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By C E. Davies

At present the source of virgin iron for steel produced in New Zealand is titanomagnetite extracted from titaniferous beachsands. Some of these beachsand deposits contain extractable quantities of ilmenite as well as titanomagnetite and both minerals represent challenging sources of vanadium and titanium products in addition to iron. This study looks at some theoretical aspects of smelting these ores directly with coal rather than with electric power, and takes into consideration the properties of the raw materials, the thermodynamics of possible process routes and the background of the economics involved.

Jan 1, 1980

By Associates

The headwaters of Skippers Creek and the Shotover River are reputed to be among the richest alluvial gold catchments in the world. This alluvial gold has no doubt been derived from reef systems similar to, and associated with, the Bullendale lodes. Physiographically the prospect covers steep ridges and deeply incised gullies between the Richardson Mountains in the west and the Harris Mountains in the east. Vegetation is mainly tussock with bush either side of Murdochs Creek. Access to the area is by metalled road to Skippers and then by 4WD track to Bullendale. Alternatively the prospect area can be reached by helicopter from Queenstown in around ten minutes.

Jan 1, 1992

By R C. A Minnitt

This paper illustrates the use of variography and moving average plots as an aid to analysing variations in the process that can be used to direct the improvement efforts. The hydrometallurgical processes used in manganese metal production consist of sequential unit operations that include milling and reduction of manganese ores. Leaching of the reduced ore, is followed by solid-liquid separation, residue disposal, solution purification and electrowinning of manganese metal completes the process. The nearly 250 integrated process control loops rely on reports of pH, flow pressure, level, temperature and chemical analyses. Metallurgical accounting, reconciliation and process control is achieved through monitoring of the chemical and mass balances within the manganese reduction plant, requiring approximately 50 000 analyses of solids, powders and liquids each month. The largest numbers of samples are taken in the cell house. Changes and variations monitored by sample statistics ensure that the manganese products comply with predetermined specification limits. Optimising the information-value of the approximately 50 000 samples in the manganese plant is carried out in tandem with ongoing process optimisation. Variographic analysis of daily sampling data suggests that the cyclical behaviour evident in the moving average plots is only a reflection of random residual variability and not a reflection of true underlying variability related to cyclical phenomena. Low resolution in the variogram of daily sampling data masks the short-range variability that emerges when hourly data are analysed. Hourly samples collected over a 39-day period (giving 941 sample data), helped identify short-range cycles in the process. The relative distribution of variability for daily sample intervals, indicate that 57 per cent arises from V[0], 18 per cent from V[process] and 16 per cent from random residual variation. V[0] includes all the uncontrolled sampling error arising from a poor sampling protocol, the fundamental error (FE), the grouping and segregation errors (GSE), the delimitation error (DE), the extraction error (EE), etc. This confirms the suspicions regarding the suboptimality of the sampling protocol and the way it is implemented. The absence of long-term trends in the leach suggests that short-term variation (less than one day) dominates the process. While the control charts indicate that the overall processes are maintained above the lower specification limits and the target values, there is nevertheless a considerable amount of variability in the system that overhangs the processes and threatens to impact them negatively. Although the variability in the leach is above the prescribed limits, the volatility is a matter of concern because it seems to be uncontrolled. The comparison of the various sources of variability in data collected on an hourly basis suggests that the short-term random variability (V[0]) accounts for almost 50 per cent of the variability in the process. The main source of this variability is due to errors in the sampling protocol and is probably related to the size of the fundamental error (FE), the grouping and segregation errors (GSE), the delimitation error (DE), the extraction error (EE), etc. Remediation of FE and GSE will probably lead to a reduction in V[0], whereas V[process] could be mitigated by reducing the biases associated with DE and EE in particular.

Jan 1, 2008

By A Asadov, D Nair

This paper discusses the determination of the percentage of crystalline material in a natural silica deposit which would be considered harmful to health (<10 ¦m). A sample of the natural silica material was recovered and split into a number of subsamples. Samples were sieved using a conventional dry sieve to remove material >300 ¦m before testing. Particle size analyses of the fine fraction showed 75 per cent of the material was below 10 ¦m. Initially XRD and XPS were run on the samples to determine the minerals and composition of the sample. The XRD revealed strong quartz peaks and smaller tridymite peaks with a high amorphous background. The XPS indicated traces of iron, titanium and carbon with dominant silicon and oxygen peaks. The structure of the sample was investigated using the SEM. It was apparent that there were a number of larger quartz crystals (>30 ¦m) with a mix of amorphous and crystalline in the finer fraction. It was also observed that amorphous material was attached to the surface of the crystals. In order to determine the percentage of crystalline quartz a known amount of quartz was added to the sample incrementally. On each addition an XRD scan was performed and the area under the peaks recorded. Back analysis of these peaks with an assumed percentage of crystalline material in the original sample gave a crystalline content of 30 per cent. The quantity at the respirable fraction was estimated to be 18.7 per cent.

Jan 1, 2003

By M E. Dunphy, P Silversmith

The Reefton Goldfield, both historically and potentially, represents a significant gold producing camp in the Westland province of New Zealand. Some two million ounces of gold have been produced from the Greenland Group host rocks between 1870 and 1951 with the most significant producers being the Blackwater and Globe Progress mines.   Steep terrain, high rainfall, poor outcrop, widespread fluvio-glacial deposits, tertiary cover and sometimes onerous environmental access conditions have proved a challenge to conventional exploration techniques. In addition classic exploration techniques have come up against a desire to reduce exploration cycle time and exploration costs while increasing both quality and quantity of geological information.   The trial, and subsequent implementation, of Wacker sampling has proved a highly successful and effective geochemical tool currently being utilised to target, discover, and define potential economic gold mineralisation in the Reefton Goldfield.

Jan 1, 1997

Near-Infrared Spectroscopy (NIRS) Sorting in the Upgrading and Processing of Skorpion Non-Sulfide Zinc Ore In 2008 Anglo American sponsored a research project at RWTH Aachen University to assess the feasibility of the use of near-infrared spectroscopy (NIRS) for ore waste discrimination at the Skorpion zinc mine. The Skorpion mine is an open pit zinc mine located in Namibia, owned by Anglo American with an annual production of 150 000 t/a of super high grade pure zinc. Opportunities for the implementation of NIRS sorting for the Skorpion process exist to upgrade currently subeconomic material, including the marginal dump (over 2000 000 tonnes, av grade of 2.5 per cent Zn). NIRS sorting is not yet implemented or established in the minerals industry however it is a proven technology in the plastics recycling industry, where more than 2000 NIRS sorters have already been installed. NIRS sorting, a type of sensor-based sorting, is a single particle sorting technique which classifies the particles based on the absorbed/reflected radiation in the near-infrared (NIR) region. A disadvantage of NIRS is that it is a surface measurement technique, but NIRS sorting shows overall great potential for the minerals industry. Skorpion ore minerals include zinc bearing phases such as sauconite, hemimorphite, smithsonite, and hydrozincite. These display diagnostic responses in the near-infrared. There are three major absorption features that characterise the reflectance spectra of the ore bearing minerals. These are due to OH and H2O molecular bonds. The spectral response of the waste material is caused by other minerals such as non-zinc-bearing clay minerals, calcite and impure quartz. Test work showed that it is theoretically possible to separate ore material from most waste material based on spectral response in the NIR region. In addition to upgrading material by removal of waste it is also potentially feasible to classify the material based on zinc grade. A tentative correlation between zinc grade and spectral response seems to exist for the sample test suite in the NIR region.

Sep 13, 2010

By S Moradi

The aim of this study was to investigate the possibility of leaching zinc from the tailing (-2 mm) of Angouran flotation plant using sulphuric acid. The tails were first calcined at 800¦C for one hour. The effect of factors such as stirring rate, temperature, initial acid concentration and solid/liquid ratio, on zinc extraction were studied. The results obtained show that at the best conditions, about 91 per cent of zinc were leached using a stirring rate of 800 rpm, a reaction temperature of 50¦C, a 30 minute reaction time, a 100 g/L initial sulphuric acid concentration and solid:liquid ratio 1:6 g/ml. The P85 of the feed material was about 150 ¦m and acid consumption was 600 kg/t.

Jan 1, 2002

Copper Recovery from Printed Circuit Board by Carbonisation

Sep 13, 2010

Flotation of Composite Synthetic Particles

Sep 13, 2010

Ledcap Pty Ltd has developed two software tools for assisting in the determination of life-of-mine (LOM) trucking requirements. The first tool generates haul paths and the second calculates truck travel time over these paths. The two step approach allows the paths to be viewed and if required edited, to better represent the actual site haul routes.The first tool automatically creates haul paths between the mine bench and the dump. To do this the user supplies a master haul route and a scheduled block model. The master haul path and the block model are interacted to create multiple haul routes, one for each pit/dump bench pair in each scheduling period. Each path carries with it a record of the scheduling period it represents and the dry tonnage hauled over the path in that period.The second tool calculates truck travel time over the path. Data from the manufacturer's rimpull and retarder curves are used to calculate accelerations and speed over each segment of the haul path. As the paths are derived from digitised representations of mine haul routes the path f les often have over a hundred segments. This detailed representation of the haul route allows the software to automatically adjust speed for different radius corners and accurately simulates the changing accelerations over the gradient changes that occur in real life mine ramps. Rolling resistance can be specified at a global level, at a segment level and at a period level. This allows rolling resistance to be changed seasonally as well as spatially.Life-of-mine trucking studies attempt to calculate an accurate answer from extremely variable inputs. This paper will detail the features of the two software tools and how the tools provided in the software can assist the mine planner to have greater confidence in their life-of-mine trucking requirements and the subsequent production capacity inputs to their scheduling calculations.

Dec 6, 2010

Application of the Anaconda Simplified Work Index for Multiple Test Sizes Vale uses Bond Work Index measurements extensively in a number of applications. The Bond Work Index is usually a good parameter for checking scale up procedures when sizing ball mills, as well as the basis for variability analysis whenever drill core data is available. It is typical to measure between 100 and 150 Bond Work Indexes, depending on the deposit characteristics. The Bond procedure is relatively complex and time costly. It also requires relatively large amounts of sample, which are very expensive to be obtained. The benefits of the Anaconda simplified procedure are: considerably smaller sample requirements and laboratory time. This makes it very much attractive at Vale's development centre, including geometallurgical mapping, operation efficiency control, mine to mill, etc. The Anaconda simplified procedure was implemented and evaluated at Vale's Development Centre using a number of ores and several samples of each ore totalling more than 190 measurements. The Anaconda simplified method was calibrated for several test sieves and a correlation for any test size was determined for Vale's test mill. The calibration was also extended for two sample top sizes. The relative error of the simplified procedure was found to be in the range of nine per cent which is within the expected error Bond standard procedure. The implementation of the Anaconda method at Vale's development center has been used with great success over the past years in several green field, brown field projects and operating plants.

Sep 13, 2010

The prospect of utilization of phosphate ores which contain high P205 values associated with Al and Fe has produced a great deal of interest over many years. Processing options have generally been based on the utilization of by-products which were required to offset the processing costs.This paper presents a range of processing options which have been investigated at laboratory or technical scale on phosphate ores which predominantly consist of crandallite, CaA13(PO4)2(OH)5.3H20 and millisite, Ca(NaK)Al6(PO4)4(OH)9.3H20. Christmas Island (Indian Ocean) and Mt. Weld (Western Australia) phosphate ores are good examples of such feedstocks. It is expected that these processes may also be applicable to such phosphate ores from other locations.

Jan 1, 1990

By K J. Thompson

This paper describes the work which has been undertaken at the Ohai coalfields in Southland to restore overburden heaps during past opencast mining operations, and procedures which have been adopted to ensure that restoration is achieved concurrent with present opencast mining activities. The system implemented for the treatment of wastewater from opencast mining operati6ns is also described.

Jan 1, 1981

By J Webb

Anoxic limestone drains (ALDs) have been widely used in the passive treatment of acid mine drainage (AMD), but their effectiveness has often been less than anticipated. Iron hydroxide often precipitates around limestone particles and inhibits neutralisation. To determine the conditions under which iron hydroxide precipitates, a small-scale laboratory ALD system was built to enable a detailed examination of the chemistry of iron within the drain. For one experiment, a mixture of limestone and quartz was introduced to the drain to assist in the determination of the key mechanism governing iron precipitation. Synthetic anaerobic acid mine drainage containing Fe2+ (~130 ppm), SO4 2- and H+ was pumped at a rate of 30 mL/min up a 90 cm tall, 15 cm diameter vertical column filled with limestone gravel of 98 per cent purity. Three sampling ports were fitted at equal intervals along the column; water was periodically extracted for analysis at the sampling ports over an 11-hour period. Experiments were run at influent pH levels of 2 and 4. Results show that acid neutralisation to pH greater than 6 occurred at the inflow end of the drain. The greatest amount of iron precipitation (19.5 per cent) also occurred in this area. The lack of iron precipitation on the quartz surfaces in the quartz/limestone mixture indicates that neutralisation is the key mechanism for the precipitation of iron hydroxide on limestone particles. A pe-pH stability diagram derived for the laboratory ALD system indicates that ALDs will not be effective for AMD with pH 2. Influent waters with pH 2 require a pe of -2 (Eh: -118.4 mV) to avoid Fe precipitation upon neutralisation. Influent waters of pH 4 require a pe between -2 and -4.

Jan 1, 2003

By P Lever, D Hainsworth, H Gurgenci

The ACARP Landmark initiative has created the opportunity to advance the level of automation in the coal industry by first focusing on the core production area of longwall mining. A Landmark Longwall Automation project was commenced in July 2001. The major outcome of automation using on-face observation has been divided into ten outcome areas that have been fully scoped for a three-year initial project life. A major facilitating technology has been the implementation inertial navigation system (INS) technology that can map the shearer position in 3D. A focus of the project is to deliver a system that is at least as productive as the current most productive manually controlled longwall face.

Jan 1, 2002

By G B. Arehart

The Midas epithermal system is one of the larger low-sulfidation epithermal vein systems discovered in the western US in recent years, containing in excess of 3 Moz of gold (premining). The deposit is spatially and temporally related to bimodal volcanism in the Northern Nevada Rift; dates on igneous rocks (16 - 14.7 Ma) bracket the age of high grade veins (15.3 Ma). Hydrothermal alteration at Midas is typical of epithermal systems, comprising proximal potassic through distal propylitic assemblages; in contrast to many epithermal systems, Midas has minimal development of wallrock illite/sericite. Mineral assemblages are clearly zoned on the vein structures that acted as focal planes for fluid upflow. Geochemical zoning patterns also show this zoning. Metals were deposited in open-space veins as the result of boiling of hydrothermal fluids; multiple episodes of crustiform mineral deposition are documented in the vein textures. The major vein minerals include quartz, adularia, calcite, selenides and sulfides, with electrum as the primary ore mineral. REE patterns for vein material are similar to patterns for coeval rhyolites, but distinctly different from patterns of the host rocks. Stable isotope data are consistent with meteoric water as the dominant ore fluid. Combined REE and stable isotope data suggest that fluid from which the main ore-bearing stage of the veins was deposited was slightly lower pH than other stages.

Jan 1, 2005

Adsorption of Starch on Kaolinite Surfaces

Sep 13, 2010

By J C. Carlile

Many low sulphidation epizonal gold and zinc-lead vein deposits within magmatic arcs are situated on basement highs, and post-date both the main volcanic episode and porphyry copper (gold) mineralisation. These features are best explained by emplacement of a flat batholith a few kilometres beneath each mineral district, as recently demonstrated by geophysical data in the Baia Mare district of Romania. The batholith provides heat for the hydrothermal system, and results in extensional faulting both through up-doming of the overlying rocks, and in some arcs through incipient collapse of the thermally weakened crust under regional extensional stress. More water-rich magmas emplaced at greater depths could explain some deep epizonal and mesothermal gold deposits situated outside magmatic arcs.

Jan 1, 1995

Societal influences, needs, and uses for recyclable materials are becoming increasingly important business and economic factors in the traditional natural resource companies. Several metals (such as steel, aluminium, zinc, lead and cadmium) are amenable ro recycle which eliminates solid waste generation and decreases the depletion of natural resources. In recent years, the non-ferrous industries have begun to recycle more materials and the next decade will see even larger recycle efforts. In addition to the traditonal recyclable materials, existing metallurgical plants are, or should be, able to handle and recycle materials viewed as 'hazardous'. Unfortunately, some national and regional regulations hinder, and in some cases prevent, the recycling of certain materials. Zinc Corporation of America (ZCA) is currently the largest producer of zinc metal in the USA and one of the world's largest producers of value-added zinc products. Over the last few years, ZCA has become one of the world's largest recyclers of zinc from various diverse materials. ZCA considers these recyclable materials as valuable 'land mines' that provide economic alternatives to the depletion of natural resources while serving society in the minimisation of solid waste disposal. Using the current production facilities of ZCA as a model, this paper overviews the recycling of zinc-bearing materials with special emphasis on: 1. the amenability for recycle within ZCA's pyrometallurgical and hydrometallurgical operations, 2. the quantities and economics of recycle, 3. the problems of recycling hindered by current national and regional regulations, 4. the concepts of total recycle rather than just recovering zinc while generating a modified solid waste, and 5. the motivators for recycling.

Jan 1, 1993

The Performance of Benzyl Arsonic Acid as a Collector in the Flotation of Wolframite and Cassiterite Slime

Sep 13, 2010