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By Wang Jingsong, Ma Tengfei, Feng Fu, She Xuefeng

In this paper the direct reduction melting separation-leaching process is investigated on recovering rare earth from rare earth Bayan Obo complex iron ore (REBOCIO). The REBOCIO was reduced and melting separated to produce iron nugget and rare-earth-rich slag at 1400°C for 12 or 15 min. The RE2O3 is enriched into Ce 4.667(SiO4)O or Ca 3Ce2[(Si,P)3O4]3F, which closely depend on chemical components, especially basic. The optimal acid-leaching parameters of rare earth elements from the rare earth slag are suggested as the hydrochloric acid concentration, the ratio of solid to liquid, leaching temperature, and the leaching time are 1 mol/L, 1:14, 50 °C and 120 min, respectively. The rare earth elements leaching efficiency are more than 95%. Adding of calcium CaCO3 and sodium Na2CO3 in direct reduction process have great in fluence on leaching ef ficiency of thorium.

Mar 1, 2018

By James F. Neill, O&apos

Brown iron ore resources in Barbour, Butler, Crenshaw, and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama. The aggregate footage drilled was 18,010 linear feet. When developed, reserves of 12,664,000 long tons of crude ore were indicated, containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet. Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons. Beneficiation of samples by simulated log washing and use of a 118-inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese. Screen-test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size. While an indicated 2,198,000 dry long tons of usable iron ore can be recovered, sink-and-float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing. However, applicable commercial processes have not been demonstrated.

Jan 1, 1965

By Muammer Kaya

This paper reviews the existing and state of art knowledge for electronic waste (e-waste) recycling. Electrical/electronic equipments (EEEs) which are unwanted, broken or discarded by their original users are known as e-waste. The main purpose of this study is to provide a review of e-waste problem, give e-waste management strategies and introduce various physical e-waste recycling processes with special attention towards extraction of both metallic values and nonmetallic substances. The hazards arise from the presence of heavy metals (e.g. Hg, Cd, Pb etc.), brominated flame retardants (BFRs) and other potentially harmful substances in e-waste. Due to the presence of these substances, e-waste is generally considered as hazardous waste and may pose significant human and environmental health risks if improperly managed. This review paper describes the potential hazards and economic opportunities of e-waste. First of all, an overview of e-waste/printed circuit board (PCB) components and substances are given. Current status and future perspectives of e-waste and waste PCB recycling techniques are described. E-waste characterization, dismantling, liberation, classification and separation processes, are also covered. Manual selective dismantling after desoldering and metal-nonmetal liberation at −150 μm with two step crushing are seen to be the best techniques. After size reduction, mainly physical separation processes employing gravity, electrostatic, magnetic separators etc., which are commonly used in mineral processing, have been critically reviewed here for separation of metals and nonmetals. The recovery of pure metals from e-waste after physical separation can be performed by pyrometallurgical, hydrometallurgical or biohydro metallurgical routes, which are not covered here. Suitable PCB recycling flowsheets for industrial applications are also given. E-waste recycling will be a very important sector in the near future from economic and environmental perspectives for both developing and developed countries. Recycling technology aims to take today’s waste and turn it into conflict-free, sustainable polymetallic secondary resources (i.e. Urban Mining) for tomorrow. Recycling technology must ensure that e-waste is processed in an environmentally friendly manner, with high metal/nonmetal recovery efficiency a lowered carbon footprint. Taking into consideration our depleting natural resources, this Urban Mining approach offers quite a few benefits; it provides a substantial secondary resource, while also ensuring that the environment is kept free from harmful toxins in e-waste. This results in increased energy efficiency and lowers demand for mining of new raw materials.

Mar 1, 2017

By A. C. Johnson

The T. L. shaft of the Eureka Corp., Ltd., near Adams Hill, Eureka, Nev., was sunk in 1954 and 1955 to permit exploration and development of the lead-zinc-silver ore that had been indicated by drilling. This paper describes the sinking of the 4-compartment, vertical shaft to a depth of 1,127 feet and includes pertinent details of equipment, methods, and costs. A shaft crew of 10 men, supplemented by 13 hoistmen, topmen, carpenter, and shop crewmen, sank and timbered the 1,127 feet of shaft in 630 workdays. Total labor per foot of shaft was 107.95 man-hours. Supplies per foot of shaft included 20 pounds of explosives, 1.61 pounds of drill steel, and 200 board-feet of timber. Power consumption, including that required for pumping, averaged 3,726 kw.-hr. per foot.

Jan 1, 1958

By J. D. Miller

"Bastnaesite is one of the important mineral resources for the production of rare earth materials, and it is typically associated with calcite and quartz as gangue minerals. Fatty acid or hydroxamic acid are recommended collectors for bastnaesite flotation. In this research, potassium lauryl phosphate was expected to provide a stronger flotation response for bastnaesite than for the calcite and quartz gangue minerals. Using potassium lauryl phosphate as collector, the results of captive bubble contact angle measurements, zeta potential determinations and microflotation experiments for bastnaesite, calcite and quartz are reported. Greater selectivity for bastnaesite was achieved using potassium lauryl phosphate than using octyl hydroxamate as collector. These results indicate that potassium lauryl phosphate might be a promising collector in the flotation of bastnaesite ores. The computation results of universal force field (UFF) interaction energies for the mineral-reagent interactions are also reported and were found to correlate well with the experimental microflotation results.IntroductionBastnaesite ((Ce,La)FCO3) belongs to the mineral class of semisoluble salt minerals, whose characteristics include ionic bonding and limited solubility in water. Bastnaesite, for the most part, contains the cerium subgroup or the lighter rare earth elements (Zhou et al., 2014). The Mountain Pass deposit in California in the United States and the Bayan Obo deposit in Mongolia in China are the two major deposits of bastnaesite (Azizi et al., 2016; Satur et al., 2016). Calcite and/ or quartz are common gangue minerals in these and many other rare earth deposits (Jordens et al., 2014)"

Jan 1, 2017

By P .. R. Ammann

A two-stage pyrometallurgical process has been developed for the recovery of copper (and other non-ferrous metals) from copper smelter slags. All types of slags, including highly oxidized, converter-type slags, are cleaned in an electric furnace which employs mechanical mixers to promote magnetite reduction and copper extraction at high rates. In a 10-ton pilot furnace, it has been demonstrated that slags can be cleaned to 0.2-0.3 per cent copper with economically acceptable usage of raw materials and energy; copper is recovered as a high-grade matte. Pilot plant data have been scaled up to a commercial furnace and engineering designs have been made for a furnace to treat 60 tons per hour of slag from a Noranda Reactor and the associated converters. Plans are being formulated for the construction of a prototype slag cleaning furnace.

Jan 1, 1976

By M. J. Hrebar

In the summer of 1990, a study was conducted to document large tractor (i.e., Caterpillar Dl1N) utilization in surface coal mining. The tractors were found to be utilized as primary production machines and in combination systems with blast casting and draglines and blast casting and excavator/truck systems. In addition, dozers were used to prebench ahead of a primary dragline system. The study also established ranges and averages for Dl1N operating costs and mechanical availability. Based on simulated production of various tractor dozing applications, the potential for low cost coal stripping was suggested (Hrebar, 1991). A follow-up study, also funded by Caterpillar Inc., was conducted in the summer of 1991 to determine actual production rates in two dozer stripping applications. These actual production rates would then serve as a foundation for estimates of stripping costs. This paper presents the results of the studies in a contour and a cast application.

Jan 1, 1992

By Gordon Kidd

Inflation and burgeoning costs are two among many factors which have generated a new surge of interest in "fringe benefits" (sometimes referred to as "supplementary remuneration" or "supplementary compensation"). Other specialized forms of compensation ("perks", in the vernacular) such as company cars, windowed offices, etc., which also are the subjects of current study, are outside the scope of this paper. For businesses, interest in fringe benefits is based on concern for employees? welfare, compliance with government requirements, and an increasingly burdensome impact on bottom lines. In 1980, according to Fred D. Lindsey in the October 1980 issue of Nation's Business, employee benefits will cost American employers an estimated $420 billion. To paraphrase Winston Churchill, "some fringes!" Indeed, few if any administrators consider employee benefits as fringes. Employee benefits impact other major areas of a company's operations as well. As listed by Beadle (1980), these areas include employee relations, collective bargaining, short-term costs, long-range funding, manpower planning, compliance with legislation, taxation for the company and for the employee, corporate image in the community, competitiveness for staff, communications, administration, claims cost containment, etc., etc.

Jan 1, 1980

By B. K. Cantrell

The U.S. Bureau of Mines and others have conducted a number of occupational exposure surveys since the publication of the International Agency for Research on Cancer report of 1989, which labeled diesel exhaust as a probable human carcinogen. These surveys have assessed diesel exhaust exposure using measurement of diesel aerosol and/or specific polycyclic aromatic hydrocarbons as indicators of exposure. This paper reviews present diesel emission standards, available diesel exhaust aerosol measurement techniques, and the results of the occupational exposure surveys. In the surveys, diesel aerosol was emphasized because it is a major component of diesel exhaust, is suspected to contribute to the health hazard, and is readily measurable. Three primary aerosol measurement techniques were used: respirable combustible dust, size-selective sampling, and measurement of the elemental carbon fraction. Occupations surveyed included mine workers, railroad workers, forklift operators, fire fighters and truck drivers. The studies found mean diesel aerosol concentration levels in the range of 0.004 to 1.74 mg/m3? Highest aerosol exposures were in confined spaces such as mines where heavy diesel equipment is used. Polycyclic aromatic hydrocarbons typically are found at very low concentration levels and are not unique to diesel exhaust.

Jan 1, 1996

By R. Boom, Y. V. Meteleva-Fischer, B. Kraaijveld, H. Kuntzel

"Segregation of impurities during refining of metallurgical grade silicon (MG-Si) is an option to produce solar grade silicon (SG-Si). Directional solidification is a last step in production of SG-Si effective for removal of metallic impurities. The possibility is investigated to use metallic impurities originally present in MG-Si for removing boron and phosphorus. MG-Si has been treated using two methods: 1) alloying with calcium and 2) refining with Na2O-CaO-SiO2 slag, both by controlled cooling. The microstructure of silicon and the impurities distribution have been studied before and after the treatments. Using EPMA phosphorus and boron have been detected in 1-2 wt% concentration range in several intermetallic compounds in grain boundaries after both treatments. This observation points to a different possible mechanism of silicon refining from boron and phosphorus. Controlled cooling improves migration of phosphorus and boron to the silicide phases in grain boundaries, which can be removed by acid leaching treatment.2. IntroductionStandards for silicon solar cells and growing demand on “green” energy require economical and efficient route to the production of solar grade silicon. Refining of cheap metallurgical grade silicon is one of the promising options, where application of existing metallurgical approaches can result in cost-efficient production on industrial scale. Focus in refining is on impurities, which are most difficult to remove: B, P, Al, Ti, due to their large segregation coefficient in silicon and low vapour pressure [1]. Moreover, more environmentally friendly technology in comparison to the traditional Siemens process [2] will be in accordance with societal needs. Based on properties of common impurities in metallurgical grade silicon, alloying refining and slag refining are suggested as competitive techniques having potential effect on removal of impurities harmful for conversion of solar energy [3, 4]. Alloying with Ca followed by acid leaching was found to be effective for removal of Fe and Ti from silicon [5] and to enhance also removal of boron [6] and phosphorus [7, 8]. In the work of Inoue et al. [8] drastically increasing removal of phosphorus from silicon has been observed with an increase of Ca content and a thermodynamics-based explanation was provided. Since phosphorus has been found to condense in the secondary precipitate mainly composed of CaSi2, it can be removed together with iron and titanium by consecutive acid leaching treatment. Slag refining is one of the metallurgical methods proposed to be effective for refining of metallurgical grade silicon from boron [9, 10]. Slags with additions of the following oxides to silica have shown positive effect on removal of boron: CaO [11-13], Na2O [11,14]. Mechanism of slag refining from boron is based on oxidation of boron followed by its incorporation in the slag network [9,11]; the same mechanism is suggested for refining from phosphorus taking into account that oxides of boron and phosphorus are known as network-formers [15]."

Jan 1, 2012

By G. E. McElroy

This report discusses the construction and use of an all-pressure psy- chrometric chart in which the requirements of simplicity of appearance and absolute accuracy have been waived, to a certain extent, to provide for the rapid determination of psychrometric data and for the rapid solution of air- conditioning problems of major interest to the mining industry. Many mines in which air-conditioning problems are important are situated at elevations far above sea level and embrace great differences in elevation - in excess of 8,000 feet in certain mines → throughout their airflow circuits. Under these conditions, the effects of variations in the pressure of the at- mosphere upon the physical properties of the mixture of air and water vapor of which it is composed are considerable and should be taken into account in the solution of problems. The simple types of psychrometric charts in common use, such as the Carrier, Bulkeley, Hill, and Goff (American Society of Heat- ing and Ventilating Engineers Guide), are not generally suitable, in that they are drawn for a single barometric pressure 29,92 inches mercury.

Dec 1, 1947

By A. S. Choudhary

India is endowed with a reasonably large reserve of chrome ore, amounting to about 100 million tons in different grades and is one of the leading producers of ore/concentrate along with South Africa, Kazakhstan and others. Chromite production in India has registered a 10 times increase during the last 30 years. Till late 1940s, the practice was to mine the high-grade ore for making ferrochrome and charge chrome and export the same leaving the low and medium grade ores stacked around the mine as waste material. This practice was continued for quite some time till the increase in world wide de-mand of chromite initiated an increase in production of chromite ore in India and the aspects of ?economy of operation? and ?conservation of mineral? dawned on the producers and associated authorities. Recovery of chrome values from low and medium grade ore was initiated to produce high-grade saleable concentrate. Suitable legislation was made by Government of India to induce and provide incentives to the operators to do so. First large scale chromite beneficiation plant in India was commissioned about three decades back at Byrapore in the Southern state of Karnataka. The ore, rather simple in nature and relatively free from clay, was obtained from underground. The processing consequently was simple washing and wet tabling. Further more, some test work, on the samples from eastern coast particularly from Orissa, was carried out at an internationally reputed laboratory by a large private operator and the plant was set up. This consisted of a combination of crushing-grinding-de-sliming-classification followed by concentration in multi stage spiral concentrators and shaking table. The plant was commissioned and operated successfully. Soon a state owned company followed suit on the basis of test work carried out in a well equipped Indian laboratory. The plant worked satisfactorily after some initial teething trouble and the company plans to double the existing plant capacity by installing balancing facilities. This development prompted a number of operators, including industry leaders to join the fray and the chrome ore processing industry flourished in India. More and more operators are now in the process of adding capacities to their existing plants. This paper attempts to chart the evolution of chrome ore beneficiation industry in India through a case study with reference to an existing plant. The process technology adopted and modified to suit the altered requirements as well as the future trends are outlined.

Jan 1, 2014

By Trevor Saldanha, Nawshad Haque, Will Sikora

This study reported life cycle assessment (LCA) of six copper mines in Australia, Papua New Guinea and Portugal. Inventory data was sourced from published papers, sustainability reports by mining companies, independent technical reports and previous CSIRO studies. Sima Pro software and various databases were used to evaluate life cycle based environmental impacts. The impact indicators were: global warming potential (GWP), acidification potential, water footprint, ecotoxicity potential, ozone depletion potential and human toxicity potential (carcinogenic and non-carcinogenic), abiotic resource depletion potential (minerals and fossil fuels), particulate matter and ionizing radiation. Generally, open pit mines were found to have a GWP of approximately 1.0 t CO2-eq/t Cu concentrate while underground mines had approximately 1.3 to 1.8 t CO2-eq/t Cu concentrate. Environmental impacts varied between mines considerably due to several factors, most notably: ore grade, mining method, flowsheets and ore mineralogy. Energy consumption and sources were significant contributors to most impact categories.

Mar 1, 2018

By Fan Yang, Zhiping Wen, Tiancheng Nie, Jinhe Pan, Ruibo Jia, Changchun Zhou

Rare earth elements have important strategic significance and economic value, and the rare earth elements in coal resources have considerable development potential. This study took coal refuse in the Jungar area of Inner Mongolia, China, as the research object, and investigated the occurrence modes of rare earth elements. A special sequential chemical extraction experiment was designed, and the results showed that the rare earth elements in coal refuse mainly occur in silicate and aluminosilicate form, accounting for approximately 65% of the total rare earth elements. According to the results of SEM-EDS, micro morphology of the sample belonged to the lamellar structure of clay minerals, and Al, Si, Fe, S, Y, and La were all present in the sample. Through SPSS software analysis, rare earth elements have an obvious linear positive correlation with Al, Si, and Fe elements, and a negative correlation with S elements. The rare-earth element occurrence mode in coal refuse can provide a definite theoretical basis for the later extraction and enrichment work.

Feb 18, 2022

By L. R. Gremillion

Chemical and mineralogical data on 25 apatitic phosphate ores of diverse origins from commercial deposits around the world were widely variable. From 14 to 18 chemical constituents of each sample were determined, and each sample contained 4 to 10 mineral phases. Altogether there were 34 different mineral phases, many of which occurred in only one sample. The samples contained varieties of francolites, fluorapatites, and mixed hydroxyl-fluorapatites. The apatite compositions calculated from the chemical data showed that certain types of substitutions were characteristic of different apatite varieties, but every variety had some degree of substitution of (CO3)2 for (PO4)3 and the P2O5 contents of the apatites ranged from 35.1% for a North Carolina apatite to 41.9% for a Missouri apatite. In a concentrate with a grade of 32% P2O5, the North Carolina sample should contain about 8.7% gangue and the Missouri sample about 23.7% gangue. To optimize the digestion process of a phosphate are, it is necessary to consider the dissolution behavior of the different mineral phases during acidulation and the effects they may have on the chemical properties of a fertilizer intermediate. In the production of wet-process acids or superphosphates, the acidulation of certain minerals may cause foaming and formation of sludge, filtration, corrosion, and handling problems.

Jan 1, 1978

By J. A. González-Anaya, F. Nava-Alonso, O. Alonso-González, F. Alvarado-Hernandez, A. Uribe-Salas, C. Jimenez-Velasco

"One of the most common hydrometallurgical methods for precious metal extraction is cyanidation. The effluents of this process may contain relatively high concentrations of copper, zinc and iron, which react with free cyanide to form complexes, adversely affecting the efficiency and the economy of the process.This preliminary work studies the use of the solvent extraction technique to remove copper, zinc and iron cyanide complexes from a synthetic solution similar to that of gold mill effluents, in order to allow the recycling of the solution back to the process. For the extraction of these anions (Cu(CN)2 -, Cu(CN)3 2-, Cu(CN)4 3-, Zn(CN)4 2- and Fe(CN)6 3-), trioctyl methyl ammonium chloride (Aliquat 336) was studied as extractant, using nonylphenol as modifier in the organic phase (iso-octane). The experimental results showed that for a synthetic solution containing 450 mg/L total cyanide, 160 mg/L copper, 50 mg/L zinc and 51 mg/L iron, it is possible to extract the 96% of copper, 91% of zinc and 75% of iron when using 0.011 mol/L of Aliquat 336 (organic/aqueous volume ratio (O/A) =1) in the pH range of 9-10."

Jan 1, 2014

By J Taylor, M Smith, A Tunnadine, D Nikolakopoulos

As Olympic Dam rapidly expands into the Southern Mine Area (SMA) the Mine Geology team has concurrently ramped up underground diamond drilling to sustain rates of above 175 km/a. With >10 underground rigs double-shifting, traditional paper sections used for the management of drill programs were no longer optimal due to scale of operations. An opportunity was identified to modernise monitoring of all underground diamond drill programs, through the integration of logged copper sulfide estimates with Olympic Dam’s first-fully integrated deposit-scale geological model in Leapfrog Geo. This paper describes the transition within the Mine Geology team from reliance on 2D paper sections, towards near-real time 3D geological modelling for optimising end-of-hole decisions in the field. This transition was enabled by innovative database solutions informing locally constrained implicit models, limited by a distance buffer around active underground fan drilling. Due to the high volume of historic drilling, there were significant computational challenges with the implementation of daily production style implicit models at Olympic Dam and initial testing of regular updates to implicit gradeshells and sulfide domains required in excess of 12 hrs to run. The enabling solution was to optimise the interfaces between the AcQuire database, Deswik MDM and Leapfrog Geo to create a dynamic, streamlined workflow that was easily completed by Mine Geologists in accordance with daily production duties. Geologists are now building rapid implicit models for a range of variables from an integrated data set of logged sulfide estimates and existing assays, spatially constrained by 150 m buffers around active drilling using a unique drill fan identifier flagged during the planning phase. Once the live-implicit models are updated, they are exported for visualisation on field tablets to be used during logging and core checks at the start and end of every shift. To manage the risk of ‘going digital’ interpretation remains at the forefront of the drill section close-out process, with Mine Geologists critically reviewing the finished sections on a standardised template with new learnings wireframed and communicated to stakeholders. The Live Field Model has enabled a step-change in the geological effectiveness of diamond drilling, reducing over – and under-drilling ore-waste at Olympic Dam continuing to push drilling effectiveness towards 20 per cent of intercepts >2 per cent Cu. In addition, upside or risk identified during the proactive management of drilling execution can be rapidly capitalised or mitigated.

Mar 22, 2022

By S. Banisi, A. Haji-Zadeh, H. Asadi, M. Maleki-Moghaddam

One area in AG/SAG milling field which has received a great attention is the optimization of liner design for any application to increase the availability of mills. The Gol-E-Gohar iron ore concentration plant uses three 9m × 2.05m autogenous mills (AG) in parallel in a dry operation. The AG mill shell is lined with three series (57 cm each) of 36-row liners. Due to large variations in feed characteristics and inadequate blending, the performance of AG mills has been lower than the target value. Therefore, to improve the comminution efficiency, the optimization of the design of AG mill shell liners was applied in this plant. By simulation it was found that increasing the liner lifter face angle from 7 to 30° while maintaining the original lifter height (i.e., 22.5 cm) could provide an appropriate charge trajectory. Measurement of the wear profiles of shell liners indicated that the wear along the liner length was not uniform and the highest wear occurred between 0.5 m and 1.2 m of the mill length. A new liner design was proposed by redistributing the metal from parts with a lower wear rate to the parts with a higher wear rate to arrive at a uniform wear profile along the liner length at the liner removal time. The non-uniform shell liner was constructed and installed in one of the three parallel dry AG mills. It was found that the first and second liner designs increased the mill throughput by 2.6 and 7.5%, respectively. After conversion to SAG milling on the account of liner change, 18% (from 413 to 489 t/h) increase in throughput was realized. It was predicted that the non-uniform liner designs will increase the liner life time by 10% and will reduce the scrap metal from the current value of 59% to 50%.

Jan 1, 2014

By Clayton R. Morlock

Airblasts have been monitored at four coal strip mines and at a limestone quarry. Thirty-seven production blasts have been monitored with three seismographs, resulting in one hundred and eleven complete air pressure records. Instrumentation selection use is described. Data analysis includes an assessment of the predictability of peak overpressures by means of the cube root scaled distance law. It is found that predictability for the cases studied here is not good. An extensive discussion of possible explanations is included. A detailed analysis of the frequency content of the observed airblasts, of considerable importance in evaluating potential annoyance problems, has been made for all records. A computer program has been written to simulate airblasts induced by multiple-hole blasts. A series of small experimental blasts have been detonated and monitored in order to allow an assessment of the program. It is clear that airblasts, especially when induced by very small charges and monitored at very close distances, are highly sensitive to detonation times. Retrofitting of airblast records occasionally was possible, but considerably improved field work is required to validate or refute the computer model.

Jan 1, 1983

By S. D. Cramer

Corrosion research is being conducted by the Federal Bureau of Mines to determine suitable construction materials for geothermal resource recovery plants. As part of this research, the corrosion resistance of 31 iron-nickel-, aluminum-, copper-, titanium-, and molybdenum-base alloys was characterized and evaluated in laboratory corrosion studies in low-and high-salinity geobrines representative of those found in the Imperial Valley, Calif. General, crevice, pitting, weld, and stress corrosion were measured at 105° and 232° C in deaerated brines and brines containing dissolved 02, C02, and CH4 General corrosion rates in deaerated brines at 105° and 232° C were usually below 5 mpy for the alloys tested except carbon steel, the low-alloy steels, Monel 400, 70-30 cupronickel, and the aluminum-base alloys. Dissolving carbon dioxide and methane in the brines at 2320 did not markedly alter these results. However, the introduction of oxygen, which can enter the brine during process operations, seriously degraded the corrosion resistance of many alloys by increasing the incidence of stress corrosion cracking, crevice corrosion and, except for the titanium-base alloys, pitting. In deaerated brine at 2320 C, the general corrosion rates for carbon steel and the low-alloy steels were relatively unaffected by pH in the range of 6.1 to 3.0. However, general corrosion rates increased sharply below pH 3.0. In deaerated brine at 232° C, welds in several iron-, nickel-, and titanium-base alloys corroded at rates comparable to the general corrosion rates of the alloys, but the addition of oxygen to the brine increased corrosion rates for welds in Inconel 625 and E-Brite 26-1. Alloys exhibiting good corrosion resistance in the deaerated Salton Sea KGRA-type brine at 232° C were E-Brite 26-1, Inconel 625, Hastelloy S, Hastelloy G, Hastelloy C-276, TiCode-12, Ti-0.2Pd, Ti-2Ni, Ti-1.7W, and TZM. The alloys most resistant to corrosion in oxygenated Salton Sea KGRA-type brine at 232° C were the titanium-base alloys. These alloys appear the most suitable for use in the construction of geothermal resource recovery plants. Carbon steel and the low-alloy steels are unsatisfactory for high-temperature, high-salinity brines and alternative low-cost materials with improved corrosion resistance should be sought.

Jan 1, 1980