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By M. A. Elliott, F. W. Brown

"INTRODUCTION During the recent war the Bureau of Mines, at the request of one of the armed services, investigated the hazards that night be encountered 5n handling perchloric acid, particularly if spilled on certain materials. The hazardous nature of perchloric acid when mixed with reducing agents had been known qualitatively, but it was desired to obtain quantitative data on the explosion hazards of such materials. Accordingly, tests were made to determine the sensitivity of mixtures of perchloric acid and oxidizable materials to initiation by heat, impact, sparks, flame, and explosive impulses. This report summarizes the results of those tests.PROPERTIES OF PERCELORIC ACIDAnhydrous perchloric acid is a colorless,hygroscopic, volatile, mobile liquid that fumes in the air. The anhydrous acid is unstable at ordinary temperatures, and therefore the commercial acid is a water solution containing either 60 percent or 70 percent by weight of the anhydrous acid. The commercial acid is widely used in chemical analysis, frequently to oxidize organic material. If proper precautions are not observed, such an oxidixation may become exceedingly rapid and result in an explosion. Several such explosions involving the acid are mentioned in the literature. 4, 5, 6/"

Jan 1, 1948

By Dong G. Chae

A model for the leaching of oxide ores is developed and II correlated with laboratory tests for percolation leaching of copper oxide are. Using the model, recovery of metal values and lixiviant concentration of the effluent solution at any time may be evaluated. For the copper oxide ore a simplified version of the model is examined for the leaching mechanism consisting of: 1) a surface flush reaction with the highest rate of lixiviant consumption; 2) penetration of lixiviant to react with copper minerals and gangue constituents; and, 3) slow lixiviant consumption, mostly by residual gangue materials. The simplified model is able to explain reasonably the leaching behavior of copper oxide ore by introducing a concept of effective initial size to correct for packing in a bed of fine particles.

Jan 1, 1979

By G. Deschênes

The Eleonore property (James Bay district of Northern Québec), owned by Goldcorp, hosts gold within stockworks of quartz-tourmaline-arsenopyrite veins and veinlets contained within microcline (potassic alteration) and brown tourmaline replacement zones. The preliminary investigation to recover gold from drill core samples showed that flotation followed ultrafine grinding and cyanidation is the preferred option. Ultrafine grinding is used to liberate gold finely disseminated in sulphides. The flotation concentrate used in the investigation had a P80 of 11 microns and contained 75.5 g/t Au, 5.0 g/t Ag, 10.3% S, 0.07% Cu and traces of antimony (0.03%). The mineralogical characterization showed the presence of 65% gangue minerals, 23% pyrrhotite (hexagonal), 9.6% arsenopyrite, 2.2% pyrite and 0.08% chalcopyrite with trace amounts of galena (0.05%) and sphalerite (0.03%). Gold was in the form of native gold and electrum. A straight cyanidation conducted at pH 11.0, DO of 3-5 ppm, 2000 ppm NaCN, 20 C 72 hours extracted 97.0% Au and consumed 31.5 kg/t NaCN. The equilibrium was reached within 24 hours. Increasing the dissolved oxygen to 16 ppm reduced the consumption of cyanide to 22.0 kg/t with 96.7% Au extraction. A 16-h pretreatment with 2.0 kg/t lead nitrate, followed by a 24-h cyanidation reduced the cyanide consumption to 6.0 kg/t with a gold extraction of 97.5%. Increasing the lead nitrate addition to 6.0 kg/t reduced the cyanide consumption to 1.2 kg/t by passivating the surface of pyrrhotite. The gold extraction remained at 97.0%. It was possible to decrease the concentration of cyanide to 800 ppm NaCN without compromising gold extraction. The associated cyanide consumption was 1.2 kg/t NaCN. The passivation of gold grains was an issue when the cyanide concentration was decreased to 550 ppm NaCN. The gold extraction decreased to 92.2%. The average lime addition for all the tests was 7.4 kg/t and the average silver extraction was 80%. Efficient cyanidation of an ultrafine sulphide concentrate with only 800 ppm NaCN represents an advance in leaching of ultrafine sulphide concentrates.

Jan 1, 2013

By Noel N. Moebs

The U.S. Bureau of Mines is conducting research on many topics relating to the mineral resources of the United States. This is done to ensure an adequate supply of minerals essential to a viable domestic industry and a sound economy. The United States is almost totally dependent on foreign supplies for a number of minerals such as chromium, niobium, tantalum, and manganese for which there is no available substitute, while many other minerals such as titanium are abundantly distributed throughout the earth but seldom occur in adequate concentrations or useful forms. This report describes an example of a small but high-grade occurrence of titanium are in Nelson County, VA. This occurrence could be exploited under favorable economic conditions with new mining technology such as borehole slurry mining. The report demonstrates that the dikes at titanium ore, a mixture of ilmenite and apatite locally termed nelsonite, can be detected and traced along strike using magnetometer traverses. This information will aid in the selection of appropriate slurry borehole mining test sites in the area.

Jan 1, 1993

By Thomas J. Crocker, Douglas B. Uthus

Tunnel Boring Machines (TBM) have gained worldwide acceptance in the construction field and are being employed in ever increasing numbers to drive underground transit lines, drainage systems, etc. However, TBM utilization in the mining industry, and more specifically coal mining, has been very limited. This paper reviews past and present applications of TBMs to coal mining and examines the needs of the industry in an attempt to offer some insight as to what a TBM system must provide if the excavation potential demonstrated in civil works projects is to be realized in coal operations. EUROPEAN EXPERIENCE Germany The Germans recognized long ago the potential of mechanized drivage for coal mine entry development. Early in the 1960's experimental runs were made with a full-face Wohlmyer roadheader at the Westerholt Mine and trials were conducted on a roller bit armed full-face Bade roadheader. But because of problems with penetrating the various carboniferous strata occurring in changing sequence and hardness, these first attempts were soon terminated. After viewing later successes in the construction industry with improved TBMs, new attempts were initiated by the German mining industry in 1971 to mechanize drivage of their development entries. Four TBMs of two different types were placed in operation.

Jan 1, 1976

By Gyimah Kasali

Rapid Load Testing was performed as part of an extensive drilled pier testing program for the University of California Berkeley Capital Improvement Program. The purpose of the program was to: (1) Verify the axial compressive design capacity values for the planned 24" piers, and to estimate the capacity of the existing 30" CIDH piers, and (2) To evaluate the seismic performance of the proposed drilled shafts. The Fundex PLT was used since the loading period of the PLT is very similar to the period of a seismic event, making it an ideal tool to model the pier response to seismic events. "Performance-based design" of structures subject to seismic loads has been of particular interest to UC Berkeley Seismic Review Committee and the Pacific Earthquake Engineering Research Center. The comparison of static tests to Rapid Load testing also provided valuable correlations. The program represents one of the most comprehensive drilled pier test programs on the West Coast. The testing program consisted of Rapid Load Testing using the Fundex PLT on 6 drilled piers. Rapid Load Tests were followed by conventional static compression and tension tests on selected piers, followed by another cycle of rapid load tests on the statically tested piers. The piers featured extensive instrumentation to allow detailed interpretation of the test result. Correlations were drawn to compare static load test result to that of the PLT in the particular soil profile, and the PLT also provided the data to analyze the ultimate seismic capacity of the piers. The load test results indicate that the ratio of interpreted failure load from the PLT data to the corresponding load from the static load test data is about 1.2 to 1.3 for the clayey soils underlying the test site. The results also indicate that the PLT offers an economical approach to defining the stiffness of drilled pier foundations subjected to seismic loads for use in performance-based design.

Jan 1, 2002

By Giuliana A. Zelada-Tumialan

Reduced workability and flowability of the concrete through the tremie tubes and drilled shaft reinforcement have been identified as the main causes of tremie-concrete drilled shaft concrete defects. This paper discusses two recent case studies of defective tremie-concrete drilled shafts. The defects (soft inclusions, aggregate segregation, and low concrete strength) were primarily caused by the combined effects of the tremie placing sequence, rapid concrete slump loss, and poor passing and blocking characteristics of the approved concrete mix design. The level of detail contained in the drilled shaft specifications varied between projects. However, even when the specifications incorporated several of the more recent recommendations for tremie-concrete placement, the case studies showed that typical provisions for concrete mix proportioning and placement can be further improved to minimize construction defects such as those described in this paper. Based on the findings of the case studies presented, recommendations for the development of more effective specifications are provided. The recommendations include requirements for mock-up testing of proposed concrete mix designs and evaluation of the tremie-concrete placement sequence. Performance of such testing and evaluation would greatly reduce the potential for drilled shaft defects and consequent time and financial burdens associated with them.

Jan 1, 2009

By K. G. Thorne, D. R. Lentz, A. F. Park

"The Main zone of the Clarence Stream gold deposit is hosted by a shear zone adjacent to the Saint George batholith in southwestern New Brunswick. The mineralization history relates to progressive deformation in the shear zone and the intrusion of the Magaguadavic granodiorite.Of three phases of deformation that have affected the area (D1-D3), D1 is not observed in the Clarence Stream shear zone. Two suites of igneous rocks intrude the shear zone: post-D2, pre-D3 gabbro; and granitic dikes, which crosscut the gabbros. Granitic dikes show a diverse range of relationships to D3 features, from pre-syn-D3 mylonitic fabrics in transposed and highly deformed enclaves, to nondeformed and entirely discordant dikes (post-D3).A variety of veins occur within this shear zone. Zoisite-bearing and later, crosscutting epidote-bearing veins are preserved as relics in quartz-mylonites, and predate quartz veins that host gold mineralization. The epidote-bearing veins are associated with pseudotachylitic cataclasite dikes, consistent with transient brittle failure during ductile deformation.Deformation relates to right-lateral strike-slip motion across the shear zone, and subhorizontal and near-vertical stretching lineations imply transpression. A late (late- or post-D3) dip-slip phase of motion is also apparent, and cooling followed a metamorphic peak early in D2-D3 history. Deformation of the shear zone, and more localized transient brittle failure, provided the permeability for fluid movement and vein emplacement. This scenario is similar to the findings of other studies, in which geochemical, tracer isotopic, and age-dating (U/Pb, 40Ar/39Ar) results suggest that the adjacent Magaguadavic granodiorite provided heat and metals. La zone principale (Main zone) du gisement d’or de Clarence Stream est encaissée par une zone de cisaillement qui longe le batholite de Saint George dans le sud-ouest du Nouveau Brunswick. L’historique de la mise en place de la minéralisation accorde un rôle important à la déformation progressive dans la zone de cisaillement et à la mise en place de la granodiorite de Magaguadavic.Des trois phases de déformation à avoir affecté la région (D1-D3), les effets de D1 ne sont pas observés dans la zone de cisaillement de Clarence Stream. Deux suites de roches ignées se sont mises en place dans cette zone de cisaillement : un gabbro post D2, pré-D3 et des dykes granitiques qui recoupent le gabbro. Les dykes granitiques montrent une grande diversité de relations avec les structures D3, allant de précoces à synchrones aux fabriques mylonitiques D3 dans des enclaves transportées et fortement déformées à des dykes complètement discordants et non déformés (post-D3).On note diverses veines dans cette zone de cisaillement. Des veines contenant de la zoisite ainsi que des veines d’épidote sécantes plus tardives, lesquelles sont préservées comme reliquats dans les mylonites à quartz et sont plus vieilles que les veines de quartz contenant la minéralisation aurifère. Les veines d’épidote sont associées à des dykes de catacalasite à texture de pseudotachylite, compatibles avec une rupture cassante épisodique durant la déformation ductile.La déformation résulte d’un mouvement décrochant dextre le long de la zone de cisaillement et les linéations d’étirement subhorizontales et quasi-verticales impliquent de la transpression. Une phase tardive (tardi- ou post-D3) de mouvement selon le pendage est aussi apparente, et le refroidissement succède à un pic métamorphique tôt dans l’histoire D2-D3. La déformation de la zone de cisaillement et la rupture cassante épisodique ont fourni la perméabilité nécessaire au mouvement des fluides et à la mise en place des veines. Ce scénario est similaire à celui proposé par d’autres études, dans lesquelles les résultats de géochimie, de traceurs isotopiques et de géochronologie (U/Pb, 40Ar/39Ar) suggèrent que la granodiorite de Magaguadavic avoisinante a fourni la chaleur et les métaux."

Jan 1, 2008

By Gerry Houlahan

The east span of the 3.5 km long SF-Oakland Bay Bridge is supported by different types of foundations along its span. Starting from the west, its first 460 m section comprising twin concrete box-girders is supported by sands and rock on Yerba Buena Island. A 620 m long steel suspension span then bridges a 25 m deep channel that is formed in sediments overlying rock. Twin concrete box girder structures, each 2.4 km long, complete the stretch over the remainder of San Francisco Bay to the engineered earth fill landing at its east end. For most of its length, the Skyway bridges water 3 to 10 m deep over soft surficial Young Bay Mud. The foundation types include spread footings with hold-downs, steel and concrete piles that are set in drilled rock sockets up to 3 m in diameter and 2.5 m diameter steel tubular piles driven to penetrations of up to 100 m. The design and construction-related considerations are presented. The different foundation types, influences of the site geology and earthquake demands on the substructures are discussed. The seismic motions of the bridge superstructures and substructures, as well as the depth-varying soil motions, influenced the foundation design. Together with performance-based design criteria, including post-earthquake footing displacement limits, these seismic demands influenced various aspects of the foundation design, including the use of battered and vertical piles.

Jan 1, 2005

By H. R. Batchelder

The Bureau of Mines Gas Synthesis Demonstration Plant at Louisiana, Mo., includes apparatus for the gasification of pulverized coal with oxygen and superheated steam. A pebble heater constructed by the Babcock & Wilcox Co. is used to superheat nominal 5-pound steam for the gasification process, usually to temperatures of 1,600° to 2,300° F. with flow rates of 1,400 to 2,300 pounds per hour. Heaters of this sort have been described. So far as is known, the Babcock & Wilcox Co. is the sole commercial manufacturer of equipment of this type. Units have been built with capacities above 18,000 pounds of steam per hour.

Jan 1, 1951

By Cecil Q. Cupps

Results are presented of a comprehensive study of the characteristics of the original oil in the Weber sandstone reservoir, Rangely oil field, Colorado. Through the medium of subsurface sampling, adequately representative samples of the original reservoir oil were obtained from many parts of the reservoir over a period of 5 years concurrent with active development of the reservoir. Data of differential gas liberation, pressure-viscosity, and. pressure-volume-temperature relationships are shown for 12 subsurface oil samples. Data also are given of reservoir pressure and. temperature, composition of liberated or solution Gas, composition of 22 produced-gas samples, and Hempel analyses of crude-oil samples from 18 wells. The characteristics or physical properties of the 12 subsurface oil samples, as determined by laboratory analyses, were correlated with elevation of the top of the Weber sandstone. These relationships of oil characteristics to elevation in the reservoir show that only the oil in contact with the initial gas cap was gas-saturated at the existing pressure and temperature. The characteristics of the original reservoir oil were marked by an appreciable decrease of saturation pressure and solution gas-oil ratio and increase of viscosity and density with depth below the gas-oil contact. The composition of solution gas and of' produced was also was found to vary with elevation of the oil in the reservoir.

Jan 1, 1951

In 2004, a total of 741 nonmetal mining operations reported employment to the Mine Safety and Health Administration (MSHA). These mines (e.g., potash, gypsum, salt) comprised 5.1% of all operations.

Sep 1, 2007

The term slag has been used to define a wide variety of material including mine spoil and slag produced at steel plants. The present paper is concerned only with the non-metallic alumino-silicates developed simultaneously with iron in blast furnaces.The control of iron quality by slag has long been appreciated but here aspects of slag control based on concurrent iron production are indicated. Consideration is given to the basic composition of slags relative to the type of allotrope required. Up to a point, the plant conditions, under which a particular slag type is processed, have some effect, but these conditions only widen the range of a given allotrope.They do not convert one slag type into another. The nature of the slag types and experiments with additives to convert one slag type into another are discussed.The various uses for allotropes of blast furnace slag are considered.Their use in air cooled slag, foamed slag, slag wool, cements, soil stabilization, glass bottles, and building bricks and blocks, is explored in some detail.INTRODUCTIONWithin recent memory, blast furnace practice has been solely concerned with the production of iron. The slag make at this time had not reached embarrassing proportions. In Britain, unlike Germany, no legislation existed to prevent the growth of unsightly slag banks. Generally slag found limited use as fill and road material in the immediate plant vicinity. This is broadly the case in Australia today. In Europe and America, where the slag make is of the order of several million tons annually, the room problem and the cost of dumping slag has stimulated commercial and scientific research on the disposal problem. Currently, most iron plants in Europe can profitably dispose of at least 95 per cent of their slag make.

Jan 1, 1964

By Seong- Rin Lim

Light-emitting diodes (LEDs) are regarded as environmentally friendly light sources due to their high energy efficiency and lack of mercury content. LEDs are used for a variety of domestic and commercial lighting systems, where they are replacing incandescent and fluorescent lamps at a rapid rate. Incandescent lamps inefficiently consume energy because electricity is mostly converted to heat rather than light. This causes unnecessary environmental impacts and energy consumption associated with power generation and transmission from a life cycle perspective. Although fluorescent lamps are more energy-efficient than incandescent lamps, their disposal at end-of-life presents special challenges because of the presence of toxic mercury. Despite the seemingly apparent advantages of LED, very few studies have rigorously addressed potential environmental consequences of their disposal. Specifically, LEDs are designed with III-V semiconductors that presumably consist of toxic and rare materials, including arsenic, gallium, and indium. We hypothesize that, depending on their concentrations and leachability, these constituents may also contribute to render LEDs as hazardous waste at the end of their useful life.

Jan 1, 2010

By Liming Yuan, Wei Tang, RICHARD THOMAS, JOHN SOLES, DAVOOD BAHRAMI

Mine equipment fires remain as one of the most concerning safety issues in the mining industry, and most equipment fires were caused by hot surface ignitions. Detailed experimental investigations were conducted at the National Institute for Occupational Safety and Health’s (NIOSH) Pittsburgh Mining Research Division on hot surface ignition of liquid fuels under ventilation in a mining environment. Three types of metal surface materials (stainless steel, cast iron and carbon steel), three types of liquids (diesel fuel, hydraulic fluid and engine oil) and four air ventilation speeds (0, 0.5, 1.5 and 3 m/s) were used to study the hot surface ignition probability under these conditions. Visual observation and thermocouples attached on the metal surface were used to indicate the hot surface ignition from the measured temperatures. Results show that the type of metal has a noticeable effect on the hot surface ignition, while ventilation speed has a mixed influence on ignition. Different types of liquid fuels also show different ranges of ignition temperatures. Results from this work can be used to help understand equipment mine fires and develop mitigation strategies.

Oct 1, 2022

By Chaoxun Zhao, TAIYOU LI, JIAQI JIN, Chen-Luh Lin, Jan D. Miller

A large portion of the energy consumed in copper concentrators is used to reduce the particle size of the feed by crushing and grinding. The cost of metal production could be reduced if low-grade particles of centimeter size were removed prior to further processing. Two copper sulfide ore samples (3 × 1 cm) from Arizona were analyzed by micro X-ray computed tomography (Micro-XCT) to determine the grade of copper sulfide in each particle. For copper ore sample A, a significant number of particles contained very low amounts of copper, while some particles had copper sulfide grains of millimeter size. Based on Micro-XCT, it was expected that 85 percent of copper for sample A could be recovered at 65 percent of mass rejection during preconcentration by sorting. However, in sample B (a different copper ore), distribution of copper sulfide was dispersed primarily in each ore particle, so for the particle size class of 3 × 1 cm, liberation of copper sulfide and gangue minerals was not significant. In view of the XCT results, dual-energy X-ray radiography was used as a basis for sorting. Pilot-scale X-ray sorting of sample A (10 × 1 cm) showed 31 percent rejection of a 0.08 percent Cu gangue product with a corresponding recovery of 90 percent copper.

The paper discusses the special mixing requirements for Metallurgical Plant Design and outlines the problems associated with the agitation in Mineral Processing Industry today. It also covers new applications such as state of the art large leach tanks and backfill for deep mining.

Jan 1, 2004

By H. Harzer

Statistics Canada record s indicate that in recent years 70 to 80% of the entire Canadian coal production originated from Western Canadian mines, in which about 55 to 65% of the coals are bituminous. Until recently, less than 20% of the latter were extracted by underground methods , the remainder being surface-mined. However, it is estimated that within the foreseeable future up to 80 or 90% will have to be gained by underground techniques. Although Western Canadian coal resources are considerable, they are unfortunately locked in severely distorted, steeply pitching and faulted seams of variable thickness. Consequently, their economic extraction poses serious engineering problems. One possible solution to the problems is to apply hydromechanical methods to underground mining. This is a well-proven method shown to be economically viable under Western Canadian conditions. This paper endeavours to widen the scope of published data on hydraulic coal mining and is based on practical engineering and cost data gathered through contacts with West German designers and operators of hydraulic mines.

Jan 1, 1978

By Zay Jeffries

From the title of this chapter the reader could expect an attempt to outline the anticipated shape of things to come, mineralwise. We have no crystal ball and if we possessed one we could claim no expertness in its use. In the first place no one can tell the future status of man. No one has any way of knowing to what extent peace will prevail, nor to what extent changes may occur in national sovereignties or forms of government or in international relationships. So future man is an uncertainty. Nor can we predict new developments that may result in significant changes in man's status or in the mineral industry or both. If, for example, this chapter had been written in the middle 1930's, nearly everything that has happened since in the field of atomic energy would have been missed. Yet what a vast change this has made in the status of man! Also the changes in the mineral industry have been important. A writer would have been bold indeed had he prophesied that uranium would play such an important role. But we need not confine our foggy vision to the atomic energy field. The steep rise in the use of aluminum, titanium, and germanium reflects the unpredictable in what may be thought of as the more normal pursuits. This should not discourage one from using the past and currently observable trends as bases for limited predictions. To do this, however, it is desirable to make certain assumptions about man's status without even a pretense that these assumptions have a high probability of fulfillment: 1. Only minor changes will occur in the geographical boundaries of the nations of the world. 2. World War III will not take place in the near future. 3. As a consequence of (2), man will not destroy himself by wanton use of atomic weapons. 4. Disarmament will take place, if at all, gradually rather than all at one time. Under the above assumptions the world will enjoy a period of relative peace even though the status may be one of an armed truce. The assump-

Jan 1, 1959

By A. L. Ling, A. K. Janzen

"Design of effective mine water treatment plants depends on the ability to reliably predict treatment outcomes, but systems with multiple chemical and physical treatment processes and recycle loops can be difficult to model. GoldPHREEQC is a modeling framework that integrates mass and flow routing capabilities of GoldSim software and water quality calculations provided by PHREEQC, and is well-suited to modeling parameters of interest in the mining industry, especially metals and sulfate. Physical processes such as membrane separation and greensand filtration are modeled by defining mass rejections for each parameter and flow routing based on vendor projections and bench- or pilot-scale equipment testing. GoldPHREEQC models chemical precipitation processes such as HDS metals removal and gypsum precipitation by (1) performing surface-aging and solubility calculations in PHREEQC and (2) using the GoldSim framework to direct supernatant and precipitate to subsequent process steps. Users can apply this modeling framework to predict effluent water quality, chemical requirements, sludge production, and required equipment capacity to support design, troubleshooting, and cost estimating. INTRODUCTION Design of effective mine water treatment plants depends on the ability to reliably predict treatment outcomes, but systems with multiple chemical and physical treatment processes and recycle loops can be difficult to model. GoldPHREEQC is a modeling framework that integrates mass and flow routing capabilities of GoldSim software (1) and water quality calculations provided by PHREEQC (2), and is well-suited to modeling treatment of parameters of interest in the mining industry, especially metals and sulfate. GoldPHREEQC can also be applied to other water treatment scenarios using inorganic reactions and processes. The GoldPHREEQC model framework moves water and mass between specified model nodes and calculates specified reaction and water quality outcomes. It can be organized to provide flow, load, and concentration information for each location, including effluent and byproduct streams, and outputs can be adapted to include power and chemical costs."

Jan 1, 2018