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A thick sequence of alkaline intrusions and volcanic rocks underlies a Quaternary caldera on Liliir Island. The sequence is host to a still active sub-aerial hydrothermal system and associated epithermal gold mineralisation. Sub-horizontal alteration horizons exhibit progressively increasing chondrite norma-lised (La/Lu) en and (La/Sm) cn ratios from unaltered shoshonites, to the potassic alteration zone, to the argillic altera-tion zone to the advanced argillic alte-ration zone. The increasing fractionation of HEE, and especially of LHEE, up the alteration sequence is the result of de-creasing pH, temperature and alkalinity of the hydrothermal fluids with increa-sing alteration intensity. HRE3 were especially mobile in argillic and advanced argillic alteration units characterised by acid fluid conditions and large fluid volumes. Abundant Cl, S and CO2 within the hydrothermal fluids and thus abundant REE complexing agents and large fluid volumes favoured the mobility of REE during hydro-thermal alteration of the volcanic rocks and intrusions. Steam escape, mixing of the gases with groundwater and a change from a magmatic neutral chloride hydro-thermal system to a meteoric acid sulphate system was accompanied by liquid/vapour ratio changes, pronounced alkalinity, pH and temperature decreases, and fluid/rock ratio increases. This caused the mobili-sation, fractionation and deposition of PF.F.

Jan 1, 1990

By Amanatidis A

In this paper, the kinetics of iron precipitation as sodium jarosite from aqueous solution is investigated. The determination of the reaction mechanism is attempted based on the experimental data of iron removal as a function of time, without using the characteristics of the precipitate.Experiments at the temperature range from 50° to 95°C were carried out with initial conditions of iron concentration IQ g/L, sodium sulphate concentration 25.44 g/L, sulphuric acid concentration 3.68 g/L, pH = 1.5 and agitation rate 600 rpm. Temperature greatly and positively influences iron precipitation from the solution and this is accompanied by pH decrease. The activation energy was determined using the maximum values of the precipitation rate, which were evaluated by polynomial fitting of the sigmoidal shape experimental curves, and it was found to be 44.37 kcallmole. The determination of the rate-controll ing mechanism was based on some criteria used for the discrimination among the three probable mechanisms of precipitation (diffusion, mononuclear nucleation, polynuclear nucleation). These criteria utilise various funetions of the recovery 'a' of iron precipitated versus time, the most important of which are the chronomals. The results of the kinetic analysis procedure showed that the polynuclear nucleation growth mechanism controls the precipitation of iron as sodium jarosite. This was confirmed by the high value of activation energy, excluding diffusion as the controlling mechanism.

Jan 1, 1993

Lower Silesia Coal Basin/SW Poland/ is adjacent to highly gas saturated igneous massiv and since the beginning of this century more than 1500 outbursts have occurred in four existing mines, including 1295 in the most hazardous mine Nowa Ruda. Prevailing part of these are carbon dioxide/coal outbursts of ejected masses 50-5000 tonnes/av.200/t and gas volume released from 200 m3 to 800,000 m3 Magnitude of these phenomena is growing with the depth and for present extraction levels/ 375-753 m/ may be expressed by a formula: M = 4.25/H-400/, where M-masses ejected, t and H - depth of extraction, m. Regulations obligatory hitherto call for gas pressure measurements to be made in 3 m long and 42 mm dia. boreholes spaces not more than 25 m along the longwall face and taking sample of drillings for desorption testing. Criteria of a hazard are following: pressure higher than 30 kPa /for C02/ or 80 kPa /for CH4/ and desorption more than 1,44 cm3/g. These criteria are not satisfactory because many outbursts occurred in spite of low values of parameters measured and for several times no hazard was evident after very high values were obtained. Moreover, observations show that a huge majority of case outbursts occurred in coal weakened by local geological distortion.

Jan 1, 1980

After the minim operation, most raw materials that occur in the earth's crust require some form of processing or refining before they can be converted into a final end product. In the mineral industry these remarks apply to materials such as iron ore, bauxite, limestone, copper ore and many others that are found in Australia in large quantities. Processing plants for these raw materials operate more efficiently, however, if the feed to them is consistent in both physical and chemical characteristics. Such uniformity rarely occurs in nature so that some form of homogenisation, or blending, is required ahead of the processing plant. Bending also assists the mining operation itself by reducing; the need for selective mining and, by combining high and low grade materials, a more uniformly graded, commercially acceptable product can be obtained, thereby increasing the commercial life of a mine or quarry. Bed blending is the most efficient of the processes available, and following its development in the United States in 1905, over 100 plants have been installed, or are under construction, all over the world. The original process, the Robins--Nessiter system, has been the subject of continued improvements and refinements, so that economical capacities are possible from less than 100 l.t.p.h. up to 10,000 l.t.p,h. and beyond.

Jan 1, 1969

As the Mount Morgan electrolytic chlorine plant is the first of its kind installed in Australia, and as the details of this method of producing chlorine have, up to the present time, been kept more or less secret all over the world, the author trusts that this paper may fill a gap in the technical literature of the subject.When an electric current is passed through a strong solution of sodium chloride the following reaction takes place -2 NaCl + 2 H 20 = 2 NaOH + C1 2 + H 2 Chlorine gas is liberated at the anode or entering pole of the current, while caustic soda and hydrogen are formed at the cathode or leaving pole of the current. If the two electrodes be simply immersed in a vessel containing salt and the current be turned on, there will be no result save slight smell of escaping chlorine gas. The passage of the current will have certainly split up the salt water according to the above equation, but as the products would be in juxtaposition they would immediately reunite, and the electrical energy would have been spent without any beneficial result having been obtained. Therefore, the all-important problem in designing an electrolytic chlorine cell is the finding of some effective means of isolating from each other the chlorine and caustic: soda as soon as liberated from the...

Jan 1, 1911

By De Cuyper J

Laboratory testwork has been performed on ancient residues from the cyanidation of a previously roasted gold-containing pyrite and arsenopyrite ore. By grinding to 95 per cent minus 60 microns, and after a strong aeration conditioning of the pulp, a gold recovery of approximately 67 per cent was obtained by cyanidation. This recovery was brought up to 80 per cent by leaching with thiourea, after a preleaching step with sulphuric acid under severe conditions of acidity and temperature. To avoid excessive capital costs bound to such processes, it was decided to investigate the possibility of applying flotation after grinding at a size similar or finer than the one used for the leaching tests. The method turned out to give interesting results because of the natural flotability observed at pH values lower than two for particles rich in gold present in the residue. After two cleaning steps, a final concentrate, representing around one weight per cent of the feed, was obtained with an approximate gold content of 350 g/t, representing a batch recovery of gold of about 50 per cent. Apart from sulphuric acid, whose addition was very high (flotation slurries at 25 g/l H2SO4), other reagents were not found necessary. Additional flotation tests were carried out to examine whether the recycling of the cleaner tails was justified but the gain observed appeared insufficient.

Jan 1, 1993

By Dixon D. R, Sparrow G. J

Pressure leach liquors from the pressure oxidation of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore were treated to remove iron, either by pressure oxidation (the Hematite process) or with particles of magnetite (the Magnetite process), followed by cementation of various metals with zinc dust to obtain a purified solution from which zinc was electrowon. Satisfactory iron removal was achieved by both processes after neutralisation to pH 4.5 or 5.5. Pressure oxidation of the liquor at 200¦C and 690 kPa oxygen overpressure, conditions similar to those of the Hematite process used in the zinc industry, resulted in the precipitation of the iron as hematite. With the Magnetite process, an iron hydroxide was precipitated onto magnetite at atmospheric pressure and ambient temperature and removed by a magnetic separation step. The performances of both these processes for the removal of iron are compared. It is concluded that the Magnetite process offers considerable cost savings. Other impurities, in particular arsenic, were also removed with the iron in both processes. Cementation at pH 5.2 and 85-90 ¦C with 3.5 g/L zinc dust reduced the levels of copper, cadmium, and nickel to a satisfactory level and subsequent electrolysis in a laboratory cell gave an acceptable deposit of zinc.

Jan 1, 1989

By J Pan, T Chun, D Zhu, Z Guo, J M. Young, T C. Ooi

With the rapid development of the Chinese steel industry, the strong demand for iron ores has led to huge imports of various iron ores from all over the world. As a relatively new force in the iron ore world and an important raw material supplier, Fortescue Metals Group (FMG) has achieved an annualised production rate of 100 Mt of iron ore fines. Typical blends were designed to simulate sinter blends employed in Chinese steel mills, and to determine sintering properties and metallurgical performance of blends comprising FMG Rocket fines in pilot sinter pot. It is shown that the sinter of typical blends comprising 15 - 20 per cent rocket fines possesses excellent sintering properties and metallurgical performance. With Rocket fines substitution for competitor ores in a typical customer mill blend comprising fully imported fines, the sinter productivity and tumble index increased from 1.45 t/m2h and 62.0 per cent to 1.54 t/m2h and 64.0 per cent, respectively, while attaining similar reducibility index and reduction degradation index at lower solid fuel consumption.CITATION:Zhu, D, Guo, Z, Ooi, T C, Chun, T, Pan, J and Young, J M, 2013. Sintering and metallurgical performance of blends comprising Fortescue Metals Group rocket fines, in Proceedings Iron Ore 2013 , pp 519-524 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By L C. Thompson

BioLix is the term for a new class of biologically-derived lixiviants for precious metals (gold and silver) recovery. BioLix can be used as an alternative to cyanide on virgin and spent ores. The BioLix process is based on inducing microbial enzymatic reactions that generate organo-lixiviant chemicals. The bioprocess involves a two-stage culture strategy. First, specialty microorganisms are cultured to generate a high biomass. Then, a food-grade quality amendment is introduced that forces the microorganisms to produce the organo-lixiviant. The second-stage culture is applied to the ore where the microbial/lixiviant system acts on mineral surfaces to extract precious metals. The process operates at ambient temperatures and near neutral pH. This paper will examine the BioLix process through an extensive laboratory development and demonstration project. Laboratory development consisted of identifying and isolating specialty microorganisms and inducing agents for the production of the organo-lixiviant solutions. A demonstration was performed on low-grade and high-grade oxidised ore from the Buffalo Valley mine in Nevada, USA. Results indicate that the BioLix process was comparable to cyanide in terms of gold recovery and operated at near neutral pH and ambient temperatures. Applications for the BioLix process will be discussed including spent-ore re-leaching, cyanide replacement for virgin ore, and in situ mining.

Jan 1, 2004

By Juras ST, Krouse RH, Godwin CI

The Buttle Lake camp is in central Vancouver Island, southwestern British Columbia, Canada. The camp hosts world-class polymetallic volcanogenic deposits of Devonian, Frasnian age (370Ma). This paper describes an on-going sulphur and lead isotope study of the major orebodies.Sulphur isotopes were determined for sulphides (pyrite, chalcopyrite, bornite and galena) and sulphate (barite). Sulphide analyses are markedly different from sulfate. The differences are explained below in a unique model.Sulphide isotopic compositions cluster tightly (del34S -6.7 to 4.6), and demonstrate isotope reversals. Calculated temperatures of correctly ordered mineral pairs are unrealistically high. We conclude that the sulphides are in isotopic disequilibrium, presumably because of rapid precipitation from a quenched plume in an anoxic environment, and because of subsequent sulphide replacement.

Jan 1, 1990

By K C. Corin, C T. O’Connor

In recent years it has been shown that the concept of using partial molar excess Gibbs energy (G̅ex) to explain the behaviour of collectors in the recovery of minerals can be usefully applied to explain flotation performance. Fundamentally this is because hydrophobicity of a mineral particle on which a collector is adsorbed may be strongly related to the fact that the alkyl chain associated with the collector behaves in the same way as any hydrocarbon would in an aqueous medium. This hydrocarbon-water system represents a classical non-ideal mixture, and such mixtures are quantified thermodynamically by determining the activity coefficient of the hydrocarbon moiety of the collector and hence its G̅ex in the mixture. It has been shown that G̅ex is a more rigorous indicator of the contributions of various alkyl groups of a collector than HLB (Corin and O’Connor, 2014) and was also able to explain aspects of froth behaviour (Harris and O’Connor, 2017) and hydrophobicity (O’Connor, 2021). The present paper is aimed at extending the above concepts in two different ways. Firstly, a study is undertaken of a range of results previously reported in which various reagents containing different alkyl groups were analysed in terms of their effect on contact angle and their performance as flotation reagents in terms of recovery. These results sustain the previous observations that there is a robust positive relationship between hydrophobicity as indicated by flotation recovery and contact angle and G̅ex of the alkyl group associated with the collector. Secondly, on the basis of the observation that increases in G̅ex are indicative of increases in the hydrophobicity of the mineral particle-collector aggregate, a study was undertaken to examine the effect of ions typical of electrolytes in water as well as the effect of the presence of alcohols and of pH on G̅ex of the collector alkyl group. In the former two instances the absence of any correlation between G̅ex and recoveries supported the proposition of the respective authors of these studies that the major effect of these electrolytes and added alcohols may be on particle–bubble attachment rather than on the hydrophobicity of the mineral/collector in the aqueous system. On the other hand, the effect of pH on G̅ex correlated reasonably well with changes reported in the literature on the effect of pH on recovery and contact angle.

Aug 24, 2022

By M Nagarajan, S Esen

This paper presents three case studies from three surface coalmines. The first case study is from a coalmine where a dragline operates in 60 m wide and 1 km long strips. Typical overburden height ranges from 30 m to 50 m. The base case blast was modelled using an advanced blasting model (Distinct Motion Code – DMC) to establish the baseline using the blasting parameters in use before optimisation. DMC was used to model the alternative blasting scenarios to obtain the following key objectives:the post-blast muck pile profile was required to have an optimum height of ~28 moptimise cast percentageachieve a well-fragmented muck pile for the draglinethe muck pile profile should be appropriate for the dragline entry into the strip.Achieving these objectives would optimise the dragline performance through reducing rehandle and improving advance along the strip. DMC modelling resulted in the following outcomes:the required muck pile profile could be achievedthe cast percentage increased from 21.1 to 25.1 – a four per cent increaserehandle volumes were reduced.Establishing a good quality assurance / quality control (QA/QC) process was essential to delivering a blast that could achieve these outcomes. The blast was fired successfully and the dragline completed the strip approximately two weeks ahead of the time taken for the previous strip.The second case study is from a coalmine where D11 dozers are used to move the blasted material to the spoil. An optimum profile was required for the dozers for this low-cost mining operation. To achieve this, an electronic blasting system (uni tronicTM 600) was introduced to optimise the muck pile profiles being delivered. The new muck pile profiles showed improved cast percentage from 10.6 per cent to 17.8 per cent. The changes in the muck pile centre of mass displacement improved dozer efficiency as a result of pushing material shorter distances to its final position. Dozer productivity (bcm/h) statistically did not change but coal was being exposed at a faster rate.The third case study summarises the results from a site where dozers are used to minimise the total mining cost. Traditionally, excavators had been used on-site with conventional blast designs. After firing the first cast shot, the blasted material was found reasonably well-fragmented. Although dozing productivity hasn’t been quantified on-site, operators were providing positive feedback (easier push) due to the reasonably good muck pile profile suiting to the dozers. This site also realised significant savings with the dozing as compared to their truck/shovel operation.CITATION:Esen, S and Nagarajan, M, 2015. Muck pile shaping for draglines and dozers at surface coalmines, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 409–416 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By H Stedman

Integrating exploration and operational blastholes into one database significantly enhances geological modelling. Benefits include: improved coal predictions, stronger interpretation of structurally complex areas, detailed mapping of heat affected coal aureoles and additional roof accuracy for blast designs that deliver better coal protection.CITATION:Stedman, H, 2014. Integrating blastholes into exploration data to improve coal recovery and modelling, in Proceedings Ninth International Mining Geology Conference 2014 , pp 237–242 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By N K. DavT, A Coggan

The performance of in situ, shallow water covers in controlling acid generation was evaluated at four recently decommissioned pyritic uranium tailings sites at Elliot Lake, Ontario, Canada. The tailings are acid generating, having a pyrite content of approximately five to ten per cent and a very low to non-existent alkaline buffering capacity. Adverse market conditions led to the closure of all operating uranium mines in the early- to mid-1990s, followed by rehabilitation and decommissioning of mine and waste management facilities. In order to control acidic drainage, all new and active tailings areas at Denison, Quirke, Panel, Spanish-American and Stanleigh mine sites were re-engineered to provide in situ submersion of these tailings under shallow water covers. The tailings impoundment dams were upgraded and reinforced or in some cases reconstructed, to minimise seepages and provide a minimum 1 m depth of water cover. With the exception of Stanleigh mine, which was closed in 1996 and rehabilitated during the late-1990s, the water covered Tailings Management Areas (TMAs) at other sites have been in operation for a period of six to nine years. The surface water quality at these sites is maintained at near neutral pH conditions by periodic addition of lime slurry to the established water covers. Additional treatment of effluent is provided as required to meet the discharge water quality standards. The performance of the established water covers at the sites was evaluated by analysing the annual equivalent limestone consumption data. The results were compared with the performance of an older, decommissioned Nordic TMA, which was rehabilitated using revegetation techniques. The water covers at these sites are performing as designed and acid generation has been reduced to low levels. Based on the total amount of yearly equivalent limestone required to maintain water quality in the water cover and at the effluent treatment plant, it is concluded that acid generation rate at the Denison TMA has reduced to less than 0.15 per cent of its pre-water cover conditions during normal operation and rehabilitation periods. In comparison to the revegetated Nordic TMA, the acid generation rates at Denison and Panel TMAs have decreased to less than 1.6 per cent of that at the Nordic TMA. The acid generation rate at the Quirke TMA was comparable or only slightly lower than that at the Nordic TMA because of its unique terraced cell configuration, having tailings in five hydraulically interconnected cells at different elevations. Historic acidity and oxidation reaction products, accumulated during normal operating and pre-water cover periods, are flushing from upstream locations to downstream cells, thus requiring much higher equivalent limestone additions for acid neutralisation and effluent treatment.

Jan 1, 2003

By Witkowski A

I have the pleasure to present 6 excellent papers in this section all of major relevance to the mining environment of today where competing social, legal and monetary interests and their often complex interaction require serious consideration. This is particularly true today where huge fluctuations in commodity prices makes mining a perilous undertaking while the world increasingly are becoming aware of the serious threat that mans activities has on his environment. The 6 papers deal with such complex issues as safety in an underground environment; How to protect sensitive wetlands well into the next century; The enormeous waterproblems in China and conflicting dewatering/water supply needs; Disposal of contaminated water in sensitive areas and the dynamic interaction between mining companies and legislation.

Jan 1, 1988

I have the pleasure to present 6 excellent papers in this section all of major relevance to the mining environment of today where competing social, legal and monetary interests and their often complex interaction require serious consideration. This is particularly true today where huge fluctuations in commodity prices makes mining a perilous undertaking while the world increasingly are becoming aware of the serious threat that mans activities has on his environment. The 6 papers deal with such complex issues as safety in an underground environment; How to protect sensitive wetlands well into the next century; The enormeous waterproblems in China and conflicting dewatering/water supply needs; Disposal of contaminated water in sensitive areas and the dynamic interaction between mining companies and legislation.

Jan 1, 1988

By R Wei, Y Peng

With the depletion of high-quality ores, the efficiency of extracting difficult gold ores through flotation and leaching becomes very important in the mining industry. Iron contaminants, sulfide and carbonaceous coatings on the surface of gold and gold bearing minerals significantly hinder the recovery of gold during gold processing. As the surface of gold minerals is easily contaminated, coatings of iron oxides and iron hydroxides originated from the grinding process and oxidation of iron sulfides will cause a retarding effect on both gold flotation and leaching.To mitigate the processing issues caused by undesirable surface coatings on gold minerals, a new technology in treating surface coatings of iron contaminants has been developed. The pulp potential and pH of the slurry are altered to allow dissolution of surface coatings which are further excluded by the use of complexing reagents. The current work shows that iron contaminants can be removed from the surfaces of gold through Eh-pH adjustment and chelation which result in significantly improved gold flotation response. The addition of complexants aids the formation of iron chelates to prevent the iron species in the solution from forming iron oxide and iron hydroxide in the flotation conditions.CITATION:Wei, R and Peng, Y, 2014. Mitigating the effect of surface coatings on gold processing, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 187–192 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By Carlini G, Ibba R

The KSS Lead Plant (Kivcet - SNAMPROGETTI - SAMIM) of Por tovesme, owned by Nuova Samim (the sector-head Company for non ferrous metals and derivatives owned by ENI), has been operating since february 1987. This plant is based on the Soviet Kivcet licence and testwork carried out on the pilot plant of VNIITSVETMET in Ust Kameno gorsk fed by the Nuova Samim's concentrates. The plant is com pletely automatized using the most advanced technologies and it is operated by nineteen people on shift work, including all ancillary units and lead decopperizing-casting. The expected performance of the plant has been confirmed and improves day by day in relation of the operating experience, thanks to the new conceptual design of the furnace. Due to the remarkable flexi bility of the process, the integration of the lead plant with the other plants of the metallurgical complex of Portovesme rro-#4 (Electrolytic Zinc Plant, Sulphuric Acid Plant, Imperial Smel ting) has shown all the economic advantages. The lead content in the ambient air, detected by the monitors, either in the working area and on the ground outside the complex, is widely Pb W" below the stricter new limits recommanded by the E.E.C. (Economic European Community) rules and by the Italian law. The whole process is carried out in equipment completely closed and under suction and it does not require manual operations with exposure to the lead. The production cost is much lower than that performed by the traditional technology. This advantage permits wide margin to consider investment to replace the traditional technology.

Jan 1, 1989

Upon subduction, water is liberated from the sediments and the porous struc- ture of the oceanic crust and from de- hydration of minerals for redistribution and chemical reaction. A survey of pro- cesses which are likely to occur along the subducting plate reveals that water may well be basic in subduction induced gas generation, magma formation and ore deposition. In analogy to the industrial water gas process, reaction of water with car- bonaceous matter, in subducted sediments is likely to yield substantial volumes of hydrogen and carbon dioxide. While water and carbon dioxide appear to play a determining role in the development of differentiated magmas, hydrogen will react with metal sulfides and sulfur to form hydrogen sulfide which is essential in sulfide ore depo- sition. A survey of possible metal extrac- tion chemistry along subduction suggests a stepwise solubilization of metals from sediments and oceanic crust, and a poten tial accumulation of dissolved metals in zones of characteristic composition. The metal spectrum in ore deposits at near surface appears to reflect the com- position of the solution in the respec- tive subduction zone. A tendency for preferential solubi- lization of copper at subductidn level, from among the transition metals, an in- creasing generation of hydrogen sulfide in the sane direction and partition effects as well as sulfide precipitation characteristics lead to enrichment in copper and to its selective deposition in the direction towards the trench as observed in S. Latin America. A postscript deals with the formation of native copper.

Jan 1, 1986

In the 25 years since Broken Hill's 75th Anniversary which was marked by an Australasian Institute and Mining and Metallurgy Conference in Broken hill, there have been some significant changes in the role of mines inspectors. This paper updates the information given by the then Chief Inspector of Mines, J.H. Burford, to that 1968 Conference, with an emphasis being placed on mines inspection, although it also reflects changes to mining legislation and regulatory bodies.

Jan 1, 1983