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By F. B. Plummer, R. B. Newcome

The practice of introducing acid into oil wells to increase production of oil and gas has been in use since 1894, when it was first used in the Pennsylvania oil fields30.‡ It is only since 1928 that it has been used to any extent in the Mid-Continent18. The process has proved successful in increasing production, at least temporarily, in depleted oil fields where the producing formation is highly calcareous and where water drive is not too pronounced. In the Zwolle field in Louisiana, where the producing horizon is a chalk, increases of 100 per cent have been recorded25. In north-central Texas, where the oil is produced from the Marble Falls limestone, equally pronounced increases have resulted3. The production also in some fields yielding oil from quartz sand cemented with calcitc has been benefited. The evidence of actual increase in total recovery of oil, however, has been questioned by some engineers18. It has been pointed out that the results of the treatment of a well in a now district, where the process has never been tried out, can never be predicted with certainty, since other factors besides percentage of calcareous content of the oil sand play a large part in determining the success of the method. Numerous articles have been published on acid treatment and on the effects of acid on limestone1-35, yet very little has been written concerning experimental work on the actual effect of acid on capillary pores and larger oil-coated voids of oil sands. This is due partly to difficulties in duplicating field conditions in a laboratory and partly to the fact that the process has been carried out largely by contracting companies that have been unwilling to publish details of their results for fear of loss of business to competitors. The authors, using equipment developed to measure the radial permeability of oil-sand cores2', have developed a method of investigating the results of acid treatment which has enabled them to test numerous cores and to study in some detail the action of acid on the different types of rocks, particularly fine-grained rocks.

Jan 1, 1936

By Chaturvedula V. K

Pillar extraction carried out using various methods (split and lift, Wongawilli and Old Ben) involves the formation of narrow fenders (commonly 7 m of coal) formed by driving "splits" for lifting off with a continuous miner. The strata above a split and fender adjacent to the goaf consists of a cantilever beam (usually >3 m thick) that extends from the solid coal and bridges across the fender. Lifting off the fender from the split in safe conditions depends upon the bridging capability of the cantilever and the fender strength. The nature and competence of the immediate and near roof, the support capability of the coal fender and the presence of faults and or joints can adversely affect the bridging behaviour of the cantilever. Insufficient knowledge of these parameters can lead to extraction under dangerous conditions. Remnants of fenders ("stooks") also support the cantilever and their dimensions are critical to obtain regular caving and goaf falls. Stook area, goaf roof span and roof stand-up time after lifting can be related and only a relatively small increase in stook area of 10-15 m2 can lead to a significantly increased stand-up time, especially under a massive roof. Such conditions strongly influence the re- distribution of abutment stresses and can create increased outbye pillar loading. Based on detailed underground geotechnical investigations, it is concluded that strata caveability, roof cantilever behaviour, fender H:W ratio and remnant stook size are all critical parameters for successful and safe pillar extraction.

Jan 1, 1992

By D. J. Fitzpatrick

The paper reviews current mining subsidence research at The Department of Mining Engineering, University of Notting- ham. Special attention is being devoted to prediction of ground movements between the mining horizon and the surface using physical and computer-based models. The paper presented discusses linear and non- linear finite element methods and compares results with those from physical models and field observations. Special attention is focussed on the determination of the effect of caved zones on overlying and underlying geological structures. The paper presents data from comparisons with U.K. case histories.

Jan 1, 1986

By F. B. Plummer, R. B. Newcome

The practice of introducing acid into oil wells to increase production of oil and gas has been in use since 1894, when it was first used in the Pennsylvania oil fields30.‡ It is only since 1928 that it has been used to any extent in the Mid-Continent18. The process has proved successful in increasing production, at least temporarily, in depleted oil fields where the producing formation is highly calcareous and where water drive is not too pronounced. In the Zwolle field in Louisiana, where the producing horizon is a chalk, increases of 100 per cent have been recorded25. In north-central Texas, where the oil is produced from the Marble Falls limestone, equally pronounced increases have resulted3. The production also in some fields yielding oil from quartz sand cemented with calcitc has been benefited. The evidence of actual increase in total recovery of oil, however, has been questioned by some engineers18. It has been pointed out that the results of the treatment of a well in a now district, where the process has never been tried out, can never be predicted with certainty, since other factors besides percentage of calcareous content of the oil sand play a large part in determining the success of the method. Numerous articles have been published on acid treatment and on the effects of acid on limestone1-35, yet very little has been written concerning experimental work on the actual effect of acid on capillary pores and larger oil-coated voids of oil sands. This is due partly to difficulties in duplicating field conditions in a laboratory and partly to the fact that the process has been carried out largely by contracting companies that have been unwilling to publish details of their results for fear of loss of business to competitors. The authors, using equipment developed to measure the radial permeability of oil-sand cores2', have developed a method of investigating the results of acid treatment which has enabled them to test numerous cores and to study in some detail the action of acid on the different types of rocks, particularly fine-grained rocks.

Jan 1, 1936

By G. G. Richards, Y. Oyediran, V. Chow

The oxygen softening process for partial removal of arsenic and antimony from lead bullion has been in use at Teck Cominco's Trail smelter since 1986. In this process, industrial oxygen is injected into bullion to remove As and Sb with the formation of an oxide slag. In Trail, the levels of these elements are reduced to concentrations suitable for processing in the Betts electrorefining plant. Recent moves toward the treatment of higher arsenic-bearing feeds have necessitated an increase in the process capacity to meet the specifications for drossing plant bullion. Process intensification trials were conducted in-plant to develop an operating strategy for higher bullion processing rates. This was preceded by a study conducted with McGill University to develop a fundamental understanding of the therm ochemistry and kinetics of the process. The results have yielded more effective control of the operation, and identified opportunities for further improvements.

Jan 1, 2008

By Shian Jia

Ultrasonic Stirring Technology (UST) is used in this study to manufacture Al-based nano-composites. Ultrasonic cavitation plays an important role in refining the microstructure, dispersing the nanoparticles and breaking up clusters of nanoparticles. In this paper, 6061/A356 alloys and Al2O3/SiC nanoparticles are used as the matrix alloys and the reinforcements, respectively. The nanoparticles were inserted into the molten alloy and dispersed by ultrasonic cavitation and acoustic streaming. A previously developed multiphase Computational Fluid Dynamics (CFD) model was used to study the cavitation and the nanodispersion phenomena during ultrasonic processing of these alloys. A comparison between the mechanical properties of the as-cast 6061 and 356 alloys and nano-composites has been performed.

Aug 16, 2017

By Will H. Coghill

The jig men of the Tri-State (Joplin-Miami) zinc district complain about the flakiness of their mill feed. They believe that the flakiness of the composite grains of gangue and mineral are to blame for losses of zinc; that is, that the flaky grains in the jig tailings have higher zinc tenor than the cubical grains. Although the evidence which follows contradicts this belief, no effort is made to give a final and conclusive answer. On the other hand, there is outlined a positive and mechanical method which the operator may use to pursue this and similar investigations. DISCUSSION OF SCREENING METHOD Hand-sorting is obviously not satisfactory for separating cubical grains from flaky grains because the personal influence can not be removed. Screens, however, may be used with success. A set of each of two types of screens is required; namely, the square-hole type and the rectangular (rectang, oblong) type. The square-hole screens must be of the double Tyler scale; that is, the order of the sieves should be after the fourth root of two instead of the customary square root of two; close sizing is important. The size of the rectang screens may be selected by trials so that a part of the material already closely sized on the square-hole screens, will pass the oblong holes. Obviously, the cubical grains will remain on the rectang and the flaky grains will pass through. Hence the mode of operation is to screen first on square-hole screens and then split the products on the oblong-hole screens.

Jan 1, 1928

By K. Kalgraf

The motion and stability of the metal/electrolyte interface is determined by Navier-Stokes equation. The equation may be decomposed into two independent equations by taking the divergence and curl of Navier-Stokes equation. The divergence determines the motion and stability of magneto-gravitational waves. The curl of Navier-Stokes equation gives an equation containing only velocity and magnetic field, and states that the magnetic field is driving a circulation pattern in the cell, and this magneto-flow has its own stability conditions. The waves are called Alfven waves, and their stability properties are related only to magnetic field and geometry.

Jan 1, 2001

By J G Bastias

It is sometimes necessary to resort to extremes in order to call attention to something that is pertinent to safety in mining. When some of the experts in occupational safety talk about this topic, they usually refer to a 'regulation' established by the Romans which stated that, due to the health hazards, usually death, no Romans but only slaves should work in mining. Since the time of the Roman Empire, a lot of ground has been covered in the field of mine safety. Nowadays, it can be said that occupational safety is being seriously addressed, with the result that the number of mining accidents has reduced dramatically, fatalities in this industry are less frequent, and the rate of accidents compared with other activities, such as construction or fanning, is low. This achievement has been possible initially through government legislation and by procedures established by the mining companies themselves. However, the dilemma for government is whether to regulate and if so, how much. It is pleasing to observe that most companies are establishing working procedures which conform with new government legislation, placing strong emphasis on the duty of care for mine employees. There will always be some regulatory aspects of legislation, and perhaps the best example of this is in the use of mine hoists where there are no international or Australian standards, and the regulations applied are of an empirical nature that err on the side of safety.

Jan 1, 1994

By R. A. Guereco

Accurate measurements of physical dimensions of a section of stainless steel capillary tubing are presented and used to develop two final working equations for an absolute gas viscosimeter. The effects of pressure and temperature on these dimensions are considered. The internal surface finish and nonuniformity of the capillary bore are discussed, as well as entrance, kinetic energy, gas slippage, and gas compressibility correction factors.

Jan 1, 1967

By M. De Ladurantaye-Noël, M. Laliberte

Selenium is widely present in the environment at usually low concentration. It is mostly present in the environment at higher oxidation states, i.e., as selenites and selenates (+4 and +6 oxidation states respectively). It is rarely present as selenides (-2 oxidation state) and almost never found as the element (0 oxidation state). Selenites and selenates are generally soluble in water, as such they cannot easily be removed from water by precipitation. Selenites can form insoluble surface complexes with metal oxides such as ferric hydrous oxide and manganese hydroxide, and can therefore be removed that way. However, it is not so common to find selenites in natural environments as it will quickly oxidize to selenate in aerobic conditions. Elemental selenium can also be produced from selenites or selenates by using a reduction process; the end product is a colloid that can be destabilized to be removed from water using the right chemistry. Because of their toxicity, selenides need to be handled with care, and if present, it can form insoluble metal salts or, at low pH, be emitted as H2Se, a noxious and highly toxic gas. The most favorable selenium forms for its removal are therefore selenite and elemental selenium. Organo-selenium species play a crucial part in understanding selenium toxicity. There are a great number of these species. Basically, any organic species that contains sulfur has an equivalent that contains selenium. Of particular interest is the substitution of sulfur by selenium in the two sulfur-bearing amino acids, cysteine and methionine, resulting in selenocysteine and selenomethionine. Methylseleninic acid (CH3SeO2H) is another organo-selenium specie which has been detected in water treated by biological processes and which is biologically active.

Feb 1, 2023

By Donald R. Clark

"Drilled shafts are being used as foundation support for parabolic solar troughs at the Genesis Solar Project being constructed near Blythe, California. Three types of drilled shaft foundations are required for the project. At project build-out, there will be a total of 23,008 drilled shafts installed at the site. Preliminary designs for the axial and lateral capacity of the drilled piers were based on conventional geotechnical engineering methodologies and soil-structure interaction. The drilled shafts and subsurface conditions were modeled through the use of the computer program LPILE v6.0.Conducting lateral load testing of drilled shafts was considered appropriate to confirm or modify the geotechnical parameters used in the preliminary design. The lateral load testing program was conducted to provide site-specific test data that would allow the design engineers (both geotechnical and structural) to predict the actual performance and adequacy of the proposed drilled shaft foundations and improve the efficiency and hopefully reduce project costs.The lateral load testing was conducted within two solar fields at the site. Three pairs of drilled shaft foundations were installed in each field, instrumented, and laterally loaded to determine load-deflection response. A value-engineered option, proposed by one of the drilled shaft contractors, was also load tested. The results of the load-deflection data obtained in the field was used to modify the soil modeling used in the original L-PILE analyses and adjust the production drilled shaft lengths.Based on the results of the lateral load testing, the in-situ moduli of the subsurface soils were significantly increased over that assumed in the preliminary analyses. Based on the final soil-structure interaction analyses, the preliminary drilled shaft lengths were reduced by 2 to 2-1/2 feet. This resulted in an overall reduction of 55,654 feet of drilled shaft construction on the entire project, a savings of approximately 16.5% over the preliminary"

Jan 1, 2017

By J. S. Rapp

This report is based on existing reports and recently gathered field data. It discusses mineral resource potential of Tertiary playas in the Fort Irwin region. An estimated 1.3 million tons of measured salt "reserves", and 20 million tons of indicated salt resources, have been identified north of the fort. Other indicated resources include 300,000 tons of celestite, 800,000 tons of gypsum, and 10 million tons of selenite. Zeolitic tuff was mined south of Fort Irwin from 1978 to 1984, and unexplored occurrences are widespread. Calcium-bentonite is mined near Barstow, and more may exist, including valuable sodium-and lithium-based bentonites.

Jan 1, 1992

By Peter Ehren

Global Geoscience is developing a Rhyolite Ridge project, a shallow boron-lithium resource deposit, located in Nevada about 25 km from Albermarle’s Silver Peak operation. The main minerals of interest are the boron mineral searlesite (40%wt) and lithium containing clay minerals. These minerals are found among principally calcite, feldspar, muscovite, dolomite, and quartz. The equivalent commercial value is about 7–9% boric acid (H3BO3) and 0.8–1.0% lithium carbonate (Li2CO3) equivalents. Selective agitated leach tests at SGS Lakefield laboratory showed that searlesite can be acid leached between 20 and 75 °C and at a pH lower than 4. On the other hand, lithium can be leached between 20 and 75 °C and at a pH lower than 1. In other words, lithium can be recovered at low temperatures if sufficient free acid is available, which gave the motivation to investigate heap leaching of the mineral. The PLS contains boric acid, magnesium, sodium, lithium, potassium aluminium, and iron sulfates.

By S. Mao

Total station has been predominantly applied in stationary survey scenarios in construction. With the moving target tracking and point survey automation functions, a robotic total station (RTS) lends itself well to more dynamic applications. Nevertheless, a RTS unit is still unable to track multiple targets simultaneously or to survey a target point when the line-of-sight is temporarily unavailable. In this paper, we propose a methodology to synchronize and automate multiple RTS units intended to address dynamic tracking and surveying applications in the construction field. By using the application programming interface (API) from the manufacturer, we implement the proposed methodology and the prototype system integrates two RTS units in regard to space and time and communicates survey command instructions among RTS units through wireless networks. The two RTS units can be operated to survey the two ends of one swinging sling concurrently in order to retrieve the actual length of the sling within several millimeters accuracy. Besides, in applications where line-of-sight between a target object and one RTS unit cannot be guaranteed all the time, continuous surveying can be materialized by automatically delegating the task to another synchronized RTS unit with clear view of the target object. A field test was conducted to demonstrate the application of the proposed automation approach in which sling length was measured of a rigging framework used for lifting industrial modules. The testing results are presented and achievable accuracy and reliability are discussed. The proposed solution overcomes the limitations of global positioning system (GPS) and laser scanning and holds high potential to provide cost effective solutions to many dynamic field applications.

Aug 1, 2013

By Ann C. Kim

This Bureau of Mines report summarizes the methods and results of many of the laboratory studies on spontaneous heating of coal published in the last 50 years. It includes a brief description of experimental methods, indices of combustibility, and important contributing factors. Adiabatic calorimetry, isothermal calorimetry, [0], sorption systems, or temperature differential are the most frequently used experimental methods. Indices of combustibility include various heating rates, crossing point temperature, ignition temperature, and CO index. Factors that affect the spontaneous heating of coal include air flow rate, changes in moisture content, particle size, rank, temperature, pyrite content, geological factors, and mining practice. Experimental conditions and results from 20 papers are summarized in an appendix, and the bibliography contains 45 references.

Jan 1, 1977

By W. M. Cross

The hydrophobic character of sapphire surfaces in SDS solutions was examined with respect to the aggregative nature of the adsorbed surfactant phase. It was found that, at equilibrium, sapphire surfaces having adsorbed SDS bi-layers exhibited no contact angle. Conversely, when the adsorbed SDS was found to be mi-cellar in nature, sapphire surfaces developed significant hydrophobic character. The surface states as detected by Fr -IRIIRS conformational analysis were found to be reversible with temperature. The variation in adsorption density with temperature was studied by in situ Fr-IRIIRS. The isosteric heat of adsorption was calculated to be -1.6 kcal/mole. Although the adsorbed SDS was found to undergo a reversible phase change between 25 and 32°C, similar to SDS in solution, the extent of adsorption was not reversible with temperature.

Jan 1, 1993

By Z. S. Shao, X. Z. Li

"Sub-critical crack growth plays an important role in long-term creep failure in brittle rock. Based on micromechanics established by using relationship between micromechanical wing crack growth model and macroscopic strain, and comparing theoretical model with testing results, a method, which applies the theory to real rock, is suggested in this paper. Using this method, properties of creep, damage and progressive failure in brittle rock are investigated. Effects of stress state on creep failure time and steady-state creep rate are analyzed and graphically presented. The results are helpful to support structure design and service life evaluation of underground structures with high geostatic stresses. INTRODUCTIONDuring the long-term operation in underground space with brittle surrounding rock, due to chemical action between pore water and rock, the failure of rock often occurs at stresses below its short-term failure strength, which brings serious effect on the long-term stability of underground structure. Thus, the long-term strength of brittle rock attracted wide interests of scholars around the world. The static fatigue limit was predicted by exponential function that is derived from abundant experiment data of stress level and failure time(Schmidtke & Lajtai, 1985), and similar result by relationship between stress state and failure time was also suggested (Lau & Chandler, 2004; Aubertin et al., 2000; Sangha & Dhir, 1972). According to relationship between steady creep rate and stress state during creep, a critical stress that transforms steady-state creep to accelerated creep was studied and the long-term strength was suggested (Tsai et al., 2008; Ma & Daemen, 2006; Lajtai et al., 1991). Based on the results of experiment in compression, the long-term strength of rock was defined by stress at volume strain reversal. When applied stresses are larger than the long-term strength, the microcracks in the rock will grow constantly, damage of rock will increase and failure of rock will occur finally (Chandler, 2013; Bieniawski, 1967; Brace et al., 1966)."

Jan 1, 2015

By Donald R. Clark

Drilled shafts are being used as foundation support for parabolic solar troughs at the Genesis Solar Project being constructed near Blythe, California. Three types of drilled shaft foundations are required for the project. At project build-out, there will be a total of 23,008 drilled shafts installed at the site. Preliminary designs for the axial and lateral capacity of the drilled piers were based on conventional geotechnical engineering methodologies and soil-structure interaction. The drilled shafts and subsurface conditions were modeled through the use of the computer program LPILE v6.0. Conducting lateral load testing of drilled shafts was considered appropriate to confirm or modify the geotechnical parameters used in the preliminary design. The lateral load testing program was conducted to provide site-specific test data that would allow the design engineers (both geotechnical and structural) to predict the actual performance and adequacy of the proposed drilled shaft foundations and improve the efficiency and hopefully reduce project costs. The lateral load testing was conducted within two solar fields at the site. Three pairs of drilled shaft foundations were installed in each field, instrumented, and laterally loaded to determine load-deflection response. A value-engineered option, proposed by one of the drilled shaft contractors, was also load tested. The results of the load-deflection data obtained in the field was used to modify the soil modeling used in the original L-PILE analyses and adjust the production drilled shaft lengths. Based on the results of the lateral load testing, the in-situ moduli of the subsurface soils were significantly increased over that assumed in the preliminary analyses. Based on the final soil-structure interaction analyses, the preliminary drilled shaft lengths were reduced by 2 to 2-1/2 feet. This resulted in an overall reduction of 55,654 feet of drilled shaft construction on the entire project, a savings of approximately 16.5% over the preliminary design.

By Xiyu Gao, Yi Yang, Mark I. Pownceby, Shuiping Zhong, Miao Chen

In the present study, X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray absorption near edge structure (XANES) spectroscopy, and Raman spectroscopy were used to investigate the effect of chloride ions on chalcopyrite bioleaching and chemical leaching at 25 °C. The leaching results show that the addition of chloride ions suppressed the dissolution of chalcopyrite in both chemical and bacterial leaching. In chemical leaching, the solution redox potential in the experiment without Cl− stayed in a range more suitable for chalcopyrite dissolution compared with experiments with Cl− . In bioleaching, the bacteria activity was suppressed by Cl− leading to low dissolution rates of Cu. Surface morphology and chemical speciation studies confirmed the formation of potassium jarosite on the surface of the chalcopyrite leach residues. In addition, S K-edge XANES indicated the formation of trace amount of elemental sulfur and covellite on the mineral surfaces.