies responded with significant technical developments to achieve this result. The initial development in Canada of the first new technologies such as the Cominco Flash Suspension Roaster and the Freeman Flash Smelting Process - both representing early versions of the modern established flash smelting technologies - and then later technologies such as the Inco Flash Smelting Process and the Noranda Process, both of which continue to this day, are discussed in this paper in terms of their contributions to the development of environmentally friendly plants. The evolution of these and other technologies is also discussed. Some comments regarding how the industry will face the future are also included.

Jan 1, 2015

By H. C. L. Reemeyer

"The mining industry faces increasing economic, environmental and social challenges, as easier deposits deplete and ores become more difficult to mine and process; head grades decline; projects migrate to increasingly remote and difficult geographies; and the industry faces more stringent environmental and social standards. While these factors increase costs and risks, they also present opportunities for a more integrated approach to mining, processing, materials handling and waste management. Two key areas of risk are in tailings and water management. As mining and processing tonnage rates continue to increase, the disturbance footprints, water and energy consumption and scale of tailings storage facilities also rise. These factors can be mitigated by more selective mining, ore sorting and pre-concentration, and more intensive tailings dewatering. Such alternatives must be considered in conjunction with the selection of mining method, metallurgical flowsheets, major equipment selection, and key process design criteria. For example, increasing the grind size of a concentrator reduces energy consumption and eases tailings dewatering, but may cause challenges with metal recovery. Emerging technologies will be reviewed, and economic and environmental trade-offs for eco-efficient alternatives will be presented for metal sulfide mines.INTRODUCTION The metals mining industry faces significant challenges that can affect its financial viability and social license to operate. There has been a consistent decline in ore grades and a relentless push towards larger operations to capture perceived economies of scale. With these larger operations, the environmental footprint of mines has increased. Water and energy consumption, and resulting GHG emissions have also risen. In recent years, two issues have raised special concerns for stakeholders and companies: • Water scarcity, particularly in drier regions of the world such as Northern Chile, SW USA, Southern Africa and Australia • Tailings risks, following the high-profile failures of the Fundao tailings dam in Minas Gerais, Brazil in 2015 and the Mount Polley tailings dam in BC, Canada in 2014"

Jan 1, 2017

By Guoqiang Lan, Jun Song, Bin Ouyang

Rare-earth pyrochlores, commonly exhibiting anomalously low lattice thermal conductivities, are considered as promising topcoat materials for thermal barrier coatings. However the structural origin underlying their low thermal conductivities remain unclear. In the present study, we investigated the phonon properties of a group of RE pyrochlores, Ln2Zr2O7 (Ln = La, Nd, Sm, Gd) employing density functional theory and quasi harmonic approximation. Through the relaxation time approximation (RTA) with Debye model, the thermal conductivities of those RE pyrochlores were predicted, showing good agreement with experimental measurements. The low thermal conductivities of RE pyrochlores were shown to largely come from the interference between the low-lying optical branches and acoustic branches. The structural origin underlying the low-lying optical branches was then clarified.

Jan 1, 2015

By W. A. Lang

"I.-IntroductionAn attempt bas been made in this paper to provide a basis for appraisal of the future of the coal briquetting industry in Alberta by outlining the processes used for briquetting various ranks of coal, by specifying the requirements of a briquetted fuel, by indicating .the status of the industry in the United States, by giving developments in Western Canada, by assessing costs of processing, and by discussing briquetting researches in progress. Much of .the detail bas been omitted since this might mask, rather than reveal, the more important phases of the problem. Reference will be made when possible to published articles where many of the details can be obtained.It should be stated at the outset that, in the writer’s opinion, there are three possible developments in Alberta as regards briquetting: (a) an expansion of the briquetting of the fines of • non-coking and coking coals of semi-anthracite, and of low and medium volatile bituminous rank; (b) the processing of the fines of high-volatile C bituminous coals; and (c) the upgrading of the lower rank high-moisture sub-bituminous coals. Details of the chemical and physical properties of these coals can be obtained in publications of the Research Council of Alberta (1, 2), and of the Fuel Research Station, Bureau of Mines, Ottawa (3).Semi-anthracite and low and medium volatile bituminons coals occur in the mountain areas of Alberta, where, during the upthrust of the Rocky mountains, the coal beds served as the sliding surface. This resulted in the coals being; crushed and consequently they contain a h1gh percentage of fines. In some cases they are high in mineral matter and require to be cleaned before being processed. However, the cleaning of fine coal is both difficult and costly. Both the amount of fines present in the mine-run coal and the amount of mineral matter associated with the coal have increased through the introduction of mechanized mining and through the recovery of coal by stripping operations."

Jan 1, 1950

By N. W. Byrne

THE study of diamond drill results at the Lake Athabaska property of Athona Mines, Limited, and the co-ordination of information secured, has demanded extensive application of methods for interpreting true conditions, both structurally and from the point of view of ore outlook. This work was in charge of a capable engineer, who, as the result of exhaustive study of the drill cores, has been able to issue maps and plans exceeding the expectations of the majority of engineers and geologists who visited the field during the past summer (1935); that is, having in view the fact that staking of the property had been completed but a few months beforehand and that geological conditions were practically unknown up to the time drilling began in April. The following pages present an outline of the work of the assay and engineering offices in co-ordinating and interpreting the results of the drilling. The writer desires to acknowledge the suggestions offered by A.P. Beavan, geologist and engineer at Athona Mines, whom he assisted during the drilling campaign, and also the co-operation of the drilling contractor's employees. The geological map, mine plans, and forms accompanying the paper are from the Company's engineering office files.

Jan 1, 1937

By M. S. Badollet

INTRODUCTION THE DEMAND for general knowledge on asbestos fibres has increased considerably in recent years. A few publications have printed data showing some of the physical and chemical prupertie3 of asbestos, but in many cases this information is difficult to find and is seldom available when needed. During the past ten years, Johns-Manville have received many inquiries on the physical and chemical properties of asbestos fibres. Fortunately, we had some of the information in our files, and we willingly supplied the data. To help relieve this need, we have tried to present briefly in this paper some of the interesting and out-standing properties of asbestos. This information was obtained over a period of years by search of the literature and by experimental investigations. PROPERTIES OF ASBESTOS FIBRES Table I (1, 2) presents, in convenient form for easy comparison, data on the principal properties of the several varieties of commercial 'asbestos' -actinolite, amosite, anthophyllite, chrysotile, crocidolite, and tremolite. Under each variety of fibre is a brief statement describing the properties in terms of structure, mineral association, origin, etc. Some of the more important data in Table I are expanded and presented in Table II (3). SOLUBILITY OF ASBESTOS A report ( 4, 5) discussing the effects of acids and caustic on asbestos fibres was published in Germany in 1927.

Jan 1, 1951

By M. A. Halim, V. I. Lakshmanan

Recycling is one of the key elements for sustainable process development for the recovery of value-added products and reducing environmental impact. Process Research ORTECH Inc. has developed several innovative and sustainable technologies, which minimizes the use of water, and chemicals for the recovery of gold, vanadium and gallium from secondary sources by maximizing the recycling of reagents, and reuse of water from process effluents.

Jan 1, 2015

By Peter R. Drummond

THE paper consists of four sections: (1) a discussion of early work; (2) presentation of the results of a chemical investigation of Falcon-bridge nickel-copper blast-furnace matte; (3) application of the results of this investigation to mattes in general; and ( 4) a summary of conclusions. All general discussion will be confined to the fundamental system of ferrous-cuprous sulphides (FeS-Cu2S). Nickel-, lead-, and zinc-bearing mattes will be treated as minor varieties of the parent system. DISCUSSION OF EARLY INVESTIGATIONS Matte investigations may be divided into three classes: first, those treating the sulphides as alloys-theoretical studies of the system FeS-Cu2S, such as those of Hofman (ll)t or Carpenter and Hayward (2); second, chemical research on mattes made under smelter conditions, such as that carried out by Hawley (3) or Avetision ( 4); third, combinations of the . above, such as the investigations of Gibb and Philp (5) or Fulton and Goodner (6). Much research in the first of these classes, including determinations of . freezing points and of data for structure-composition diagrams of the system FeS-Cu2S, was carried out in the period 1890-1910. LeChatelier and Ziegler (1, 13) proved that FeS, when heated alone above its melting point, dissociated in part, and Friedrich ( quoted by Fulton, 6) showed the same for Cu2S. The reactions may be expressed by the following equations: [xFeS yFe + yS (volatilized)+ (x -y)FeS xCu2S )'Cu+ yS ( vohtilized) + (x -)')Cu,S ] Sulphur is lost by volatilization, leaving a melt of metallic iron plus ferrous sulphide in the one case, and of metallic copper plus cuprous sulphide in the other. If the mixed sulphides are heated far above their melting points, there results either an iron-rich matte containing Fe-FeS-Cu2S or a copper-rich matte containing FeS-Cu2S3-Cu, depending on the relative amounts of each sulphide in the mixture.

Jan 1, 1940

"In an environment of rising energy prices and mining at greater depths, cost-efficient loading and hauling equipment is essential. Conducted at an underground mining operation, this study analyzes the energy consumption and gas emissions of diesel and electric load-haul-dump machines (LHDs) with similar bucket capacities. Based on energy prices from the first quarter of 2014, results of discrete event simulation show that energy costs for diesel and electric LHDs are US$0.24/t and US$0.07/t, respectively. Also, diesel LHDs emit 2.68 kg CO2 per litre of diesel fuel, whereas using electric machines reduces the need for ventilation to mitigate engine heat and emissions and reduces energy costs.RÉSUMÉ Dans un contexte de croissance des prix de l’énergie et d’exploitation minière à des profondeurs de plus en plus grandes, il est essentiel d’avoir des équipements de chargement et de transport les plus rentables possible. La présente étude, effectuée dans une mine souterraine, analyse la consommation énergétique et les émissions de gaz de chargeuses-navettes (LHD) au diésel et à l’électricité ayant des capacités de godet similaires. En se basant sur les prix courants de l’énergie, les résultats d’une simulation d’événements discrets montrent que les coûts énergétiques pour les LHD au diésel et à l’électricité sont respectivement de 0,24 $US/t et de 0,07 $US/t. De plus, les LHD au diésel émettent 2,68 kg CO2 par litre de combustible diésel alors que les machines utilisant l’électricité réduisent le besoin de ventilation pour atténuer la chaleur des moteurs et les émissions en plus de réduire les coûts énergétiques."

Jan 1, 2015

By D. C. Peck, James. R. S., Chubb. P. T.

"Abstract -The East Bull Lake gabbro-anorthosite intrusion is one of several Early Proterozoic layered matie intrusions occurring along the Southern Province - Superior Province boundary in the Elliot Lake - Sudbury region, Ontario. The base of the East Bull Lake intrusion comprises abundant plagioclase cumulates (Leucogabbronorite Zone) hosting two distinct styles of sulfide mineralization: (1) disseminated magmatic sulfides, and (2) disseminated to massive, structurally controlled sulfides. Both types of mineralization are enriched in Pd, Pt, Au, Cu and Ni. The host rocks to the sulfide mineralization display a range of interesting features including nodular textures, dendritic­ pegmatitic matie pods, inclusion-rich zones (pyroxenite, anorthosite and granitic inclusions) and mag­ matie breccias. Disseminated chalcopyrite, pyrrhotite and pentlandite occur in concentrations of up to lOOJo within erratically distributed gossan pods near the base of the intrusion. The sulfides were originally precipitated from intercumulus liquids, but were subsequently recrystallized and locally remobilized along fractures during the major period of metamorphism and deformation that af­ fected the East Bull Lake intrusion. The base- and precious-metal tenor of the structurally controlled sulfides can be explained by extensive remobilization and reconcentration of the pre-existing magmatic sulfides in the vicinity of a major shear zone. Both styles of sulfide mineralization locally contain ppm abundances of POE + Au and are generally Pd- and Cu-rich, although both display large variations in Pd :Pt and Cu:Ni ratios. The magmatic sulfides are more strongly enriched in POE and contain up to 1470 ppm Pd in 100% sulfide. Severa! factors, including source characteristics, magmatic processes (crustal assimilation, fractional crystallization) and post-magmatic inter­ action with hydrous fluid, have influenced the present distribution of POE, Cu and Ni in the East Bull Lake intrusion .The magmatic sulfide occurrences from the East Bull Lake intrusion compare favorably with marginal-type deposits from rift-related intrusions (Noril'sk-Talnakh region, Siberia; Duluth Com­ plex, U.S.A.) in terrns of their distribution, but are most similar to reef-type POE deposits with respect to their base- and precious-metal geochemistry. The combination of high POE tenors and large tonnages that is observed for the POE-Cu-Ni mineralization from the East Bull Lake intrusion suggests that a good potential exists for the presence of economie concentrations of Pd, Pt, Au, Cu and Ni in the intrusion. On a global scale, the East Bull Lake intrusion is part of a suite of Early Proterozoic plutons, many of which contain significant volumes of stratiform and/or marginal­ type POE-Cu-Ni mineralization. The East Bull Lake intrusion is also one of the oldest mineralized intrusions derived from a sub-Superior Province mantle source region that has given rise to several significant magmatic POE-Cu-Ni deposits during the period 2.5 Ga to 1.1 Ga."

Jan 1, 1993