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By D. J. Carney, J. Chipman, N. J. Grant

An absolute calibration has been achieved for sampling and analyzing liquid steel for hydrogen based on Sieverts' values of hydrogen solubility in iron. Further checks were made in nickel, iron-nickel, and 18-8 stainless melts. The sampling method was successfully applied to a large number of commercial steel melts in various types of furnaces. The concurrent problem of sample storage was also solved. THE problem of sampling of liquid steel for hydrogen is more difficult than the problem of analysis. Hydrogen has a greater mobility than any other element; it is the only element that will diffuse out of steel at room temperature. In accordance with the known relation between temperature and diffusivity, the diffusion of hydrogen is extremely rapid at the temperature of liquid steel. Consequently, in the past, attempts to quench molten steel to retain the dissolved hydrogen have not been as successful as similar attempts with nitrogen or oxygen. The retention of hydrogen is especially difficult since it will continue to escape at room temperature even if the molten metal has been rapidly quenched. The hydrogen sampling methods may be classified broadly as (1) the rapid quenching techniques which attempt to preserve super saturation and (2) those methods which attempt to collect the gases evolved as the metal freezes and cools to room temperature. With all methods of sampling but especially with the rapid quenching methods, there is also a concurrent problem of storing the sample until analysis is undertaken. The two problems are interrelated and must be considered together when discussing liquid steel sampling techniques. The major obstacle in liquid steel sampling has been that there was no way of evaluating properly the various sampling and storage techniques which have been developed. It has not been possible to compare the accuracy of the various methods. For evaluation of sampling methods some known standard is required; this may be found in the published work on the equilibrium solubility of hydrogen in liquid iron which has been determined in three separate investigations.1,2,3 The data are shown in table I. Sieverts' original method of obtaining gas solubilities involved measurement of the volume of gas required to saturate the liquid metal contained in an evacuated bulb of known volume. This procedure, improved by introduction of high frequency induction heating, has yielded reproducible results which appear to be entirely dependable. Using Sieverts' method, it has been proved for iron and other metals and alloys that the hydrogen solubility is proportional to the square root of the pressure of the hydrogen gas above the liquid, so that one may work with various partial pressures of hydrogen to put different amounts of hydrogen in solution. From Sieverts' law it is possible to know accurately what amount of hydrogen is dissolved in the liquid metal at the time of sampling. The accuracy of a sampling method may be gauged by reference to this known solubility. It was the purpose of this investigation to develop a method for sampling liquid steel and for storing the sample so that the analytical result would represent the actual hydrogen content of the metal bath. For this purpose an induction furnace was

Jan 1, 1951

By Eugene Leonardon

THE search for oil has required, and without a doubt supplies, a tremendous amount of information on the structure, composition, physical properties, and history of sedimentary rocks. The earliest and most complete source of knowledge is the sample or core of the rock itself, the uses of which are well known. The purpose of this paper is primarily to discuss a new method for obtaining these cores, and to illustrate its use in connection with electrical logs. Most cores have been obtained through a special adaptation of rotary drilling, and the results have been remarkably good, considering the mechanical problems involved. Unfortunately, because of the time and expense, this method cannot be used for the entire length of the drill hole. Even though ingenious contrivances have been evolved in order to reduce the time spent in round trips, such as wire-line coring equipment, mechanical coring still remains too expensive to be carried out con-tinuously. In practice, therefore, one is finally compelled to estimate the probable depths of the more interesting horizons and, allowing a wide margin of safety, to core through those sections only. It is true also that interesting results have been obtained by examining the cuttings brought to the surface by the mud circulated in the well during the process of drilling. Be that as it may, the inescapable fact remains that key horizons may be passed inadvertently, for one reason or another, while the drilling operations are being performed. The only continuous record of the formations encountered is that furnished by electrical surveys. Obviously, it would be desirable to make the electrical survey first and to take the samples from the wall of the hole according to the indications on the electrical log. In this way, it would be possible to core only the exact sections desired, eliminating the otherwise inevitable estimates as to the point at which to start coring, and thereby reducing to a minimum this expensive operation. At the same time this method would provide a maximum' of useful samples.

Jan 1, 1939

By G. C. Gould

The nature of freckle segregation is determined by chemical analyses, microradiograplzy, and electron microprobe. In addition, the influence of chemistry variation on freckle formation is studied in laboratory experiments. It is demonstrated that controlled laboratory solidification can produce freckle segregation. "FRECKLE" segregation is a discontinuous, rod-like segregation observed in vacuum consumable -electrode ingots. Figs. 1 and 2 show this segregation as pencil-like, dark etching areas of segregation found in longitudinally and transversely sectioned consumable-electrode ingots. In most cases the segregation is perpendicular with respect to gravity and parallel to the longitudinal axis of the ingot. The segregation is most often encountered at or around midradius in large vacuum consumable-electrode ingots. The austenitic alloys, A-286* and 718, † have shown particular susceptibility to this mode of segregation. The origin of these rodlike pockets of segregation is not well-understood. It has been suggested that the segregation is a result of a portion of the electrode dropping off and passing through the arc un-melted. On the other hand, smeltzer1 has demonstrated the freckle segregation in A-286 to be comprised of low-melting constituents relative to the matrix melting point. The discontinuous nature of the segregation is the most perplexing facet of the freckle-segregation problem. It was to gain some insight into this part of the problem that this work was undertaken. I) PROCEDURE At the outset of the work identification of the phases present and the elements concentrated in the freckle areas was undertaken. The electron micro-probe was used to determine general enrichment as well as -specific phase chemistry. Microradiography using cobalt and chromium radiation was also used on the freckle areas again to determine the elements involved in the segregation. X-ray diffraction patterns were made from portions of these same foil specimens. Optical microscopy and Knoop hardness measurements were also used

Jan 1, 1965

By Eugene Leonardon

THE search for oil has required, and without a doubt supplies, a tremendous amount of information on the structure, composition, physical properties, and history of sedimentary rocks. The earliest and most complete source of knowledge is the sample or core of the rock itself, the uses of which are well known. The purpose of this paper is primarily to discuss a new method for obtaining these cores, and to illustrate its use in connection with electrical logs. Most cores have been obtained through a special adaptation of rotary drilling, and the results have been remarkably good, considering the mechanical problems involved. Unfortunately, because of the time and expense, this method cannot be used for the entire length of the drill hole. Even though ingenious contrivances have been evolved in order to reduce the time spent in round trips, such as wire-line coring equipment, mechanical coring still remains too expensive to be carried out con-tinuously. In practice, therefore, one is finally compelled to estimate the probable depths of the more interesting horizons and, allowing a wide margin of safety, to core through those sections only. It is true also that interesting results have been obtained by examining the cuttings brought to the surface by the mud circulated in the well during the process of drilling. Be that as it may, the inescapable fact remains that key horizons may be passed inadvertently, for one reason or another, while the drilling operations are being performed. The only continuous record of the formations encountered is that furnished by electrical surveys. Obviously, it would be desirable to make the electrical survey first and to take the samples from the wall of the hole according to the indications on the electrical log. In this way, it would be possible to core only the exact sections desired, eliminating the otherwise inevitable estimates as to the point at which to start coring, and thereby reducing to a minimum this expensive operation. At the same time this method would provide a maximum' of useful samples.

Jan 1, 1939

By O?Harra B. M.

THE work here described had for its purpose the procuring of data from which some quantitative estimate might be made of the results obtainable by using oxygen-enriched air in roasting zinc ores on a commercial scale. The principal metallurgical advantages of using enriched air in roasting zinc ores would be: 1. The rate of roasting would be increased, with consequent gain in the capacity of the roasting furnace. 2. As less air would be required for roasting, the volume of hot gases leaving the furnace and the heat carried out of the furnace as sensible heat in these gases would be less per ton of ore roasted; partly for this reason and partly because of the increased quantity of heat generated in the furnace by the larger amount of ore that could be roasted, the consumption of fuel by the furnace would be lessened; and by the use of air sufficiently enriched with oxygen the necessity of using fuel might be entirely obviated. 3. Roaster gas having a higher SO2 content could be produced; this would make possible greater capacity and more economical operation of the sulfuric-acid plant. Certain phases of the application of enriched air to roasting can be worked out only by experimenting with a furnace of commercial, or at least semicommercial, size. Thus the precautions necessary to secure proper. distribution of heat in the furnace;1 the volume of enriched air; and the proportion of oxygen in this air, necessary to give the desired increase in roasting capacity of the furnace and in SO2 content of the roaster gases;; and the most desirable frequency of raking, thickness of

Jan 11, 1924

By C. Stansfield Hitchen

THE introduction of the logarithmic sector method of quantitative spectrography by Scheibe and Neuhäusser in 1928, and the subsequent .modification and improvement of the method by Twyman and Simeon, would seem to have marked yet a further advance in quantitative spec-trum analysis and its industrial application, inasmuch as it offers a simple means of eliminating some of the uncertainties inherent in the older methods based upon mere visual comparison of line intensities. In their recent admirable review of the position and capabilities of industrial spectroscopy, Brownsdon and van Someren1 say: Ways and means of facilitating the comparison of line-intensities so as to give them numerical values are helpful, and of these a logarithmic sector rotating in front of the slit appears to he one of the most promising; . . . the success recently experienced by the author in using this method for the examination of steels and solutions of metallic salts prompted him ,to investigate its possible use in estimating the impurities commonly present in crude and refined tin. The results of this investigation are submitted in the present paper. Details of a number of spectrographic analyses of tin for various impurities have already been published. Thus, Schweitzer2 describes the spectrographic examination of tin for lead, bismuth and cadmium, and was able to distinguish between such atomic percentages as 0.01, 0.05, 0.10, 0.30, 0.60, 1.20, 3.00 and 10.00. Negresco3 investigated the bismuth content of tin over a range of from 0.0005 to 35 per cent. Meggers, Kiess and Stimson4 compare spectrographic and chemical analyses of tin metal for copper, lead, iron, zinc, silver, nickel and bismuth. They stress also the value of spectrum analysis in the examination of tin used for boiler plugs, where the requirements that only minute quantities of impurities shall be present render the chemical analysis both tedious and difficult.

Jan 1, 1933

By Fred A. Anderson, George B. Wallace, Edward J. Slebir

Auburn Dam will be a thin, double-curvature concrete arch dam about 685 ft high. With a crest length of about 4000 ft, it will be the world's longest single-arch dam. The site is located on the North Fork of the American River about 40 miles northeast of Sacramento, Calif. Construction is scheduled to get under way in 1970. In planning for the design and construction of Auburn Dam (see artist's conception), the foundation material, with its various discontinuities, is being investigated and the structural characteristics of the rock mass evaluated. The investigation and testing programs will aid in defining the pertinent geologic features and their individual and cumulative influence on the foundation. The work includes geologic surface mapping, surface trenching, core drilling, geophysics, tunneling, excavating shafts and raises, performing in-situ tests, and conducting laboratory tests on core and block samples. Competent amphibolite is the predominant material in the foundation, but significant bodies of chloritic, talcose, and metasedimentary rocks, a strongly developed jointing pattern, faults, and shear zones also affect the deformability of the rock mass. A comprehensive rock mechanics program, closely coordinated with geologic investigations as well as the engineering studies, therefore is required The rock mechanics work is a combination of many analytical studies and experimental investigations. The experimental work includes laboratory tests on core samples from holes drilled for geological studies of the entire foundation and in-situ tests performed in selected areas. The laboratory testing program evaluates the general properties of all important rock types and aids in correlating many of the key structural features encountered within the foundation. To derive maximum benefit from the field tests, they are conducted in materials which represent a

Jan 1, 1970

By J. J. Jakosky

A REVIEW of the progress in applied geophysics during the recent depression years reveals marked advances "over the methods employed several years ago. Of late, geophysical work has been curtailed to a con-siderable extent in the fields of oil and base-metal exploration, its especial domains a few years ago. Greater attention has been directed toward the use of geophysical technique in other engineering problems. Constantly maintained research programs have developed new instruments and per-fected better field, laboratory and interpretation techniques based on experience and skill acquired from years of application in the older geophysical field. During the past two years, geophysical methods have been employed in problems that required information on thickness of fill materials and subsurface bedrock contours. Considerable success has been attained, with subsequent drilling checking the predicted depths within one to five per cent. In general, these problems were similar as far as the fundamen-tal physical and geological conditions were concerned, but they have varied widely in specific detail and in engineering aspects. Character-istic of the different problems are: (1) yardage and bedrock profile in gold-placer mining; (2) water supply, involving underground drainage and storage conditions; (3) bedrock contours in dam-site and other structural investigations; (4) gravel and fill yardage, and other structural features along rights of way and in rock and gravel quarrying. Of particular interest, perhaps, to mining men are the problems of gold placer deposits and water supply. Geophysical work on gold placers is of especial interest because of the present expanded activity in all phases of gold mining. The development of a suitable water supply at, an economical cost is often of prime importance in insuring a successful mining venture. Particularly is this true in the arid Southwest. How-ever, the use of geophysical work in water supply is not confined to the needs of mining development.

Jan 1, 1933

By Gerald Edmunds

Although the phenomenon of season cracking is still imperfectly understood, there seems to be ample evidence that season cracks are propagated by the combined action of corrosion and a stress of either internal (residual) origin or external origin. The factors that influence season cracking may therefore be grouped according to corrosive media, nature of stress, and character of the material. Thus the important mass of evidence pointing to ammonia as the most frequently active corroding agent causing season - - cracking of brass has naturally led to the development of laboratory tests of a moderately accelerated character based upon ammonia together with auxiliary agents such as air, water vapor, and carbon dioxide as the corroding agent. Similarly, the knowledge that stress must be present has led to the use of externally applied and therefore accurately measurable stresses in laboratory testing. A companion paper(^)^ to the present one discusses the development of these test methods in our laboratories. The present paper discusses data bearing on factors concerning the nature of stress such as its magnitude and direction of application. It also deals extensively with the character of the brass, particularly in regard to the copper-zinc ratio and the structure as developed by mechanical work-

Jan 1, 1945

By Bevan Presley

THERE has been developed at Latouche a rather unusual system of mining which, for want of a better name, has been called the "Latouche system of mining." It is a modified form of shrinkage stoping applicable to orebodies of large or fairly large size where the ground is such that timbering would not be required in stoping. Mention has been made of this method of mining by Birch,1 who gave no details as it had been in use only a short time and the final outcome undetermined. The system, however, has proved to be entirely successful and it is thought that a paper covering it might be of general interest. Before proceeding with a detailed description of the "Latouche system" a brief description of the property and the various mining methods previously used will be given. LOCATION The Beatson mine of the Kennecott Copper Corp. is situated on the west coast of Latouche Island-, in Prince William Sound, Southwestern Alaska, 45 miles east of Seward, the coast terminus of the U. S. Government Railroad. It is a regular port of call for ships on the Southwestern Alaska run. The island is about 12 miles long and 3 miles wide. A ridge of mountains runs the entire length with a maximum elevation of 2500 feet. CLIMATE Latouche has to contend with possibly the greatest amount of precipitation on the North American continent. The annual average precipitation for the past 4 years has been 188 in., with 248 in. for the year 1926. A rainfall of 4 in. per day is not uncommon. In the winter the thermometer rarely falls below +20° F. and the snowfall is usually heavy during the months of March and April.

Jan 1, 1927

By Luis Salazar

Internal improvements are the great seals; stamping upon the history of nations their epochs of peace, in which notable enterprises are conceived, and fresh impulses given along the path of progress. Such forerunners of national benefits have never been so notable in Mexico as in the last four decades of the nineteenth century, during which the national faith in the consolidation of peace has been a guaranty of the development of all the elements of national prosperity. Among all the improvements which have been realized with the unanimous approbation of the people, the railroads occupy a preferred place, for upon them depends the expansion of commerce, of agriculture and of mining, the three great factors of the wealth of Mexico. In a country so extensive as the Mexican Republic, where the inhabitants are greatly scattered, and great distances separate the producer from the consumer, the only way to encourage home industry, and the development of commerce, agriculture and mining, is to construct railroads, which shorten distance, facilitate transportation and minimize its costs. The mountainous character of the country makes the navigation of its rivers practically impossible, except very near to

Jan 1, 1902

By P. A. Vukmanic, M. Gensamer

Only recently has it been realized that preferred orientations are common in hot-rolled steels. In a recent paper, N. P. Gossl stated that hot-rolled mild steel exhibits a texture different from that characteristic of cold-rolled steel. No complete study of these hot-rolling textures has been reported using the pole-figure method of Wever. The material used in the work reported in this paper was the same material used by Gensamer and Mehl2 in a recent study of preferred orientations in cold-rolled steel, to which reference may be made for the composition and thermal history of the steel. Automobile-body sheet bar 1/4 in. thick was hot-rolled at two temperatures, 780' and 910' C. (1436' and 1669' F.). These temperatures refer to the temperature of the furnace in which the steel was heated; after each pass the steel was returned to the furnace and held there long enough to return to temperature. Although no accurate method was used to measure the temperature after each pass, it was estimated by color that only a slight drop in temperature occurred. In order to determine the effect of any preferred orientation that might have persisted through the normalizing treatment, one specimen at each temperature was rolled in the same direction as the original working direction and the other at right angles to it. The total reduction in each case was 85 per cent, the specimens having been reduced from 0.250 to 0.0375 in. in five passes. Final cooling was in air. Pinhole reflection photograms were taken of all four specimens, with the rolling direction vertical and the X-ray beam at an angle of 7' with the transverse direction (the transverse direction is defined as that direction in the rolling plane perpendicular to the rolling direction). These photograms, taken with a Mo target at 35 kv., are reproduced in Figs. 1, 2, 3 and 4. They show that a more pronounced texture was developed by the low-temperature rolling (780' C.), and that of the two

Jan 1, 1937

By A. E. Lehman

A RECENT demand for some form of panoramic display of an important railway line, showing its branches, connections, and terri tory controlled by it, revealed to the writer the advantages of' a topographical model or relief map fix this purpose. Hitherto, maps of this nature have been used chiefly for scientific and geographical purposes, and confined to a comparatively narrow field of service. They deserve to become more popular and to have their advantages better understood. Much has been written and accomplished in this direction by Prof. Lesley, Messrs. Harden, Moulten, de Mendonca Cortez, and others; but I believe their pub lished descriptions of the methods employed in the construction of these models are confined to those used by themselves. It is the writer's aim to present in condensed form these various methods, and some suggestions of practical value as to the most economical course of procedure, as well as to mention some of the uses that may be made of the results obtained Methods of Construction.—Many different materials have been prepared and used in the preparation of relief maps, such as metal, clay, plaster, gypsum, wax, putty, Card-board, papier-mache, wood, and compositions of varions kinds, with results more or less success ful : wood, however, in the writer's experience, has been found to be by far the most satisfactory, combining the advantages of stability, accuracy and ease of handling. The following is a brief description of several of the methods used in constructing topographical models : When clay, wax, putty, compositions or materials of a plastic nature are used, the operator carries his work up from its base by means of measurements or by the eye, manipulating and shaping the material as best he can, ac cording to such features of his subject as he wishes to delineate. This process requires remarkable skill, and given this, will probably fall short even then of an approximation to accuracy; lacking essential elements of detail nil over the work and exactness, particularly in position and elevation of the most important points in the territory mapped. When either of the above mentioned materials or compositions are used, metal or wooden pins are sometimes driven into the base or level datum plane of wood, the top of these pins giving the eleva-

Jan 1, 1886

By Frederic Benard

The electrolytic copper refinery at Copper Cliff, Ont., is operated by the Ontario Refining Co., Ltd. The associated companies behind the enterprise are the International Nickel Co. of Canada, Ltd.; The American Metal Co.; The Consolidated Mining & Smelting Co. of Canada, Ltd.; and Ventures, Ltd. The plant was the outgrowth of the rapid development of copper resources in the nickel-copper ores of the Frood and other great mines in the Sudbury district, and of the desire to have all primary production units grouped together as closely as possible. The refinery is near the intersection of the Sault Ste. Marie to Sudbury highway and the Canadian Pacific Railway. It is about one mile south of The International Nickel Company's smelter at Copper Cliff. The standard-gage track systems of the refinery and of the smelter are connected by a standard-gage timber railroad trestle that crosses the railway and the highway by means of steel girder spans. The Canadian National Railway has access to the plant by means of this trestle and the nickel company's tracks, so that the refinery has connections with both the Canadian Pacific and the Canadian National railways, as well as a direct connection with The International Nickel Company's smelter, from which the bulk of the copper to be refined is hauled by the latter's electric locomotives. Buildings The refinery (Fig. 1) covers approximately 60 acres, enclosed by an unscalable chain-link fence. The main buildings have a content of 23,000,000 cu. ft., with a total roof area of approximately 600,000 sq. ft. and near them are the substation, cooling pond and main standard-gage track system (Fig. 2). A ladder track for car storage extends 1200 ft. south of the coal-pulverizer tracks and the scale house is on this spur. The intake and pumphouse for fresh water supply are at Kelly Lake, about 3000 ft. south of the plant. Owing to the severity of the winters, when temperatures of from 20" to 40' below zero are to be expected, the building of this refinery involved a number of problems in insulation, layout, ventilation, etc., which were

Jan 1, 1934

By I. M. Roberts

The war emergency has affected every phase of industry. The gas and coke-oven companies have sought faithfully to discharge their responsibility in this critical period and have willingly modified their operations where possible to meet the ever increasing demands made upon them. Our company made commitments for blast-%urnace coke for war purposes which necessitated a reduction in coking time in order to produce the amount required to meet the new demands. At the same time there were certain customers of long standing, who had been supplied with foundry and egg-sized coke produced on fairly long coking periods, who also were engaged in war work and whose patronage we desired to retain. Coke produced on short coking rates from the coal mixture we were then using would not have been satisfactory for these customers. The average width of our ovens is 19¾ in., which is a little wider than the more modern ovens of the present day. They were originally designed to give somewhat cool tops in order to produce a rich gas. This necessitates carrying the heats a little on the warm side so that the tops will be fully carbonized. A reduction in coking time, as is generally known, is accompanied by a reduction in the average size of the coke produced. This is due to the greater shrinkage that takes place at the higher temperatures required to carbonize the charges in a shorter time. The net result is that the coke is more cross fractured and longitudinally fractured and breaks up into small sizes on handling. The cokes produced from the better coking coals seem to be more susceptible to fracture at high temperatures than those from poorer coking coals. A coal mixture that produces a beautiful foundry-sized coke at 30 to 36 hr. may yield a product at 18 hr. that would be so badly fractured as to be unsatisfactory for foundry practice. Coking Characteristics OF Coals Our problem was to find some economical innovation and develop a method that would enable us to reduce the coking time and still produce a coke satisfactory to our foundry trade. However, before discussing the results of our present operations, it might be well to present a few observations on the coking characteristics of coals in general. Most coke-oven operators carbonize a blended mixture of coals. It may consist of a single high-volatile coal with a single low-volatile coal, or of a combination of several high-volatile and low-volatile coals. Medium-volatile coals of the Eagle seam are used for the production of high-grade foundry coke. Medium and high-volatile coals are often blended with one or more low-volatile coals. The possibilities are almost infinite, but the combinations are limited by such factors as cost and facilities for handling multicoal mixtures, and by other practical considerations. Every coal has characteristics that make it blend better with a particular coal or coals in preference to others. This property has

Jan 1, 1944

By I. M. Roberts

The war emergency has affected every phase of industry. The gas and coke-oven companies have sought faithfully to discharge their responsibility in this critical period and have willingly modified their operations where possible to meet the ever increasing demands made upon them. Our company made commitments for blast-%urnace coke for war purposes which necessitated a reduction in coking time in order to produce the amount required to meet the new demands. At the same time there were certain customers of long standing, who had been supplied with foundry and egg-sized coke produced on fairly long coking periods, who also were engaged in war work and whose patronage we desired to retain. Coke produced on short coking rates from the coal mixture we were then using would not have been satisfactory for these customers. The average width of our ovens is 19¾ in., which is a little wider than the more modern ovens of the present day. They were originally designed to give somewhat cool tops in order to produce a rich gas. This necessitates carrying the heats a little on the warm side so that the tops will be fully carbonized. A reduction in coking time, as is generally known, is accompanied by a reduction in the average size of the coke produced. This is due to the greater shrinkage that takes place at the higher temperatures required to carbonize the charges in a shorter time. The net result is that the coke is more cross fractured and longitudinally fractured and breaks up into small sizes on handling. The cokes produced from the better coking coals seem to be more susceptible to fracture at high temperatures than those from poorer coking coals. A coal mixture that produces a beautiful foundry-sized coke at 30 to 36 hr. may yield a product at 18 hr. that would be so badly fractured as to be unsatisfactory for foundry practice. Coking Characteristics OF Coals Our problem was to find some economical innovation and develop a method that would enable us to reduce the coking time and still produce a coke satisfactory to our foundry trade. However, before discussing the results of our present operations, it might be well to present a few observations on the coking characteristics of coals in general. Most coke-oven operators carbonize a blended mixture of coals. It may consist of a single high-volatile coal with a single low-volatile coal, or of a combination of several high-volatile and low-volatile coals. Medium-volatile coals of the Eagle seam are used for the production of high-grade foundry coke. Medium and high-volatile coals are often blended with one or more low-volatile coals. The possibilities are almost infinite, but the combinations are limited by such factors as cost and facilities for handling multicoal mixtures, and by other practical considerations. Every coal has characteristics that make it blend better with a particular coal or coals in preference to others. This property has

Jan 1, 1944

By Dr. O’Neil Thomas J., Donald W. Gentry

Pure gold was hidden in the quartz, they said, 'Twas proved by dreams and signs, and rods divining, By chemic tests, and spirits of the dead, In fact by everything-except by mining. " from R.E. White, "The Mining Town," Alta California, August 18,1873 Textbooks in mining engineering have traditionally covered ore reserve estimation and mine valuation in a single volume. Indeed, Examination and Valuation of Mineral Property by R. D. Parks (1957), having been the standard of the profession for over 20 years, is a classic example. However, the state of knowledge in these two fields has grown tremendously. Most mining engineering curricula now cover these topics in separate courses, and in practice, these tasks are usually performed by different individuals. Thus, this trend now suggests the need for separate, specialized publications rather than a single volume for both topics. Because of the separate development of the science of ore reserve estimation, it is important to state at the beginning what this chapter does not cover. It does not address in detail the design of sampling programs, sampling methods, or the processing of samples or sample data compilation. There are a number of suitable references available on these topics, including Peters (1978), Gy (1979), as well as the previously cited book by Parks. Furthermore, this chapter does not cover in any substantial detail either the traditional methods for using sample data to calculate ore reserves or the more recently developed geostatistical methods. The traditional methods are thoroughly covered by Popoff (1966) and more concisely by Barnes (1980). Among the more useful references for statistical applications in ore reserve estimation are Barnes (1980), David (1977), and Clark (1979). A thoughtful review of the entire science and art of ore reserve estimation is provided by King, McMahon, and Bujtor (1982). In spite of the fact that expansion of knowledge now calls for separate books on ore reserve estimation and financial evaluation, neither publication can ignore the important interrelationships between the two fields. In regard to this text, the unique and crucial role of ore reserves can not be omitted entirely; however, the field is now simply too extensive to treat here in any comprehensive manner.

Jan 1, 1984

By J. W. Walker, G. J. Heuer, E. W. Hough

An improved apparatus is described for the deterrni-nation of interfacial tension* by the pendant drop method in the pressure range from 15 to 15000 psi and the temperature range from 100º td 280°F. The chief characteristics of this apparatus are reliability and ease of operation. Temperature control was accomplished by means of an electrically heated jacket which could he completely removed while cleaning the apptrratus. The cell was designed so that the camera could he placed about I in, from the window without overheating the carnera lens. Separate "0" rings employed to seal each window and corresponding window backup plate gave very reliable window operation at 10,000 psi. An extra pistorr-cylinder combination was added so that a high compression ratio could he attained when gas was employed as one phase in the pendant drop cell. Other essential parts of the system were similar to an apparatus already described.' The interfacial tension for carbon dioxide and water varies from about 69 dynes/cm at 15 psi to about 19 dynes/cm at 1,250 psi for 100°F. For pressure.r between t,500 and 3,500 psi, the interfacial tension is between 32 and 24 dynes/cm at this temperature. The interfacial tension at 280°F varies from about 50 dynes/cm at 200 psi to about 17 dynes /cm at 10,000 psi. The maximum surface excess for carbon dioxide, assuming the surface excess of water to be zero, occurs at about 1,500 psi jor the 100°F isotherni and Itas a value of about -79 X 1014 mol/sq cm. At 160°F this maximum IS shifted to about 2,000 psi and has a value of about 10 X 1014 111ol/.sq cm. Other maxima, us well as several minima, are present at these and other temperatures. Judging from the data on the solubility of water in carbon dioxide at elevtrted pressures2,3, it appears that the principal maxinza natned are in regions of increasing solubility of the water in the carbon dioxide rich phase. INTRODUCTION AND APPARATUS A pendant drop interfacial tension apparatus which would accommodate an opaque liquid in a gas phase was constructed several ycars ago' for industrial purposes. This apparatus was used as a starting point for the present development. The objective of the present development was to enhance reliability and convenience of operation. Other articles'" have described pendant drop apparatus which could not accommodate a gaseous phase adjacent to the windows. A schematic diagram of the apparatus is shown in Fig. 1. The water used followed the path; A, intro-

By Charles M. Rolker

The main tin-producing regions of the world are known to be England, Australia and the Dutch East Indian possessions, chiefly Banca and Billiton. During recent years, the tin of the Malay Peninsula, exported from Penang and Singapore, has been coming prominently to the front. France, Austria, Hungary, Germany, Spain, South America, Russia and China still present insignificant figures. The conspicuous part which the Dutch possessions in the Indian Archipelago have taken in supplying the world with tin, is well known. Tin was discovered in Banca as early as 1710, and has been produced there ever since; but the supply has been most important since Banca came fully into the possession of Holland, in 1821. In Billiton and the adjoining island of Singkep, the existence of tin was known prior to 1822.* The Lingganese knew of its existence in the valley of Embalong, from creeks and streams in the neighborhood of Tima and Simper hills, on Billiton and also on Singkep island, but the prevailing superstition that tin-mining brought misfortune, influenced them to let this industry lie idle. The attempts of the Dutch government to test this question were lukewarm, perhaps by reason of the fear of reducing, through new discoveries, the price of Banca tin, and the island was abandoned in 1826, leaving only a military post. In 1850, Dr. Crookewit, a chemist and naturalist, was sent out to verify the rumors that tin existed in Billiton. His report was unfavorable; but in 1851 Mr. C. De Groot, a mining engineer, found tin readily, and the active work on Billiton dates from that time. Less than 600 tons were produced during the first ten years, and 3000 tons in the next decade. Billiton tin-mining is done by

Jan 1, 1892

By P. G. Beckett

The problem of handling the large quantities of water encountered in the Old Dominion mine presents many features of interest. In the present paper are discussed the probable sources of water, the pumping equipment, the increased flow into the mine in the early part of 1915, culminating in the flooding of the 18th and 16th levels in March of that year, and the difficulties that were met with during the high-water period. I. PRELIMINARY The Old Dominion mine, situated 1 mile north of the town of Globe, Ariz., has long been one of the prominent copper producers of the State, and until the opening up of the copper schist deposits in the neighboring mines of Miami, was responsible for the greater part of the copper output from the Globe district. As the gradual exhaustion of its orebodies near the surface led to the downward development of the mine, more water was encountered in the western portions directly underlying the dacite formation until the drainage problem became a serious factor in the operation of the mine and in the economical extraction of the ore. A heavy inrush of water on the 10th level of the mine in 1906, preceded by still earlier water difficulties, rendered imperative the immediate installation of a pumping equipment capable of handling large flows of water. While the Old Dominion has been recognized as a wet mine since its early days and one in which the complete control of the water situation was of paramount importance in the development of the lower levels, it is chiefly in the last nine years, since the installation of the increased pumping equipment, that the mine has developed and handled large quantities of water. Its maximum pumping record was reached in the first six months of 1915, during which time, following a prolonged period of abnormal precipitation, the pumps handled 1,624,740,000 gal. of water; while in the month of March alone, over 407,000,000 gal. of water were pumped from the mine.

Jan 1, 1917